Effect Of Solvent Medium Research Articles

Quantifying plasmonic characteristics of pure and alkali doped aluminium clusters

Study of plasmonic response of molecules and metal nanoclusters have drawn a considerable attention during recent times due to their various practical applications. In this study, the optical properties and the plasmonic response of our recently reported Al13+ cluster [Guin et al. Journal of Molecular Graphics and Modelling, 2020, 97, 107544] and its alkali doped counterparts [Guin et al. Journal of Molecular Modeling, 2021, 27, 235] have been investigated based on Transition dipole moment (TDM), Natural Transition Orbital (NTO) and transition inverse participation ratio (TIPR) indices. Recently these indices have been utilized by various scientists to characterize plasmonic transitions of molecular systems and metal nanoclusters. In TDM analysis, the magnitude of all the contributing TDMs associated with the molecular orbital transitions have been estimated along with the angles the individual dipoles make with the resultant dipole moment vector. A transition having at least two dominating TDM contributions along with phase matching indicate a collective or plasmonic transition. The collectiveness of orbital transitions is also corroborated through NTO and TIPR analysis. The effect of solvent medium on the optical properties and plasmonic transitions have also been studied using time dependent density functional theory in the conductor like polarizable continuum model (TDDFT-CPCM). The solvent has a strong impact on the optical properties as well as the plasmonic response of the clusters. The dielectric environment of the solvent red shifts and broadens the spectra with respect to that in the gas phase. Plasmon like excitations have been found for Li doped Al13+ cluster without solvent and Na doped Al13+ cluster in ethanol and THF.

Preferential solvation and solvato(fluor)chromism of a green synthesized carbon nanodots in aqueous low molecular weight alcohols

Solvent medium effects on the optical spectra of a carbon nanodot (C-dots) as a solvato(fluor)chromic indicator have been investigated. The molar fluorescence transition energies of C-dots in different aqueous low molecular weight alcohols (C1-C3) were interpreted in terms of the Kamlet, Abboud and Taft equation. Emission results demonstrate that acidity is the most influential feature for the case of lighter methanol and ethanol, whereas the polarizability of the mixed solvent was the dominant factor for the propanol. The preferential solvation of the C-dots under consideration in the mixed water/alcohol solvents has been studied and were analyzed using two different models. In words, solvent exchange process and an excess function model were employed to evaluate the extent of preferential solvation. Correspondingly, both models exploited, confirmed the tendency of C-dots to be preferably solvated by alcohols rather than water. Interestingly, with an increase in the length of the alcohol carbon chain the extent of preferential solvation illustrated a decreasing trend.

Synergistic studies of Cassia tora gum with xanthan and guar gum: Carboxymethyl synthesis of cassia gum-xanthan synergistic blend and characterization

The present study describes the study of synergistic behavior of the Cassia tora (CTG) gum with xanthan gum (XG) and comparison with CTG and guar gum (GG) at varying temperatures. A carboxymethyl derivative of CTG: XG blend, having synergistic activity was synthesized and the reaction conditions were optimized using Taguchi's L′9 statistical design. The effect of solvent medium on the degree of substitution (DS) and the gelling property was also studied. The results reveal that synergistic interaction was found in the CTG: XG mixture whereas CTG: GG blend did not show synergistic behavior. The CTG: XG blend shows a highly viscous solution having 8371.9 cps viscosity at ambient temperature and gel is obtained by heating the blending solution and thereafter lowering the temperature. In continuum, an optimized carboxymethyl derivative (DS 0.16) also exhibits gelling properties. The carboxymethyl derivative was characterized by 1H NMR, FTIR spectroscopy and FESEM analysis. The synergistic action of gums may be utilized in food, cosmetics and pharmaceutical applications.

Spin-Flip Density Functional Theory for the Redox Properties of Organic Photoredox Catalysts in Excited States.

Photoredox catalysts (PCs) have contributed to the advancement of organic chemistry by accelerating conventional reactions and enabling new pathways through the use of reactive electrons in excited states. With a number of successful applications, chemists continue to seek new promising organic PCs to achieve their objectives. Instead of labor-intensive manual experimentation, quantum chemical simulations could explore the enormous chemical space more efficiently. The reliability and accuracy of quantum chemical simulations have become important factors for material screening. We designed a theoretical protocol capable of predicting redox properties in excited states with high accuracy for a selected model system of dihydroquinoxalino[2,3-b]quinoxaline derivatives. Herein, three factors were considered as critical to achieving reliable predictions with accurate physics: the solvent medium effect on excited-state geometries, an adequate amount of Hartree-Fock exchange (HFX), and the consideration of double-excitation character in excited states. We determined that it is necessary to incorporate solvent medium during geometry optimizations to obtain planar excited-state structures that are consistent with the experimentally observed modest Stokes shift. While density functionals belonging to the generalized gradient approximation family perform well for the prediction of photoelectrochemical properties, an incorrect description of exciton boundedness (spontaneous dissociation of excitons or extremely weak boundedness) on small organic molecules was predicted. The inclusion of an adequate amount of Hartree-Fock exchange was suggested as one approach to obtain bound excitons, which is physically reasonable. The last consideration is the double-excitation character in S1 states. As revealed by the second-order algebraic diagrammatic construction theory, non-negligible double excitations exist in S1 states in our model systems. Time-dependent density functional theory (TDDFT) is blind to doubly excited states, and this motivated us to use spin-flip DFT (SF-DFT). We established a theoretical protocol that could provide highly accurate estimations of photophysical properties and ground-/excited-state redox properties, focusing on the three factors mentioned above. Geometry optimization with DFT and TDDFT employing the B3LYP functional (20% HFX) in solution and energy refinement by SF-DFT reproduced the experimental redox properties in the excited and ground states remarkably well with mean signed deviations (MSDs) of 0.01 and -0.15 V, respectively. This theoretical protocol is expected to contribute to the understanding of exciton behavior in organic PCs and to the efficient design of new promising PC candidates.

OXIDATION OF DL-METHIONINE, A SULFUR-CONTAINING AMINO ACID BY DIETHYL AMMONIUM CHLOROCHROMATE

Oxidation of DL-methionine (Met), sulphur-containing amino acid by Diethylammonium chlorochromate (DEACC) in dimethylsulphoxide (DMSO) is leading to produce its consecutive sulphoxide. The reaction is of first-order w. r. t. methionine and DEACC. The addition of an acid enhance the reaction rate, the effect of acidity is expressed by the relation kobs = a + b [H+ ]. The rate of the oxidation of methionine is recorded in 19 non aqueous solvent medium. The effect of solvent medium is was studied in nineteen different organic solvents. The solvent effect is evaluated by the models of Kamlet and Swain multiparametric equation. Importance of the cation solvating powers is predominantly seen in the effects of solvent medium. On the basis of results and discussion a suitable mechanism is proposed.

Hyperpolarizability studies and Hirshfeld surface analysis of two heterocyclic chalcones.

In this work, the nonlinear optical (NLO) properties of two heterocyclic chalcones, (E)-1-(5-chlorothiophen-2-yl)-3-(thiophen-2yl)-2-propen-1-one (CLTT) and (E)-1-(5-methylfuran-2-yl)-3-(5-methylthiophen-2-yl)prop-2en-1-one (2MFT), are investigated. Using an iterative electrostatic embedding approach via the Møller-Plesset perturbation (MP2) theory, the chalcone crystals were simulated and the polarization effects on the isolated molecules are investigated. The electrical parameters of CLTT and 2MFT as dipole moment and linear polarizability were calculated via MP2/6-311++G(d) and the second hyperpolarizability was obtained via DFT/CAM-B3-LYP/6-311++G(d) level. A significant influence of the molecular packing on the chalcone electric parameters was observed. The static linear refractive index and the third-order electric susceptibility of the compounds were calculated and compared with experimental results available for other chalcone derivatives, indicating the CLTT crystal as a promising candidate for NLO applications in photonic and optoelectronic devices. The Hirshfeld surface analysis has been used to quantify the intermolecular interactions of the molecular crystals. Additionally, the solvent medium effects on the electrical properties of the heterocyclic chalcones were also studied.

On the potential as nonlinear optical material of a new chalcone derivative and its crystal and topological analysis

We report a study of the structural and the linear and nonlinear optical and electrical properties of a new chalcone. Using the Møller-Plesset Perturbation and the Density Functional approaches, the dipole moment, linear polarizability and second hyperpolarizabilities were calculated in static and dynamic electric fields. The supermolecule approach was used to simulate the crystalline environment of our crystal and the linear refractive index. Lorentz local field correction factor and third order macroscopic susceptibility were calculated, and the effects of solvent media on the non-linear optical properties are also taken into account through the Polarizable Continuum Model. This chalcone is almost planar, except for slight rotations in its open-chain which allows electron delocalization. This is also confirmed by an intramolecular hydrogen bond formed between the carbonyl and amine groups. Interestingly, a good third order macroscopic susceptibility value of 13.31 × 10−22m2V−2 was calculated, which is even higher than those reported for related chalcone derivatives.

Bare and functionalized nanodiamonds in aqueous media: A theoretical study

Nanodiamond particles, basically those produced by detonation method, are acquiring progressive attraction in different fields such as material, biomedical, and environmental engineering. Aqueous environments are usually dealt with at different stages of preparation, preservation, and application of these particles. The aim of this article is to perform a systematic first-principles density functional theory analysis on the interaction of C35 ultrasmall octahedral nanodiamond and its full homogeneous carboxylated and aminated forms, with water derived specie, namely, neutral, protonated, and deprotonated water and (H2O)20 water cluster. The effect of solvent media on the interactions has been considered through conductor like screening model. Through the calculations, C35 showed a hydrophobic nature, and C35(COOH)36 and C35(NH2)36 demonstrated hydrophilic characteristics. The interactions of all the water derived specie with the non-functionalized C35 were more intense compared with the functionalized C35(COOH)36 and C35(NH2)36 nanodiamonds, either in the gas phase or water media. Interestingly, in water media, the interaction energies of H3O+ and OH− with C35(NH2)36 were almost zero; only the interaction of H3O+ with C35(COOH)36 was zero, testifying to its Brønsted-Lowry acidic nature. To understand the nature of the interactions the electron density differences were utilized.

Third-Order Nonlinear Optical Properties of a Carboxylic Acid Derivative

We report a study of the structural and electrical properties of a carboxylic acid derivative (CAD) with structural formula C5H8O2 ((E)-pent-2-enoic acid). Using the M∆ller-Plesset Perturbation Theory (MP2) and the Density Functional Theory (DFT/CAM-B3LYP) with the 6-311++G(d,p) basis set the dipole moment, the linear polarizability and the first and second hyperpolarizabilities are calculated in presence of static and dynamic electric field. Through the supermolecule approach the crystalline phase of the carboxylic acid derivative is simulated and the environment polarization effects on the electrical parameters are studied. Static and dynamic estimation of the linear refractive index and the third-order nonlinear susceptibility of the crystal are obtained and compared with available experimental results. The characteristic vibrational modes and functional groups present in CAD were analyzed by Fourier Transform Infrared Spectrum (FTIR) in the region of 400-4000 cm-1. Through the Hirshfeld surface analysis the molecular structure and the vibrational modes properties of the CAD crystal are explored. The effects of solvent medium on the molecular properties are taken into account through the Polarizable Continuum Model (PCM). Also, the frontiers molecular orbitals, the band gap energy, and the global chemical reactivity descriptors are discussed. All the properties studied suggest that the present material may be considered for nonlinear optical material.

Effect of Solvent Medium on Optical and Structural Properties of ZnO–SnO2 Nanocomposite

Effect of Solvent Medium on Optical and Structural Properties of ZnO–SnO₂ Nanocomposite

INFLUENCE HALOGEN IN REACTION ARYLTELLUR TRYHALOHENIDE ELECTROPHILIC CYCLIZATION OF N-ALKENYL OF 2-TIOXOBENZO (THIENO)PYRIMIDIN-4-ONES

It is known from the literature that electrophilic heterocyclization of unsaturated substrates under the action of aryltellurium trichlorides is widely used to obtain tellurium-containing polycondensed heterocyclic systems, whereas the use of p -alkoxyphenyltellurium tribromides in such reactions is almost not described. p -Ethoxyphenyltelluriumtribromide was used for study the influence of a halogen in the electrophilic aryltelluronium reagent on products' yields and on the direction of the electrophilic intramolecular cyclization of N-alkenyl-2-thioxobenzo(thieno)pyrimidine-4-ones. It was not possible to obtain this electrophile with the reaction of tellurium tetrabromide with benzene containing electron donating group, so it was synthesized by bromination of the corresponding ditelluride in chloroform medium. The interaction between tellurium-containing electrophile and N-alkenyl-2-thioxobenzo(thieno)pyrimidine-4-ones was carried out in glacial acetic acid at room temperature. It has been established that during aryltellurobromination of 3-allyl-quinazoline-2-thione and N-alkenyl thioxo-thieno-pyrimidinones, the annelation of the thiazoline ring takes place, with the formation of a linear condensed system with an exocyclic aryltellurium fragment – hydrobromides of 3-[dibromo(4-ethoxyphenyl)telluromethyl]-2,3-dihydro-5 H -[1,3]thiazolo[2,3-b]quinazolin-5-one, 2-(dibromo(4-ethoxyphenyl)-telluromethyl)-2,3,6,7,8,9-hexahydro-5 H -benzo[4,5]thieno[2,3-d][1,3]thiazolo[3,2-a]pyrimidin-5-one and 2-methyl-2-(dibromo(4-ethoxyphenyl)-2,3,6,7,8,9-hexahydro-5 H -benzo[4,5]thieno[2,3-d][1,3]thiazolo[3,2-a]pyrimidine-5-one. The structure of the products of bromotelluro-cyclization is similar to the structure of products of aryltellurochlorination of the corresponding heterocycles. However, the yields of salts with the exocyclic bromoaryltellurium fragment are smaller compared to chloro- analogs. Lower yields of hydrobromides are associated with lower stability of intermediate bromotelluronium cation compared with chlorotelluronium, which is confirmed by theoretical calculations of Gibbs free energy of interaction of aryldihalidetellanium cation with an unsaturated substrate. Computations were performed using DFT level of theory in PRIRODA 17 program with using of GGA PBE functional and 3ζ basis set. The effect of solvent medium (acetic acid) was taken into account using the COSMO model with PM7 Hamiltonian in MOPAC2016 program. The composition and structure of all obtained compounds are proved by elemental analysis and NMR spectra.

Quinone based oligomeric sensors as colorimetric probes for cyanide anion: Effects of solvent medium and substituent on sensing

The main objective of the present study is to understand the structure-property relationships of sensor capable of colorimetric response, upon the addition of particular anions, due to hydrogen-bonding association between sensor and anion. Further, hydrogen-bonding association between sensor and anion, and thereby colorimetric response of the receptor in various solvent media was also targeted. For this, we have synthesized chloro-substituted quinone based oligomer sensor (QO-Cl) and cyano-substituted quinone based oligomer sensor (QO-CN), which contain the thiourea as a binding site. These oligomeric sensors were exploited as colorimetric sensors for cyanide anion [CN−]. Further, the sensing abilities of these sensors for CN− recognition in various solvents were monitored to investigate the influence of solvent on the hydrogen bonding association between sensor and anion. Our colorimetric and spectrometric results unveiled that the QO-CN sensor has shown the better binding constant (KQO-CN-CN−=39,317M−1) and detection of limit (DOL=1.2μM) for CN− than that of QO-Cl, (KQO-Cl-CN−=1950M−1; DOL=69μM). This can be attributed to the higher electron withdrawing nature of CN than the moderately electron-withdrawing substituent Cl.

Photoswitching in nanostructured benzofuro[3,2-b]pyridin-9-ol and benzothio[3,2-b] pyridin-9-ol compounds as red- and yellow-light-emitting molecules: A TD-DFT approach

In this work, intramolecular photo-induced proton transfer in Benzofuro[3,2-b]pyridin-9-ol (BFPO) and Benzothio[3,2-b] pyridin-9-ol (BTPO) were investigated using TD-DFT method at PBE0/6-311++G(2d,2p) and M06-2X/6-311++G(2d,2p) levels of theory. Both molecules are able to render both normal and tautomer emissions and exhibit the large Stokes-shifted fluorescence in gas and solvent media. The potential energy surfaces at ground and excited states, structural parameters, H-bonding energy, absorption and emission bands, vertical excitation and emission energies, oscillator strength, fluorescence rate constant, dipole moment, atomic charges and electron density at critical points were calculated. The effect of solvent media on electronics transition energies and absorption as well as florescence spectra are presented. The potential of these molecules as emissive materials in designing and generation of new displays and light sources were predicted based on their high Stokes shifts.

Effect of solvent medium on the structural, morphological and optical properties of ZnS nanoparticles synthesized by solvothermal route

Different morphologies of ZnS have been synthesized by a facile solvothermal approach in a mixed solvent made of Ethylenediamine (EN) and distilled water. The effect of solvent medium on the structural, morphological and optical properties of ZnS nanoparticles were investigated. The formation mechanism of different morphologies was proposed based on the experiment results. The as-prepared samples were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), energy dispersive spectrometer (EDS), Raman spectroscopy and UV-Vis-IR spectrophotometer. The results show that phase transformation is easily induced and there is a strong correlation between morphology and structure of the ZnS nanocrystals by changing the solvent. The results also show that we have successfully produced hexagonal phase ZnS nanorods with mixed solvent. The grain sizes in the range of 17–22 nm were obtained according to elaboration conditions. Raman spectra show the intense peak at 346 cm−1, which is a typical Raman peak of bulk ZnS crystal, no signature of secondary phases. The band gap of ZnS increased from 3.49 to 3.74 eV with an increase in the EN composition in the solvent, implying that the optical properties of these materials are clearly affected by the synthesis medium.

Effect of solvent medium on the structural, morphological and optical properties of ZnO nanoparticles synthesized by the sol–gel method

ZnO nanoparticles were synthesized using a sol–gel method. The effect of solvent medium on the structural, morphological and optical properties of ZnO nanoparticles were investigated using X-ray diffraction (XRD), scanning electron microscopy (SEM), photoluminescence spectroscopy (PL), UV–vis spectroscopy (UV–vis) and Energy-dispersive X-ray spectroscopy ( EDS). The XRD patterns showed single phase hexagonal structure. The crystallite size of as prepared ZnO nanoparticles was found to decrease from 28.1nm to 10.8nm with the increase in volume ratio of ethanol in the solvent as peak intensities and sharpness increase with corresponding increase in volume ratio of water. SEM micrographs showed that samples prepared in water medium are fairly spherical which turned to tiny rods with increasing volume ratios of ethanol. A sharp ultraviolet (UV) emission peak centred about 385nm and a broad green–yellow emission at about 550nm are observed with PL measurements. The band gap of ZnO decreased from 3.31 to 3.17eV with an increase in the ethanol composition in the solvent, implying that the optical properties of these materials are clearly affected by the synthesis medium.

Solvolysis mechanisms of RNA phosphodiester analogues promoted by mononuclear zinc(II) complexes: mechanisic determination upon solvent medium and ligand effects.

The solvolysis mechanisms of RNA phosphodiester model 2-(hydroxypropyl)-4-nitrophenyl phosphate (HpPNP) catalyzed by mononuclear zinc(II) complexes are investigated in the paper via a theoretical approach. The general-base-catalyzed (GBC) and specific-base-catalyzed (SBC) mechanisms are thoroughly discussed in the paper, and the calculations indicate a SBC mechanism (also named as the direct nucleophilic attack mechanism) when the cyclization of HpPNP is promoted by the Zn:[12]aneN3 complex ([12]aneN3 = 1,5,9-triazacyclododecane). The ligand effect is considered by involving two different catalysts, and the results show that the increasing size catalyst provides a lower energy barrier and a significant mechanistic preference to the SBC mechanism. The solvent medium effect is also explored, and reduced polarity/dielectric constant solvents, such as light alcohols methanol and ethanol, are more favorable. Ethanol is proven to be a good solvent medium because of its low dielectric constant. The computational results are indicative of concerted pathways. Our theoretical results are consistent with and well interpret the experimental observations and, more importantly, provide practical suggestions on the catalyst design and selection of reaction conditions.

Amination of glycidyl methacrylate-grafted polystyrene particles and their adsorption capacity for Nd3+ and Cd2+

A new chelating adsorbent was prepared by grafting glycidyl methacrylate (GMA) onto polystyrene (PS) particles using simultaneous radiation technique and amination of graft copolymers by reacting with diethylenetriamine. The effects of various parameters such as, irradiation doses, inhibitor concentrations, amination temperature, and reaction time were investigated. The grafting yield increased with irradiation dose to reach its maximum value at 15 kGy. The accelerative effect of solvent medium on the grafting yield was higher in THF than DMF. The addition of 0.001 % (wt) inhibitor to the reaction medium led to a sharp increase of grafting yield. The best conversion ratio was obtained at 115 °C during 24 h. By using a column separation technique, the adsorption behaviors of the adsorbent toward Cd2+ and Nd3+ in aqueous solution were examined. The adsorption amount of both Cd2+ and Nd3+ increased with initial ions concentration. The maximum equilibrium of Cd2+ and Nd3+ adsorbed ions were 18.1 and 17.58 mg/g, respectively. It was observed that the functionalized GMA-g-PS was reusable by desorbing with 0.1 M nitric acid almost without losing their adsorption capacity. FTIR test indicates that epoxide and amine groups were introduced onto GMA-g-PS and aminated GMA-g-PS, respectively. The Tg of graft copolymer slightly decreased, and that of aminated GMA-g-PS was higher than graft copolymer.

S055022 バイオポリマー水溶液の抵抗減少効果に関する研究 : 第2報 キサンタンガム水溶液の円管内圧力損失に及ぼす溶媒の影響([S05502]流れの抵抗低減(2))

S055022 バイオポリマー水溶液の抵抗減少効果に関する研究 : 第2報 キサンタンガム水溶液の円管内圧力損失に及ぼす溶媒の影響([S05502]流れの抵抗低減(2))

Preparation of chelating fabrics by radiation‐induced grafting of itaconic acid and acrylonitrile onto polypropylene nonwoven fabrics and subsequent amination of graft copolymer

AbstractA mixture of acrylonitrile (AN) and itaconic acid (IA) was cografted onto polypropylene (PP) nonwoven fabrics by preirradiation method. The effects of graft polymerization conditions such as temperature, reaction time, Mohr's salt concentration, solvent mixture ratio, and comonomer composition on the total grafting yield were investigated. The addition of AN as a comonomer increased the amount of IA that reacted with PP fabrics. An increase in the temperature from 40 to 60°C increased the grafting rate, but the final grafting yield decreased at high temperature. The addition of 0.01 wt % Mohr's salt to the reaction medium leaded to a sharp increase of grafting yield. The accelerative effect of solvent medium on the grating yield was higher in dimethylformamide (DMF) and methanol mixtures, when compared with DMF or methanol. Chelating fabrics was synthesized by subsequent amination of grafted fabric with ethylene diamine (EDA) and phenylhydrazine (PH). The conversion yield reached maximum value at about 90% for 80% PP‐g‐AN‐IA fabrics at 90°C. At same amination conditions, the conversion yield is higher when PP‐g‐AN‐IA fabrics react with EDA compared with PH. FT‐IR data indicate that amine groups were introduced onto PP‐g‐AN‐IA fabric through amide linkage between grafted AN or IA and EDA or PH. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011

Effects of Solvent Media and Temperature on the Self-Aggregation of Cationic Dimeric Surfactant 14−6−14, 2Br− Studied by Conductometric and Fluorescence Techniques

To explore how the solvent characteristics influence the self-aggregation of the cationic dimeric surfactant hexamethylene-1,6-bis(tetradecyldimethylammonium bromide) (14-6-14, 2Br(-)) and to obtain various energetic parameters, conductometric experiments were performed on the binary mixtures of three organic solvents--viz., 2-methoxyethanol (ME)-, acetonitrile (AN)-, and formamide (FA)- water (WR) at different temperatures ranging from 298.15 to 323.15 K. The steady state fluorescence measurements allowed us to calculate the average aggregation number (N(agg)) and the air-bulk phase surface tension helped us to correlate the solvent cohesive energy density with Gibbs energy of micellization (DeltaG(0)(m)). The results showed that, although micellization process becomes less favorable with the increase in volume % of the ME, AN and FA in the binary mixed media, the increment in the cmc below 20% (v/v) of the organic solvents is comparatively less showing the predominance of WR character in the bulk phase. Because of the decrease in Gibbs interfacial energy contribution (DeltaG(0)(interf)) to DeltaG(0)(m), the average aggregation number (N(agg)) decreased with the increase in the volume % of the organic solvent in the mixed media. As the enthalpy of micellization became more negative, the corresponding entropy change became less positive and enthalpy-entropy compensation phenomenon was observed for the micellization of 14-6-14, 2Br(-) in all the mixed media in the studied temperature range.