Plasma Emission Research Articles

Identification of nonlinear effects of background asymmetry on solitary oscillations in a cylindrical plasma

A symmetry-breaking in rotational spatial pattern of quasi-periodic solitary oscillations is revealed with tomography measurement of plasma emission, simultaneously with background asymmetry in stationary plasma structure. Although the oscillatory pattern deformation is a natural course in the presence of asymmetry, elaborate analyses identify existence unfeatured nonlinear effects of the background asymmetry, i.e., its nonlinear couplings with harmonic modes of rotational symmetry, to produce non-harmonic mode to break the symmetry and cause the oscillatory pattern to be chaotic. The findings suggest the unrecognized fundamental process for plasmas to be turbulent.

Study on the effect of oil shale ash on potassium retention characteristics during pyrolysis of corn stalk

In a multi-station fast pyrolysis reactor, the influence of oil shale ash on the potassium retention characteristics of corn stalk under different pyrolysis conditions was investigated in the study. The influence of oil shale ash on the potassium migration process during the pyrolysis of corn stalk was elucidated by analyzing changes in the composition and concentration of potassium and other minerals in the pyrolysis semi-coke of corn stalk. This analysis was conducted using inductively coupled plasma emission spectroscopy (ICP-AES), X-ray diffraction (XRD), and complemented by thermodynamic simulation. The findings demonstrate that oil shale ash could fix potassium in corn stalk, and the potassium retention rate peaked when the oil shale ash additive amount reached to 10 %. This is because the silica-aluminum compounds in the oil shale ash reacts with potassium salts in a semi-molten state to produce KAl2Si3AlO10(OH)2, KAlSi3O8, and KAlSi2O6.When the amount of oil shale ash added is increased to 15 %, KAlSi3O8 and KAlSi2O6 in the semi-coke would continue to react with Al2O3 and SiO2, converting to KAl2Si3AlO10(OH)2. Thermodynamic simulation results indicate that the alkali metal potassium in corn stalk semi-coke mainly existed in potassium metasilicate, potassium feldspar, and leucogranite. In order to enhance potassium fixation in corn stalk, the addition of oil shale ash would promote the transformation of potassium-solidifying minerals from potassium metasilicate to potassium feldspar and leucite in the semi-coke.

Origin and Geochemical Characterization of Groundwater from Coal Seam: A Case Study of Balasu Coalfield, Ordos Basin.

The hydrochemical characteristics of groundwater are of great significance for studying the source, development, and utilization of groundwater. This study investigated the characteristics of anions and cations, total dissolved solids (TDS), hydrochemical types, and hydrogen and oxygen isotopes of surface water and groundwater in the Balasu coalfield. By conducting experiments using inductively coupled plasma emission electron spectrometry, ion chromatography, acid-base titration, and gravimetric analysis, the characteristics of ion concentration and TDS in different aquifers were analyzed to determine the possible source of groundwater in C2 (number 2 coal seam in Yan'an Formation). The Piper trilinear diagram was used to determine the hydrochemical types of aquifers, and the source of groundwater was determined based on the stable isotope characteristics of hydrogen and oxygen. The changes in ion, TDS, hydrogen, and oxygen isotopes of surface water and groundwater were analyzed, and the groundwater differences between the two sets of coal seams were compared. The research results indicate that the groundwater in C2 (number 2 coal seam in Yan'an Formation) is caused by the original sedimentary water and the infiltration of Zhiluo Formation and A1 (strata at the top of the Yan'an Formation to number 2 coal seam). However, C4 (number 3 coal seam in Yan'an Formation) is hindered by the well-developed mudstone in A3 (bottom of number 2 coal seam to the top of number 3 coal seam), which hinders the infiltration of groundwater. The study emphasizes that the overlying strata can have a significant impact on the coal seam when the moisture content is high and there is a lack of overlap, thereby promoting changes in the moisture content of the coal seam. This study provides some insights into the safety of coal mines, especially in mining areas with a high coal seam moisture content.

Optical properties of low-pressure DC Ar plasma torch with N2–SiH4–B2H6 gas mixture injection for Si–B–N thin film deposition

Si–B–N ceramic hard films were prepared by injecting N2+SiH4+B2H6 reaction gas into an argon DC arc plasma jet at reduced pressure. XPS, FT-IR, SEM, and microhardness tester were used to characterize the samples, and the optical properties of Ar discharge plasma jet with and without reaction gas injection were studied by a multichannel high-resolution spectroscopy and a wide spectral range spectroscopy. It is found that the deposited films are mainly composed of Si, B, N and O. The film surface presents a dense structure with hundred-nanometer-sized clusters, and the hardness of sample is greatly enhanced. When the reaction gas is injected into the plasma jet, the emission of excited atoms in the background plasma is greatly reduced, and the growth rate of Si–B–N film shows a significant downward trend as the reaction gas injection ring or substrate holder is moved away from the torch nozzle. A slight enhancement of background plasma emission is observed near the substrate surface with increasing the distance between gas injection ring and torch nozzle, which indicates that the suppression effect of the reactive gas injection on the background plasma emission and the activation efficiency of the reaction gas are weakened, thereby reducing the deposition rate.

Polarization properties of the decameter spikes

An analysis of the observational polarization properties of the decameter spikes is presented in the paper. It is shown that decameter spikes possess high degree of circular polarization with average value of about 60%. In the frames of “leading spot” theory we associated the spikes activity with a certain active region on the solar disk and determined the mode of the emission. Supposing plasma emission mechanism we link and determine coronal plasma and fast electron beam parameters.

Evaluation of plasma parameters’ impact on MRR and surface roughness in plasma polishing of fused silica: An investigation of surface characterization

Advanced fabrication methods with high efficiency are needed to meet the rising demand for precision optical components. This study proposes a plasma-based isotropic polishing method to remove fused silica's surface defects and subsurface damaged layers. Hence, a medium-pressure plasma process is developed to serve this purpose. The qualitative analysis of the plasma and atom emission spectrum explores the plasma generation and scattering of the activated fluorine (F*) radicals inside the plasma chamber. Material removal rate (MRR) and surface roughness variations with different total pressures of 5–30 mbar and substrate dimensions (i.e., varying length between 5 and 45 mm with fixed width and thickness of 5 and 2 mm) at fixed process parameters, i.e., radio-frequency power of 80 W, pressure ratio of 1:1, gas composition of 90:10, have been investigated. The highest and lowest MRR, i.e., 0.039 mm3/min and 0.0061 mm3/min, are achieved at 5 and 30 mbar total pressures on substrates having lengths 45 and 5 mm, respectively. The highest and lowest percentage change in surface roughness observed are 86.4 % and 17.1 % at 5 mbar and 30 mbar for substrates with 5 and 45 mm lengths, respectively. Surface morphology analysis shows the micro-cracks are reduced after plasma processing. The presence of elements, i.e., F and C, through EDX analysis, confirms the reactions on the plasma processed surface. Moreover, The XPS findings demonstrated that minimal radicals could be incorporated onto the fused silica surface during He/O2/SF6 plasma processing. At lower pressure, the surface roughness value increases due to the increased excitation and ionization rate caused by more interaction between the fluorine and surface atoms. The MRR increases with substrate dimension with constant pressure. Larger substrate dimensions result in increased MRR at lower pressure.

Iron ion detection and life cycle assessment of cutting fluid based on photoluminescent nitrogen-doped carbon quantum dots

Cutting fluid (CF) ensures machining accuracy and improves tool life in machining, which is of great significance for its impurity content detection and life cycle evaluation. In this paper, citric acid and arginine were used as carbon and nitrogen sources, photoluminescent (PL) nitrogen-doped carbon quantum dots (N-CDs) with a particle size ranging from 8 to 14 nm and well dispersion in water-based CF were synthesized by a one-pot hydrothermal reaction method. The N-CDs have the best signal under 360 nm ultraviolet light excitation, which well avoids the autofluorescence of the CF. The N-CDs dispersion have good selectivity and linearity in the Fe3+ concentration range of 2 to 80 μM, and the detection limit is 1.2 μM. The N-CDs were used to detect the concentration of Fe3+ in CF with different working hours, and the results were consistent with the results of coupled plasma emission spectroscopy. This study provides an intelligent sensing platform for the highly sensitive and selective detection of Fe3+ in the CF environment, and provides a promising strategy for the evaluation of the CF lifetime.

Investigating the Soft X-Ray Spectra of Solar Flare Onsets

In this study, we present the analysis of six solar flare events that occurred in 2022, using new data from the third-generation Miniature X-Ray Solar Spectrometer, also known as the Dual-zone Aperture X-ray Solar Spectrometer (DAXSS). The primary focus of this study is on the flare’s onset phase, which is characterized by elevated soft X-ray emissions even before the flare’s impulsive phase. We analyze the temporal evolution of plasma temperature, emission measure, and elemental abundance factors during the flare onset phase by fitting the DAXSS spectra with the Astrophysical Plasma Emission Code model. The model fitting results indicate that the flaring plasma is already at a high temperature (10–15 MK) during the onset period. The temperature rises during the onset phase, followed by a decrease and subsequent increase during the impulsive phase. Elemental abundance factors show a trend of falling below preflare values during the onset phase, with some recovery before the impulsive phase. During the impulsive phase, the abundance factors decrease from elevated coronal values to about photospheric values. We also analyze images from the 193 Å channel of the Atmospheric Imaging Assembly (AIA), highlighting the formation or brightening of coronal loop structures during the onset phase. Two distinct onset loop configurations are observed, which are referred to as one-loop and two-loop onsets. Both DAXSS and AIA observations indicate that the flare onset phase exhibits hot coronal plasma properties similar to those of the impulsive phase, suggesting that the onset phase may act as a preconditioning effect for some flares.

Preliminary design of an AXUV photodiode-based bolometer camera for MT-I spherical tokamak

The MT-I is a spherical tokamak at the Pakistan Tokamak Plasma Research Institute, and has a major radius of 15 cm and a minor radius of 9 cm. This paper presents the design and computational analysis of the Absolute eXtreme Ultra-Violet (AXUV) photodiode-based bolometer camera, which will be used for the first time in the MT-I tokamak. The bolometer camera contains a single array of 16 AXUV photodiodes placed behind an aperture to compute the line of sight (LOS) and field of view (FOV) of the system. This array is located at the midplane of the vessel, which provides a radial resolution of about 16 mm. The individual FOV of each photodiode and the collective FOV of the array are 4.1° and ±34.5°, respectively. The impurity densities and their cooling rates for elements like carbon, oxygen, and iron are used to compute the plasma emissivity distribution, the power incident on the photodiode array, and signal-to-noise ratio (SNR) analysis. The analysis reveals that the radiated power loss is about 10 % of the ohmic heating input power. The geometrical etendue falls within the range of 2.2 × 10−5 to 3.2 × 10−5 Sr cm2. The bolometer exhibits a frequency response bandwidth of 10 kHz, and its temporal resolution is around 0.1 milliseconds.

Application of Optical Emission Spectroscopy to Electron Cyclotron Resonance Ion Sources

Electron Cyclotron Resonance Ion Sources (ECRIS) are widely used for production of highly charged high intensity ion beams for research, medical and industrial applications.ECRIS performances, especially the charge state distribution and beam intensity, depend significantly on the electron energy distribution function that ranges from a few eV to hundreds of keV. Further improvements of ECRIS performances require a deeper and deeper understanding of the plasma heating mechanisms and ion generation by means of opportune plasma diagnostics. Amongst others, optical emission spectroscopy (OES) is the most remarkable for application in ECRIS: it is a non-invasive diagnostics able to operate also in high-voltage conditions and it requires small room for operation. OES has been already tested for plasma diagnostics in proton sources.This work presents the experimental set-up developed for the plasma diagnostics of the Advanced Ion Source for Hadrontherapy (AISHa), an ECRIS for medical applications, together with the strategy applied to relate plasma emission lines in the visible and near-infrared domain to plasma parameters for some ions of interest. Preliminary results and perspectives will be also discussed.

Laser-induced breakdown spectroscopy (LIBS) of animal fat (lard): Efficient sample preparation for onsite analysis and influence of sample temperature on the signal intensity and plasma parameters

We report an efficient sample preparation method (freezing) for onsite fat and meat analysis via a specially designed thermoelectric cooling and temperature-controlling system. This investigation also focused on the effect of phase change on the sensitivity and reproducibility of LIBS emission signals and plasma parameters. The plasma emissions of animal fats (lard) were recorded when the sample was frozen (−2 °C), fluid (15 °C), and in a liquid state (37 °C) with a thermoelectric cooling system. At each temperature, the plasma emissions were acquired at laser pulse energy from 50 to 300 mJ and detector gate delay (DGD) from 0.5 to 5 μs. With increasing sample temperature, the DGD, where the optical emission intensity reached a maximum, decreased. At a laser pulse energy of 200 mJ and a sample temperature of −2 °C, the emission signals increased fourfold, the signal-to-noise ratio (SNR) improved tenfold, and the self-absorption in the emission lines decreased significantly. The repeatability of the emission signals and plasma parameters of frozen and liquid fat samples was determined using the relative standard deviation (RSD) of Se I (473.08 nm) and K I (766.48 nm) emission lines. The RSDs of the emission signals improved from 40 to 18 % and 37 to 16 %, whereas the shot-to-shot RSDs of the electron temperature and electron number density get improved from 11 to 6 % and 12 to 6.8 %, respectively.

Cathode Plasma Expansion at Early Vacuum Arc at Pulsed Plasma Emission

Cathode Plasma Expansion at Early Vacuum Arc at Pulsed Plasma Emission

A comprehensive X-ray analysis of the massive O-type binary HD 93250 over two decades

Massive star winds are known to be responsible for X-ray emission arising from wind plasma heated by the strong shocks up to temperatures of 10$^6$--10$^7$ K in the case of colliding wind binaries. The investigation of X-ray emission from massive stars thus constitutes a valuable tool for identifying binaries, which is otherwise a difficult task using classical techniques. We investigated thermal and nonthermal X-ray emission from the massive O-type star HD\,93250 to unveil its binary orbital parameters independently. To meet our goal, we analyzed X-ray data obtained with European Photon Imaging Camera on board XMM-Newton spanning over sim 19 years. Additionally, we analyzed NuSTAR observations of HD\,93250 taken at various epochs. We determine the variability timescale of the X-ray emission to be 193.8pm 1.3\,d, in full agreement with the 194.3pm 0.4\,d period derived from the astrometric orbit. The X-ray spectrum of HD\,93250 is well explained by a three-temperature thermal plasma emission model with temperatures of 0.26, 1.0, and 3.3 keV. The resulting X-ray flux varies in compliance with the typical colliding wind emission from eccentric massive binaries where it enhances near periastron passage and decreases gradually close to apastron in proportion to the inverse of the binary separation. The periastron-to-apastron X-ray emission ratio points to an eccentricity range of 0.20-0.25, once again in agreement with the previously determined astrometric orbit. Finally, we do not detect any hard X-ray emission attributable to nonthermal emission above 10 keV. Given the derived plasma temperature, the strong phase-locked variability, and the significant over-luminosity in X-rays, we establish that the X-ray emission from HD\,93250 is dominated by the colliding-wind region. Our results lend support to the idea that X-ray time analysis of massive stars constitutes a relevant tool for investigating their multiplicity and for extracting relevant information on their basic orbital parameters ---such as period and eccentricity--- independently of any orbital solution derived from classical techniques.

Element recognition of laser-induced breakdown spectroscopy by comparing vectors of peak quantities

Element recognition of laser-induced breakdown spectroscopy (LIBS) can be achieved by analyzing the corresponding peaks of plasma emissions. However, it is still challenging to make quick judgments due to database disagreements, such as wavelength or line-ratio. This study presents a simple method to conduct element recognition based on comparing vectors established by the quantities of spectral peaks, which allows an accurate recognition of the principle elements regardless of wavelength shifts. By examining deep-sea samples, this method demonstrates the recognition effectiveness for rare earth elements (REEs) with an accuracy over 80%. The developed method proves to be practical in LIBS qualitative analysis, and it can serve as an effective complement to existing approaches for element identification.

Fenton reaction in the process of “Laser + Fe” mode excited plasma for Rhodamine B degradation

The spectral emission of laser-induced plasma in water has a broadband continuum containing ultraviolet light, which can be used as a novel light source for the degradation of organic compounds. We studied the degradation process of the organic dye Rhodamine B (RhB) using plasma light source excited by the “Laser + Fe” mode. Spectral analysis and reaction kinetics modelling were used to study the degradation mechanism. The degradation process using this light source could be divided into two stages. The initial stage was mainly photocatalytic degradation, where ultraviolet light broke the chemical bond of RhB, and then RhB was degraded by the strong oxidising ability of ·OH. As the iron and hydrogen ion concentrations increased, the synergistic effect of photocatalysis and the Fenton reaction further enhanced the degradation rate in the later stage. The plasma excited by the “Laser + Fe” mode achieved photodegradation by effectively enhancing the ultraviolet wavelength ratio of the emission spectrum and triggered the Fenton reaction to achieve rapid organic matter degradation. Our findings indicate that the participation of the Fenton reaction can increase the degradation rate by approximately 10 times. Besides, the impact of pH on degradation efficiency demonstrates that both acidic and alkaline environments have better degradation effects than neutral conditions; this is because acidic environments can enhance the Fenton reaction, while alkaline environments can provide more ·OH.

Generation Mechanism and Beaming of Jovian nKOM From 3D Numerical Modeling of Juno/Waves Observations

AbstractThe narrowband kilometric radiation (nKOM) is a Jovian low‐frequency radio component identified as a plasma emission produced in the region of the Io plasma torus. Measurements from the Waves instrument onboard the Juno spacecraft permitted to establish the distribution of nKOM occurrence and intensity as a function of frequency and latitude. We have developed a 3D geometrical model that can simulate at large scale the plasma emissions occurrence observed by a spacecraft based on an internal Jovian magnetic field model and a diffusive equilibrium model of the plasma density in Jupiter's inner magnetosphere. With this model, we propose a new method to discriminate the generation mechanism, wave mode, beaming and radio source location of plasma emissions. Here, this method is applied to the study of the nKOM observed from all latitudes by the Juno/Waves experiment to identify which conditions reasonably reproduce the observed occurrence distribution versus frequency and latitude. The results allow us to exclude the two main nKOM models published so far, and to show that the emission is produced at the local plasma frequency and then beamed anti‐parallel to the local density gradient into free space. We also propose that depending on its latitude, Juno observes two distinct kinds of nKOM: the low frequency nKOM in ordinary mode at high latitudes, and the high frequency nKOM on extraordinary mode at low latitudes. Both radio source locations are found to be distributed near the centrifugal equator ranging from the outer edge to the inner edge of the Io plasma torus.

Self-Calibrated Laser-Induced Breakdown Spectroscopy for the Quantitative Elemental Analysis of Suspended Volcanic Ash.

Real-time analysis of fine ash in volcanic plumes, which represent magma fragments expelled from the crater during explosive eruptions, is a valuable tool for volcano monitoring and hazard assessment. To obtain the chemical characterization of the juvenile pyroclastic material emitted in volcanic plumes, many analytical techniques can be used. Among them, laser-induced breakdown spectroscopy (LIBS) is the one that can most easily be adapted to advanced applications in extreme environments. In this paper, LIBS experiments based on self-calibrated approaches are used to determine the elemental composition of suspended volcanic ash. To simulate the conditions of dispersed volcanic ash in the atmosphere, different sizes of volcanic ash samples are suspended in the air by laser-induced shockwaves in a dedicated chamber, and a parametric study is carried out to establish the optimal experimental conditions for recording usable plasma emission spectra for each ash size. The quantitative analysis is performed using a self-calibrated analytical method, including calibration-free LIBS, which is based on the calculation of the spectral radiance of a uniform plasma in local thermodynamic equilibrium. The method accounts intrinsically for self-absorption since it modifies the intensity of spectral lines and thus leads to an underestimation of the elemental fraction. An intensity calibration of the spectra based on the measurements of Fe lines intensities was also used in this work to deduce the apparatus response from the spectrum itself and avoid the use of standard calibration lamps. Results demonstrate the potential of real-time measurements of elemental fractions in volcanic ash with good agreement with the literature composition.

Optical Evidence of Compositional Fractioning between Plasma‐Condensed and Melt Pool Matter

Control of multicomponent alloys during welding is challenging because it lacks a real‐time understanding of composition. The optical emissions of plasma formed during laser‐induced metal welding correlate with the composition of particles ejected from the melt pool. Plasma emissions observed in this study contain large iron, manganese, chrome, and copper signatures, which match the composition of emitted particles. Particles recovered closest to the melt pool exhibit a core–shell morphology that is composed of iron‐manganese‐chrome intermetallic cores within copper shells. Particles collected farther from the melt pool, do not share this core–shell morphology, though similar elemental compositions are observed. The correlation between plasma optical emissions and particle composition can be used to predict the composition of the melt pool, allowing for real‐time welding and sintering control.

Dependence of spectral purity of Gd plasma emission around 6.7 nm on laser irradiation conditions

Gadolinium is a compelling candidate for the next-generation 6.x nanolithography light source. We present a systematically study on the spectral purity at 6.7 nm in the gadolinium laser produced plasma. Variations in extreme ultraviolet spectra are observed over a wide range of laser focal spot sizes and laser pulse energies due to the combined effect of plasma temperature and opacity. When varying laser focal spot size, ionic populations of Gd ions at different electron temperatures were estimated by the collisional-radiative model for the explanation of changes in the spectral profile. When adjusting the laser pulse energy, modifications in the electron density profile were measured through Nomarski interferometry, and the related optical depth was quantified assisted with a one-dimensional radiation transfer model. Results show that, appropriate laser energy and focal spot size are necessary to achieve the high spectral purity, and with a lens with focal length of f = 175 mm and a laser pulse energy of 100 mJ, a spectral purity of Gd plasma up to 3.7% over range of 5.5–10 nm is achieved.

Deposition rate and optical emissions in niobium oxide processes by reactive sputtering

Niobium oxide films find various applications, such as antireflective optical layers, gas sensors, and solar cells. They also show promise for emerging applications such as electrochromic and photocatalytic devices. In order to optimize the deposition of niobium oxide films by RF reactive sputtering, a detailed investigation of the plasma parameters was performed. A pure metallic target and a mixture of Ar and O2 in different proportions were used in the experiments. The deposition power was varied between 120 and 260 W, while the total pressure was kept at 0.67 Pa throughout. Deposition rates, discharge self-bias voltage, and plasma optical emissions were monitored and analyzed. Additionally, computer simulations of the process utilizing existing models were conducted and a comparative analysis with the experimental results was performed. The main findings include mapping the deposition conditions as functions of oxygen flow rate. The flow ranges in which the deposition regime changes from metallic to oxygen contaminated target conditions were identified. The narrow O2 flow range associated with the regime changes was characterized by significant changes in the self-bias voltages and plasma emissions from oxygen, argon, and niobium. The observations evidence the importance of the detailed analysis of the deposition process to get the desired stoichiometry and optimized film properties.