Electromagnetic Waves Research Articles

Construction of cobalt zinc metal-organic frameworks derived Co/CoO/C composites toward broadband and high-efficiency electromagnetic wave absorption

The fabrication of novel carbon-based electromagnetic wave (EMW) absorbers with broad absorption bandwidth, strong absorption strength, low filler loading ratio and thin matching thickness remains a challenging task. Metal-organic frameworks (MOFs) are widely recognized as ideal self-sacrificial templates for the construction of carbon-based EMW absorbers. In this work, bimetallic CoZn-MOFs derived Co/CoO/C composites were prepared by combining magnetic stirring with subsequent pyrolysis treatment. The results showed that the morphology of carbon skeletons evolved from an irregular agglomerate to a uniform hexagonal star shape and then to an agglomerate again by reducing the molar ratio of Co2+ to Zn2+. Remarkably, excellent EMW absorption capacity in the Ku-band was achieved through carefully regulating the molar ratio of Co2+ to Zn2+. When the filling ratio was 20wt.%, the prepared Co/CoO/C composite exhibited the best EMW absorption performance with the minimum reflection loss of -64 dB at a thickness of 1.79mm and the maximum effective absorption bandwidth of 6GHz at a thickness of 2.14mm. Furthermore, the radar cross section in the far-field was simulated by computer simulation technique. In addition, the possible EMW attenuation mechanism was proposed. Therefore, the results of this paper could be helpful for developing carbon-based magnetic composites derived from MOFs as broadband and high-efficiency EMW absorbers.

Electromagnetic absorption properties of composite mortar with graphene and manganese-zinc ferrite

Electromagnetic wave absorption of building structures plays a crucial role in safeguarding information and mitigating electromagnetic radiation. This study delves into the absorption capabilities of composite mortar made with graphene (GR) and manganese-zinc ferrite (MFO) across frequencies of 1−18 GHz. The mechanical strength, microstructural examinations, and numerical simulations to elucidate the underlying mechanisms of wave absorption in the composite mortar are investigated. The results indicate that incorporating 30% MFO reduces the strength of mortar due to its low bonding capacity and diluting effects, whereas GR enhances the strength of mortar by facilitating cement hydration. Electromagnetic examinations reveal that MFO boosts the magnetic loss performance, while GR augments dielectric loss properties. In addition, the presence of needle, rod, mesh, and flake hydration products in the pores of composite mortar also contributes to increased wave depletion. According to the simulation of electromagnetic absorption based on the finite difference time domain (FDTD) method, the composite mortar with GR and MFO exhibits a superior performance of electromagnetic wave absorption. With the 25 mm thickness of composite mortar with 30% MFO, an absorption below -10 dB, covering a bandwidth of 1.68−4.34 GHz are obtained, with a peak reflection loss of -22.13 dB at 3.23 GHz. Thus, by combination magnetic loss of MFO, dielectric loss of GR, and the reflective capabilities of porous mortar, a composite mortar with a better electromagnetic wave absorption can be achieved.

Synergistic dielectric and magnetic effects boosting electromagnetic wave absorption in Flower-Ball-like VSe2@CoFe2O4 composites

Designing absorbers with an electromagnetic synergistic effect is one of the most appropriate ways to achieve efficient electromagnetic absorption. In this research, VSe2@CoFe2O4 composites are created by incorporating magnetic ferrite CoFe2O4 particles adhered to 2D VSe2 nanosheets to generate a distinct flower-ball-like structure. The electromagnetic wave absorption properties of the composites can be meticulously calibrated by manipulating the proportion of CoFe2O4 to VSe2. In the optimal ratio, the minimum reflection loss of VSe2@CoFe2O4 is −65.39 dB and the effective absorption bandwidth is 5.7 GHz. Furthermore, an enlarged EAB to 6.37 GHz can be observed by increasing the mass of CoFe2O4. Theoretical approaches including first-principles calculation and far-field simulation are employed to comprehensively elucidate the microwave absorption mechanism and effect. The study provides profound insights into collaborative dielectric-magnetic composites for electromagnetic wave absorption engineering.

Synthesis of nano-diamond modified Ti3C2Tx MXene heterostructure for enhanced electromagnetic wave absorption

The highly efficient electromagnetic wave (EMW) absorption materials are considered a promising approach to combatting electromagnetic radiation pollution. We synthesized a novel heterostructure 2D Ti3C2Tx MXene composite film modified by 0D nano-diamond (ND) particles using simple mechanical stirring and a vacuum filtration method. Subsequently, we investigated its microstructure and EMW absorption properties. The ND modification not only regulated the impedance matching of the composite films but also enhanced the diversity of EMW losses, demonstrating excellent microwave absorption performance. With a 40 wt% ND content, the minimum reflection loss (RLmin) of the films reached −43.0 dB, corresponding to a film thickness of 2.5 mm. This study explored a novel and promising microwave absorption film, expanding the application of diamond in microwave absorption, and addressing the theoretical gap in diamond-enhanced MXene microwave absorption performance.

Chain-arranged Ni1-xCox micro/nano particles prepared via a magnetic field-assisted reduction for enhanced electromagnetic wave absorption

Transition metal magnetic alloys have garnered extensive interests in electromagnetic wave absorption due to the remarkable magnetic loss capacity and unique magnetism-frequency characteristics. Herein, we report a novel magnetic absorbent of Ni1-xCox micro chains that synthesized through a magnetic field-assisted reduction method. The precipitated Ni1-xCox particles could be connected and aligned during the magnetic reduction process. Due to the modified electronic structure of the Co active site by Ni, the particle size in the Ni1-xCox micro chains noticeably increases with increased x. Meanwhile, the complex dielectric constants exhibit a decreasing trend, which contributes to the improved impedance matching and higher resonance frequencies. The connected Ni1-xCox micro/nano particles not only benefit to the conductive loss, but also strengthened the polarization loss on the contacted interfaces among the particles. As a result, significantly enhanced electromagnetic wave absorption performance was obtained with the minimum reflection loss of −21.0 dB and the effective absorption bandwidth of 3.92 GHz at a thickness of only 1.35 mm. Overall, this work has demonstrated the strategy of designing aligned bimetallic absorbent, possessing great potentials in improving their microwave absorption properties.

Enhanced microwave absorption using multiple heterostructures derived from in-situ grown Sn-metal-organic framework on La-doped Fe3O4

As a representative magnetic oxide absorber, Fe3O4 has attracted considerable research attention owing to its remarkable magnetic saturation strength as well as semiconducting properties. Doping Fe3O4 with La3+ leads to 3d-4f magnetic coupling and ion distribution changes due to the unique electron configuration and large ionic radius of La3+, thereby greatly enhancing the magnetic performance. However, high density, low dielectric loss, and low permeability at high frequencies inhibit the electromagnetic wave absorption (EMWA) performance of ferrites. In this study, stick-shaped Sn metal-organic framework (MOF) is in-situ grown on La3+-doped Fe3O4 using a surfactant. After high-temperature annealing, the SnO2/porous carbon composites derived from Sn-MOF wrap the ferrite, forming a core-shell heterostructure, which not only prevents oxidation but also enhances the EMWA performance. Among the prepared LaxFe3-xO4/SnO2/C (LFSC) samples, LFSC-2 (with LaxFe3-xO4 to Sn-MOF ratio of 1:2) exhibits strong absorption performance with a minimum reflection loss (RLmin) of −44.1 dB. Furthermore, the gradient metamaterial based on LFSC-3 shows ultra-broadband EMWA with an effective absorption bandwidth (RLmin ≤ −10 dB) of 13.17 GHz. In addition, the LFSC-2 sample demonstrates excellent radar stealth capability in the radar cross section (RCS) far-field response, achieving an RCS reduction value of 20.4 dB·m2.

Mode Measurement of Vortex Electromagnetic Wave With Random Receiving Array Element Defects via Low Rank Matrix Completion

Mode Measurement of Vortex Electromagnetic Wave With Random Receiving Array Element Defects via Low Rank Matrix Completion

Simultaneously enhancing the EMI shielding performances and mechanical properties of structure–function integrated CF/PEEK composites via chopped ultra-thin carbon fiber tapes and interfacial engineering with MXene

The functionalization of carbon fiber reinforced poly(ether-ether-ketone) (CF/PEEK) structural composites with high electromagnetic interference shielding efficiency (EMI SE) has important engineering application in the fields of aviation and aerospace. However, the simultaneous enhancement of interfacial properties and EMI SE in the CF/PEEK composite remains a significant concern. To address this issue, we have employed a continuous impregnation approach that involved synthesizing PFEEK as a binder and then utilizing mechanical spreading technology to prepare chopped ultra-thin CF tapes as the reinforcement phase. Subsequently, we deposited 2D MXene (Ti3C2Tx) on the CF tape surface to endow the interface properties and EMI SE for the CF/PEEK composites. As a result, when the MXene content was 1.0 mg/ml, the flexural strength, flexural modulus, and interlaminar shear strength (ILSS) of the obtained CF/PEEK composites achieved 17.6 %, 13.3 % and 36.6 % enhancement higher than that of the virgin CF/PEEK composites, respectively, which may be owing to the elevated interfacial properties via the hydrogen bonds, physical entanglement, π-π interactions, and mechanical interlocking with the incorporation of PFEEK and MXene. The optimal ILSS value and specific EMI SE/t value of the CF/PF-M1/PEEK composites can reach 113.7 MPa and 80.8 dB/mm, respectively. The enhancement in the EMI SE can be attributed to the enhancive reflection, the increased polarization losses, and multiple interlayer reflections of EM waves facilitated by the incorporation of MXene and multi ultra-thin CF/PF-MXene layers. This approach resulted in a structure–function integrated CF/PEEK composite, which holds promising application prospects across various cutting-edge domains.

Electromagnetic frequency prediction pattern for electrical circuited shell based on FSTT theory using electromagnetic wave prediction method

This research focuses on electromagnetic analysis of electrical circuited shell to predict possible failure using wave prediction method. The equation is established considering axial and lateral hydrostatic pressure based on first order shear deformation theory of shell motion using the wave propagation approach and classic Flügge shell equations. For validation of accuracy of this research method, a comparison carried out with experimental data. With this method the effects of circuit parameters as well as different t power-law exponent on the frequencies are investigated. The results showed fantastic agreement between the present method and experimental ones.

Enhanced Electromagnetic Energy Conversion in an Entropy‐driven Dual‐magnetic System for Superior Electromagnetic Wave Absorption

AbstractThermochemical conversion is a highly effective method for upgrading organic solid wastes into high‐value materials, contributing to carbon neutrality and peak, carbon emission goals. It also serves as a pathway to develop energy‐efficient electromagnetic wave absorbing (EMWA) materials. In this study, fish skin to successfully in situ nitrify Prussian Blue into Fe3N under external thermal driving condition, resulting in high saturation magnetization is utilized. The resulting Fe3N@C demonstrates outstanding EMWA property, achieving a minimum reflection loss of −71.3 dB. Furthermore, by introducing cellulose nanofiber, a portion of the iron nitride is transformed into iron carbide, resulting in Fe3C/Fe3N@C. This composite exhibits enhanced EMWA properties owing to wider local charge redistribution and stronger electronic interactions, achieving an effective absorption bandwidth (EAB) of 6.64 GHz. Electromagnetic simulations and first‐principles calculations further elucidate the EMWA mechanism, and the maximum reduction value of the radar‐cross section reached 37.34 dB·m2. The design of multilayer gradient metamaterials demonstrated an ultra‐broadband EAB of 11.78 GHz. This paper presents an efficient strategy for atomic‐level biomass waste utilization to prepare Fe3N, provides novel insights into the conversion between metal nitrides and metal carbides, and offers a promising direction for the development of advanced EMWA materials.

4D-printed intelligent reflecting surface with improved beam resolution via both phase modulation and space modulation

Recently, intelligent reflecting surfaces (IRSs) have emerged as potential candidates for overcoming the line-of-sight issue in 5 G/6 G wireless communication. These IRSs can manipulate the direction of reflected beams, enabling efficient beam steering to enhance the performance of wireless communication. Each unit cell (or unit structure) of an IRS commonly consists of electrical elements for phase modulation. However, by employing phase modulation alone, an IRS can steer the reflected electromagnetic waves toward only discrete and specific angles, leaving a wide range of out-of-beam areas. In this work, an IRS that uses both phase modulation and space modulation is presented to improve the beam resolution and continuously cover out-of-beam areas that phase modulation alone cannot address. A positive-intrinsic-negative diode is mounted on a unit cell for phase modulation, and a 4D-printed reconfigured structure is fabricated to demonstrate space modulation. The beam-steering function is achieved by alternating the states of the diodes in the same columns, while the beam resolution is improved by controlling the gaps between the columns. The functions are first theoretically and numerically analyzed and then experimentally verified, demonstrating that additional angles of −46°/+50°, −22°/+14°, and −16°/+12° are achieved with space modulation and −60°/+62°, −30°/+22°, and ±16° are achieved by phase modulation alone. The proposed IRS offers the possibility of functional integration in a variety of indoor applications within the wireless communication field.

Graphene pixel based broadband polarization insensitive THz absorber

Abstract Suppressing undesired radiation and eliminating stray radiation in a high-frequency circuit might be challenging. Ultra-high frequency (UHF) electromagnetic wave absorbers are finding new applications in both the military and civilian domains. Obtaining an ultra-wide absorption band in a thin, single-layer Terahertz absorber becomes difficult. Also, achieving perfect absorption bandwidth on transverse electric (TE) and transverse magnetic (TM) mode is very sensitive. This paper presents a polarization-independent graphene-based absorbers with a near unity absorption band of 2.32 THz and 3.78 THz in a lower mid-infrared regime. The structure’s unit cell consists of cross-slot circular patches with Au as a ground separated by SiO2. To improve the absorption band another graphene layer was placed between the top and dielectric material. The absorber is polarization independent under normal incidence because of the deposited graphene structure’s fourfold symmetry. Both TE and TM polarizations were investigated, with wide-band absorption observed up to 60° incident angles in both cases. In terms of the lowest frequency of absorption, the prototype is deemed to be as thin as ∼ 0.1 λ max for both absorbers. Similarly, the effective homogeneity criteria in the subwavelength region are supported by the unit cell’s period of ∼ 0.1 λ max . The proposed absorber-2 shows 10 % higher FBW than existing work.

Does radiofrequency radiation impact sleep? A double-blind, randomised, placebo-controlled, crossover pilot study

The most common source of Radiofrequency Electromagnetic Field (RF-EMF) exposures during sleep includes digital devices, yet there are no studies investigating the impact of multi-night exposure to electromagnetic fields emitted from a baby monitor on sleep under real-world conditions in healthy adults. Given the rise in the number of people reporting to be sensitive to manmade electromagnetic fields, the ubiquitous use of Wi-Fi enabled digital devices and the lack of real-world data, we investigated the effect of 2.45 GHz radiofrequency exposure during sleep on subjective sleep quality, and objective sleep measures, heart rate variability and actigraphy in healthy adults. This pilot study was a 4-week randomised, double-blind, crossover trial of 12 healthy adults. After a one-week run-in period, participants were randomised to exposure from either an active or inactive (sham) baby monitor for 7 nights and then crossed over to the alternate intervention after a one-week washout period. Subjective and objective assessments of sleep included the Pittsburgh Insomnia Rating Scale (PIRS-20), electroencephalography (EEG), actigraphy and heart rate variability (HRV) derived from electrocardiogram. Sleep quality was reduced significantly (p < 0.05) and clinically meaningful during RF-EMF exposure compared to sham-exposure as indicated by the PIRS-20 scores. Furthermore, at higher frequencies (gamma, beta and theta bands), EEG power density significantly increased during the Non-Rapid Eye Movement sleep (p < 0.05). No statistically significant differences in HRV or actigraphy were detected. Our findings suggest that exposure to a 2.45 GHz radiofrequency device (baby monitor) may impact sleep in some people under real-world conditions however further large-scale real-world investigations with specified dosimetry are required to confirm these findings.

Phonon polariton-mediated heat conduction: Perspectives from recent progress

AbstractIt has been well-accepted that heat conduction in solids is mainly mediated by electrons and phonons. Recently, there has been a strong emerging interest in the contribution of various polaritons, quasi-particles resulting from the coupling between electromagnetic waves and different excitations in solids, to heat conduction. Traditionally, the polaritonic effect on conduction has been largely neglected because of the low number density of polaritons. However, it has been recently predicted and experimentally confirmed that polaritons could play significant roles in heat conduction in polar nanostructures. Since the transport characteristics of polaritons are very different from those of electrons and phonons, polariton-mediated heat conduction provides new opportunities for manipulating heat flow in solid-state devices for more efficient heat dissipation or energy conversion. In view of the rapid growth of polariton-mediated heat conduction, especially by phonon polaritons, here we review the recent progress in this field and provide perspectives for challenges and opportunities. Graphical abstract

Bamboo-Based Carbon/Co/CoO Heterojunction Structures Based on a Multi-Layer Periodic Matrix Array Can Be Used for Efficient Electromagnetic Attenuation

With the popularization of wireless communication, radar, and electronic devices, the hidden harm of electromagnetic radiation is becoming increasingly serious. The design of green biomass carbon-based interface heterojunctions based on lightweight porous materials can effectively protect against electromagnetic radiation hazards. In this work, we constructed an anisotropic heterojunction interface with magnetic and dielectric coupling based on a honeycomb-like periodic matrix multi-layer array repeating unit. The removal of lignin components from bamboo through oxidation enriches the impregnation pores and uniform adsorption sites of the magnetic medium. Further, in situ pyrolysis promotes the formation of a large number of electric dipoles at the interface between the magnetic medium and dielectric coupling inside the periodic cell carbon skeleton, enhancing interface polarization and relaxation. Local carrier traps and uneven electromagnetic density enhance dielectric and hysteresis losses, resulting in excellent impedance matching. Therefore, the obtained bamboo-based carbon multiphase composite absorbent has satisfactory electromagnetic loss characteristics. At a thickness of 1.55 mm, the effective absorption bandwidth reaches 5.1 GHz, and the minimum reflection loss (RL) value reaches −54.7 dB. In addition, the far-field radar simulation results show that the sample has an excellent RCS (radar cross-section) reduction of 33.3 dB·m2. This work provides new directions for the diversified development of green biomass and the optimization of the design of magnetic and dielectric coupling in periodic array structures.

Experimental and numerical validation of tape-based metasurfaces in guiding high-frequency surface waves for efficient power transfer

We present an effective method for transmitting electromagnetic waves as surface waves with a tape-based metasurface design. This design incorporates silver square patches periodically patterned on an adhesive tape substrate. Specifically, our study proposes a strategy to enhance the efficiency of power transfer in high-frequency bands by guiding signals as surface waves rather than free-space waves. Both the numerical and experimental results validate the markedly enhanced efficiency in power transfer of high-frequency signals compared to that achieved with conventional methods, such as wireless power transfer and microstrips. Importantly, our metasurface design can be readily manufactured and tailored for various environments. Thus, our study contributes to designing power-efficient next-generation communication systems such as 6G and 7G, which leverage high-frequency signals in the millimeter-wave and terahertz bands.

Research on wireless channel model based on improved ray tracing algorithm that considers multiple diffuse scattering and employs pyramid-shaped ray tubes as the carrier

This paper extensively utilizes fine three dimensional environmental data obtained from laser point clouds. Based on theories such as geometrical optics and effective roughness theory, a deterministic wireless channel model is established, which integrates higher-order diffuse scattering. This model is referred to as the ray tracing fusion with higher-order diffuse scattering model. To expedite the collision calculation between rays and the scene, this paper introduces a combined approach of voxelization and signed distance field, resulting in a remarkable 16-fold improvement in computational speed. Moreover, aiming to balance accuracy and efficiency, the paper systematically analyzes the optimization computation parameters of the model. Finally, the proposed model is validated using measurement data in the frequency range of 1 GHz to 6 GHz in mountainous terrain. The results indicate that the predicted outcomes of the proposed model have an accuracy within 6 dB compared to the measurement results, and are superior to ITU-R P.1546, which is an international standard recommended by the International Telecommunication Union for modeling electromagnetic wave propagation in undulating terrain. This provides necessary technical support for network planning and optimization.

LPI Radar Waveform Recognition Based on Hierarchical Classification Approach and Maximum Likelihood Estimation

The importance of information gathering is emphasized to minimize casualties and economic losses in warfare. Through electronic warfare, which utilizes electromagnetic waves, it is possible to discern the enemy’s intentions and respond accordingly, thereby leading the battle advantageously. Consequently, related research is actively underway. The development of various radar signal modulation techniques has revealed limitations in the existing modulation recognition methods, necessitating the development of distinguishing features to overcome these limitations. This paper proposes and analyzes distinguishing features that can differentiate various modulation schemes. Eleven distinguishing features were employed, and twenty-two types of modulated signals, including analog, digital, and composite modulation, were classified using hierarchical classification approach and maximum likelihood estimation (MLE). The proposed method achieves a recognition performance of 99.76% at an SNR of 20 dB and 98.45% at an SNR of 8 dB.

Nanostructures/TiN layer/Al2O3 layer/TiN substrate configuration-based high-performance refractory metasurface solar absorber

Metasurface solar absorber serves as a kind of important component for green energy devices to convert solar electromagnetic waves into thermal energy. In this work, we design a new solar light absorber configuration that incorporates the titanium nitride substrate, aluminum oxide layer, titanium nitride layer, and the topmost refractory nanostructures. The metasurface absorber based on this configuration can achieve an average spectral absorption of over 91% and a total solar radiation absorption of 91.5% at ultra-wide wavelengths of 300–2500 nm. It is discovered that the excellent performance of the proposed metasurface absorber is attributed to the synergistic effects of surface plasmonic effect and Fabry–Pérot (FP) cavity resonance by comprehensive analysis of the simulated field distributions. Furthermore, the effect of geometrical parameter of the proposed configuration on absorber performance is studied, indicating the proposed configuration possesses a large fabrication tolerance. Moreover, the proposed configuration is not sensitive to the polarization direction and the angle of incident light. It is also found that the use of other refractory metal materials and other shapes as the topmost absorbent nanostructures also have good results with this configuration. This work can offer a universal platform for constructing and guiding the design of refractory metasurface solar absorbers.

Hierarchical structure Fe@CNFs@Co/C elastic aerogels with intelligent electromagnetic wave absorption

AbstractDeveloping intelligent electromagnetic wave (EMW) absorption materials with real‐time response‐ability is of great significance in complex application environments. Herein, highly compressible Fe@CNFs@Co/C elastic aerogels were assembled through the electrospinning method, achieving EMW absorption through pressure changes. By varying the pressure, the effective absorption bandwidth (EAB) of Fe@CNFs@Co/C elastic aerogels shows continuous changes from low frequency to high frequency. The EAB of Fe@CNFs@Co/C elastic aerogels is 14.4 GHz (3.36–17.76 GHz), which covers 90% of the range of S/C/X/Ku bands. The theoretical simulation indicates that the external pressure prompts a reduction in the spacing between the fiber layers in the aerogels and facilitates the formation of a 3D conductive network with enhanced attenuation ability of EMW. The uniform distribution of metal particles and appropriate layer spacing can effectively optimize the impedance matching to achieve the best EMW absorption performance. This work state clearly that the hierarchically assembled elastic aerogels composed of metal–organic frameworks (MOFs) derivatives and carbon fibers are ideal dynamic EMW absorption materials for intelligent EMW response.image