Electron Motion Research Articles

Extreme magnetoresistance at high-mobility oxide heterointerfaces with dynamic defect tunability

Magnetic field-induced changes in the electrical resistance of materials reveal insights into the fundamental properties governing their electronic and magnetic behavior. Various classes of magnetoresistance have been realized, including giant, colossal, and extraordinary magnetoresistance, each with distinct physical origins. In recent years, extreme magnetoresistance (XMR) has been observed in topological and non-topological materials displaying a non-saturating magnetoresistance reaching 103−108% in magnetic fields up to 60 T. XMR is often intimately linked to a gapless band structure with steep bands and charge compensation. Here, we show that a linear XMR of 80,000% at 15 T and 2 K emerges at the high-mobility interface between the large band-gap oxides γ-Al2O3 and SrTiO3. Despite the chemically and electronically very dissimilar environment, the temperature/field phase diagrams of γ-Al2O3/SrTiO3 bear a striking resemblance to XMR semimetals. By comparing magnetotransport, microscopic current imaging, and momentum-resolved band structures, we conclude that the XMR in γ-Al2O3/SrTiO3 is not strongly linked to the band structure, but arises from weak disorder enforcing a squeezed guiding center motion of electrons. We also present a dynamic XMR self-enhancement through an autonomous redistribution of quasi-mobile oxygen vacancies. Our findings shed new light on XMR and introduce tunability using dynamic defect engineering.

Directional movement of electron induced by interfacial coupling in CuS@NiCo-LDHs for efficient alkaline oxygen evolution reaction

Heterojunction has the characteristics of adjusting catalyst structure, improving oxygen evolution kinetics and breaking the elevated reaction barrier of oxygen evolution process. In this paper, a heterostructure catalyst of NiCo-LDHs nanosheets encapsulated CuS hollow nano-octahedrals has been reported, which has better stability and higher mass transfer efficiency compared with two-dimensional nanosheets. Density functional theory (DFT) calculations indicate that the heterostructure strengthens the orbital hybridization of metal 3d and O 2p, at the same time, the heterointerface coupling induces the directional movement of electrons from NiCo-LDHs to CuS, which together provide abundant high-valence Ni and Co active sites, promote the conversion of *OH to *O species, thus reducing the energy required for the reaction. Hence, CuS@NiCo-LDHs exhibits excellent OER performance and good stability in 1 M KOH. When the current density is 10 mA/cm2, the overpotential and Tafel slope of this catalyst is only 253 mV and 56 mV/dec, respectively. This study furnishes the construction of heterogeneous structures and the catalyst exploitation with serviceable insights.

Fabrication of highly flexible, wearable, free-standing symmetric supercapacitors with high voltage operation enabled by hierarchical graphene/cerium oxide/polypyrrole hybrid films

Flexible, free-standing supercapacitors play a significant role in the development of future wearable energy storage devices. Herein, we successfully fabricated the highly flexible and free-standing graphene/cerium oxide/polypyrrole hybrid films by thermal reduction of graphene oxide (GO) followed by the sol–gel synthesis of CeO2 and then the addition of PPy. By regulating oxygen functional groups in GO, the electronic conductivity and electroactive sites of the hybrid films are significantly controlled, leading to enhanced energy storage capability. Finally, a symmetric flexible supercapacitor (FSC) device was developed using the prepared films as electrodes. Resulting, the integrated symmetric GO-400/CeO2/PPy FSC manifests excellent areal capacitance of 49.0 mF cm−2 at 1 mA cm−2, with a durability of 83.1 % over 10,000 cycles. Specifically, the FSC exhibited capacitance retention of 77.2 % after 10,000 cycles under bending state with exceptional rate ability. Meanwhile, an impressive energy density of 19.69 µW h cm−2 was attained at a power density of 0.85 mW cm−2. Evidently, the synergistic interactions between GO and PPy nanosheets, along with CeO2 favour the rapid electron movement of electrode material for next-generation wearable, portable electronics.

Phase control of nonlinear Breit-Wheeler pair creation

Electron-positron pair creation occurs throughout the universe in the environments of extreme astrophysical objects, such as pulsar magnetospheres and black hole accretion disks. The difficulty of emulating these environments in the laboratory has motivated the use of ultrahigh-intensity laser pulses for pair creation. Here we show that the phase offset between a laser pulse and its second harmonic can be used to control the relative transverse motion of electrons and positrons created in the nonlinear Breit-Wheeler process. Analytic theory and particle-in-cell simulations of a head-on collision between a two-color laser pulse and electron beam predict that with an appropriate phase offset, the electrons will drift in one direction and the positrons in the other. The resulting current may provide a collective signature of nonlinear Breit-Wheeler, while the spatial separation resulting from the relative motion may facilitate isolation of positrons for subsequent applications or detection. Published by the American Physical Society 2024

Deciphering Charge Transfer Processes in Transition Metal Complexes from the Perspective of Ultrafast Electronic and Nuclear Motions.

Chemical transformations in charge transfer states result from the interplay between electronic dynamics and nuclear reorganization along excited-state trajectories. Here, we investigate the ultrafast structural dynamics following photoinduced electron transfer from the metal-metal-to-ligand charge transfer state of an electron donor, a Pt dimer complex, to a covalently linked electron acceptor group using ultrafast time-resolved wide-angle X-ray scattering and optical transient absorption spectroscopy methods to disentangle the interdependence of the excited-state electronic and nuclear dynamics. Following photoexcitation, Pt-Pt bond formation and contraction takes up to 1 ps, much slower than the corresponding process in analogous complexes without electron acceptor groups. Because the Pt-Pt distance change is slow with respect to excited-state electron transfer, it can affect the rate of electron transfer. These results have potential impacts on controlling electron transfer rates via structural alterations to the electron donor group, tuning the charge transfer driving force.

Analysis of undergraduate chemistry students’ responses to substitution reaction mechanisms: a road to mastery

Abstract This study analyzed third-year undergraduate Chemistry major students’ drawings and written explanations of substitution reactions. Seventy (70) students were purposively selected for this study. The main data collection instrument was a diagnostic test and students’ responses were analyzed using deductive coding. The study aimed to unearth students’ conceptual understanding and difficulties on substitution reactions to provide significant insights into improving teaching strategies and learning outcomes. The findings revealed that: 1. Students were more familiar with SN2 reaction mechanisms and could answer questions on SN2 reaction mechanisms better than SN1 reaction mechanisms; 2. Students’ use of ‘chemical vocabulary’ did not translate into an understanding of electron movement and causal mechanistic explanation; 3. About 97 % of the students who gave a correct/partially correct description provided a description of what was happening in the reaction without any further explanation of why the reaction occurred; 4. Students had a slightly better understanding of drawing the correct mechanisms than providing accurate explanations. This study recommends that, in teaching organic reaction mechanisms, instructors should emphasize on electron-pushing formalisms and explain how and why reactions occur to encourage mechanistic thinking in students. Also, students should be given ample practice in organic reaction mechanisms to improve mastery.

Photo-Fenton-like degradation of tetracycline through peroxymonosulfate activation over 2D BiOBr/FeOOH nanosheets and membrane application

The selection of photosensitizer substrates with high photocatalytic efficiency is crucial for leveraging the advantages of metal-based materials in photo-Fenton-like process. Herein, we report a novel 2D layered BiOBr/FeOOH nanosheets equipped with a built-in electric field (BIEF) to activate peroxymonosulfate (PMS) for the degradation of tetracycline (TC). The photocatalytic efficiency of BiOBr is enhanced by fine-tuning the Br source quantity. Both experimental and theoretical analyses confirm that BIEF at the BiOBr/FeOOH heterointerface expedites the movement of photogenerated electrons, significantly boosting both photocatalytic and photo-Fenton-like activities. The BiOBr/FeOOH + PMS + Vis system exhibits a high TC removal rate of 96 % with only 0.24 mM of PMS and nearly 100 % of PMS utilization. Moreover, affixing BiOBr/FeOOH nanosheets onto a PVDF microfiltration membrane, we establish a continuous flow reactor system for antibiotic wastewater treatment. This system demonstrates a remarkable TC removal efficiency consistently above 97.5 % for 6 h of continuous injection, underscoring its practicality and potential for real-world applications.

Statistical Properties of Exohiss Waves and Associated Scattering Losses of Radiation Belt Electrons

AbstractExohiss waves are a type of structureless whistler‐mode waves that exist in the low density plasmatrough outside the plasmapause and may potentially perturb the motions of electrons in the radiation belt and ring current. Using data from Van Allen Probe A, we analyze the distribution of magnetic power spectral density (PSD) of exohiss waves in different magnetic local time (MLT) and L‐shell regions near the geomagnetic equator. The results reveal that the peak magnetic PSD of exohiss waves is the weakest at MLT = 0–6 and the strongest at MLT = 12–18. The magnetic PSDs of exohiss waves are much lower than those of chorus and hiss waves except for the MLT = 12–18 sector. In addition, we calculated the quasi‐linear bounce‐averaged pitch angle and momentum diffusion coefficients (〈Dαα〉 and 〈Dpp〉) of electrons caused by exohiss waves. The diffusion coefficients are then compared with those caused by chorus and hiss waves. The peak 〈Dαα〉 of electrons driven by exohiss waves becomes stronger as L‐shell increases at all MLTs and is the greatest on the dayside, especially in the sector of MLT = 12–18. Exohiss waves have more significant effect on the loss of radiation belt electrons with specific energy levels related to MLT and L‐shell region compared to chorus and hiss waves. On the other hand, 〈Dpp〉 of electrons caused by exohiss waves is very small, which illustrates that exohiss waves have almost no acceleration effect on electrons.

Unraveling charge transfer dynamics in AgBr/Bi4Ti3O12/Bi2Sn2O7 ternary S-scheme heterojunction photocatalyst

In this study, AgBr/Bi4Ti3O12/Bi2Sn2O7 (ABr/BTO/BSO) composites were successfully synthesized to facilitate multi-channel fast charge transfer. This directs the charge carriers to travel along multichannel pathways and suppresses carrier recombination. The mechanisms underlying charge transfer in the dual S-scheme heterojunction composites were elucidated using density functional theory (DFT) and in situ irradiated X-ray photoelectron spectroscopy (ISI-XPS). Furthermore, electron spin resonance (ESR) and burst experiments verified h+, ·O2 -, and ·OH as the primary active species in the catalytic process. The ABr/BTO/BSO composites demonstrated exceptional photocatalytic redox capabilities, completely degrading rhodamine B (RhB) and achieving degradation rates of 77.21% for tetracycline (TC) and 81.04% for Cr (VI). Both experimental and theoretical analyses confirmed the intrinsic efficacy of photo-induced electron movement within the composites. This research introduces innovative design concepts and strategies for the advanced exploration of electron channel transfer in ABr/BTO/BSO ternary composites and the development of novel composite photocatalytic systems.

Particle traps constructed on the insulator of conductive slip rings for surface flashover mitigation under particle adhesion

The generation of abrasive particles is an unavoidable consequence of sliding electrical contact wear in conductive slip rings (SRs). The adhesion of abrasive particles to the insulators may lead to a decrease in flashover voltage, posing a risk to satellite power transmission. In this paper, the effect of abrasive particles on flashover is first studied. Surface abrasive particles can distort the surface electric field of the dielectric, absorb scattered electrons, and then re-emit them, thereby accelerating the development and formation of secondary electron avalanches. Flashover test results indicate that surface abrasive particles lead to a significant reduction in flashover voltage. To mitigate the impact of particle adhesion on flashover, a method of constructing particle traps on the surface of insulators is proposed. The location and structural parameters of the particle trap are further optimized and determined. The flashover test results using planar dielectric samples and SR insulator samples both demonstrate that the optimized particle trap can significantly improve the flashover voltage. The dielectric maintains high electrical strength even when particles are trapped in particle traps. The physical details of the impact of particles on flashover and the effect of particle traps are analyzed utilizing an electron movement simulation, corroborating the experiment from a microscopic aspect.

Metal–organic framework–derived trimetallic particles encapsulated by ultrathin nitrogen-doped carbon nanosheets on a network of nitrogen-doped carbon nanotubes as bifunctional catalysts for rechargeable zinc–air batteries

Economical oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) bifunctional catalysts with high activity aimed at replacing precious metal catalysts for rechargeable zinc-air batteries (ZABs) must be developed. In this study, a multiple hierarchical-structural material is developed using a facile dielectric barrier discharge (DBD) plasma surface treatment, solvothermal reaction, and high-temperature carbonization strategy. This strategy allows for the construction of nanosheets using nitrogen-doped carbon (NC) material-encapsulated ternary CoNiFe alloy nanoparticles (NPs) on a network of NC nanotubes (NCNTs), denoted as CoNiFe–NC@p–NCNTs. Precisely, the presence of abundant CoNiFe alloy NPs and the formation of M–N–C active sites created by transition metals (cobalt, nickel, and iron) coupled with NC can provide superior OER/ORR bifunctional properties. Moreover, the prepared NC layers with a multilevel pore structure contribute to a larger specific surface area, exposing numerous active sites and enhancing the uniformity of electron and mass movement. The CoNiFe0.08–NC@p–NCNTs show remarkable dual functionality for electrochemical oxygen reactions (ORR half-wave potential of 0.811 V, limiting current density of 5.73 mA cm−2 measured with a rotating disk electrode at a rotation speed of 1600 rpm, and OER overpotential of 351 mV at 10 mA cm−2), which demonstrates similar ORR performance to 20 wt% Pt/C and better OER performance than the commercial RuO2. A liquid ZAB prepared using the proposed material has excellent bifunctionality with an open-circuit voltage of 1.450 V and long-term cycling stability of 230 h@10 mA cm−2.

Integration of Sn(IV)porphyrin on mesoporous alumina support and visible light catalytic photodegradation of methylene blue

Two composite catalysts, designated as SnTTP/SA@Al2O3 and SnTTP@Al2O3, were synthesized by the reaction of Al2O3 and trans-dihydroxo-[5,10,15,20-tetrakis(p-tolyl)porphyrinato]tin(IV) (SnTTP) with and without succinic acid (SA) pretreatment, respectively. Chemically, SnTTP was more tightly incorporated onto the surface of Al2O3 through the anchoring group SA in SnTTP/SA@Al2O3 than that in SnTTP@Al2O3. The SA bridging anchoring groups hindered the dissociation of SnTTP from SnTTP@Al2O3 during photodegradation. Therefore, the strong association between Al2O3 and SnTTP via SA connections not only intensified the quantity of tin porphyrin on the surface of Al2O3 but also accelerated electron movement from the excited SnTTP molecules to the conduction band of Al2O3. The aforementioned mechanism demonstrates a significant improvement in the catalytic photodegradation of methylene blue (MB) dye for SnTTP/SA@Al2O3 compared to SnTTP, Al2O3, and SnTTP@Al2O3 under visible-light irradiation. Within 90 min of using SnTTP/SA@Al2O3 at a rate of 0.0406 min−1, the photodegradation capacity of MB was found to be 98 %. The synergistic effect between Al2O3 and SnTTP improved the catalytic efficiency of SnTTP/SA@Al2O3 compared to that of both SnTTP and Al2O3. This study provides a new direction for the construction of highly efficient porphyrin-based photocatalysts and has significant value for extending their applications in water treatment.

Theoretical triple differential cross sections for ionization of N 2 and CH 4 molecules by electron impact

We present the angular distribution of electron emission by calculating the triple differential cross sections for (e, 2e) process on N 2 and CH 4 by using the three-body formalism of molecular first Born approximation (MFBA), two-Coulomb wave (M2CW), and three-Coulomb wave (M3CW) models, respectively. In these models, a Coulomb distorted wave is considered for the motion of the incident electron. We have considered the continuum-continuum correlation effect by choosing the final state as the three-Coulomb and two-Coulomb wave functions in M3CW and M2CW models, whereas the ejected electron is affected by a single centre field of the target in the MFBA model. In the M2CW model, the interaction between scattered electron-residual target ion has been described as a plane wave. The distinguishing feature among the three models has been noted in the TDCS as a strong binary peak with and without a recoil peak for several electron emission energies at fixed scattering angle. In the case of N 2 molecule, the TDCS shows oscillatory behaviour with the variation of the electron emission angle. The positions of the binary peak obtained by our theoretical models are well established by the experimental findings, but a large deviation is found in the region of the recoil peak. The contributions of TDCS for different molecular orbitals of the molecules to the spectrum of angular distributions at different electron emission energies have also been analyzed. Finally, a comparison is made with the measurement in coplanar asymmetry geometry. Overall, good agreement was found between experiments and M3CW theory.

Controlling electron motion with attosecond precision by a shaped femtosecond intense laser pulse

Controlling electron motion with attosecond precision by a shaped femtosecond intense laser pulse

Computer vision-based real-time monitoring for swivel construction of bridges: from laboratory study to a pilot application

PurposeThe swivel construction method is a specially designed process used to build bridges that cross rivers, valleys, railroads and other obstacles. To carry out this construction method safely, real-time monitoring of the bridge rotation process is required to ensure a smooth swivel operation without collisions. However, the traditional means of monitoring using Electronic Total Station tools cannot realize real-time monitoring, and monitoring using motion sensors or GPS is cumbersome to use.Design/methodology/approachThis study proposes a monitoring method based on a series of computer vision (CV) technologies, which can monitor the rotation angle, velocity and inclination angle of the swivel construction in real-time. First, three proposed CV algorithms was developed in a laboratory environment. The experimental tests were carried out on a bridge scale model to select the outperformed algorithms for rotation, velocity and inclination monitor, respectively, as the final monitoring method in proposed method. Then, the selected method was implemented to monitor an actual bridge during its swivel construction to verify the applicability.FindingsIn the laboratory study, the monitoring data measured with the selected monitoring algorithms was compared with those measured by an Electronic Total Station and the errors in terms of rotation angle, velocity and inclination angle, were 0.040%, 0.040%, and −0.454%, respectively, thus validating the accuracy of the proposed method. In the pilot actual application, the method was shown to be feasible in a real construction application.Originality/valueIn a well-controlled laboratory the optimal algorithms for bridge swivel construction are identified and in an actual project the proposed method is verified. The proposed CV method is complementary to the use of Electronic Total Station tools, motion sensors, and GPS for safety monitoring of swivel construction of bridges. It also contributes to being a possible approach without data-driven model training. Its principal advantages are that it both provides real-time monitoring and is easy to deploy in real construction applications.

Feynman checkers: External electromagnetic field and asymptotic properties

In this paper, we study Feynman checkers, one of the most elementary models of electron motion. It is also known as a one-dimensional quantum walk or an Ising model at an imaginary temperature. We add the simplest non-trivial electromagnetic field and find the limits of the resulting model for small lattice step and large time, analogous to the results by Narlikar from 1972 and Grimmet–Jason–Scudo from the 2000s. It turns out that the limits in the model with the added field are obtained from the ones without field by mass renormalization. Also, we find an exact solution of the resulting model.

Direct observation of a magnetic-field-induced Wigner crystal.

Wigner predicted that when the Coulomb interactions between electrons become much stronger than their kinetic energy, electrons crystallize into a closely packed lattice1. A variety of two-dimensional systems have shown evidence for Wigner crystals2-11 (WCs). However, a spontaneously formed classical or quantum WC has never been directly visualized. Neither the identification of the WC symmetry nor direct investigation of its melting has been accomplished. Here we use high-resolution scanning tunnelling microscopy measurements to directly image a magnetic-field-induced electron WC in Bernal-stacked bilayer graphene and examine its structural properties as a function of electron density, magnetic field and temperature. At high fields and the lowest temperature, we observe a triangular lattice electron WC in the lowest Landau level. The WC possesses the expected lattice constant and is robust between filling factor ν ≈ 0.13 and ν ≈ 0.38 except near fillings where it competes with fractional quantum Hall states. Increasing the density or temperature results in the melting of the WC into a liquid phase that is isotropic but has a modulated structure characterized by the Bragg wavevector of the WC. At low magnetic fields, the WC unexpectedly transitions into an anisotropic stripe phase, which has been commonly anticipated to form in higher Landau levels. Analysis of individual lattice sites shows signatures that may be related to the quantum zero-point motion of electrons in the WC lattice.

An Overview of the Electronic Structure of Monolayer Graphene

Monolayer graphene is a nanostructured material that consists of layers of graphene, each layer of single-layer graphene consists of a layer of carbon atoms that are interconnected in a hexagonal lattice. The crystal structure of monolayer graphene is two dimensional and carbon atoms are inserted in a hexagonal lattice. The band structure of monolayer graphene includes two main bands that located at points K and K’ considered as quantum bands of electrons and holes. The electronic properties of monolayer graphene include the movement of electrons at very high speed and maintaining their spin. Also, monolayer graphene has unique optical properties and can be used as an optical switcher in electronic devices. Which from the basis of the contemporary technology of graphene and is progressing, therefor, research in this field is important and this research was carried out in a library method and its purpose is to investigate the electronic structure of single – layer graphene.

Classical and quantum light-induced non-adiabaticity in molecular systems

The exchange of energy between electronic and nuclear motion is the origin of non-adiabaticity and plays an important role in many molecular phenomena and processes. Conical intersections (CIs) of different electronic potential energy surfaces lead to the most singular non-adiabaticity and have been intensely investigated. The coupling of light and matter induces conical intersections, which are termed light-induced conical intersections (LICIs). There are two kinds of LICIs, those induced by classical (laser) light and those by quantum light like that provided by a cavity. The present work reviews the subject of LICIs, discussing the achievements made so far. Particular attention is paid to comparing classical and quantum LICIs, their similarities and differences and their relationship to naturally occurring CIs. In contrast to natural CIs, the properties of which are dictated by nature, the properties of their light-induced counterparts are controllable by choosing the frequency and intensity (or coupling to the cavity) of the external light source. This opens the door to inducing and manipulating various kinds of non-adiabatic effects. Several examples of diatomic and polyatomic molecules are presented covering both dynamics and spectroscopy. The computational methods employed are discussed as well. To our opinion, the young field of LICIs and their impact shows much future potential.

Rotation in attosecond vibronic coherence spectroscopy for molecules

Excitation or ionization of a molecule by ultrafast laser pulses can create a superposition of electronic states, whose dynamics is influenced by the interplay of electronic coherence and nuclear motion, resulting in charge migration and possibly charge transfer. Probing the vibronic coherence is therefore vital to monitoring electronic dynamics and controlling chemical reactivity, as recently demonstrated in molecules via attosecond transient absorption spectroscopy (ATAS). However, theories supporting the interpretation of ATAS experiments neglect the effects of molecular rotation, often leading to inaccurate interpretation of experimental data. Here, we develop a comprehensive theory for ATAS of molecules encompassing the entire pump-probe process. Applying the theory to N2, we demonstrate that the emergence of coherent signals critically depends on the consideration of molecular rotation. This work contributes to close the gap between theory and ATAS experiments, paving the way for monitoring electronic motion and controlling chemical reactivity in diverse molecular systems.