Volatile organic compounds (VOCs) air pollutants are the precursors of ozone and PM2.5, all harmful to human health. To reduce the equipment volume further and improve the treatment capacity at room temperature, a novel microbial fuel cell (MFC) system, with a sprinkler and water recycle module, was designed to integrate bio-electricity generation from biodegradation and photocatalytic oxidation of VOCs over cathodic diatomic Co-Fe/g-C3N4 doped activated carbon felt (Co-Fe/g-C3N4/ACF). The removal of trimethylamine in both the gas and liquid phase was proved (VOCs concentration in air ≈ 0.93 g m−3, the removal capacity reached ≥ 119.97 mg gcat-1h−1). Through the sprinkler-water cycle, the trimethylamine molecules in air transferred and diffused to the liquid phase, then acted as the only carbon source for the electrogenic bacteria, that supplied the electricity to drive photoelectric catalysis under light illumination. The high efficiency (>2086 mg gcat-1h−1) and low energy consumption in the new system at room temperature means broad application prospect in VOCs treatment.
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