The effect of the magnetization field on molecular interactions of the bioethanol-gasoline fuel blends was investigated. This technique was promoted to escalate both the increase in combustion energy and reduce emissions in the internal combustion engine. The bioethanol and gasoline fuel are used for the single-cylinder four-stroke engine with different mixtures, namely E0, E10, E20, and E30, serially. Distinguish of electromagnetic field strength with various intensity was given into the fuel by lower than 1,500 Gauss. The absorption intensity and the functional groups of the fuel molecules are characterized in detail by Fourier Transform Infra-Red (FTIR) spectroscopy. The exhaust gas emission and the fuel blends energy are performed using a gas analyzer and calorimeter bomb. By increasing the magnetic field, the de-clustering of the fuel molecules is demonstrated by growing the absorption intensity to be advanced. There is no change in the chemical composition of the fuel as the magnetic induction was enforced. Reduction of namely Carbon monoxide (CO), Nitrogen monoxide (NO), Nitrogen oxides (NOx), and Sulphur Dioxide (SO2) gas emissions was attained to be 29 %, 25 %, 26 %, and 31 % using a magnetic field of 1,419.57 Gauss, respectively, compared to gasoline fuel without magnetic condition. The greater reduction occurs by employing E30 fuel with the same magnetic intensity, achieved up to 38 %, 42 %, 70 %, and 63 %, regularly. The magnetization treatment leads to improved combustion quality with efficiency increases up to 11.32 %. It contributes to perfect combustion in a single-cylinder four-stroke engine system. Reducing gas emissions can also bring a good environmental impact in the life, although the heat energy gradually deteriorated as the fuel utilized more bioethanol blends
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