Four rocket-borne ejectable instruments, called ‘thermosphere probes,’ launched into the thermosphere above Wallops Island, Virginia, have measured the concentration and temperature of molecular nitrogen and electrons under various atmospheric conditions during the period approaching solar minimum. A fixed-tuned omegatron mass spectrometer mounted within an orificed chamber was employed for the N2 concentration measurements. The gas temperature was derived from the N2 scale height, and in some cases was measured directly by a velocity scan technique. Cylindrical and hemispherical Langmuir probes were employed for the electron temperature and density measurements. The four launchings were carried out in the afternoon, at sunset, at night, and during the July 20, 1963, solar eclipse. Calculations of energy deposition confirm earlier experimental and theoretical results which show that solar extreme ultraviolet is the major source of electron heating in the daytime F region. This is also clear from the factor of 2 reduction of F-region electron temperature during the eclipse. The heating observed in the E region can be explained only in part by solar X rays and appears to require an additional source such as an electric field. The gas temperatures agree well with theoretical model temperatures, but the model values of N2 concentration appear to be high by about a factor of 2. The flights reveal a temporal variation in N2 concentration in the lower thermosphere which may be either diurnal or seasonal. These variations suggest either large temperature variations below the diffusion level or mass motion phenomena such as winds or tides. Comparison of electron temperature and density data with simultaneous data from Explorer 17 obtained during a flight launched over the satellite shows the measurements to agree among themselves and to be consistent with ionosonde electron density results.