The microstructures and microhardness of laser-processed Fe-0.2wt.%C-20wt.%Cr alloys were investigated as a function of melt depth in single and multiple (overlapping) laser passes. The single-laser-pass alloys exhibited duplex austenite-ferrite structures with no evidence of carbide precipitation. Melt depths of up to 600 μm did not influence this microstructure. The multiple-laser-pass alloys consisted of lath martensite-ferrite structures in deep (about 600 μm) penetration melts and austenite-ferrite structures in shallow (about 120 μm) penetration melts. The transformation of austenite to martensite in multiple-laser-pass alloys, observed only in deep penetration melts, was explained as due to the effects of tempering temperature, time and quench rate obtained during subsequent laser passes. Conventional furnace heat treatments of single-laser-pass alloys substantiated these conclusions.
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