With the increase of energy storage demand for many applications, sustainable technologies must be developed. On one hand, Li-ion batteries (LIBs) offer high energy density but high cost and safety issues for high-power density applications, especially at low temperature. On the other hand, supercapacitors (SCs) exhibit high power and cyclability but insufficient energy density and self-discharge problems. The aforementioned properties result in a performance gap between LIBs and SCs. They are unable to meet the requirements for specific applications for storing/delivering large amount of energy within a short time during many cycles like regenerative braking in vehicles, memory backup in electronics or high voltage pulse delivery in industrial and medical sectors. Therefore, devices with a good energy density, an excellent power density and a long cycling stability are urgently required. This is the purpose of a hybrid capacitor by combining the electrostatic phenomena at a positive capacitor-type electrode and the faradic process at an oversized negative battery-type electrode. Fast charging is then possible while ensuring a higher energy density than conventional EDLCs. This higher energy density is possible because of the widen operating voltage range in hybrid configuration. Thanks to the deployment of Li-ion battery, the use of lithium is generally applied on hybrid capacitors. However, technologies using lithium chemistries (LIC and LIB) are dependent on critical and strategic materials (copper, lithium), use carbonate electrolytes and give rise to safety problems and a limited lifetime linked to the formation of dendrites. The idea of replacing lithium with other alkali elements is then gradually emerging. For example, potassium benefits of abundant resources, low standard electrode potential as well as low costs.The potassium-ion capacitor (KIC) presented here consist of an activated carbon positive electrode and a graphite negative one immersed in an acetonitrile based-non-aqueous electrolyte and a potassium salt. The hybrid configuration avoids specific problems inherent in the use of potassium. Indeed, the system is designed so that a high stage of graphite intercalation compound (GIC) is obtained in order to avoid critical volume expansion. Furthermore, with the spontaneous reaction between acetonitrile and metallic alkali elements, dendrites formation is not possible.However, the technology still faces obstacles that are being studied to be removed. Among them, a non-monotonous cycle ageing, with discharged capacities which decrease then increase drastically in a few thousand cycles, as well as a non-reproducibility of the results for identical cells were observed with the system initially developed. These results will be presented in order to show how they could be improved. In addition, the operation of KIC systems results in gas generation that induces cell swelling. This is a well-known issue whether for supercapacitors or Li-ion batteries. In the case of KIC technology, it has been proven to result from the combination of SEI formation at the negative electrode and side reactions between the functional groups of the positive electrode and the electrolyte. All these results highlight the necessity to develop an adequate formation protocol for KIC cells. Indeed, the first cycles of use of an electrochemical system, known as "formation", are essential to ensure its proper long-term operation.In the case of Li-ion battery, the formation protocol is well defined with galvanostatic charge/discharge cycles at low current regime and high temperature. Whereas in the case of KICs, about ten cycles at 5C/5D (C the theoretical value of the positive electrode capacity) and at room temperature were performed. The influence of the current regime and the temperature during first galvanostatic charge/discharge cycles were investigated to define a protocol specific to KIC cells and will be presented. In addition, another type of formation was considered following the swelling tests, which will be presented in order to understand the approach followed. Three different formations principles (Figure) were therefore tested. The first leads to non-reproducible and unstable performance. The second conducts in reproducible results but unstable long-term performance. The last provides stable and reproducible results with high energy densities. The cells started then aging tests at 100C/100D, which corresponds to a charge/discharge time of 30 seconds. Those having undergone the last formation show an excellent stability in cycling over more than 100,000 cycles. The stability of the energy density of KIC during long-term cycling is highly remarkable and hardly observed in the case of LIC.To conclude, the potassium-ion capacitor presented offers a good energy density of up to 14 Wh/kgelectrochemical core at pouch cell level, the possibility of fast charging and a long stability cycling. Improvements are still needed for operation at different temperatures and self-discharge. Figure 1