We investigated the distribution of ions around charged membranes at a lipid/water/air interface by using a molecular dynamics (MD) simulation with a sufficiently large cell size for water. It was shown that the thickness of the electronic double layer is different from the classical Debye length, which is a bit longer than the former. It was also found that the distance between the ions in the solution and the membrane charge changes depending on the difference in ionic charge owing to the water molecules around the ions. Detailed analysis of ion distribution near the lipid/water surface was presented.