Miniaturized and wearable electronic products require electromagnetic interference shielding (EMI) materials with sensing functions to cope with complex application situations. Herein, an effective dual-network structure is designed to fabricate two-dimensional transition metal carbides and nitrides/bacterial cellulose-thermoplastic polyurethane (MXene/BC-TPU) foams with intriguing EMI shielding property and piezoelectric sensing ability under both compressive and tensile strains. Anisotropic MXene/BC aerogels, as conductive networks, with impressive conductivity (1912 S m-1), ultrahigh EMI shielding effectiveness (SE) of 86 dB, and absolute SE up to 63,608 dB cm2 g-1 can be built by directional freezing. Interpenetrated neuro-like TPU network is embedded into the MXene/BC aerogels by controllable coagulation to provide elasticity. Inheriting the elastic TPU network, the light weight MXene/BC-TPU foams show superb elasticity and remarkable fatigue resistance suffering both compressive and tensile strains with a wide strain range (-80-80%). Meanwhile, benefiting from the separated conductive MXene/BC network and the elastic TPU network, the MXene/BC-TPU foams display an outstanding EMI SE (76 dB) with an EMI SE retention of 86.8% after 5000 compression-release cycles and an EMI SE retention of 69.7% after 100 stretch-release cycles, respectively. Furthermore, the MXene/BC-TPU foams reveal stable resistance signal output as piezoresistive sensors in a wide strain range of -80-80%. The highly conductive, stretchable, and compressible MXene/BC-TPU foams are suitable as EMI shielding and motion monitoring materials for wearable electronics.
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