Effect Of Water Saturation Research Articles

Pore-scale study of the dynamic evolution of multi-phase seepage parameters during hydrate dissociation in clayey silt hydrate-bearing sediments

Unlike conventional oil and gas sources, natural gas hydrate (NGH) is stored in solid form within the pores of loose submarine sediments. Production by any method poses a complex problem involving phase transition and multi-phase flow of gas and water. The evolution of hydrate dissociation from the solid phase to gas and liquid phases in a hydrate reservoir is a dynamic process incorporating pore structure and multi-phase seepage. The solid–gas-liquid phase dissociation of NGH affects reservoir seepage properties by altering the micropore structure of the hydrate-bearing sediments. This study, based on the lattice Boltzmann method of modeling fluids flow, clearly demonstrates the micropore-scale changes in pressure and heat transfer that take place during hydrate dissociation. Pore-scale heterogeneity is found to influence the complex development of hydrates in a porous clayey silt medium during dissociation. The effect of hydrate, gas and water saturation on the evolution of relative permeability is identified, and the relationship between relative permeability and hydrate saturation during hydrate dissociation is quantified. These findings provide theoretical support for the implementation of marine natural gas hydrate production testing and future commercial production in China.

Assessment of the Thermal Properties of Gypsum Plaster with Plastic Waste Aggregates.

Building material manufacturers must support new production models that encourage the manufacture of more efficient and sustainable products. This includes thinking about savings in the use of raw materials, a contribution to the energy efficiency of buildings during their useful life, and a reduction in the generation and deposit of waste in landfills. In this research, an analysis of the thermal properties of gypsum composites added with plastic waste is carried out using the most common methods, the steady state method and the transient plane source method, and the effect of water saturation on these composites is tested. The results show an improvement in the thermal performance of the composites (values reduced with respect to the reference by 4-7%), despite their heterogeneity, as well as a variation in the measurements carried out, depending on the method used for the measurements (variation up to 10%). It is also found that the degree of humidity negatively affects the thermal conductivity coefficient but, on the contrary, this coefficient is not altered in the composites with plastic waste, due to their lower hygroscopicity. Therefore, it is considered that the proposed eco-plasters are a good alternative to traditional plasters, with which to contribute to the achievement of the objectives of the current European directives on waste and circular economy.

High pressure salt water and low temperature effects on the material performance characteristics of additive manufacturing polymers

The effects of salt water exposure at deep ocean depth pressures when coupled with low temperatures on the material characteristics of three unique additively manufactured polymers has been investigated through a detailed experimental approach. The polymers in the study were manufactured utilizing both Vat Photopolymerization and Material Extrusion printing techniques. The Material Extrusion process was utilized to produce material specimens of Stratasys ULTEM 9085 and Markforged Onyx while the Vat Photopolymerization process was used to produce specimens of Accura ClearVue. The ULTEM 9085 and Markforged Onyx are filament based polymers and the ClearVue is a liquid based resin. The specimens were first submerged in a high pressure, salt water bath of 3.5% NaCl solution at 34.5 MPa (5000 lb/in2) for a total exposure time of 60 days to determine the water absorption characteristics. Subsequent to the salt water exposure at high pressure, the specimens were evaluated to determine changes in tension, compression, flexure, and in-plane fracture properties. To determine the effects of water saturation and low temperature coupling, the mechanical testing was performed at temperatures of 20 °C, 0 °C and −20 °C in both dry and saturated conditions. Additionally, non-destructive testing in the form of TeraHertz and FIRT imaging was conducted to analyze the physical material changes through the thickness of the material due to the saline water absorption. To quantify the change in material storage and loss moduli properties, Dynamic Mechanical Analysis (DMA) characterization was performed on each of the AM polymers in dry and saturated states. The DMA testing also quantified changes in the Glass Transition Temperature because of salt water exposure. In summary, The current study investigates the effects of coupled long term/high pressure salt water exposure with low temperatures on the mechanical and material characteristics of three unique AM polymers by: (1) immersing the materials in a salt water solution at 34.5 MPa for 60 days, (2) Conducting post exposure mechanical testing on the materials at 0 °C and −20 °C with comparisons to 20 °C testing on dry specimens, and quantifies changes in material properties through DMA experiments. The results from all testing in the study show that high pressure salt water exposure when coupled with low temperatures has unique effects on each of the materials considered in the study and careful consideration to each parameter must be given based on the material type when components will be employed in marine operations.

An enhancement in the petrophysical evaluation in a vuggy carbonate gas reservoir by integrating the core data and empirical methods, Zagros basin, south of Iran

The presence of vuggy pore types poses challenges in accurately assessing effective porosity. This study focuses on the significant scientific issue of improving petrophysical evaluation in vuggy carbonate gas reservoirs. The Kangan Formation is one of the main gas reservoir formations in the southern Zagros region, Iran. The main objective of the current research is to distinguish and exclude the influence of vuggy pore types from effective porosity in the reservoir pay zones of the Kangan reservoir.In the current research, a combination of full suite logs, image logs, core analysis, and thin section studies was employed. The image logs illustrate that vuggy porosity is abundant in the Kangan Formation and these results are confirmed by the available core thin sections, specifically in Zone Kangan_B; Additionally, the cross plots of compressional velocity versus bulk density and total porosity, as a part of rock physics study, indicate the characteristics of the vuggy reservoir. Two methods are utilized to quantify vuggy porosity. The first method, the Velocity Deviation Log (VDL) approach, identifies various available pore types, especially vugs. The second method is a newly proposed approach that can exclude vuggy porosity from the computed effective porosity. In this novel approach, a variable porosity exponent (m) is derived by adopting the Lucia equation to exclude vuggy porosity from the effective porosity computations. Thus, petrophysical evaluation can be implemented based on the constant and variable “m”. Comparing both petrophysical results, it is evident that the amounts of effective porosity and water saturation are modified in the vuggy-bearing intervals. Applying the proposed approach will improve the accuracy of petrophysical properties and lead to the proper calculation of the hydrocarbon volume in the carbonate reservoir rocks containing isolated vugs, particularly in gas-bearing reservoirs where conventional logs are affected by gas contents.

Impact toughness and dynamic constitutive model of geopolymer concrete after water saturation

The dynamic compression test of geopolymer concrete (GC) before and after water saturation was carried out by the split Hopkinson pressure bar (SHPB). And the effects of water saturation and strain rate on impact toughness of GC were studied. Based on Weibull statistical damage distribution theory, the dynamic constitutive model of GC after water saturation was constructed. The results show that the dynamic peak strain and specific energy absorption of GC have strain rate strengthening effect before or after water saturation. The impact toughness of GC decreases after water saturation. The size distribution of GC fragments has fractal characteristics, and the fractal dimension of GC fragments after water saturation is smaller than that before water saturation. The dynamic constitutive model based on Weibull statistical damage distribution theory can accurately describe the impact mechanical behavior of GC after water saturation, and the model fitting curves are in good agreement with the experimental stress–strain curves.

Investigating the Effect of Water Saturation on Rock Fracture Characteristics: Some Insights from Digital Image Correlation Technology

Investigating the Effect of Water Saturation on Rock Fracture Characteristics: Some Insights from Digital Image Correlation Technology

The Effect of Salt Concentration on Dielectric Permittivity and Interfacial Polarization in Carbonate Rocks with Complex Pore Structure

Summary Broadband dielectric dispersion measurements are attractive options for the assessment of water-filled porosity. Dielectric permittivity is influenced by salinity as well as other rock/fluid properties. However, the effect of salinity on Maxwell-Wagner polarization (i.e., interfacial polarization) and dielectric permittivity in rock samples with complex pore structures requires further investigation. The objectives of this work are (a) to perform frequency-domain dielectric permittivity numerical simulations on 3D pore-scale rock samples at different salt concentration levels, (b) to quantify the effect of salinity on dielectric permittivity and interfacial polarization in the frequency range between 20 MHz and 5 GHz, and (c) to quantify the critical frequency (i.e., the frequency at which the relative permittivity becomes frequency-independent). We first perform pore-scale frequency domain dielectric permittivity simulations in fully water-saturated carbonate samples with complex pore structures to obtain the complex dielectric permittivity in the frequency range of 0.01–5 GHz and at different salinity levels. Next, we numerically create partially water/hydrocarbon-saturated water-wet samples and perform simulations at different salinity and water saturation levels to investigate the combined effect of salinity and water saturation on dielectric permittivity. Finally, we investigate how reliable conventional mixing models, such as the complex refractive index model (CRIM) and Hanai-Bruggeman (HB), are in the assessment of water saturation at different salinity levels. We used 3D pore-scale rock samples with complex pore structures from Austin Chalk, Estaillades Limestone, and Happy Spraberry formations. The increase in salinity from 2 to 50 parts per thousand (PPT) resulted in the relative permittivity to increase by 18% at 20 MHz. Similarly, an increase in salinity from 2 PPT to 50 PPT resulted in electrical conductivity to increase by 15 times at 20 MHz. However, at 5 GHz, the difference between the relative permittivity of the samples at different salinities was negligible. We demonstrated that the critical frequency was above 1 GHz. Thus, if complex dielectric permittivity at 1 GHz is being used, an accurate salinity assumption is required in the interpretation of conventional dielectric mixture models in carbonate formations. Finally, we observed 52% and 42% average relative errors in water saturation quantification when applying CRIM and HB models at all the frequencies of interest, respectively. The results also indicated that conventional models should not be used in the presence of uncertainty in salinity at lower frequencies. The results of this work quantified the frequency at which the water-filled pore volume rather than the Maxwell-Wagner polarization controls the relative permittivity of rock samples saturated with a wide range of brine salinity. Moreover, the results demonstrated that the relative permittivity of the rock samples with complex pore structures may still be significantly affected by the interfacial polarization even at 1 GHz. Moreover, the results suggested that the conventional mixture methods cannot reliably take into account the salt concentration of formation water, and this can lead to significant errors in reserves assessment.

The response of dry and wet silica sand to high velocity impact

Understanding the mechanisms governing the interaction of high-velocity projectiles and sand targets is important for numerous applications and industries. The high-velocity penetration of sand targets is known to be controlled by micromechanical phenomena; however, our quantification of these phenomena and our understanding of water saturation effects on target response is presently limited. To help improve our understanding of these phenomena, we performed impact experiments on wet and dry sand with in-situ and post-mortem analysis in a two-stage gas gun with varying impact chamber pressures. For in-situ analysis, we developed and used a novel experimental method for measuring projectile depth and three-dimensional displacement fields from orthogonal flash X-ray images acquired during the penetration process. We also employed in-situ high-speed imaging of ejecta. For post-mortem analysis, we examined final depths of penetration, particle size distributions, and permanent penetrator deformation. We found that impacts into wet sand targets featured enhanced sand displacements around projectiles, enhanced ejecta, and enhanced intermediate and final depths of penetration as compared to impacts into dry targets. We also found that impacts into wet targets led to less particle breakage than impacts into dry targets. Target chamber pressure was found to significantly influence final depth of penetration, likely through a fluidization process as air and fluid escaped the sample’s pores to equilibrate with the surrounding chamber pressure after initial impact. We discuss our findings in the context of existing literature and discuss the hypothesized origin of several of our observations with support from modeling efforts described elsewhere.

Water saturation effects on rock abrasivity and TBM tunneling efficiency

Tunnel boring machine (TBM) tunneling efficiency is influenced by surrounding rocks, TBM design, and interaction between the TBM cutter and rocks. Using a case study from a water conveyance tunnel project located in northwestern China and involving five different lithologies (metamorphic andesite, sandstone, granite, quartz schist, and quartz diorite), this work investigates the water saturation effects on Cerchar abrasivity index (CAI) and its correlations with other physical and mechanical rock properties and TBM disc cutter and energy consumption. The results show that water saturation reduces CAI for all examined rocks except for the quartz diorite at the 90 % confidence level. CAI of saturated rocks (CAIsat) has statistically better correlations with weighted Mohs hardness value of rock minerals (Ha), equivalent quartz content (EQC), and uniaxial compressive strength (UCS), than CAI of dry rocks (CAIdry). The in-situ construction data analyses suggest that the average disc cutter consumption increases exponentially with the rise of CAI values in both dry and saturated conditions, and the water saturation effects significantly reduce the disc cutter consumption within medium-hard and hard surrounding rocks. Both disc cutter and specific energy consumption have a quadratic relationship with the ratio of the maximum cutter spacing to penetration depth (Smax/P), and water saturation can significantly shift the quadratic relationships. Optimal Smax/P ranges for minimizing the disc cutter and energy consumption are recommended for different rocks under dry and saturated conditions. The findings from this study can support estimating cutter and energy consumption with considerations of groundwater effects.

(Digital Presentation) Modeling the Effect of Membrane Electrode Assembly Microstructure on Thermal and Water Transport in Polymer Electrolyte Fuel Cells

The effect of water management on oxygen transport plays a critical role in the design of high-performance polymer electrolyte fuel cells (PEFCs) for the automotive industry, especially at low cathode platinum loading [1,2]. In this regard, optimizing the hierarchical pore structure of the membrane electrode assembly (MEA) is crucial to alleviate cathode flooding while ensuring good membrane hydration [3]. However, this task is complicated due to the small dimensions involved in the problem. Mathematical modeling has turned out to be a key tool to understand transport in the thin layered assembly used in PEFCs, including the catalyst layer (CL), microporous layer (MPL) and gas diffusion layer (GDL).In this work, oxygen, heat and two-phase water transport in the MEA are examined by means of a 1-dimension continuum bundle of capillary tubes model. Experimental pore size distributions (PSDs) are considered for the GDL/MPL/CL assembly. The model takes especial care in analyzing thermal and water behavior in catalyst layer by considering micro (< 20 nm of pore radius), meso (between 20 and 300 nm) and macroscale (> 300 nm) structures as different interconnected domains, each with their own effective thermal conductivity and water saturation. In this aspect, taking into account pore hydrophilicity or hydrophobicity is determinant as water behavior is extremely different.The model predictions are validated against previous experimental data for various operating conditions and pore structures (Figure 1a). The results offer precise information on the coupling between heat and water transport in both liquid and gas phases, and the impact of operating conditions and transport properties on the saturation distribution through the MEA layers (Figure 1b). Then the continuum bundle of capillary tubes model is also used to run a parametric analysis centered on the obtention of optimal PSD-dependent effective transport properties to produce improved MEA microstructures.[1] A. Sánchez-Ramos, J.T. Gostick, P.A. García-Salaberri, Modeling the Effect of Low Pt loading Cathode Catalyst Layer in Polymer Electrolyte Fuel Cells: Part I. Model Formulation and Validation, Journal of the Electrochemical Society 168 (2021) 124514.[2] A. Sánchez-Ramos, J.T. Gostick, P.A. García-Salaberri, Modeling the Effect of Low Pt loading Cathode Catalyst Layer in Polymer Electrolyte Fuel Cells: Part II. Parametric Analysis, Journal of the Electrochemical Society 169 (2022) 074503.[3] M. Gomaa, A. Sánchez-Ramos, N. Ureña, M.T. Pérez-Prior, B. Levenfeld, P.A. García-Salaberri, M. Rabeh, Characterization and modelling of free volume and ionic conduction in copolymer proton exchange membranes, Polymers 14(9) (2022) 1688. Figure 1

Constrained nonlinear amplitude-variation-with-offset inversion for reservoir dynamic changes estimation from time-lapse seismic data

We develop a novel elastic amplitude-variation-with-offset (AVO) inversion process to estimate the fluid saturation and effective pressure or variations in these properties from time-lapse seismic data sets. These changes occur in oil and gas reservoirs caused by fluid injection or hydrocarbon production that leads to changes in the elastic wave properties, reflectivity, and seismic response. Our method is based on a seismic forward model that consists of a linearized AVO equation and a rock-physics model. The AVO equation links the elastic wave properties to seismic reflection amplitudes, whereas the rock-physics model maps the saturation and pressure into seismic velocities and density. The inversion approach relies on the gradient descent technique to estimate the unknown variables by searching for the minimum of the least-squares misfit between the observed and modeled data. The first-order gradient equations of the least-squares data misfit function with respect to effective pressure and water saturation are derived by using the adjoint-state method and the chain rule. The optimization method used to minimize the misfit function and obtain the best optimal solution is a limited-memory quasi-Newton algorithm. This inversion process allows us to incorporate prior constraints by using the logistic function to map the model variables to a bounded range. To achieve a stable solution to ill-posed inversion problems, optimal regularization weights are applied. The application of the developed workflow on 1D synthetic and real well-log data from the Edvard Grieg oil field simulating various saturation-pressure conditions during production demonstrates the validity of the approach with different noise levels. The inversion is then applied to a 2D synthetic data set modeled from the reservoir model of the Smeaheia field, a potential site for a large-scale offshore CO2 storage field located in the North Sea. Our results illustrate that our inversion method efficiently and accurately estimates reservoir saturation and pressure variations.

Estimate and Analyze The Impact to the Brittleness Index of Digital Rock Image of Carbonate

Digital rock physics is a modern method of determining the elastic properties, an important parameter to analyze the brittleness index, combining the digital technique with the numerical method. This paper analyses the effect of mineral content, water saturation, fluid type, and porosity. Carbonate digital images with 501 × 450 × 482 pixels which are divided into sub-cubes of 50 pixels3 are used. Calculating stress and strain with a numerical approach to producing the modulus elastic, and then the brittleness index can be approximated. The result shows calcite and ankerite are stiffer than quartz but not resistant to shear stress. An increase in the fluid saturation decreases the modulus value linearly in the oil case but suddenly in the gas case. For porosity variation, the greater the porosity in a material or rock will make it less rigid and not easily deformed. The effect on brittleness increases when water is replaced by fluids (either oil or gas) but decreases when there is more calcite, and ankerite and also goes down if the porosity gets bigger. So this study concludes, calcite, ankerite, and increasing porosity make the material more ductile but fulfilling with fluid will make it a little more brittle.

Effect of water saturation on Cerchar abrasivity index (CAI) of clay-rich rocks at different scratch lengths

Predicting the cutter consumption rate of mechanical excavators using the Cerchar abrasivity index (CAI) results is possible. However, changing operational parameters in the field may cause differences between the estimated cutter consumption rate based on CAI test results and the real cutter consumption rate observed in the field. One of the essential parameters in the field that affects the cutter consumption rate is the increase in the water content of the excavated rocks. In theory, an increase in the water content of rocks is expected to reduce their abrasivity. In addition, the prediction of cutter consumption rate is based solely on CAI test results conducted on dry surfaces. However, especially during the excavation of low-strength clay-rich rocks, the excavated rock material can adhere to the cutters and block them, leading to a higher cutter consumption rate than initially predicted. This study aims to analyze the rock-pin interaction in CAI tests conducted on wet surfaces of clay-rich rocks and investigate the effect of water saturation on CAI at different scratch lengths. CAI tests were conducted on dry and wet surfaces of 20 clay-rich rocks with low strength at 10, 30, 50, and 70 mm scratch lengths, respectively. The relationships between the CAI test results obtained on dry and saturated rock surfaces were statistically analyzed for each scratch length. A positive linear correlation was found between CAI values obtained on dry (CAIDry) and saturated surfaces (CAISat) at each scratch length. The percentage variations in CAI values at each scratch length were analyzed in detail. It was found that 90 % of samples have higher CAIDry than CAISat at 10 mm scratch length. However, it was observed that as the scratch length increased, the relationship between the CAI values obtained in dry and saturated conditions changed, and the proportion of samples with CAIDry higher than CAISat decreased to 65 %, 55 %, and 25 % at scratch lengths of 30 mm, 50 mm, and 70 mm, respectively. In CAI tests conducted on saturated surfaces, it was observed that the excavated rock material adhered to the test pins, and as the scratch length increased, the increase in CAISat values was considered to be due to this situation. This study revealed the importance of considering the adhesion potential of rocks to cutters at water-saturated conditions for the accurate prediction of cutter consumption in the excavation of clay-rich rocks.

Poroelastic response of unsaturated soils to cyclic loads with arbitrary waveforms

AbstractWe develop an analytical solution to the problem of one‐dimensional consolidation of unsaturated soil subjected to cyclic loads with arbitrary waveforms. The solution predicts the excess pore water and pore air pressures and the accompanying vertical compression in a poroelastic, unsaturated soil material. Cyclic loading occurs in a variety of engineering applications and often generates higher excess pore fluid pressures and larger vertical compression than does a time‐invariant load. In the present study, the loading function is allowed to take on any arbitrary waveform represented by a Fourier trigonometric series. Analytical solution to the boundary‐value problem in one dimension is given in closed form describing the frequency‐independent and frequency‐dependent components of the poroelastic response. We verify the analytical solution through representative examples involving cyclic loads with square and triangular patterns. Apart from the shape of the forcing function, we also investigate the effects of initial water saturation, soil texture, and excitation frequency on the system response.

Influence of water saturation on interlayer properties of HDTMA-, HDTMP-, and HDPy-modified montmorillonite organoclays

Surfactant-modified clay minerals, organoclays, are well-studied and used commercially for removing contaminants from water. Nevertheless, dry organoclay properties are typically used to understand and predict contaminant sorption. In this work, the effects of water saturation on two properties important to contaminant sorption were examined: organoclay interlayer space and surfactant alkyl tail conformational ordering. Montmorillonite was modified to 0.25–3.0 CEC using three surfactants: hexadecyltrimethylammonium (HDTMA), hexadecylpyridinium (HDPy), and hexadecyltrimethylphosphonium (HDTMP). At low surfactant-loadings (< 1 CEC and < 15% fOC), water saturation expanded the maximum organoclay interlayer by 4–8 Å, depending on the surfactant and its loading but had little effect on surfactant tail conformational ordering. At low surfactant loadings, water saturation likely promotes contaminant sorption relative to expectations based on dry organoclay properties, particularly for larger contaminants, due to a relaxation of the physical constraints of the interlayer. At higher surfactant loadings, HDTMA and HDTMP organoclays showed relatively small effects of water saturation, but effects were significant for HDPy organoclays. The maximum interlayer space of the HDPy organoclay at 20.7% fOC expanded 3-fold (+22.3 Å) upon hydration, which is attributed to a substantial rearrangement of the pyridinium headgroup. All HDPy organoclays with fOC > 20% experienced a notable increase in the alkyl tail conformational ordering upon hydration, becoming fully solid-like, even as negligible interlayer expansion occurred at the highest loadings. At high HDPy-loading water saturation would likely restrict sorption of contaminants relative to what might be expected based on dry properties, due to the energetic barrier of cavity formation in the more solid-like interlayer phase. This work provides evidence from three types of organoclays that water-saturated organoclay properties can differ substantially from those of dry organoclays. Characterization of organoclays under water-saturated conditions that are relevant to contaminant sorption will facilitate our understanding and improvement of organoclay performance.

Mechanical Behavior and Failure Mechanism of Rocks under Impact Loading: The Coupled Effects of Water Saturation and Rate Dependence

Mechanical Behavior and Failure Mechanism of Rocks under Impact Loading: The Coupled Effects of Water Saturation and Rate Dependence

Kinetic mechanisms of methane hydrate replacement and carbon dioxide hydrate reorganization

The carbon dioxide replacement is an ideal way to mine natural gas hydrates. However, current challenges of low replacement efficiency and immature technology compromise its application spectrum. This study aims to simulate the displacement of methane hydrate by carbon dioxide in a porous media system and verify the effect of water saturation on methane hydrate through experimental tests. By constructing a molecular dynamics model to investigate the replacement process of methane hydrate with carbon dioxide, the role of free water in this process was examined. Additionally, the study elucidated the factors contributing to suboptimal methane storage rate and low carbon dioxide recovery rate from a heat exchange perspective. The results show that methane replacement from methane hydrate can be divided into four stages. When the water saturation approach to hydrate saturation, and the temperature and pressure are between the phase curves of methane hydrate and carbon dioxide hydrate, the carbon dioxide storage rate and methane recovery rate can be significantly improved. The participation of free water can make the replacement more complete. The primary factor determining the replacement effect is the area of contact between carbon dioxide and methane hydrate, which is followed by the newly created carbon dioxide hydrate, which will impact the subsequent mass transfer. Although the heat released by the formation of carbon dioxide hydrate favor the replacement reaction proceed, most of the heat may get lost with the volatilization of carbon dioxide, resulting in the inability or incomplete decomposition of methane hydrate far away from free water. This research will surely have a profound impact on how hydrate replacement mining is monitored and managed as well as the ecosystem around it.

Cyclic Impact Damage and Water Saturation Effects on Mechanical Properties and Kaiser Effect of Red Sandstone Under Uniaxial Cyclic Loading and Unloading Compression

Cyclic Impact Damage and Water Saturation Effects on Mechanical Properties and Kaiser Effect of Red Sandstone Under Uniaxial Cyclic Loading and Unloading Compression

Investigation of the Influence of Formation Water on the Efficiency of CO2 Miscible Flooding at the Core Scale

This study investigated the impact of formation water on the mass transfer between CO2 and crude oil in low-permeability reservoirs through CO2 miscible flooding. Formation water leads to water blocks, which affect the effectiveness of CO2 miscible flooding. Therefore, we studied the impact and mechanisms of formation water on the CO2-oil miscibility. The microscale interaction between formation water-CO2-core samples was investigated using CT scanning technology to analyze its influence on core permeability parameters. In addition, CO2 miscible flooding experiments were conducted using the core displacement method to determine the effects of formation water salinity and average water saturation on minimum miscibility pressure (MMP) and oil displacement efficiency. The CT scanning results indicate that high-salinity formation water leads to a decrease in the porosity and permeability of the core as well as pore and throat sizes under miscible pressure conditions. The experimental results of CO2 miscible flooding demonstrate that CO2-oil MMP decreases as the salinity of the formation water increases. Moreover, as the average water saturation in the core increases, the water block effect strengthens, resulting in an increase in MMP. The recovery factors of cores with average water saturations of 30%, 45%, and 60% are 89.8%, 88.6%, and 87.5%, respectively, indicating that the water block effect lowers the oil displacement efficiency and miscibility.

Effects of Water Saturation and Loading Condition on Rock Tensile Strength: Insights from Acoustic Emission Analysis

Effects of Water Saturation and Loading Condition on Rock Tensile Strength: Insights from Acoustic Emission Analysis