Spectral Range Research Articles

Numerical optimization of cesium tin-germanium triiodide/antimony selenide perovskite solar cell with fullerene nanolayer

SCAPS-1D platform was used to simulate a solar cell with FTO/CdS/Sb2Se3/CuInSe2/Au structure which was recently fabricated by Liu et al. (2022) [1] [Journal of Energy Chemistry68 521–528 (2022)] and a very similar result was obtained. Reported parameters were Fill Factor (FF) = 53.60 %, short circuit current density (JSC) = 26.18 mA/cm2, open circuit voltage (VOC) = 0.37 V, and power conversion efficiency (PCE) = 5.19 %, while simulated parameters were FF of 54.68 %, JSC of 27.54 mA/cm2, VOC of 0.36 V, and PCE = 5.55 %. The advancements have been evaluated by analyzing FTO/CdS/Sb2Se3/CuInSe2/Au and FTO/C60/Sb2Se3/CuInSe2/Au configurations, serving as the reference cells. To improve the cell performance, the CdS layer was replaced with another layer (C60) which shows excellent electron transport properties. Replacing the CdS layer with C60 led to an increase in the power conversion efficiency by 65 % (from 5.55 % up to 9.20 %). In photovoltaic systems, the PCE constitutes a pivotal parameter that can be enhanced through the absorption of a broad spectrum of incident photons. Consequently, the implementation of two absorber layers within a solar cell, each characterized by a graded band gap energy, enables the capture of solar photons over a more extensive spectral range. Therefore, a perovskite containing a band gap of 1.5 eV, lead-free, and Sn-based was used as the second absorber layer in the device. Therefore, a solar cell with FTO/C60/CsSn0.5Ge0.5I3/Sb2Se3/CuInSe2/Au structure was simulated, and significant results were achieved. Results showed that inserting the CsSn0.5Ge0.5I3 layer led to an increase in PCE up to 11.42 %.

The YMDB catalog: Young massive detached binaries for the determination of high-precision absolute stellar parameters

Context. Massive stars play a crucial role in the cosmic dynamics and chemical evolution of galaxies. Despite their significance, our understanding of their evolution and properties remains limited. An accurate determination of stellar parameters, such as the mass and radius, is essential for advancing our knowledge. Detached eclipsing binaries (DEBs) are particularly valuable for these determinations due to the minimal interaction between their stellar components, allowing for precise measurements. Aims. This study aims to introduce the Young Massive Detached Binary (YMDB) catalog, designed to address the gap in the high-precision absolute parameter determination for young massive stars. By focusing on DEBs within the spectral range O9-B1, this catalog seeks to provide a reliable database for future astronomical studies and improve our understanding of massive star evolution. Methods. We conducted a photometric analysis of 87 young massive stars in detached eclipsing systems using TESS light curves (LCs) that were processed through a custom pipeline. This analysis involved determining the amplitude of magnitude variations, orbital periods, times of minima, eccentricities, and the presence of apsidal motion and heartbeat phenomena. A thorough literature review was performed to obtain MK spectral classifications. We performed our own spectral classification of 19 systems to support the sample where a new classification was lacking or inconclusive. Results. The analysis identified 20 previously unreported binary systems, with 13 newly recognized as variable stars. Among the 87 stars examined, 30 are confirmed as YMDB members, and 25 are candidates pending spectral classification. The exclusion of the remaining 32 stars is attributed to unsuitable spectral types or their nondetached binary nature. Notable findings include the identification of new LC classifications, eccentricities in 13 systems, and heartbeat phenomena in several targets. Conclusions. The YMDB catalog offers a resource of high-quality LCs and reliable stellar classifications, serving as a valuable tool for the astronomical community.

Analysis and simulation of opto-electronics characterization of two-dimensional Janus monolayers for energy applications

First-principles simulations are conducted to investigate the absorption and optoelectronic efficacy of molybdenum–sulfur–selenium, referred to here as MoSSe, and molybdenum–sulfur–oxygen, referred to here as MoSO, Janus monolayers. The materials MoSSe and MoSO demonstrate characteristics of semiconductors, as they possess bandgaps of 2.00 eV (direct) and 1.61 eV (indirect), respectively. This property renders them highly suitable for efficient light absorption. The efficiency of absorption of the device was calculated for the MoSSe and MoSO families, leading to the observation that these material families demonstrate a broad absorption range spanning from the infrared to the ultraviolet regions of the electromagnetic spectrum. This finding represents a novel discovery. Furthermore, the design as a topmost cell is particularly attractive due to its exceptional device absorption efficiency and broader bandgap. This particular family ensures that its band edges remain in alignment with the water-redox potentials. Molybdenum sulfide and molybdenum selenide exhibit promising potential as photocatalysts and in optoelectronic device applications. This is attributed to their appealing photocatalytic properties and notable efficiency in absorbing light for the purpose of water splitting.

MAUVE: An Ultraviolet Astrophysics Probe Mission Concept

We present the mission concept “Mission to Analyze the UltraViolet universE” (MAUVE), a wide-field spectrometer and imager conceived during the inaugural NASA Astrophysics Mission Design School. MAUVE responds to the 2023 Announcement of Opportunity for Probe-class missions, with a budget cap of $1 billion, and would hypothetically launch in 2031. However, the formulation of MAUVE was an educational exercise and the mission is not being developed further. The Principle Investigator-led science of MAUVE aligns with the priorities outlined in the 2020 Astrophysics Decadal Survey, enabling new characterizations of exoplanet atmospheres, the early-time light curves of some of the universe’s most explosive transients, and the poorly-understood extragalactic background light. Because the Principle Investigator science occupies 30% of the observing time available during the mission’s 5 yr lifespan, we provide an observing plan that would allow for 70% of the observing time to be used for General Observer programs, with community-solicited proposals. The onboard detector (THISTLE) claims significant heritage from the Space Telescope Imaging Spectrograph on Hubble, but extends its wavelength range down to the extreme UV. We note that MAUVE would be the first satellite in decades with the ability to access this regime of the electromagnetic spectrum. MAUVE has a field of view of 900″ × 900″, a photometric sensitivity extending to m UV ≤ 24, and a resolving power of R ∼ 1000. This paper provides full science and mission traceability matrices for this concept, and also outlines cost and scheduling timelines aimed at enabling a within-budget mission and an on-time launch.

Seeing the light: key inventions that illuminate our world

Abstract In the vast expanse of the electromagnetic spectrum the role of light has been paramount in shaping human civilisation as its applications extend beyond mere illumination. This paper delves into the profound influence of light-based technologies on society, culture and various scientific fields by exploring the understanding of the electromagnetic spectrum and highlighting seminal inventions developed from our understanding of it. Historically the visible spectrum served as humanity’s primary interface with light, giving rise to basic tools like the magnifying glass and the prism. However, the 19th and 20th centuries heralded groundbreaking revelations about the broader spectrum—discovering rays invisible to the naked eye from gamma rays to radio waves. This understanding stimulated technological revolutions, profoundly altering our daily lives and global infrastructures. Prominent inventions such as the radio, televison, X-ray machines, optical fibres and lasers, each harnessing distinct parts of the spectrum, have propelled advancements in communication, medicine, materials and information technology. Additionally light technologies have been pivotal in critical breakthroughs in quantum mechanics, relativity and astrophysics, deepening our understanding of the Universe. Light-based technologies rooted in our evolving comprehension of the electromagnetic spectrum have indelibly impacted our world. From fundamentally altering industries to reshaping daily rituals the influence of light is a testament to humanity’s enduring quest for progress and understanding.

A thorough experimental assessment of THz-TDS plasma diagnostic techniques for nuclear fusion applications.

In this paper, the study of a plasma diagnostic system based on the THz time domain spectroscopy technique is presented. Such a system could potentially probe a large part of the electromagnetic spectrum currently covered by several other diagnostics in a single measurement. This feature, keeping in mind the basic requirements for plasma diagnostics in nuclear fusion experiments, such as robustness and hard environment applicability, as well as durability and low maintenance, makes the diagnostic of great interest. A conceptual design of the THz-TDS diagnostic has been developed, starting from the well-established classical microwave and far infrared plasma diagnostics landscape. The physical constraints and required instrumental characteristics have been studied and are described in detail here, together with the solutions available for each type of plasma measurement. Specific experimental laboratory tests of the different experimental configurations have been carried out, evaluating the capacity and potential of the novel diagnostic, together with the instrumental constraint, within the diagnostic parameter space.

Big Science and the Universe: mega-projects in astronomy

Abstract Astronomy studies the constituents of the Universe and seeks to understand physics at the largest scales. The Universe is the ultimate big physics laboratory – we can observe but not influence. Today Astronomy is a cooperative, international field of ‘Big Science’. Our largest telescopes cost billions of dollars. Each telescope has systems specialised in detecting signals from one part of the electromagnetic spectrum or alternatively, in responding to particle streams or gravitational wave phenomena.

SERS activity of silver nanoparticles and silver-modified 2D graphitic carbon nitride towards ciprofloxacin drug

Herein, silver nanoparticles (AgNPs) and silver-loaded graphitic carbon nitride (Ag@g-C3N4) nanocomposites have been synthesized and used as an effective surface-enhanced Raman scattering (SERS) substrates for the detection of low concentrations (10-14 M) of ciprofloxacin (CIP), a commonly bioactive medication used to treat bacterial illnesses. A combined approach of vibrational spectroscopy and density functional theory (DFT) has been developed to understand the possible modes of analyte (CIP) and SERS substrate (AgNPs and Ag@g-C3N4) interactions. Furthermore, it has been noticed that the behavior of drug molecules in terms of SERS response and energetics of interaction changed significantly when interacted with the noble metal AgNPs decorated onto the g-C3N4 framework in comparison to only AgNPs as substrate. The most prominent interaction scenario between AgNPs and CIP is likely to be through the –NH moiety of drug molecule with an interaction energy of −306 kcal/mol. Whereas, the CIP molecules adsorbed onto Ag@g-C3N4 nanocomposite were more flexible with interaction energy of −107 kcal/mol, suggesting a greater association of analyte with the skeletal modes of substrate leading to Raman enhancements in the low wavenumber region i.e. below 600 cm−1. Hence, the Ag@g-C3N4 nanocomposite-based SERS substrates investigated served two distinct spectral ranges, making them complementary of each other in terms of SERS detection of CIP. The characteristics of the computed frontier molecular orbitals indicated a pronounced amount of charge transfer between the drug and the substrate, highlighting the significance of the chemical mechanism of the overall process. These results represent a successful approach to have an extended spectral range that covers lower wavenumber shifts by applying simple and meaningful modifications to the normally utilized noble metal-based nanoparticles, which can lead to more effective and reliable detection of bioactive drugs.

Tunability of plasmonic resonances in stratified hyperbolic metamaterials

We numerically and experimentally demonstrate the tunability of plasmonic resonances in the spectral range from 550 nm to 900 nm for type II hyperbolic metamaterials, as a function of their number of layers, period, and filling fraction. The type II hyperbolic metamaterial consisted of stratified periodic arrays of gold and titanium dioxide thin layers on top of a glass substrate. Through numerical and experimental characterization of the totally internally reflected spectra as a function of incidence angle, we show that the tunability of the plasmonic resonance mainly depends on the filling fraction, while the number of layers and the period of the structure only affect the contrast of attenuated reflected spectra. In addition to demonstrating the capability of tuning plasmonic resonances in simplistic stratified mediums, this work contributes to the understanding of light interaction with hyperbolic metamaterials for the improvement of optical devices for sensing applications.

Enhanced solar hydrogen evolution by laminated integration of n+p-SiIP/TiO2/Pt inverted pyramid black Si photocathode

The nano/microstructuring of silicon (Si) via chemical methods has garnered significant attention due to its excellent light-trapping capabilities across a wide spectral range. Current research has predominantly focused on the synthesis of pyramidal-shaped microtextures, which enable two reflections on the surface, while largely overlooking the superior light-trapping potential of inverted pyramid silicon (SiIP) microtextures, which theoretically allow for three reflections. Moreover, there has been limited investigation into the application of inverted pyramid black silicon for solar-driven hydrogen evolution. This study reports the synthesis of uniformly arranged inverted pyramid-textured black silicon using the copper-assisted chemical etching (Cu-ACE) method to enhance the efficiency of solar-driven water splitting for hydrogen production. The formation mechanism and the influence of copper-localized surface plasmon resonance (Cu-LSPR) from Cu nanoparticle (NP) byproducts on photoelectrochemical (PEC) activity were systematically analyzed. To reduce sidewall defects and minimize photogenerated carrier recombination, the surface of the SiIP was treated with tetramethylammonium hydroxide (TMAH). A vertical PN junction was developed through ion implantation to reduce the external bias of the SiIP. Additionally, a uniform TiO₂ antireflective layer was deposited via atomic layer deposition (ALD), reducing the average reflectance of the SiIP-T4 to 5.78 % over the 300–1100 nm wavelength range. MoSₓ and Pt NPs were electrodeposited to improve the fill factor and enhance HER kinetics. With optimized catalyst loading, the n+p-SiIP-T4/TiO₂/Pt 80 mC electrode achieved a photocurrent density of 8.0 mA cm−2 at 0 V vs. RHE, an applied bias photon-to-current efficiency (ABPE) of 0.93 % at 0.24 V vs. RHE, and a double-layer capacitance (Cdl) of 91 μF cm−2. The onset potential (Von) was positively shifted by ∼1.13 V to 0.49 V vs. RHE compared to a SiIP photocathode, and the photocathode operated continuously at 0 V vs. RHE for 27 h in an acidic electrolyte. These results demonstrate that SiIP has significant potential for PEC hydrogen evolution, with further performance optimization achievable through structural and surface engineering.

High-sensitivity and wide-range refractive index sensing based on the envelope spectrum of the subwavelength grating waveguide racetrack microring resonator.

Integrated microring resonators (MRRs) on silicon on insulator (SOI) are attractive candidates for excellent performance sensing systems. In this work, a novel, to the best of our knowledge, subwavelength grating waveguide racetrack microring resonator (SWGW-RMRR) on SOI with high-sensitivity and wide-range refractive index (RI) sensing is proposed and demonstrated experimentally. Owing to the exceptional evanescence field of the Bloch mode for the SWGW, the SWGW-RMRR provides highly sensitive RI sensing. Meanwhile, the SWGW-RMRR makes the free of free spectral range (FSR) limitation on the detection range (DR) by monitoring the envelope spectrum. By combining the advantages of the evanescent field and envelope spectrum, a SWGW-RMRR sensor has been demonstrated with a RI sensitivity of 860.8 nm/RIU, a limit of the detection value of 1.9 × 10-5 RIU, and a wide range of detection range. The measured Q-factor of the SWGW-RMRRs with an 88.8 µm total cavity length is 6200. This work can successfully realize high-sensitivity and wide-range RI sensing, showing the promising applications of silicon photonics sensors on chips.

On the impact of the vertical structure of Martian water ice clouds on nadir atmospheric retrievals from simultaneous EMM/EXI and TGO/ACS-MIR observations.

Retrieving the optical depth of the Martian clouds (τcld) is a powerful way to monitor their spatial and temporal evolution. However, such retrievals from nadir imagery rely on several assumptions, including the vertical structure of the clouds in the atmosphere. Here we compare the results of cloud optical depth retrievals at 320 nm from the Emirates eXploration Imager (EXI) onboard the Emirates Mars Mission (EMM) “Hope” orbiter performed using a basic uniform cloud profile used in previous studies and using derived cloud profiles obtained from near-simultaneous Solar Occultation observations in the 3.1–3.4 μm spectral range from the Middle-Infrared channel of the Atmospheric Chemistry Suite (ACS) instrument onboard the ESA Trace Gas Orbiter (TGO). We show that the latitudinal dependence of the cloud vertical profiles can have a strong impact on the nadir retrievals; neglecting it can lead to a significant underestimation of τcld in the polar regions (up to 25 % to 50 %, depending on the vertical distribution of the dust in the atmosphere) and to a lesser extent, to an overestimation of τcld around the equator. We also discuss the impact of a vertically-dependent particle size profile, as previous studies have shown the presence of very small water ice particles at the top of the clouds. From this analysis, we provide recommendations for the improvement of water ice cloud parameterization in radiative transfer algorithms in nadir atmospheric retrievals.

Horizontal aluminum magneto-plasmonic metasurface for efficient magneto-optical Kerr modulation and sensing in the ultraviolet range.

Most of the plasmonic nanostructures utilized for magneto-optical (MO) enhancement have been limited to noble metals with resulting enhancement in the visible and infrared spectral range. Here, we designed a horizontal aluminum magneto-plasmonic metasurface, with the ability to control the Kerr rotation angle and enhance the RI sensing performance based on magneto-plasmons, by exploiting the polarization degree of freedom in the ultraviolet range. The surface composes of L-shaped magnetic dielectric embedded in the Al film. The reflection spectrum and the Kerr rotation angle map are both symmetric about the polarization angle of 45° and 135°. It is demonstrated that the sign change of the two maximal Kerr rotation angles at polarization angle of 0° and 90°, originates from the relative contribution of the two mutually orthogonal oscillating electric dipoles. In addition, the RI sensing FoM based on Kerr reversal at 372 nm of this structure reaches 5000/RIU, which is superior to the result in the visible or infrared range (1735/RIU). The results of our investigation demonstrate the potential of Al-based magneto-plasmonic effect and offer opportunities to push the MO spectral response out of the visible range into the ultraviolet range.

LUMINESCENCE CHARACTERISTICS OF CASO4:TB,M (M=NA,K,RB) PHOSPHORS

In the present study, the investigation of complex luminescence terbium centres as well as the analysis of technological features of the synthesis of small-grained wide-gap CaSO :Tb3+ anhydrite phosphors containing 1% of Tb3+ and some amount of additional impurity ions (Na+, K+, Rb+) have been continued using the methods of optical and thermoactivation spectroscopy. Of particular interest was a contribution of calcium ions into formation of complex luminescence centres. Ca causes efficient dynamic hybridization of electronic states and influence on the formation of terbium and near-terbium electronic excitations. The excitation spectra of Tb3+-centre emission have been measured in the VUV spectral range at 77 or 300 K. The excitation band related to the lowest f–d transition of Tb3+ ions at ≈5.9 eV in CaSO4 undergoes broadening toward the long- wavelength side, when the radius of a charge compensator increases (K+→ Rb+). The band at 7.5–9 eV ascribed to the excitation of oxyanions has a different shape in CaSO4:Tb,K and CaSO4:Tb,Rb. Thermally stimulated luminescence (80–700 K) have been analyzed for a set of anhydrite phosphors previously irradiated by X-rays at 80 and 300 K. Keywords: CaSO , Tb3+, photoluminescence, thermoluminescence, vacuum ultraviolet spectroscopy.

Exploring the categorical nature of colour perception: Insights from artificial networks

The electromagnetic spectrum of light from a rainbow is a continuous signal, yet we perceive it vividly in several distinct colour categories. The origins and underlying mechanisms of this phenomenon remain partly unexplained. We investigate categorical colour perception in artificial neural networks (ANNs) using the odd-one-out paradigm. In the first experiment, we compared unimodal vision networks (e.g., ImageNet object recognition) to multimodal vision-language models (e.g., CLIP text-image matching). Our results show that vision networks predict a significant portion of human data (approximately 80%), while vision-language models account for the remaining unexplained data, even in non-linguistic experiments. These findings suggest that categorical colour perception is a language-independent representation, though it is partly shaped by linguistic colour terms during its development. In the second experiment, we explored how the visual task influences the colour categories of an ANN by examining twenty-four Taskonomy networks. Our results indicate that human-like colour categories are task-dependent, predominantly emerging in semantic and 3D tasks, with a notable absence in low-level tasks. To explain this difference, we analysed kernel responses before the winner-takes-all stage, observing that networks with mismatching colour categories may still align in underlying continuous representations. Our findings quantify the dual influence of visual signals and linguistic factors in categorical colour perception and demonstrate the task-dependent nature of this phenomenon, suggesting that categorical colour perception emerges to facilitate certain visual tasks.

Optical properties of transition metals complex films derived from hydrazone oxime for optoelectronic devices

Hydrazone incorporating oxime nucleus and its Ni2+, Mn2+, Zn2+ and UO22+ metallic chelates have been prepared and completely characterized by different spectral, theoretical, and analytical techniques including NMR, FT-IR, mass, and EAS spectroscopy. The finding denoted that the Hydrazone ligand bonded as a dibasic tridentate chelator via deprotonated oximato nitrogen, enol carbonyl oxygen and hydrazono azomethine nitrogen atoms resultant in octahedral geometry for Ni2+, Mn2+, Zn2+ and UO22+. Theoretical studies by DFT/B3LYP/LANLDZ together with dipole moment, geometrical optimization, energetic parameters, and energy gap (HOMO–LUMO) were employed to support the geometrical structure of the synthetics. Additionally, these complexes were prepared in the form of thin film onto cleaned glass substrate by spin-coating technique. The values of the optical band gap (Eg) and film index of refraction (n) have been determined by many different methods. It was found that the hydrazone-oxime (OBBH2) film has the highest value of Eg (eV) where the UOBB complex film has the smallest value of Eg (2.56 eV). The latter is very close to the Eg value of ZnSe (2.58 eV). The refractive index changes with wavelengths show normal dispersion which is well discussed in terms of Sellmeier's dispersion model. Also, the nonlinear optical parameters viz. the first (χ(1)) and third (χ(3)) orders of nonlinear optical susceptibilities and the non-linear index of refraction (n2) have been studied. The complex dielectric constant (ε⌣=εr+iεi)), conductivity (σ⌣=σr+iσi), sheet resistance (Rs), and thermal have been investigated over the whole spectral range. According to the results of χ(1), χ(3) and n2 the complex films under study are candidates to be used in optical switching gadgets, optical modulators, and optical signal processing.

Enhanced Photothermal-Assisted Hydrogen Production via a Porous Carbon@MoS2/ZnIn2S4 Type II-S-Scheme Tandem Heterostructure.

MoS2/ZnIn2S4 flower-like heterostructures into porous carbon (PC@MoS2/ZIS) are embedded. This ternary heterostructure demonstrates enhanced light absorption across a broad spectral range from 200 to 2500nm. It features both Type-II and S-scheme dual heterojunction interfaces, which facilitate the generation, separation, and transfer of photoinduced carriers. The PC enveloped by MoS2/ZIS composite microspheres serves as a photothermal source, providing additional energy to the carriers. This process accelerates charge separation and migration, enhancing photothermal-assisted photocatalytic H2 evolution. The optimal H2 evolution rate for PC@MoS2/ZIS reaches an impressive 18.79mmolg-1h-1, with an apparent quantum efficiency of 14.1% at 400nm. This work presents a promising approach for effectively integrating multicomponent heterostructures with photothermal effects, offering innovative strategies for efficient solar energy utilization and conversion.

Measurement and assignment of J = 5 to 9 rotational energy levels in the 9070-9370cm-1 range of methane using optical frequency comb double-resonance spectroscopy.

We use optical-optical double-resonance spectroscopy with a continuous wave (CW) pump and a cavity-enhanced frequency comb probe to measure the energy levels of methane in the upper part of the triacontad polyad (P6) with higher rotational quantum numbers than previously assigned. A high-power CW optical parametric oscillator, tunable around 3000 cm-1, is consecutively locked to the P(7, A2), Q(7, A2), R(7, A2), and Q(6, F2) transitions in the ν3 band, and a comb covering the 5800-6100cm-1 range probes sub-Doppler ladder-type transitions from the pumped levels with J' = 6 to 8, respectively. We report 118 probe transitions in the 3ν3 ← ν3 spectral range with uncertainties down to 300kHz (1 × 10-5cm-1), reaching 84 unique final states in the 9070-9370cm-1 range with rotational quantum numbers J between 5 and 9. We assign these states using combination differences and by comparison with theoretical predictions from a new abinitio-based effective Hamiltonian and dipole moment operator. This is the first line-by-line experimental verification of theoretical predictions for these hot-band transitions, and we find a better agreement of transition wavenumbers with the new calculations compared to the TheoReTS/HITEMP and ExoMol databases. We also compare the relative intensities and find an overall good agreement with all three sets of predictions. Finally, we report the wavenumbers of 27 transitions in the 2ν3 spectral range, observed as V-type transitions from the ground state, and compare them to the new Hamiltonian, HITRAN2020, ExoMol, and the WKMLC line lists.

Spectroscopic ellipsometry investigation of a 6H–SiC single crystal plate for potential use in graphene optoelectronic devices

At room temperature, the spectroscopic ellipsometry SE parameters Epsi (ψ) and Delta (Δ) for 6H–SiC crystal substrate were measured in the wavelength range 350–1700 nm at four different angles of incidence, 60°, 65°, 70°, and 75°. An SE model was developed to extract optical consents of 6H–SiC crystal substrate from the experimentally measured SE parameters. In the wavelength range 350–1700 nm, the refractive index of the 6H–SiC crystal substrate was extracted and fitted to two terms of the Sellmeier dispersion function. In the wide spectral range (350–1700 nm), the Wemple-DiDomenico (WDD) dispersion model shows how the real refractive index changes with wavelength. The analysis of refractive index dispersion of the 6H–SiC crystal substrate using Sellmeier dispersion function and WDD optical model allows to extract oscillator strength Nfij, average oscillator energy Eo, dispersion energy of the single oscillator Ed, lattice oscillator strength El, Abbe dispersion number, energy gap Eg, density of valence electrons nv, refractive index at infinite wavelength n∞, lattice dielectric constant εL, the ratio of free carrier density to free carrier effective mass (N/m∗), and plasma frequency ωp. For the 6H–SiC crystal substrate, in the desired spectral range (240–1700 nm), it does not have any depolarization effect on the reflected polarized light.

Critical current density of high-temperature superconducting ceramics BSCCO Bi-2223

In the paper the results of the study on the synthesis of high-temperature superconducting ceramics of nomi- nal composition Bi1.6Pb0.4Sr2Ca2Cu3Oy by various methods were presented based on amorphous phases using glass-ceramic technology and solid-phase method. For comparison, amorphous phases were obtained in two ways. In the first case, a heating furnace of a special design was developed to obtain an amorphous phase, which provides melting without using a crucible. The heating of the initial samples for melting is carried out due to the combined effect of the convection heat flux and the radiation of heating elements, which consists of the IR region of the spectrum at a melting temperature in the spectral range of 1300–1350 nm. In the se- cond case, melting is carried out under the influence of broadband optical radiation, including UV, visible and IR spectral regions. The production of glassy precursors is carried out by draining the melt onto a quenching device in the form of a propeller made of stainless steel. Studies of the formation rate of the superconducting high-temperature phase Bi-2223 were carried out in the same temperature conditions at 848–850 °C with in- termediate grinding every 24 hours and the study of the phase composition by X-ray diffraction method. Studies showed that the glass phase-based method ensures the completeness of the formation of the high- temperature phase Bi-2223 and the rate of its formation is significantly higher than by the solid-phase method (2.5–3 times). Studies of the critical density of the transport current have shown that the current value is 7.05×103 mA/cm2, (measured by the criterion of 1 µV/cm), which is significantly higher compared to other methods.