Observed relationships between anhydrite and halite in the A unit of the Michigan basin are not easily explained by classical evaporite depositional models. Within the Northern Reef trend, productive Niagaran pinnacle reefs are surrounded by A unit halite, which commonly exceeds 100 m in total thickness. However, A unit evaporites consist of thick anhydrite deposits on reef flanks and above reefs in the A-1 and A-2, respectively, Stratigraphic data suggest that the anhydrites surrounding reefs are contemporaneous with off-reef halite deposits. This reef-evaporite relationship poses three problems. (1) Why would gypsum precipitate from a halite-saturated brine (2) Why are anhydrites associated with the reefs (3) Why are anhydrites significantly thicker than predicted by evaporation models In a normal marine evaporation sequence (Hardie-Eugster model), gypsum is deposited from a brine until calcium is depleted. Upon further evaporation, the resultant halite-saturated brine would precipitate gypsum only in contact with a calcium source. The authors propose a calcium pumping mechanism whereby calcium-rich water associated with pinnacle reefs is responsible for gypsum precipitation around these reefs contemporaneous with off-reef halite. The additional supply of calcium also explains the anomalous thickness of these anhydrite deposits. Similar anhydrite halos around pinnacle reefs have been observed in more » the Devonian Elk Point basin. « less
Read full abstract