Compared with their inorganic counterparts, the flexoelectric effect of polymers is much less studied, and the mechanisms underlying this gradient electromechanical coupling effect have rarely been explored. In this work, the temperature dependence of the flexoelectric coefficients of PVDF-based copolymers and terpolymers was measured, and the mechanisms that affect the flexoelectric response of the polymers were investigated. For these polymers, the flexoelectric response decreases abruptly in the temperature range where the peaks of dielectric loss or mechanical loss are observed. These loss peaks originate from the phase transition or polymer chain relaxation processes. Based on this observation, we propose that the temperature dependence of the flexoelectric response of the polymers is closely related to polymer chain mobility and relaxation processes. Our study provides an in-depth understanding of the flexoelectric effect in polymers.
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