Shift Of Emission Research Articles

A Preliminary Assessment of Global CO2: Spatial Patterns, Temporal Trends, and Policy Implications.

This study offers a comprehensive analysis of the distribution, evolution, and driving factors of CO2 emissions from 1990 to 2016 at multiple spatial scales. Utilizing 26 indicators encompassing various facets of CO2 emissions, it is employed principal component analysis (PCA) and empirical orthogonal functions (EOFs) to identify the dominant characteristics of global CO2 emissions. This model retained three core components, accounting for 93% of the global CO2 variation, reflecting emission trajectories and associated economic metrics, such as Gross domestic product (GDP). The analysis differentiated the effects of these components based on countries' economic standings. Using a novel aggregated index, significant national contributors to global CO2 emissions are pinpointed. Notably, the leading contributors are found among developed nations (e.g., the United States, Canada, Japan), Gulf states (e.g., Saudi Arabia, Qatar), and emerging economies (e.g., China, Brazil, Mexico). Furthermore, these results highlight that shifts in global CO2 emissions over the past 30 years are predominantly influenced by factors like industrial emissions and GDP. Results also demonstrate a distinct relationship between a country's CO2 emissions and its physical and socioeconomic factors. Specifically, the nation's coastline length, population density in coastal regions, and the diversity of its climatic conditions significantly influence its carbon footprint.

Structural diversity and photoluminescence enhancement of indium-based hybrid metal halides

Low-dimensional organic-inorganic metal halides have attracted increasing attention for their diverse structure and excellent photoelectric properties. Here, we report two zero-dimensional indium-based halides, (C3H12N2)3In2Cl12·2 H2O ([C3H12N2]2+ is N-methylethylenediamine cation) with space group of P-1 and (C3H12N2)2InCl7 with space group of P21/c. Upon UV excitation, 1 %Sb doped (C3H12N2)3In2Cl12·2 H2O exhibits luminescence centering at 588 nm with a full width at half-maximum of 149 nm (0.527 eV), as well as a large Stokes shift of 262 nm (1.69 eV) with photoluminescence quantum yields as high as 56 %. The broad emission originates from the electron transitions of the Sb3+ 5s2 lone pair. 1 %Sb doped (C3H12N2)3In2Cl12·2 H2O exhibits more intense, broader emission and larger Stokes shift than that of 1 %Sb doped (C3H12N2)2InCl7 which is due to that the crystalline water increases the hydrogen bonding and leading to more distorted [SbCl6]3- octahedra. This work unveiled the relationship between structure and photoluminescence properties, and provide new types of organic-inorganic metal halides for potential application in light-emitting diodes.

Development of a Ratiometric Fluorescent Cu(II) Indicator Based on Poly(N-isopropylacrylamide) Thermal Phase Transition and an Aminopyridyl Cu(II) Ligand.

An aqueous Cu2+ and Zn2+ indicator is reported based on copolymerizing aminopyridine ligands and the environment-sensitive dansyl fluorophore into the responsive polymer poly(N-isopropylacrylamide) (PNIPAm). The metal ion binding creates charge and solvation that triggers PNIPAm's thermal phase transition from hydrophobic globule to hydrophilic open coil. As a basis for sensing the metal-binding, the dansyl fluorescence emission spectra provide a signal at ca. 530 nm and a signal at 500 nm for the hydrophobic and hydrophilic environment, respectively, that are ratiometrically interpreted. The synthesis of the title pyridylethyl-pyridylmethyl-amine ligand (acronym PEPMA) with a 3-carbon linker to the copolymerizable group, aminopropylacrylamide (PEPMA-C3-acrylamide), is reported, along with a nonpolymerizable model ligand derivative. The response of the polymer is validated by increasing temperature from 25 °C to 49 °C, which causes a shift in maximum emission wavelength from 536 nm to 505 nm, along with an increase in the ratio of emission intensity of 505 nm/536 nm from 0.77 to 1.22 (λex = 330 nm) as the polymer releases water. The addition of divalent Cu or Zn to the indicator resulted in a dansyl emission shift of 10 nm to a longer wavelength, accompanied by fluorescence quenching in the case of Cu2+. The addition of EDTA to the Cu2+-loaded indicator reversed the fluorescence shift at 25 °C to 35 °C. The affinities of Cu2+ and Zn2+ for the PEPMA derivatives are log Kf = 11.85 and log Kf = 5.67, respectively, as determined by potentiometric titration. The single-crystal X-ray structure of the Cu2+-PEPMA derivative is five-coordinate, of-geometry intermediate between square-pyramidal and trigonal-bipyramidal, and is comparable to that of Cu2+ complexes with similar formation constants.

Rational design synthesis and evaluation of a novel near-infrared fluorescent probe for selective imaging of amyloid-β aggregates in Alzheimer's disease

Alzheimer's disease (AD) is a degenerative neurological disorder that remains incurable to date, seriously affecting the quality of life and health of those affected. One of the key neuropathological hallmarks of AD is the formation of amyloid-β (Aβ) plaques. Near-infrared (NIR) probes that possess a large Stokes shift show great potential for imaging of Aβ plaques in vivo and in vitro. Herein, we proposed a rational strategy for design and synthesis of a series of NIR fluorescent probes that incorporate a tricarbonitrile group as a strong electron-withdrawing group (EWG) to enable NIR emission and large Stokes shift for optimal imaging of Aβ plaques. The probe TCM-UM exhibited remarkable in vitro performance, including strong NIR emission (λem = 670 nm), large Stokes shift (120–245 nm), and its affinity for Aβ42 aggregates (Kd = 43.78 ± 4.09 nM) was superior to the commercially available probe Thioflavin T (ThT, Kd = 896.04 ± 33.43 nM). Further, TCM-UM was selected for imaging Aβ plaques in brain tissue slices and APP/PS1 transgenic (AD) mice, the results indicated that TCM-UM had an excellent ability to penetrate the blood-brain barrier (BBB) compared with ThT, and it could effectively distinguish wild-type (Wt) mice and APP/PS1 transgenic (AD) mice.

Spectral shift in terahertz emission by ultrafast laser-induced demagnetization

We demonstrate a spectral shift in the peak frequency of terahertz (THz) emission by ultrafast laser-induced demagnetization in the Fe20Ni80 (Py) film. Experimentally, red spectral shifts of the THz emission are achieved by increasing the laser fluence or decreasing the Curie temperature of the Py film. Based on the microscopic three-temperature model, it is found that such redshifts are attributed by the slowing down of laser induced demagnetization processes in the Py film. The results not only enrich our understanding of THz emission introduced by ultrafast laser-induced demagnetization but also provide a practical way to detect the timescale of laser-induced ultrafast demagnetization dynamics.

Photoanodic properties of In/β-Ga2O3 nanostructures fabricated under hydrogen reducing ambient by the vapour-phase growth method

A great deal of efforts have been dedicated to reduce carrier recombination problem in β-Ga2O3 using strategies, such as doping, compositing, and interfacing with different materials to enhance device performance. However, reports are rarely available for integrating In with β-Ga2O3 for photoelectrochemical applications. Herein, we reports the effect of In addition in β-Ga2O3 to produce In/ β-Ga2O3 nanocomposite for photoelectrocatalysis. The intrinsic sample exhited mixed-phase (α-β)-Ga2O3, whereas the composite showed a mixed-phase β-Ga2O3-indium. A significant amount of In was detected on the heterogenous film, suggesting that doping was exceeded. A significant bandgap narrowing was observed from 4.79 to 4.45 eV upon In incorporation. The presence of In in β-Ga2O3 resulted in a shift in photoluminescence emission from violet to green light. Photoelectrochemical measurements in 0.1 M KOH solution demonstrated a relatively high photocurrent density of 1.720 mA/cm2 at 1.0 V vs. Ag/AgCl for the In/ β-Ga2O3 heterogeneous film.

Predicting the performance and emissions of an HCCI-DI engine powered by waste cooking oil biodiesel with Al2O3 and FeCl3 nano additives and gasoline injection – A random forest machine learning approach

This study presents a novel method for predicting the performance and emissions of a Homogeneous Charge Compression Ignition-Direct Injection (HCCI-DI) engine fuelled by waste cooking oil biodiesel (WCOB) blended with Aluminum oxide (Al2O3) and Ferric chloride (FeCl3) nano additives and premixed with gasoline. The test fuels considered were pure diesel, WCOB, B50 (a 50–50 blend of diesel and WCOB), and the nano-additives at concentrations of 50 ppm and 100 ppm. All experiments were performed on a 4.4 kW HCCI-DI engine operating at 1500 rpm. The results revealed that, utilization of WCOB showed a substantial reduction in emissions. Hydrocarbon (HC), carbon monoxide (CO) and smoke emissions decreased by 54.17 %, 50 %, and 22.69 %. Nevertheless, oxides of nitrogen (NOx) emissions increased by 18.32 %. When introducing gasoline (20 %) as a premix in HCCI-DI engines, a favourable shift in emission and efficiency metrics was observed. The brake thermal efficiency (BTE) increased 4.23 %. Moreover, NOx and smoke emissions decreased by 4.3 % and 39.21 %. Furthermore, compared to conventional diesel-fueled combustion, the integration of the nano additives manifested promising results. After introducing Al2O3 into neat fuel, The BTE improved by 11.27 % for direct injection (DI) combustion and 18.31 % for HCCI-DI combustion. Additionally, there was a marked decrease in exhaust emissions. FeCl3 nano additive into the test fuel significantly reduced HC, CO, and smoke emissions. Furthermore, the random forest machine learning approach demonstrated an extensive accuracy in forecasting both engine performance and emissions for the HCCI-DI engine. The innovative combination of cutting-edge machine learning techniques and combustion technology used. This model to understand the complicated correlations between input parameters and engine outputs and account for the system's intrinsic non-linearities and interactions. This dramatically improves standard prediction approaches, often assuming linear correlations or disregarding variable interdependencies.

Modulating the fluorescence properties of carbon dots by varying the stoichiometric ratios of citric acid and urea during the synthesis

Varying the ratios of citric acid and urea during the synthesis of carbon dots (CDs) provides a strategy to modulate their fluorescence properties. The impact of different precursor ratios on the resulting CDs' size, surface chemistry, and structure was investigated using X-ray diffraction (XRD) analysis and confirmed through transmission electron microscopy (TEM). Fourier transform infrared spectroscopy (FTIR) was employed to study the influence of precursor ratios on the types and densities of surface functional groups. The optical properties of the CDs were examined using a UV–visible absorption spectrometer, photoluminescence excitation (PLE) spectra, and photoluminescence spectroscopy (PL). Smaller CDs generally exhibit higher energy emissions, resulting in bluer light, while larger CDs tend to emit lower energy light, appearing redder. By adjusting the precursor ratios, it is possible to induce shifts in fluorescence emission, leading to CDs with different fluorescence colours. Furthermore, the antimicrobial activity of CDs against bacterial pathogens was assessed, and their potential for promoting plant growth was explored by coating seeds with concentrated and diluted CDs solutions.

A near-infrared fluorescent off-on probe with large Stokes shift for sensing hydrazine in vitro and in vivo

The development of effective approaches for detecting toxic hydrazine (N2H4) is of great importance for public health. In this work, a near-infrared (NIR) fluorescent probe (QLN-Hy) for trace hydrazine detection with a large Stokes shift was constructed. Hydrazine-activatable QLN-Hy displayed striking characteristics of high sensitivity (detection limit: 0.25 μM), high selectivity, as well as notable fluorescence enhancement at the NIR emission (692 nm) and large Stokes shift (104 nm). In particular, the color of QLN-Hy changed from purple to light blue, enabling the direct visualization of hydrazine in vapor and aqueous phases through the naked eye readily. Meanwhile, the practical feasibility of QLN-Hy was successfully evaluated by quantitatively detecting trace hydrazine in water samples (lake water, river water, rain water, tap water, drinking water) and mice samples (urine, serum). Importantly, probe QLN-Hy can be conveniently applied to monitor and visualizing hydrazine in cells and in vivo, clearly demonstrating its invaluable potential biological applications.

Development of a Ratiometric Fluorescent Probe with Zero Cross-Talk for the Detection of SO2 Derivatives in Foods and Live Cells.

Sulfur dioxide (SO2) derivatives are extensively utilized as both a preservative for foods and an active gaseous signal molecule in various physiological and pathological processes, but their excessive intake would bring harmful effects on human health; so, the determination of SO2 derivatives is of great importance. Herein, we developed a ratiometric fluorescent probe named 2-(2'-hydroxyphenyl)benzothiazole-3-ethyl-1,1,2-trimethyl-1H-benzo[e]indolium (HBT-EMBI) by introducing a hemicyanine unit of EMBI to an HBT group for the detection of SO2 derivatives via an excited-state intramolecular proton transfer (ESIPT) and intramolecular charge transfer (ICT) effects. The probe displays some advantages, such as a colorimetric change from purple to colorless, a ratiometric fluorescence with zero cross-talk, and a remarkably large emission shift (Δλ = 164 nm) under a single-wavelength excitation. Accordingly, the probe HBT-EMBI has been successfully employed for the colorimetric and ratiometric determination of SO2 derivatives in real food samples and the quantitative visualization of SO2 derivative variations in HepG2 cells.

A large Stokes shift and emission shift ratiometric mitochondria-targeted fluorescent probe for sensing HClO with an ESIPT-ICT integrated platform

Hypochlorous acid (HClO) is regarded as a significant oxidative stress marker and plays key factor in various pathological and physiological processes. However, the overexpression of HClO is relation to variety of diseases due to cellular damage and oxidative stress. Studies have described that the HClO level in mitochondria is crucial to maintain the normal function of mitochondrial. Herein, we presented a simple mitochondria-targeted fluorescent probe (BA-MR), which consists of the benzothiazole dye as the fluorescent signaling unit, the methyl thioether as the HClO recognition group, and the imine pyridinium salt moiety as the mitochondria targeting group. The free probe BA-MR possessed a super large Stokes shift (260 nm) and displayed a red fluorescent at 600 nm. Upon addition of HClO, the methyl thioether of BA-MR was oxidezed exclusively into a sulfoxide group, thereby leading to the generation of compound BAO-MR with a prominent blueshift of emission at 450 nm. As expected,the probe displayed highly sensitive and selective fluorescence response to HClO with fast response (120 s) and a low detection limit (86 nM). Importantly, the newly-synthesized probe was displayed to have low cytotoxicity, and could be successfully used to imaging HClO in mitochondria, which demonstrated the probe BA-MR can act as an effective tool for researching HClO-related physiological and pathological processes.

Ratiometric lysosome-targeting luminescent probe based on a coumarin-ruthenium(II) complex for formaldehyde detection and imaging in living cells and mouse brain tissues.

Ratiometric luminescence probes have attracted widespread attention because of their self-calibration capability. However, some defects, such as small emission shift, severe spectral overlap and poor water solubility, limit their application in the field of biological imaging. In this study, a unique luminescence probe, Ru-COU, has been developed by combining tris(bipyridine)ruthenium(II) complex with coumarin derivative through a formaldehyde-responsive linker. The probe exhibited a large emission shift (Δλ>100nm) and good water solubility, achieving ratiometric emission responses at 505nm and 610nm toward formaldehyde under acidic conditions. Besides, ratiometric luminescence imaging of formaldehyde in living cells and Alzheimer disease mouse's brain slices demonstrates the potential value of Ru-COU for the diagnosis and treatment of formaldehyde related diseases.

New electron-deficient 2,1,3-benzothiadiazole-cored donor–acceptor compounds: Synthesis, photophysical and electroluminescent properties

Three new 2,1,3-benzothiadiazole-containing luminophores with different electron deficiency of acceptor block have been prepared via the Pd-catalyzed Suzuki cross-coupling and nucleophilic fluorine substitution with cyano group. Photophysical and electroluminescent properties of the compounds obtained were investigated to estimate their potential for optoelectronic applications. The introduction of two fluorine atoms in the benzothiadiazole moiety leads to the hypsochromic shift of the electroluminescent emission, whereas the incorporation of two cyano groups shifts it into the long-wave region. All synthesized compounds were used as emissive layers in OLED devises.

Triarylborane-"Click" Fluorescent Tag for Orthogonal Amino Acid Labelling, Interactions with DNA, Protein, and Cyclodextrins.

The innovative design of a triarylborane (TB)-dye with one NMe2-alkylated (propargylated) group and one NMe2 group yielded a system that is both an NMe2 π-donor and an inductive NMe2-alkyl cationic acceptor. Consequently, the new TB-dye was highly sensitive to a "click" reaction with an azide-substituted lysine side chain (yielding TB-lysine), resulting in a bathochromic shift of emission of 100 nm. In addition, fluorene attached to the lysine C-terminus showed FRET with the TB-chromophore, also sensitive to interactions with targets. Both the TB-dye and TB-lysine showed high affinities towards both DNA and proteins, reporting binding by an opposite fluorimetric response for DNA/RNA (quenching) vs. BSA (increase). Thus, the novel TB-dye is an ideal fluorimetric probe for orthogonal incorporation into bio-targets by "click" reactions due to fluorescence reporting of the progress of the "click" reaction and further sensing of the binding site composition. The TB-dye is moderately toxic to human cell lines after 2-3 days of exposure, but efficiently enters cells in 90 min, being non-toxic at short exposure. The most important product of the "click" reaction, TB-lysine, was non-toxic to cells and showed equal distribution between mitochondria and lysosomes. Further studies would focus particularly on the very convenient monitoring of the progress of "click" conjugation of the TB-dye with biorelevant targets inside living cells by confocal microscopy.

Rational Design of Near-Infrared Fluorescent Probes for Accurately Tracking Lysosomal Viscosity with Allyl Snchoring Si-Rhodamine.

The abnormal microenvironment parameter, viscosity, is closely connected with various diffusion processes, signal transduction, molecule interactions, and various diseases. It is greatly significant to design viscosity-dependent near-infrared (NIR) small molecule fluorescence probes for visualizing biological processes or diagnosing diseases. Herein, through the stepwise modulating structure of the silicon-rhodamine fluorophore (SR), we report three viscosity probes with allyl or methyl group as rotors, named SR-T-Al, SR-S-Al, and SR-T-Me. Among them, SR-T-Al demonstrates better viscosity responsibility from 1.0 to 1410.4 cP of viscosity. Therefore, the probe of SR-T-Al is successfully applied to sensitively monitor lysosome microscopic viscosity changes of living cells induced by oxygen stress. What's more, based on its advantages in NIR emission (669 nm) and large Stokes shift (201 nm), we also use it to image variations of viscosity in an acute hepatitis mouse induced by carbon tetrachloride. Both time and concentration-dependent induction models display the great ability of SR-T-Al to detect viscosity alteration. All the experimental results indicated that this allyl-rotor-based NIR viscosity probe could provide a general platform to monitor abnormal physiological processes and diseases relating to viscosity.

A smart probe for multi-analyte signaling: Cascade detection of HSA mediated by N2H4

Human serum albumin (HSA) and hydrazine (N2H4) are known biomarkers and damage agents of liver function activity, respectively. However, the mechanism of association between HSA and N2H4 in the liver remains unexplored. Herein, we report a naphthalimide-based smart fluorescent probe NI-2 for the N2H4 mediated cascade detection of HSA (N2H4 ∩HSA). Results showed that the levulinate recognition group on NI-2 is ammonolyzed within seconds in response to N2H4, releasing the compound NI-OH, triggering a hypsochromic shift of the emission to 400 nm; while with the coexistence of HSA, the entry of NI-OH into the hydrophobic cavity of HSA, resulting a bathochromic emission shift to 670 nm. We have further revealed the reaction mechanism of NI-2 cascade reacting with N2H4 ∩HSA through HRMS, replacement experiment and molecular docking method. NI-2 has been successfully applied in detecting N2H4 ∩HSA in human urine quantitatively and N2H4 in water samples or plants. A qualitative test paper strip model for quick response of N2H4 and N2H4 ∩HSA has also been established. Moreover, NI-2 can be applied in bioimaging of HepG2 cells and zebrafish, indicating that NI-2 can be a potential tool for the study of liver damage.

Regional Differences, Dynamic Evolution and Convergence of Carbon Emissions from Rural Residents’ Living Consumption: Evidence from China

Actively exploring a reduction in carbon emissions from rural residents’ living consumption (RRLC) is necessary to address climate change and achieve high-quality development of the rural economy. Based on the measurement of the carbon emissions from RRLC in China between the years 2000 and 2021, and it uncovers regional differences, dynamic evolution and convergence. The main findings are as follows: (1) Using the Dagum Gini coefficient, it was found that the differences in carbon emissions from RRLC in the nationwide and low-income level group (LLLG), low-middle-income level group (LMLG), upper-middle-income level group (UMLG), and high-income level group (HHLG) are all significantly decreasing, and the intensity of transvariation is the primary source of the overall difference. (2) Using the kernel density estimation, it was found that the level of carbon emissions from RRLC in the nationwide and the four major regions have generally gone upward, as well as a polarisation phenomenon. (3) Using the Markov chain, it was shown that there is an instability in the carbon emissions from RRLC, which can be transferred downward to the ideal state, but there is also a risk of increasing the upward shift of carbon emissions. (4) The nationwide level and the four regions showed typical σ convergence characteristics and absolute β convergence. After considering the influence of socio-economic and natural climatic factors, conditions β convergence trend is shown. And there are significant regional differences in spatial β convergence. The limitation of this study is that the data on carbon emissions from RRLC are only obtained at the macro level, which cannot accurately reflect the micro and individual impact on RRLC. On this basis, the paper puts forward policy recommendations to reduce the spatial imbalance of carbon emissions from RRLC.

Tracking Carbon Flows from Coal Mines to Electricity Users in China Using an Ensemble Model.

Accurately tracking carbon flows is crucial for preventing carbon leakage and allocating responsibility for reducing CO2eq emissions. In this study, we developed an ensemble model to effectively track carbon flows within China's power system. Our approach integrates coal quality tests, individual power plant datasets, a dynamic material-energy flow analysis model, and an extended version of an interconnected power grid model that incorporates transmission and distribution (T&D) losses. Our results not only provide accurate quantification of unit-based CO2eq emissions based on coal quality data but also enable the assessment of emissions attributed to T&D losses and emission shifts resulting from interprovincial coal and electricity trade. Remarkably, for CO2eq emissions from coal-fired units, the disparity between the guideline and our study can be as high as [-95%, 287%]. We identify Guangdong, Hebei, Jiangsu, and Zhejiang provinces as the major importers of both coal and electricity, responsible for transferring nearly half of their user-based emissions to coal and power bases. Significantly, T&D losses, often overlooked, contribute to 15-20% of provincial emissions at the user side. Our findings emphasize the necessity of up-to-date life cycle emissions and spatial carbon shifts in effectively allocating emission reduction responsibilities from the national level to provinces.

3D dynamic tracking Aβ plaques in live brains using vinyl-bridged dyes with two-photon excitation/NIR emission and large Stokes shifts

Real-time studies of biomarkers for neurological disorders present significant opportunities for diagnosing and treating related diseases, and fluorescent probes offer a promising approach to brain imaging. However, intracerebral fluorescence imaging is often limited by blood-brain barrier permeability and penetration depth. Moreover, only very few probes have rapid intracerebral metabolic properties, which are critical for in vivo imaging. Here, we developed a novel class of fluorescent dyes with two-photon excitation and near-infrared (NIR) emission (920/705 nm). The representative WAPP-4 probe exhibits a large Stokes shift (Δλ = 324 nm in ethanol) and excellent blood-brain barrier permeability. Notably, using WAPP-4, we achieved in vivo 3D dynamic imaging of Aβ plaques in the brains of living mice with Alzheimer's disease (AD). In addition, super-resolution imaging showed that WAPP-4 could effectively characterize the distribution and shape of Aβ plaques in isolated brain slices. This study demonstrates that newly developed fluorescent dyes with large Stokes shifts and blood-brain barrier permeability enable real-time imaging of amyloid plaques, which will contribute to the development of other valuable tools for near-infrared imaging and super-resolution imaging in the brain.

A Luminescence Assay in the Red for the Detection of Hydrogen Peroxide and Glucose Based on Metal Coordination Polyelectrolyte-Induced Supramolecular Self-Assembly of Alkynylplatinum(II) Complexes.

A new sensing strategy towards hydrogen peroxide based on metal coordination polyelectrolyte-driven self-assembly of alkynylplatinum(II) 2,6-bis(benzimidazol-2'-yl)pyridine (bzimpy) complex was demonstrated. The cationic in situ-generated Ag(I)-thiocholine coordination polyelectrolytes were shown to induce the supramolecular self-assembly of anionic low-energy red-emissive alkynylplatinum(II) bzimpy complexes via non-covalent Pt(II)⋅⋅⋅Pt(II), electrostatic and π-π stacking interactions. The presence of hydrogen peroxide was shown to inhibit the formation of coordination polyelectrolytes and the coordination polyelectrolyte-induced self-assembly of platinum(II) complexes. The weakening of Pt(II)⋅⋅⋅Pt(II), electrostatic and π-π stacking interactions was supported by UV-vis absorption, emission, and resonance light scattering (RLS) studies. The present assay was also applied to probe glucose indirectly based on the enzymatic reaction of glucose oxidase on the substrate. Operating in a label-free manner, together with the low-energy red emission and large Stokes shift of alkynylplatinum(II) complexes, these features render the proposed design attractive for biological applications.