Absorption Efficiency Research Articles

Piperazine-Based Mixed Solvents for CO2 Capture in Bubble-Column Scrubbers and Regeneration Heat

This work used piperazine (PZ) as a base solvent, blended individually with five amines, which were monoethanolamine (MEA), secondary amines (DIPAs), tertiary amines (TEAs), stereo amines (AMPs), and diethylenetriamine (DETA), to prepare mixed solvents at the desired concentrations as the test solvents. A continuous bubble-column scrubber with one stage (1 s) was first used for the test. Six parameters were selected, including the type of mixed solvent (A), the ratio of mixed solvents (B), the solvent feed rate (C), the gas flow rate (D), the concentration of the mixed solvents (E), and the liquid temperature (F), each one having five levels. Using the Taguchi experimental design, only 25 runs were required. The outcome data, such as the absorption efficiency (EF), the absorption rate (RA), the overall mass-transfer coefficient (KGa), and the absorption factor (φ), could be determined under steady-state conditions. The optimal mixed solvents were found to be A1 (PZ + MEA) and A2 (PZ + DIPA). The parameter importance and optimal conditions for EF, RA, KGa, and ϕ were determined separately; the verification of all optimal conditions was successful. This analysis found that the importance of the parameters was D > C > A > E > B > F, and the gas flow rate (D) was the most important factor. Subsequently, multiple-stage scrubbers were used to capture CO2. Comparing 1 s and 3 s (three-stage scrubber), EF, RA, KGa, and φ increased by 33%, 29%, 22%, and 38%, respectively. The desorption tests for the four optimal scrubbed solutions, including multiple stages, showed that the heat of regeneration for the three scrubbers was 3.57–8.93 GJ/t, in the temperature range of 110–130 °C, while A2 was the best solvent. Finally, the heat regeneration mechanism was also discussed in this work.

Enhancing pump absorption efficiency in exciting Er3+/Ce3+ co-doped microsphere lasers via single scanning

In this paper, we propose a high-efficiency pumping method, which enhances the pump absorption efficiency of Er3+/Ce3+ co-doped microsphere lasers via single scanning. Due to the restoration of thermal stability in the whispering gallery mode (WGM) microsphere, the pump light is relocated at a new WGM resonance after wavelength scanning. This results in a redshift of WGM and an increase of absorbed pump power, with a proportionality between them. An Er3+/Ce3+ co-doped microsphere is prepared to verify the enhancement of pump absorption and lase at the 1550 nm band, where the Ce3+ ions are introduced for improving the fluorescence emission at the communication band with energy transform. When the scanning rate is set to 2.0 nm/s, the pump absorption efficiency increases by 66.3%. Furthermore, the L-band single-mode lasing can be excited using a scan-assisted 980 nm pump and 1490 nm pump, respectively. The proposed scheme has proved to be a convenient and efficient pumping approach, showing significant potential in microlasers.

Electron Migratory Polarization of Interfacial Electric Fields Facilitates Efficient Microwave Absorption

AbstractHigh‐performance microwave absorption materials (MAM) are often accompanied by synergistic effects of multiple loss mechanisms, but the contribution share of various loss mechanisms has been neglected to provide a template and reference for the design of MAM. Here, a highly conductive 2D structure is designed through a functional group‐induced structure modulation strategy, composite L‐Ni@C can reach an effective absorption bandwidth of 6.45 GHz at 15% fill rate, with a maximum absorption efficiency of 99.9999%. Through the layer‐by‐layer analysis of the loss mechanism, it is found that the strong loss originates from the polarization loss at the heterogeneous interface. The movement of space charge between the two‐phase interface forms an interfacial electric field, and the in situ doping of nitrogen is cleverly achieved by the introduction of amino functional groups, which significantly enhances the rate of space charge transfer between the two‐phase interface and greatly facilitates the electron migration polarization. The space charge motion law of the interfacial electric field is also simulated using COMSOL simulation software to illustrate the electron migration polarization mechanism at heterogeneous interfaces. This work fills the gap of functional group‐induced structural modulation and presents new theories into the mechanism of space charge movement at heterogeneous interfaces.

Mechanisms and efficiency of CO2 absorption in polyamidoamine dendrimers: Experiments and theoretical calculations

To investigate the effect of amino number and viscosity on the absorption properties of PAMAM dendrimers and CO2, different initiation cores and different generations of PAMAM dendrimers were used to absorb the CO2. Molecular simulations were also employed to explain the regulatory mechanisms governing CO2 absorption, and an evaluation method of the absorption capacity was constructed for PAMAM dendrimers. The results exhibited that the viscosity of PAMAM dendritic polymers increased according to the increase of the initiator carbon chain length and nitrogen-containing functional groups. The high viscosity of G1.0 PAMAM-T and G2.0 PAMAM-D resulted in absorption loadings that were only slightly higher than those of G1.0 PAMAM-D and much lower than the theoretical capacity. The molecular simulations confirm that increasing the number of amino groups enhances the ability of PAMAM dendrimers to bind CO2, the correlation is not entirely linear. The increase in viscosity increases the resistance to mass transfer of CO2 molecules in the absorption system, thus limiting diffusion and reducing absorption efficiency. Consequently, the optimal benefits of PAMAM dendrimers are achieved only by balancing the advantages of multi-amino groups with the disadvantages of increased viscosity. 13C NMR confirms that the CO2 absorption mechanism of the PAMAM dendrimers follows the zwitterionic mechanism in which primary and secondary amines react with CO2 to produce carbamate.

Defect introduction and interfacial strategies for enhancing microwave absorption in carbon-based materials

Poor impedance matching and a single loss mechanism are typical challenges for carbon-based materials to become efficient microwave absorbers. To address these issues, defect introduction and interfacial strategies are effective methods for enhancing microwave absorption through the micro-mechanism of material interaction with microwaves. Additionally, forming a homogeneous composite material is crucial for achieving good impedance matching. In this study, we used a controlled solvent-thermal method to achieve self-assembled interfacial intercalation, yielding amorphous VOPO4/rGO nanohybrids, which show significantly enhanced microwave absorption properties. The abundant defects introduced by VOPO4 within the amorphous layered composites disrupt the charge distribution, contributing to polarization loss. The graphene nanosheets expose more VOPO4 structural units, facilitating increased conductivity and enriching the microwave absorption mechanism. As a result, the prepared VOPO4/rGO nanohybrids demonstrate outstanding microwave absorption, with the effective absorption bandwidth covering the entire Ku-band (11.6–18.0 GHz) at a thickness of 2.3 mm. This research provides an important reference for understanding the mechanisms that enhance the electromagnetic wave absorption of carbon-based materials.

CO2 gas-liquid equilibrium study and machine learning analysis in MEA-DMEA blended amine solutions

The combination of primary and tertiary amines represents a promising approach to improve sorbent performance in CO2 capture by enhancing absorption efficiency and reducing regeneration energy. This study focuses on investigating the absorption performance of binary mixtures of ethanolamine (MEA) and N,N-dimethylethanolamine (DMEA) at temperatures between 298–323 K and CO2 partial pressures between 5–60 kPa. The species generated during the absorption were analyzed using 13C NMR spectroscopy, to clarify the intricate role of MEA and DMEA in the capture process. A developed excess property model for MEA-DMEA, based on excess CO2 loading, predicted equilibrium CO2 solubility data with an average absolute relative deviation (AARD) of 1.6 %. Additionally, the machine learning models XGBoost, RBFNN, and SVR were applied, providing AARD values between 0.86 % and 1.28 %, demonstrating strong agreement between experimental and predicted outcomes. These comprehensive findings enhance our understanding of mixed amines’ mechanisms and practical applications, contributing to ongoing research development.

3D/2D lead-free halide perovskite CsSnBr3/MoX (X = Se2, SSe, S2) heterostructures for high-efficiency solar cell: Interface engineering strategies and transition of band alignments

The rapid progress in the fabrication of van der Waals (vdW) heterostructures based on perovskite has significantly advanced the fields of optoelectronics and solar cells by integrating the exceptional properties of different materials. Overall, perovskite-based vdW heterostructures display unique functional characteristics due to their varied type-I, type-II, and type-III energy band configurations. However, it is a challenge to achieve flexible regulation of band edge alignment in heterostructures for different applications. Using first-principles density functional theory, we systematically study the electronic and optical properties of vdW heterostructures system consisting of three-dimensional lead-free all-inorganic halide perovskite materials CsSnBr3 and MoX (X = Se2, SSe, S2). The research results show that in the CsSnBr3/MoX vdW heterostructures, type I, II, and III transitions of band arrangements are achieved through interface engineering strategy to adapt to different applications. Meanwhile, by calculating the light absorption efficiency of the constructed 3D/2D vdW heterostructures, it was found that the interface effect enhances the optical absorption range and intensity of the perovskite-based heterostructures. The theoretically estimated power conversion efficiency (PCE) of the heterostructure thin-film solar cell reaches 21.4 %. The results of our research indicate that the controllable band alignment of CsSnBr3/MoX heterostructures has significant potential for future applications in optoelectronics.

Carbon Based Composite Materials for Microwave Absorption in Low Frequency S and C Band: A Review

With the rapid advancement of 5G technologies and electronic devices, there is a growing demand for microwave absorbing materials, especially those effective in low frequency microwave bands (2 – 8 GHz), making it an essential requirement. In recent years, many innovative microwave absorbers have been developed for low frequency absorption, with carbon/magnetic composite materials becoming particularly promising due to their various loss mechanisms and optimized impedance matching characteristics over wide frequency range. However, there is currently a lack of a comprehensive review that summarizes the findings on low frequency absorbers. This review article thoroughly examines the current research on carbon/magnetic composite materials with efficient absorption performance in the low‐frequency S and C bands, and provides a detailed discussion on the microwave absorption performance of these composite materials. Furthermore, the composite design strategies, synthesis techniques, microstructure performance relationship, and microwave attenuation mechanisms are summarized. Lastly, the challenges and future outlook for low frequency microwave absorbing materials are addressed. This review article aspires to provide new insights into designing and synthesizing composite materials to accomplish effective low‐frequency microwave absorption, thereby promoting practical applications.

Tailoring SrFe12O19 – MoS2 composites for enhanced microwave absorption performance in X-band

The electromagnetic wave-absorbing composites, incorporating strontium hexaferrite and molybdenum disulfide (SrFe12O19-MoS2), are synthesized by mixing in different weight ratios. In the present work, strontium hexaferrite (SrFe12O19) is developed through a low-temperature auto-combustion method while two-dimensional molybdenum disulfide (MoS2) is synthesized by a facile hydrothermal process. The materials and their composites undergo analysis using characterization techniques such as X-ray diffraction (XRD), fourier transform infrared (FTIR) spectroscopy, field emission scanning electron microscopy (FESEM), and vibrating sample magnetometer (VSM) to assess their structural, morphological, and magnetic properties, respectively. The minimal reflection loss (RLmin) of – 47.35 dB is observed at 8.66 GHz for the SrFe12O19-MoS2 (50 %-50 %) composite cast into pellets for microwave absorption analysis in the X-band frequency range. This RLmin is obtained with a sample thickness of 1.7 mm. An adequate bandwidth of 3.1 GHz, representing 77.5 % of the entire X band, is observed for a loss below −10 dB. The synergistic interaction between magnetism and dielectricity makes it an efficient electromagnetic absorber for modern technologies.

Porous flexible molecular-based piezoelectric composite achieves milliwatt output power density

Molecular ferroelectrics have made breakthrough progress in intrinsic piezoelectric response that can be on par with advanced inorganic piezoelectric ceramics. However, their successful applications in high-density energy harvesting and self-powered flexible devices have been great challenge, owing to the low elastic moduli, intrinsically brittle, and fracture proneness of such material systems under mechanical loading. Here, we have developed a flexible porous composite piezoelectric material by using soft thermoplastic polyurethane (TPU) and molecular ferroelectric materials. Benefiting from the porous structure of TPU, the flexible piezoelectric composites enable effectively large doping ratio (50%) of [Me3NCH2Cl]CdCl3 (TMCM-CdCl3) and highly efficient stress absorption, coupled with the excellent piezoelectric properties of TMCM-CdCl3, to realize a superior power density (636.9 µW cm−2 or 1273.9 µW cm−3). This output is 2000 times higher than that of flexible piezoelectric materials represented by poly(vinylidene fluoride) (PVDF). We believe that the outstanding performance of the porous composite piezoelectric material would pave a feasible way for real industrial applications of molecular ferroelectrics.

One-pot fabrication of open-spherical shapes based on the decoration of copper sulfide/poly-O-amino benzenethiol on copper oxide as a promising photocathode for hydrogen generation from the natural source of Red Sea water

Abstract Harnessing green hydrogen production from natural Red Sea water offers an innovative solution to address energy challenges. A one-pot fabrication method is used to create novel nanocomposite thin films with open-spherical shapes, utilizing copper sulfide/poly-O-amino benzenethiol decorated on copper oxide as a promising photocathode. After thorough analysis, a unique morphology characterized by open spherical shapes is projected, which contributes to improved optical absorption. The bandgap of the nanocomposite is 1.17 eV, enabling efficient absorption of light across the entire optical spectrum, extending up to 950 nm. Utilizing Red Sea water as an electrolyte, the generated J ph serves as an indicator of H2 gas production. The substantial J ph value of −0.82 mA cm−2 is achieved at −0.85 V under light illumination. Furthermore, J ph values exhibit variability, starting at −0.58 mA cm−2 (at 730 nm) and increasing to −0.75 mA cm−2 at a wavelength of 340 nm. The estimated hydrogen gas production rate reaches 1.5 µmole h−1 cm−2, translating to an impressive 15 µmole h−1 for every 10 cm². This remarkable rate underscores the effectiveness of the photocathode, especially given its fabrication through a single-step process that is suitable for mass production. In addition, its cost-effectiveness further enhances its appeal as a viable solution for renewable energy production for hydrogen gas generation from seawater.

Broadband acoustic metamaterial absorber

Constrained by the causality nature, it is a challenge to achieve low-frequency broadband efficient absorption via passive materials. By coupling local resonances as many as possible, broadband metamaterial absorbers can be realized. In this scenario, the coupling effect is crucial for improving the absorption efficiency. Here, we demonstrate a kind of acoustic metamaterial absorber capable of high-efficiency broadband absorption by optimizing the non-local coupling effect. Cascade neck-embedded Helmholtz resonator is designed as the subunit of the metamaterial absorber. By coupling 36 subunits, a metamaterial absorber is constructed with the aid of optimization algorithm. The simulation results suggest that strong non-locality is induced in the near field, which effectively suppresses the impedance oscillations and absorption dips at the antiresonance frequencies. Eventually, the presented metamaterial absorber realizes impedance matching to the air from 320 Hz to 6400 Hz, leading to efficient broadband absorption performance. The results and methodologies in this work reveal the significance of non-local coupling effect in coupled-resonant metamaterials.

Enhancing railway noise reduction through advanced multilayer acoustic absorbent systems with tunable resonators

Railway noise poses a significant environmental challenge, prompting the need for effective mitigation strategies. In response, noise barriers are often employed to reduce noise near railways. This research focuses on the use of porous materials, more specifically porous concrete, for acoustic absorption, particularly in the context of railway noise reduction. A novel approach is proposed, wherein porous multilayer metamaterial systems are developed, with each layer's macroscopic parameters strategically optimized to enhance the overall sound absorption curve. Additionally, to broaden the frequency range of noise attenuation, tunable resonators are seamlessly integrated into the multilayer system. The analytical framework for analyzing both the multilayer system and resonators involves employing equivalent fluid models and the analytical transfer matrix method. Linear regressions were employed to establish relationships between porosity, density, and other macroscopic parameters, enabling the derivation of the sound absorption curve solely from these parameters. Through systematic optimization and integration of resonators, it is expected that, the proposed approach demonstrates significant advancements in railway noise reduction efficacy across a wide frequency range. This research aims to contribute to the development of more efficient and versatile acoustic absorbent systems for mitigating railway noise pollution.

Development and analysis of Fe-doped ZnO nanoparticle-infused sisal fiber reinforced hybrid polymer composites for high-performance sound absorption and thermal insulation applications

In the current study, sisal fiber-reinforced hybrid composites have been developed by integrating a bidirectional mat with a blend of epoxy using Fe-doped ZnO (IDZO) nanoparticles at concentrations of 0.2, 0.4, 0.6, and 0.8 wt%. Hand-lay-up approach was used to create the composites. The composites were characterized through a comprehensive analysis of their density, water absorption, elasticity, thermogravimetric analysis, mechanical resistance, thermal conductivity, microhardness, and propagation of sound properties, including sound absorption coefficients and sound transmission class ratings. As filler loading increased, the bio-composite sample’s hardness increased under the density and void volume fraction values, with 0.8 wt% composite sample showing the superior micro-hardness. A positive correlation was observed between the ZnO nanoparticle weight percentage and thermal conductivity, with improve nanoparticle content leading to improved thermal performance. Composites containing 0.4 wt percent nanoparticles showed superior tensile strength (66.8–84.16 MPa), flexural strength (97.69–120.02 MPa) and flexural modulus (3.56–7.68 GPa). It has been observed that the weight percentage of IDZO filler greatly influences the sound absorption efficiency of the current composites. These findings highlight the promising potential of these novel biocomposites in advanced engineering applications, emphasizing their usefulness in demanding environments with biodegradability and high-performance thermal, mechanical, and acoustic properties. Based on the sound transmission class ratings, the sisal fiber biocomposites have been regarded as great adoptions for use as sound-absorbing materials such as wall partitions, doors, enclosures, and structural components, thermal insulation systems, and electrical insulation.

Improvement of Self-Driven Nanowire-Based Ultraviolet Photodetectors by Metal-Organic Frameworks for Controlling Humanoid Robots.

Self-driven photodetectors (PDs) hold significant potential for the development of new information devices, which boast the advantages of ultralow power consumption and straightforward fabrication. In this study, we have proposed and demonstrated a self-driven ultraviolet PD utilizing gallium nitride/metal-organic framework (GaN/MOF) heterojunction nanowires successfully. By introducing Gd-ETTC MOFs on the surface of GaN nanowires, the photocurrent and responsivity of the device can be improved by approximately 75% under 310 nm illumination. Furthermore, they can also be effectively enhanced under visible light illumination. Owing to the appropriate energy level alignment, Gd-ETTC MOFs can serve as both a light harvester and a hole conductor, facilitating the efficient absorption, separation, and transmission of photogenerated carriers. It has been observed that due to reduced interface resistance, MOFs can enhance the charge transport through the acceleration of charge transfer. Furthermore, the PD equipped with MOFs is capable of continuous operation for 30,000 s, a feat attributable to the exceptional stability of both GaN nanowires and Gd-ETTC MOFs. By implementation of the humanoid robot systems, the control commands from the self-driven PD can drive the humanoid robot to execute different actions. The PD-equipped autonomous feedback system of a humanoid robot enables a seamless integration of light perception with intelligent robotic actions. Therefore, the design and demonstration of GaN/MOF nanowires hold significant reference value for further enhancing the performance of PDs and broadening their applications in ultralow-power artificial intelligence systems, humanoid intelligent robots, etc.

CO2 absorption with polyethyleneimine solution intensified by a rotating packed bed with liquid detention

This study explored the absorption of CO2 by the polyethyleneimine (PEI) solution in a rotating packed bed (RPB). In order to boost the CO2 absorption effect, the liquid detention phenomenon in the RPB was utilized to overcome the short residence time of liquid. The effects of different operating parameters on CO2 absorption efficiency (η) and gas-phase volumetric mass transfer coefficient (KGav) in the RPB were investigated. The experimental results indicated that the RPB can greatly intensify the absorption of CO2. η and KGav increased from 3.3 % and 0.041 kmol·m−3·h−1·kPa−1 to 76.0 % and 1.634 kmol·m−3·h−1·kPa−1, respectively, as the rotational speed of the RPB rose from zero to 700 rpm with 250 mL detained liquid. It was also found that the liquid detention phenomenon can significantly elevate η and KGav as a result of extended liquid residence time and increased liquid holdup in the RPB. When the detained liquid volume increased from zero to 250 mL, η and KGav increased by 55.6 % and 113.1 %, respetively. In addition, it was observed that CO2 load in the rich PEI solution increased from 9.650 to 11.189 molCO2/kg PEI while η remained around 85 % after five cycles of absorption–desorption, suggesting an excellent cyclic stability of PEI. This work contributes to the development of viable CO2 capture technologies by intensifying the CO2 absorption process in the RPB with an efficient absorbent.

Ultra-broadband polarization-insensitive versatile solar thermal harvester

Sustainable and Renewable Energy is essential because it's non-polluted and available in nature. Solar energy is the most important of them all as its the essential of them all. Sun energy is a clean and finest alternative to renewable energy sources. The slotted cylinder-shaped Mxene-based resonator solar absorber (SCMRSA) achieved an average of 95.06 % efficient absorption. The MXene material is used as a resonating material above the titanium oxide layer based on the MXene layer. The wide angle of incidence is achieved which is analyzed by changing the different angles of incidence. The E-field response is also observed for the TE and TM modes. The results show a similar response for both TE and TM modes. The optimization of the structure is also observed for different variable variations and the final optimized design is used for the highly efficient absorptance results. The SCMRSA is also applicable for various solar thermal applications and energy harvesters.

S-Modified Graphitic Carbon Nitride with Double Defect Sites For Efficient Photocatalytic Hydrogen Evolution.

Graphitic carbon nitride (gC3N4) is an attractive photocatalyst for solar energy conversion due to its unique electronic structure and chemical stability. However, gC3N4 generally suffers from insufficient light absorption and rapid compounding of photogenerated charges. The introduction of defects and atomic doping can optimize the electronic structure of gC3N4 and improve the light absorption and carrier separation efficiency. Herein, the high efficiency of carbon nitride photocatalysis for hydrogen evolution in visible light is achieved by an S-modified double-deficient site strategy. Defect engineering forms abundant unsaturated sites and cyano (─C≡N), which promotes strong interlayer C─N bonding interactions and accelerates charge transport in gC3N4. S doping tunes the electronic structure of the semiconductors, and the formation of C─S─C bonds optimizes the electron-transfer paths of the C─N bonding, which enhances the absorption of visible light. Meanwhile,C≡N acts as an electron trap to capture photoexcited electrons, providing the active site for the reduction of H+ to hydrogen. The photocatalytic hydrogen evolution efficiency of SDCN (1613.5µmolg-1h-1) is 31.5 times higher than that of pristine MCN (51.2µmolg-1h-1). The charge separation situation and charge transfer mechanism of the photocatalysts are investigated in detail by a combination of experimental and theoretical calculations.

Experimental investigation of a nano coating efficiency for dust mitigation on photovoltaic panels in harsh climatic conditions

Dust accumulation on photovoltaic (PV) panels in arid regions diminishes solar energy absorption and panel efficiency. In this study, the effectiveness of a self-cleaning nano-coating thin film is evaluated in reducing dust accumulation and improving PV Panel efficiency. Surface morphology and elemental analysis of the nano-coating and dust are conducted. Continuous measurements of solar irradiances and ambient temperature have been recorded. SEM analysis of dust revealed irregularly shaped micron-sized particles with potential adhesive properties, causing shading effects on the PV panel surface. Conversely, the coating particles exhibited a uniform, spherical shape, suggesting effective prevention of dust adhesion. Solar irradiance ranged from 120 W/m² to a peak of 720 W/m² at noon. Application of the self-cleaning nano-coating thin film consistently increased short circuit current (Isc), with the coated panel averaging 2.8 A, which is 64.7% higher than the uncoated panel’s 1.7 A. The power output of the coated panel ranged from 7 W to 38 W, with an average of approximately 24.75 W, whereas the uncoated panel exhibited a power output between 3 W and 23 W, averaging around 14 W. These findings highlight the substantial potential of nano-coating for effective dust mitigation, particularly in dusty environments, thus enhancing PV system reliability.

The low-dimensional units modulation of 3D floral Fe/Ni@C towards efficient microwave absorption

Metal-organic frameworks (MOF) derivatives have great potential in microwave absorption (MA) due to their customizable components, topology, and high porosity. However, the correlation between the structural parameters of the low-dimensional units and the MA performance of the 3D MOF derivatives remains unclear. Herein, we prepared a series of floral Fe/Ni@C with different petal sizes and aspect ratios to investigate the effect of low-dimensional structural parameters on the MA properties of 3D MOF derivatives. Specifically, we proposed a competitive coordination strategy. By adjusting the ratio of coordination metals, we successfully obtained floral FeNi-MOF-74 with different petal sizes and aspect ratios. Subsequently, the floral Fe/Ni@C was obtained by thermal-field modulation. It shows that, on the one hand, as the petal size increases, the conductive path is extended and the electron hopping is enhanced, thus facilitating the conductivity loss. And, with the rise of the petal aspect ratio, the tip effect is enhanced, which strengthens the polarization loss. On the other hand, the graphitization degree of the carbon components as well as the size and magnetic properties of the alloy particles can be effectively modulated by optimizing the thermal field modulation temperature. Noteworthily, under the conditions of a coordination metal ratio of 1:1 and an annealing temperature of 700 °C, the obtained MOF derivative exhibited excellent microwave absorption (−65.47 dB at 1.56 mm) and broadband (6.09 GHz at 1.76 mm). This strategy provides new ideas for modulating the microstructure and electromagnetic properties of MOF derivatives.