Electric Charge Research Articles

Impact of external heating and state of charge on discharge performance and thermal runaway risk in 21700 Li-ion batteries

This study investigates the combined effects of external heating and State of Charge (SOC) on the discharge performance and thermal runaway risk of 21700 Li-ion batteries. Experiments subject commercially available 21700 cylindrical cells to various external heating conditions at different SOC levels (20, 40, 60, 80, and 100 %) while measuring discharge performance and thermal behavior at different discharge rates (0.2, 0.5, 1, and 1.5C). The study emphasizes the significance of Li-ions' spatial arrangement and maintaining electrical charge in the electrolyte to evaluate battery performance. Numerical simulations are then conducted to complement the experimental data and provide deeper insights. The results reveal a significant degradation in discharge performance with increasing external heat, characterized by voltage drops and reduced capacity. Cells with higher SOC levels exhibit more severe exothermic reactions during external heating, leading to a higher likelihood of thermal runaway. Cells operated at a moderate SOC of 40 % demonstrate a significantly lower risk of thermal runaway under similar heating conditions. The rapid rise in temperature at 100 % SOC of batteries showed a sharp increase of over 20 °C per second. Temperature spikes were noted at specific time intervals corresponding to different SOC levels: 100, 80, 60, 40, and 20. At this critical point, temperatures ranged from 135 to 182 °C, indicating potential thermal issues from internal short circuits causing separator melting. These findings highlight the critical role of SOC management in ensuring the safe and reliable operation of 21700 Li-ion batteries, particularly in applications involving elevated temperatures.

Clean-up of wastewater discharged from zinc industry through application of zeolite 4A produced from a waste contaminated by lubricant oil components

The zeolite 4 A powders were sustainably derived from clay-based waste contaminated with the spent lubricant oil. Then, the products were used to treat the wastewater discharged from a local zinc industry. The main challenge is removal of toxic organic components from the waste and conversion of obtained precursor to the zeolite structure, simultaneously. The variation in crystallinity was studied as a function of composition, fusion temperature, aging, and recrystallization times. The zinc adsorption was found to be markedly dependent not only on sodium carbonate/waste ratio but also on aluminum hydroxide content. However, pronounced adsorption was observed over the particles fabricated through the fusion at 900 °C. The relative crystallinity, ∼32 %, is crucial for the effective immobilization of heavy metal ions like Cd2+, Ni2+, and Zn2+ from the wastewater. This level of crystallinity is achievable with the control of aging and recrystallization times, both in 3 h. The maximal zinc adsorption capacity, ∼143 mg g−1, was obtained for the particles with large pores, 48 nm, facilitating the ion diffusion into the adsorbent. On the other hand, the appropriate electrical charge surface expressed based on zeta potential, −43 mV, provided a proper condition for the electrostatic adsorption.

Selective Control of Electric Charge of Weyl Fermions in Pyrochlore Iridates.

Weyl fermions can exhibit exotic phenomena due to their magnetic charge in momentum space, while Weyl nodes are usually located away from Fermi energy, which forms electron or hole pockets as the electric charges. Previous studies have mostly focused on the magnetic charge, however, the electric charges are rarely explored. Here, the intriguing Hall responses arising from the interplay between magnetic and electric charges of Weyl fermions in pyrochlore iridates are reported. Explicitly, unexpected linear scaling is observed between the anomalous Hall conductivity and Hall carrier density in strained Nd2Ir2O7 thin films, and its slope shows a sign change approaching the Néel temperature of Nd. Theoretical calculations unveil that the cluster magnetic multipoles induce local energy inversion of Weyl nodes, which alters the electric charge of Weyl fermions and accounts for the observed nontrivial Hall responses. Moreover, the correlation between the magnetic and electric charges is further probed by voltage-controlled hydrogenation, which leads to the suppression of the anomalous Hall effect through electron filling. This work not only reveals the essential role of the both magnetic and electric charges of Weyl fermions, but also demonstrates the hydrogenation as an effective tuning knob in exploring correlated topological properties.

Deflection of light by a compact object with electric charge and magnetic dipole in Einstein–Born–Infeld gravity

We consider the bending of light around a compact astrophysical object with both the electric field and the magnetic field in Einstein–Born–Infeld theory. From the null geodesic of a light ray passing a massive object with electric charge and magnetic dipole, the effective metric was obtained from the light cone condition reflecting the nonlinear electromagnetic effects. We found the asymptotic form of the effective metric up to the first order in gravitational constant G and Born–Infeld parameter 1/β2\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$1/\\beta ^2$$\\end{document} on the equatorial plane. Then we compute the bending angle of light from the geodesic equation. The result includes particular cases where only one type of field is present taking the appropriate limits.

A robust sliding mode control strategy for DC voltage stabilization in solar powered electric vehicle charging station

ABSTRACT Integrating DC power sources and AC grid in an electric vehicle charging station through converters can introduce oscillations, potentially leading to system instability. This paper explored the utilization of a sliding mode controller in a bidirectional DC-DC buck-boost converter for DC bus voltage control within the charging station. This controller aims to promptly respond to power fluctuations, offering robustness against variations in system parameters, external disturbances, and uncertainties. Control strategies play a critical role in mitigating DC link voltage fluctuations and ensuring power stability. The system entails a photovoltaic array employing maximum power point tracking for optimal energy harnessing. In addition, a bidirectional buck-boost converter is employed to effectively manage battery charging in buck mode and discharging in boost mode. A comparative analysis between Proportional-Integral control and sliding mode control incorporating a washout filter was conducted. This assessment is simulated and validated using MATLAB/Simulink, and the Sim Power System toolbox. The proposed model offers a comprehensive solution for integrating solar power, battery storage, and grid-based charging by enhancing overall system efficiency and reliability.

Impact of frictional heat and electric charge on the thermomechanical contact properties of piezoelectric quasicrystals: A DC-FFT algorithm

Piezoelectric quasicrystals (PEQCs) are quasicrystals with piezoelectricity. It combines the excellent properties of piezoelectric materials and quasicrystal materials, and is expected to be used as actuators in fields such as aerospace, automotive, and intelligent manufacturing. This article investigates the physical and mechanical properties of one-dimensional hexagonal piezoelectric quasicrystals (1D HPEQCs) coating under normal force and frictional heat and current density by using the discrete convolution-fast Fourier transform (DC-FFT) algorithm-based hybrid element method (HEM). The general solution of the model in the two-dimensional Fourier domain is obtained by combining the two-dimensional Fourier transform with strict operator theory and the Almansi’s theorem. The DC-FFT algorithm-based HEM is used to efficiently and accurately cope with the issue of transforming the fundamental solution in the Fourier domain into the spatial domain. Therefore, the numerical solutions and distribution of stress and displacement in the phonon and phason fields are obtained. The results indicate that current density has a significant impact on the phason field, and an increase in current density enhances the mechanical behavior of the phason displacement. The research results can provide theoretical guidance for 1D HPEQCs as intelligent coating materials.

FORMATION OF A SYSTEM FOR ASSESSING THE EFFECTIVENESS OF INNOVATIVE DEVELOPMENT OF LOGISTICS ACTIVITIES OF MOTOR TRANSPORT ENTERPRISES ENGAGED IN FREIGHT TRANSPORTATION IN TERMS OF SUSTAINABLE DEVELOPMENT

The article discusses the importance of implementing innovations at road transport enterprises in the context of achieving the region's sustainable development goals. The author emphasizes that road transport enterprises are significant sources of harmful emissions and environmental pollution, so using innovative technologies, such as electric vehicles, hybrid cars, and alternative fuels, is an important tool for reducing the negative environmental impact. In particular, these technologies help to reduce greenhouse gas emissions and other harmful substances, which is in line with Sustainable Development Goals 7 (access to modern energy), 13 (combating climate change), and 15 (protecting terrestrial ecosystems). In addition, innovations in transport technologies, such as automated driving systems, help to improve road safety and reduce the number of road accidents, which is in line with Goal 3 (good health and well-being). The creation of new jobs and infrastructure development through the construction of electric charging stations and the introduction of intelligent transport systems (smart cities) are also linked to Sustainable Development Goals 9 (sustainable infrastructure) and 11 (sustainable urban development). The author analyses the performance indicators of innovations at motor transport enterprises, taking into account economic, social, and environmental aspects. Particular emphasis is placed on the adaptation of these indicators to the current realities of Ukraine. Using game theory, the article develops a model for the selection of optimal strategies for motor transport enterprises and the region. This model allows us to find the Nash equilibrium - a situation where both parties achieve the optimal result. Enterprises that implement innovations not only improve their own performance indicators, but also contribute to the achievement of sustainable development goals of the region. The article also presents two sets of strategies: for the development of logistics activities of a motor transport enterprise and the sustainable development of the region. Both approaches aim to comprehensively improve the region's environmental, economic, and social situation. The conclusions emphasize the importance of implementing innovation development assessment systems as a tool for making strategic decisions and improving the efficiency of logistics operations.

STAR results on strangeness and electric charge dependent splitting of rapidity-odd directed flow

STAR results on strangeness and electric charge dependent splitting of rapidity-odd directed flow

Study on the effects of strain and electrostatic doping on the magnetic anisotropy of GaN/VTe2 van der waals heterostructure

Using a first-principles approach, this study delves into the effects of strain and electrostatic doping on the electronic and magnetic properties of the GaN/VTe2van der Waals (vdW) heterostructure. The results reveal that when the GaN/VTe2vdW heterostructure is doped with 0.1h/0.2hof electrostatic charge, its magnetization direction undergoes a remarkable reversal, shifting from out-of-plane orientation to in-plane direction. Therefore, we conduct a thorough investigation into the influence of electron orbitals on magnetic anisotropy energy. In addition, as the strain changes from -1% to 1%, the 100% spin polarization region of the GaN/VTe2vdW heterostructure becomes smaller. It is worth noting that at a doping concentration of 0.1h, the GaN/VTe2vdW heterostructure has a Curie temperature of 30 K above room temperature. This comprehensive study provides valuable insights and provides a reference for analyzing the electronic and magnetic properties of low-dimensional systems.

An interpretation of scalars in SO(32)

We propose an interpretation for the adjoint representation of the SO(32) group to classify the scalars of a generic Supersymmetric Standard Model having just three generations of particles, via a flavour group SU(5). We show that this same interpretation arises from a simple postulate of self-consistence of composites for these scalars. The model looks only for colour and electric charge, and it pays the cost of an additional chiral +4/3\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$+4/3$$\\end{document} quark per generation.

Traversable wormholes with electric and magnetic charges in general relativity theory

Traversable wormholes with electric and magnetic charges in general relativity theory

Heterogeneity in electric taxi charging behavior: Association with travel service characteristics

A comprehensive understanding of charging behaviors among electric vehicle users is crucial for advancing green transportation and deploying effective charging infrastructure. This study conducted large-scale empirical research using data from electric taxi fleets in Shenzhen to explore the heterogeneity of charging behaviors among taxi drivers. The study hypothesized that distinct charging patterns exist within the electric taxi fleet, impacting fleet-wide fluctuations and repetitions of charging and service activities. Employing a covariate-enhanced latent profile analysis model, we examined unique charging patterns within the fleet and investigated relationships between taxi service attributes and charging behavior heterogeneity. Fleet-wide diurnal fluctuations, daily repetitions, and subgroup-specific charging patterns were identified. At the micro level, operational activity sequence similarity and between-group diversity were assessed. The findings offer valuable insights for policymakers and stakeholders involved in promoting green transportation and optimizing charging infrastructure.

Unveiling the Electrostatically Driven Collapsing and Relaxation of Polyelectrolyte-Colloid Complexes: A Tunable Pathway to Colloidal Assembly.

Polyelectrolyte-colloid (PEC) complexes, ubiquitous across diverse fields, exhibit remarkable phase transitions, mimicking intricate biological assemblies. While the role of electrostatic forces in the PEC complex assembly is undeniable, achieving a holistic comprehension remains an elusive goal. This study unveils a fascinating phenomenon: the formation of highly collapsed coacervate structures in PEC complexes at elevated polyelectrolyte concentrations, followed by the swelling of complexes at even higher concentrations. Employing anionic silica colloids and cationic chitosan as a model system, small-angle X-ray/neutron (SAXS/SANS) elucidates the transition from a bead-on-a-necklace-like phase to a dense packed coacervate state (with volume fraction ∼0.62) until 3 wt % concentration of the polyelectrolyte. However, beyond 3 wt %, swelling of the dense collapsed assembly is observed. This structural evolution of PEC complexes as a function of chitosan concentration is attributed to the interplay of electrostatically driven interactions and the Donnan effect. Notably, the critical concentration for coacervation, Cs*, demonstrates a linear dependence on the initial colloid concentration. Interestingly, a complete expansion of the coacervate is observed at a high polyelectrolyte concentration, particularly for dilute colloid solutions (2 wt %). Furthermore, the addition of an electrolyte sheds light on the delicate interplay of forces. While a low electrolyte concentration partially screens charges, leading to a shift in phase diagram, higher concentrations trigger complete coacervate dissolution beyond the critical electrolyte concentration of 0.2 M, due to the complete screening of electrostatic charges.

EPDB: An Efficient and Privacy-Preserving Electric Charging Scheme in Internet of Robotic Things

EPDB: An Efficient and Privacy-Preserving Electric Charging Scheme in Internet of Robotic Things

The mercurial rise in research of halide perovskites: what´s next

AbstractPerovskites are of high potential in the ongoing academic research, due to their distinctive electrical properties and crystalline structures. Halide perovskites show high light emissive properties and panchromatic light absorption across the visible spectrum. The exceptional electrical characteristics, such as their long carrier lifespan, high diffusion length, and charge carrier mobility, allow the electric charges to be transported and collected effectively. Furthermore, by tuning the cations and anions composition, perovskite’s opto-electrical properties can be altered. Moreover, dimension reduction affects their band gap and intrinsic features to induce higher structural stability but at the cost of the quantum confinement effect. Owing to their exceptional properties, halide perovskites are being researched in energy-related and semiconducting applications, hold high promise and the future looks bright. But challenges remain, and the larger question is what needs to be done to make them more stable.

Casimir wormholes inspired by electric charge in Einstein–Gauss–Bonnet gravity

This investigation assesses the feasibility of a traversable wormhole by examining the energy densities associated with charged Casimir phenomena. We focus on the influence of the electromagnetic field created by an electric charge as well as the negative energy density arising from the Casimir source. We have developed different shape functions by defining energy densities from this combination. This paper explores various configurations of Casimir energy densities, specifically those occurring between parallel plates, cylinders and spheres positioned at specified distances from each other. Furthermore, the impact of the generalized uncertainty principle correction is also examined. The behavior of wormhole conditions is evaluated based on the Gauss–Bonnet coupled parameter (μ) and electric charge (Q) through the electromagnetic energy density constraint. This is attributed to the fact that the electromagnetic field satisfies the characteristic ρ = −p r . Subsequently, we examine the active gravitational mass of the generated wormhole geometries and explore the behavior of μ and Q concerning active mass. The embedding representations for all formulated shape functions are examined. Investigations of the complexity factor of the charged Casimir wormhole have demonstrated that the values of the complexity factor consistently fall within a particular range in all scenarios. Finally, using the generalized Tolman–Oppenheimer–Volkoff equation, we examine the stability of the resulting charged Casimir wormhole solutions.

An Ultra‐High Voltage AC/DC Isolated Matrix Converter Applied to V2G Electric Vehicle Charging Piles

ABSTRACTIn recent years, in order to alleviate global environmental problems, renewable energy power generation and the electric vehicle industry have been vigorously promoted by many countries. During this background, many scholars have proposed the development of vehicle‐to‐grid (V2G) systems to alleviate the impact of renewable energy generation on grid quality, and electric vehicle charging piles are the core part of realizing V2G systems. This article proposes an ultra‐high voltage AC/DC isolated matrix converter applied to V2G electric vehicle charging piles, which can achieve bidirectional flow of energy, and proposes the control strategy that can reduce the current stress of the device. In addition, the ultra‐high voltage module of the proposed topology can provide wide voltage range and high voltage charging power for different types of electric vehicles. The proposed topology and control strategy are verified by simulation.

The Control Strategies for Charging and Discharging of Electric Vehicles in the Vehicle–Grid Interaction Modes

In response to the challenges posed by large-scale, uncoordinated electric vehicle charging on the power grid, Vehicle-to-Grid (V2G) technology has been developed. This technology seeks to synchronize electric vehicles with the power grid, improving the stability of their connections and fostering positive energy exchanges between them. The key component for implementing V2G technology is the bidirectional AC/DC converter. This study concentrates on the non-isolated bidirectional AC/DC converter, providing a detailed analysis of its two-stage operation and creating a mathematical model. A dual closed-loop control structure for voltage and current is designed based on nonlinear control theory, along with a constant current charge–discharge control strategy. Furthermore, midpoint potential balance is achieved through zero-sequence voltage injection control, and power signals for the switching devices are generated using Space Vector Pulse Width Modulation (SVPWM) technology. A simulation model of the V2G system is then constructed in MATLAB/Simulink for analysis and validation. The findings demonstrate that the control strategy proposed in this paper improves the system’s robustness, dynamic performance, and resistance to interference, thus reducing the effects of large-scale, uncoordinated electric vehicle charging on the power grid.

Thermo- and pH-Responsible Gels for Efficient Protein Adsorption and Desorption

Protein adsorption behavior was examined on poly(N-isopropylacrylamide-co-sodium methacrylate)-based hydrogels at different temperatures: 5, 20, and 37 °C, and pH: 4.5, 7, and 9.2. The hydrogels, whose covalent skeleton contains pendant anionic units due to the presence of the sodium methacrylate co-monomer, exhibited both thermo- and pH-sensitivity with different extents, which depended on the content of ionizable moieties and the cross-linker density. The hydrogel composition, temperature, and pH influenced the zeta potential of the hydrogels and their swelling properties. The proteins selected for the study, i.e., bovine serum albumin (BSA), ovalbumin (OVA), lysozyme (LYZ), and a monoclonal antibody (mAb2), differed in their aminoacidic composition and conformation, thus in isoelectric point, molecular weight, electrostatic charge, and hydrophobicity. Therefore, the response of their adsorption behavior to changes in the solution properties and the hydrogel composition was different. LYZ exhibited the strongest adsorption of all proteins with a maximum at pH 7 (189.5 mg ggel−1); adsorption of BSA and OVA reached maximum at pH 4.5 (24.4 and 23.5 mg ggel−1), whereas mAb2 was strongly adsorbed at 9.2 (21.7 mg ggel−1). This indicated the possibility of using the hydrogels for pH-mediated separation of proteins differing in charge under mild conditions in a water-rich environment of both the liquid solution and the adsorbed phase. The adsorption affinity of all proteins increased with temperature, which was attributed to the synergistic effects of attractive electrostatic and hydrophobic interactions. That effect was particularly marked for mAb2, for which the temperature change from 5 to 37 °C caused a twentyfold increase in adsorption. In all cases, the proteins could be released from the hydrogel surface by a reduction in temperature, an increase in pH, or a combination of both. This allows for the elimination of the use of salt solution as a desorbing agent, whose presence renders the recycling of buffering solutions difficult.

Bio-Pesticidal Potential of Nanostructured Lipid Carriers Loaded with Thyme and Rosemary Essential Oils against Common Ornamental Flower Pests

The encapsulation of essential oils (EOs) in nanostructured lipid carriers (NLCs) represents a modern and sustainable approach within the agrochemical industry. This research evaluated the colloidal properties and insecticidal activity of NLCs loaded with thyme essential oil (TEO-NLC) and rosemary essential oil (REO-NLC) against three common arthropod pests of ornamental flowers: Frankliniella occidentalis, Myzus persicae, and Tetranychus urticae. Gas chromatography–mass spectrometry (GC-MS) analysis identified the major chemical constituents of the EOs, with TEO exhibiting a thymol chemotype and REO exhibiting an α-pinene chemotype. NLCs were prepared using various homogenization techniques, with high shear homogenization (HSH) providing the optimal particle size, size distribution, and surface electrical charge. A factorial design was employed to evaluate the effects of EO concentration, surfactant concentration, and liquid lipid/solid lipid ratio on the physicochemical properties of the nanosuspensions. The final TEO-NLC formulation had a particle size of 347.8 nm, a polydispersity index of 0.182, a zeta potential of −33.8 mV, an encapsulation efficiency of 71.9%, and a loading capacity of 1.18%. The REO-NLC formulation had a particle size of 288.1 nm, a polydispersity index of 0.188, a zeta potential of −34 mV, an encapsulation efficiency of 80.6%, and a loading capacity of 1.40%. Evaluation of contact toxicity on leaf disks showed that TEO-NLC exhibited moderate insecticidal activity against the western flower thrips and mild acaricidal activity against the two-spotted spider mite, while REO-NLC demonstrated limited effects. These findings indicate that TEO-NLCs show potential as biopesticides for controlling specific pests of ornamental flowers, and further optimization of the administration dosage could significantly enhance their effectiveness.