Effect of solvent medium on the structural, morphological and optical properties of ZnO nanoparticles synthesized by the sol–gel method

Abstract

ZnO nanoparticles were synthesized using a sol–gel method. The effect of solvent medium on the structural, morphological and optical properties of ZnO nanoparticles were investigated using X-ray diffraction (XRD), scanning electron microscopy (SEM), photoluminescence spectroscopy (PL), UV–vis spectroscopy (UV–vis) and Energy-dispersive X-ray spectroscopy ( EDS). The XRD patterns showed single phase hexagonal structure. The crystallite size of as prepared ZnO nanoparticles was found to decrease from 28.1nm to 10.8nm with the increase in volume ratio of ethanol in the solvent as peak intensities and sharpness increase with corresponding increase in volume ratio of water. SEM micrographs showed that samples prepared in water medium are fairly spherical which turned to tiny rods with increasing volume ratios of ethanol. A sharp ultraviolet (UV) emission peak centred about 385nm and a broad green–yellow emission at about 550nm are observed with PL measurements. The band gap of ZnO decreased from 3.31 to 3.17eV with an increase in the ethanol composition in the solvent, implying that the optical properties of these materials are clearly affected by the synthesis medium.