The urban building morphology is one of the most important effects of urban thermal environment (UTE). The sky view factor (SVF) is a crucial structure index of buildings and it combines height and density attributes. These attributes have impacts on the air temperature(Tair). However, there are few studies on the association between SVF and Tair across block scales. In this paper, we designed ten scenarios according to the characteristics of Beijing's commercial and residential buildings. Furthermore, we used ENVI-met, a microclimate simulation model, to simulate the Tair in designed scenarios and evaluate the impact of SVF on the Tair of each component. A number of significant observations were noted based on the experimental results: (1) from 10:00 to 17:00, there is a positive correlation between SVF and Tair; from 18:00 to 9:00 the next day, there is a negative correlation between SVF and Tair (2) the relationship between building shadow ratio (BSR) and Tair is not a single negative correlation: at sunrise, BSR is the maximum in a day, but the cooling effect of BSR on Tair is not obvious because of the weak solar radiation. In addition, the arrangement of building directions has a great influence on the relationship between BSR and Tair (3) for the same building scenario, BSR decreases with the increase of SVF (4) the synergistic effect of SVF and BSR on Tair in the daytime can be divided into two periods, the separation time points are 7:00 and 14:00. This study can provide instructions for urban design in optimizing building layout and mitigating the urban heat impact on human health.