Carbonation technology using MgO and CO2 has been considered a rapid, effective, and environmentally friendly method for improving weak soils, mainly applied in shallow foundation treatments. This study introduced a novel MgO-carbonated composite pile (MCP) technique developed by injecting CO2 through a gas-permeable pipe pile into a MgO-mixing column for carbonation and solidification and its applications in weak subgrade treatments. Several field tests were carried out to study the characteristics of MCP as well as the performance of the MCP-reinforced foundations, including carbonation reaction temperature monitoring, pore-water pressure monitoring, standard penetration tests (SPT), unconfined compressive strength (UCS) tests, static load tests, and subgrade deformation monitoring. Results showed vigorous and uniform carbonation within the MgO-mixing column, confirming the feasibility of constructing large-diameter MgO-mixing columns. The distribution, evolution, and affected zone of excess pore-water pressure induced by MCP installation were determined. The MCP exhibited good pile quality, with average SPT-N and UCS values of 39 and 1021 kPa, respectively. MCP’s bearing capacity was superior to pre-stressed high-strength concrete pipe piles, with ultimate vertical and lateral bearing capacities of 1920 kN and 119 kN, respectively. The MCP-reinforced foundation exhibited a small settlement of 54.5 mm under embankment loads. Life cycle assessment indicated significant carbon reduction benefits for MCP, with 44.7% lower carbon emissions compared to traditional composite piles.
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