Effect Of Condensation Research Articles

Two-fluid model of rf current condensation in magnetic islands

The stabilization of tearing modes with rf waves is subject to a nonlinear effect, termed rf current condensation, that has the potential to greatly enhance and localize current driven within magnetic islands. Here we extend previous investigations of this effect with a two fluid model that captures the balance of diffusive and thermal equilibration processes within the island. We show that the effective power and resulting strength of the condensation effect can be greatly enhanced by avoiding collisional heat loss to the ions. The relative impact of collisions on the overall power balance within the island depends on the ratio of the characteristic diffusion timescale and the electron–ion equilibration time, rather than the latter alone. Although relative heat loss to ions increases with island size, the heating efficiency does as well. In particular, we show that the latter safely dominates for large deposition profiles, as is typically the case for lower hybrid current drive. This supports the possibility of passive stabilization of neoclassical tearing modes without the precise aiming of the rf waves required for electron cyclotron current drive stabilization.

Equatorial modons in dry and moist-convective shallow-water systems on a rotating sphere

Abstract

Experimental study on the composition evolution and selective separation of biomass pyrolysis vapors in the four-staged indirect heat exchangers

This study was devoted to proposing an effective experimental method based on bio-oil composition inversion for understanding biomass pyrolysis vapor evolution in four-staged condensers. The effective length of each condenser was 200 mm. The evolution curves and heat maps of condensable vapors in the whole multi-staged condensing field were provided by Logistics model fitting. With changing condition from “365-345-325-305” to “345-325-305-285”, the condensing efficiency of the first condenser increased by 100% but that of the third condenser decreased by 80%. Under condition “365-345-325-305”, the largest recovery rate of water was observed at 400 mm away from multi-staged condensing field entrance while that of eugenol was observed at 50 mm away from the entrance, which explained that water was primarily recovered by the second and third condensers whereas eugenol was recovered by the first condenser, and verified the remarkable effect of fractional condensation on the separation of water and high-boiling phenols.

Evaluation of Thermodynamic Researches of Layered Fluids in the Design and Development of Deposits of Hydrocarbon Raw Materials

At present, publications devoted to modern experimental equipment are widely used in domestic and foreign scientific journals aimed at specialists in the field of hydrocarbon processing. Thus, the installation of PVT ratios from Chandler Engineering allows us to conduct research in a wide range of pressures and temperatures and determine the phase processes of hydrocarbons. In the experimental work performed with natural mixtures and reservoir gas condensate systems, a pattern was found. At high reservoir pressures and temperatures, condensates are characterized by an increased content of high molecular weight hydrocarbons of complex structure, which affects phase processes. The parameters and indicators determined on this installation are the initial ones for calculating the balance reserves of ethane, propane, butane, non-hydrocarbon components in the formation gas, designing development and field development, as well as further processing of condensate. The main goal of the work is to determine the effect of contact condensation, which manifests itself when the deposits are unevenly developed by the area of the field on the development of hydrocarbon reserves based on experimental thermodynamic studies.

Structure of Electric Double Layer under Cationic Langmuir Monolayer: Charge Condensation Effect.

Langmuir monolayers consisting of mixtures of 1-hexadecanol (HD) and 1,2-dipalmitoyl-3-trimethylammonium-propane (DPTAP) (having quaternary amine headgroup) at different molar ratios were prepared to investigate the effect of the surface charge density on the structure of an electric double layer. The fatty alcohol molecules worked as passive spacers to widen the distance between the amine groups in the monolayer, to vary the surface charge density of the monolayer, and these mixture monolayer systems were probed by surface-sensitive sum-frequency vibrational spectroscopy. A strong sum-frequency signal in the OH range for a pure DPTAP monolayer (with a surface charge density of ∼0.4 C/m2) hardly decreased as the surface charge density was reduced up to ∼0.12 C/m2 (1 e per 140 Å2) and afterward decreased monotonically as more HD occupied the monolayer. The Gouy-Chapman theory incorporating a charged-condensed layer in which the counterion concentration is limited by a close packing of the counterions could account for the above saturation behavior in the sum-frequency spectra.

Simulation Study on Indoor Air Distribution and Indoor Humidity Distribution of Three Ventilation Patterns Using Computational Fluid Dynamics

Due to recent industrial developments and the COVID-19 pandemic, people are spending more time indoors. Consequently, many researchers have focused on the indoor environment, and indoor air quality is considered more important for human health. Improving indoor air quality depends on effective ventilation and reasonable air distribution. In an air-conditioned room, the form of airflow organization affects air quality, so air distribution is an important aspect of air-conditioning system design. In this study, we used Airpak software by Fluent to perform numerical calculations on the indoor humidity calculation model and study the effects of different ventilation methods on indoor temperature and humidity distribution. The Reynolds averaged Navier–Stokes equation and the RNG (Re-Normalisation Group) k-epsilon model were used to predict the airflow pattern in a room, the effects of ventilation on the dew rate, the effects of different ventilation methods, and the effect of indoor wall condensation. The results of the simulation showed that the ventilation mode significantly affected the distribution of condensation on the indoor wall surface.

Precise determination of inundation effect coefficient of film condensation on an array of horizontal new three-dimensional finned tube

To accurately evaluate the condensation heat transfer performance of new 3D finned tubes in shell-and-tube condenser, the inundation effect of the film condensation of R-134a on an array of 6 horizontal new 3D (three-dimensional) finned tubes is experimentally investigated with a new experiment method of homologous method. And the precise inundation effect coefficient of film condensation is determined. A novel test facility, whose test section contains two arrays of 8 horizontal tubes to realize the homologous method, is developed and constructed. The outer diameter of the tube and effective tube length in the test section are 19.05 and 500 mm, respectively. The condensation heat transfer coefficient of new 3D finned tube and inundation effect coefficient of new 3D finned tube bundle are determined under different conditions. The results show that the inundation effect coefficient of new 3D finned tube bundle decreases from 1.00 to 0.78 as Re increases from 75 to 1860. And the effect of heat flux on the inundation effect is more sensitive than the condensing temperature. Furthermore, for new 3D finned tube, the condensation heat transfer and inundation effect models are established, and the deviations of results between experiment and models are almost within ±6.0%. In comparison with literatures, the average inundation effect coefficient of new 3D finned tube bundle is 10.0-25.0% higher than that of 3D finned tube bundle in literatures, within 3.0% lower than that of two-dimensional finned tube bundle, and 15.2% higher than that of plain tube bundle. And the average condensation heat transfer coefficient of new 3D finned tube bundle in this article is 5.0-25.0% higher than that of 3D finned tube bundle in literatures, 10.0-30.0% higher than that of 2D finned tube bundle, and more than 10 times that of plain tube bundle. The precise inundation effect coefficients can be used as benchmark data to build precise and universal inundation effect model of 3D finned tube, and the models established in this study will help guide the thermal design of the new 3D finned tube applied in shell-and-tube condenser.

A novel pulse width modulation for metal radiant panels to control the condensation risk in a hot and humid environment

A novel pulse width modulation (PWM) control method with surface condensation-evaporation cycle was proposed for metal radiant panels to control the condensation risk in hot and humid environments. Through an on-off solenoid valve, a whole cycle of the PWM consists of a fixed on-period duration, i.e., 20 min and an adjustable off-period duration in order to guarantee the formed condensate water on the panel during the on period evaporated completely at the end of the off period. A numerical heat transfer model of the radiant panel validated by experiment was utilized to evaluate the dynamic thermal performance of the PWM. According to the simulation results, the maximum accumulated condensation mass in the whole cycle was far smaller than the falling criteria of condensate droplets, revealing the ability of the PWM in eliminating the negative effects of surface condensation on the indoor environment. Furthermore, compared with the variable temperature control method with a supply water temperature equal to the dew point temperature, the radiant panel utilizing the PWM provided a 10% higher cooling capacity. The radiant metal panels using the PWM has an application prospect for retrofit buildings with low airtightness of the envelope in hot and humid regions by a significant reduction of condensation risks.

ESTUDANDO A SUBLIMAÇÃO DE DIÓXIDO DE CARBONO

Background: The utilization of dry ice in cooling and storage units requires adjusting the intensity of sublimation due to the requirements of prudently using CO2 to maintain preset thermal conditions. Aim: When designing a carbon dioxide cycle, it is essential to consider the influence of thermal gradients on the adsorption and desorption of carbon dioxide. Methods: tests were conducted to study the production and sublimation of carbon dioxide. The testes were aimed to define the temperature relation of the dry ice sublimation period, the density of pressed СО2, and the humidity of the environment and concentration. Results and Discussion: According to the obtained test data, there was a linear relationship between the sublimation intensity and the ambient air temperature in the specified conditions. The effect of moisture condensation on the sublimation rate appeared weaker than expected, for the amount of moisture on the surface of the specimens was insignificant. The heat exchange was intensified by the fall of hoarfrost and the related surface expansion. However, much moisture froze out without reaching the dry ice surface, and the formed layer of ice formed a heat insulation surface, and the sublimation under that layer was less intensive. The direct influence of sublimation came from the pressure at which a specific specimen was formed; however, 75 kN pressure was optimal. Conclusion: Despite higher weight losses during the storage, the difference in spent energy is more critical than 90 kN. The factor no less important was the carbon dioxide storage temperature. The maximal sublimation time of a 55 g cylinder formed at 75 kN and stored at – 80°С was 135 hours, much higher than at similar parameters but at -60°С. That said, the amount of energy spent on operating a low-temperature chamber was almost identical.

STUDYING THE SUBLIMATION OF CARBON DIOXIDE

Background: The utilization of dry ice in cooling and storage units requires adjusting the intensity of sublimation due to the requirements of prudently using CO2 to maintain preset thermal conditions. Aim: When designing a carbon dioxide cycle, it is essential to consider the influence of thermal gradients on the adsorption and desorption of carbon dioxide. Methods: tests were conducted to study the production and sublimation of carbon dioxide. The testes were aimed to define the temperature relation of the dry ice sublimation period, the density of pressed СО2, and the humidity of the environment and concentration. Results and Discussion: According to the obtained test data, there was a linear relationship between the sublimation intensity and the ambient air temperature in the specified conditions. The effect of moisture condensation on the sublimation rate appeared weaker than expected, for the amount of moisture on the surface of the specimens was insignificant. The heat exchange was intensified by the fall of hoarfrost and the related surface expansion. However, much moisture froze out without reaching the dry ice surface, and the formed layer of ice formed a heat insulation surface, and the sublimation under that layer was less intensive. The direct influence of sublimation came from the pressure at which a specific specimen was formed; however, 75 kN pressure was optimal. Conclusion: Despite higher weight losses during the storage, the difference in spent energy is more critical than 90 kN. The factor no less important was the carbon dioxide storage temperature. The maximal sublimation time of a 55 g cylinder formed at 75 kN and stored at – 80°С was 135 hours, much higher than at similar parameters but at -60°С. That said, the amount of energy spent on operating a low-temperature chamber was almost identical.

Quiescent luminosities of accreting neutron stars with different equation of states

We model the quiescent luminosity of accreting neutron stars with several equation of states (EOSs), including the effect of pion condensation and superfluidity. As a consequence of comparison with the observations, we show that the results with Togashi EoS (the strong direct Urca process is forbidden) and TM1e EoS (mass at direct Urca process is $2.06 M_\odot$) can explain the observations well by considering pion condensation and the effect of superfluidity, while LS220 EoS and TM1 EoS can explain the observations well by considering the baryon direct Urca process and the effect of superfluidity. Besides, we compare the results with the observations of a neutron star RX J0812.4-3114 which has the low average mass accretion rate ($\langle\dot{M}\rangle\sim(4-15)\times 10^{-12}~M_\odot ~\rm yr^{-1}$) but high thermal luminosity ($L_q^\infty\sim(0.6-3)\times10^{33}~\rm erg ~ s^{-1}$), and we suggest that a low-mass neutron star ($<1M_\odot$) with minimum cooling can explain the lower limit of the observation of thermal luminosity of RX J0812.4-3114, which is qualitatively consistent with the previous work~\cite{Zhao2019}. However, to explain its upper limit, some other heating mechanisms besides standard deep crustal heating may be needed.

Multi-Phase Impact on the Heat Load Characteristics of a Multi-Element Methane-Oxygen Rocket Thrust Chamber

Aiming at the capability to numerically model relevant operating conditions in rocket thrust chambers, this research work introduces a real gas multi-phase data extension to investigate the impact of water condensation within a widely studied sub-scale research test case. Following a dense gas approach and embedded into a state-of-the-art timescale based frozen non-adiabatic flamelet combustion model able to capture the characteristic hydrocarbon chemical reaction and recombination phenomena, the pre-computed manifold incorporates the underlying physical processes to describe the properties of the fluid mixture. The modeling framework is initially evaluated against simplified non-reacting experimental studies of water condensation along a cooled wall structure in the presence of non-condensable gases to confirm its ability to predict the phase change impact on the wall heat transfer. The good agreement with experimental heat load data is further confirmed in the frame of a conjugate heat transfer simulation of a multi-element methane-oxygen rocket thrust chamber, for which the design of the regenerative cooling system leads to localized condensation effects as the wall temperature remains below saturation conditions. The associated release of the formation enthalpy coupled with a change of the fluid properties captured by the newly developed model formulation leads to higher wall heat loads compared to the numerical predictions of an ideal gas single-phase model.

Condensation Effects on Electron Chiral Asymmetries in the Photoionization of Serine: From Free Molecules to Nanoparticles.

Structural changes at the molecular level, occurring at the onset of condensation, can be probed by angle-resolved valence photoelectron spectroscopy, which is inherently sensitive to the electronic structure. For larger condensed systems like aerosol particles, the observation of intrinsic angular anisotropies in photoemission (β parameters) is challenging due to the strong reduction of their magnitude by electron transport effects. Here, we use a less common, more sensitive observable in the form of the chiral asymmetry parameter to perform a comparative study of the VUV photoelectron spectroscopy and photoelectron circular dichroism (PECD) between pure gas phase enantiomers of the amino acid serine and their corresponding homochiral nanoparticles. We observe a relatively large (1%) and strongly kinetic energy-dependent asymmetry, discussed in terms of the emergence of local order and conformational changes potentially counterbalancing the loss of angular information due to electron transport scattering. This demonstrates the potential of PECD as a sensitive probe of the condensation effects from the gas phase to bulk-like chiral aerosol particles surpassing the potential of conventional photoemission observables such as β parameters.

Massive Δ -resonance admixed hypernuclear stars with antikaon condensations

In this work, we study the effect of (anti)kaon condensation on the properties of compact stars that develop hypernuclear cores with and without an admixture of $\Delta$-resonances. We work within the covariant density functional theory with the parameters adjusted to $K$-atomic and kaon-nucleon scattering data in the kaonic sector. The density-dependent parameters in the hyperonic sector are adjusted to the data on $\Lambda$ and $\Xi^-$ hypernuclei data. The $\Delta$-resonance couplings are tuned to the data obtained from their scattering off nuclei and heavy-ion collision experiments. We find that (anti)kaon condensate leads to a softening of the equation of state and lower maximum masses of compact stars than in the absence of the condensate. Both the $K^-$ and $\bar K^0$-condensations occur through a second-order phase transition, which implies no mixed-phase formation. For large values of (anti)kaon and $\Delta$-resonance potentials in symmetric nuclear matter, we observe that condensation leads to an extinction of $ \Xi^{-,0}$ hyperons. We also investigate the influence of inclusion of additional hidden-strangeness $\sigma^{*}$ meson in the functional and find that it leads to a substantial softening of the equation of state and delay in the onset of (anti)kaons.

Numerical Assessment of Earth to Air Heat Exchanger with Variable Humidity Conditions in Greenhouses

Earth to air heat exchangers are widely utilized to cool or heat passive buildings for energy savings. They often need to deal with high humidity air conditions, especially in the greenhouse due to plant transpiration, and the condensation phenomenon is frequently observed during the cooling process. To evaluate the effect of humidity and condensation on thermal performance, a three dimensional computational fluid dynamic (3D-CFD) model was developed. The distribution of relative humidity in each pipe was investigated, and the impact of inlet air relative humidity on the integrated performance of the earth to air heat exchanger was discussed. The effects of inlet air temperature and volume flow rate were also analyzed. Moreover, the influence of the heat exchanger configurations on the performance of the air condensation was researched. The results indicated that condensation had few effects on the airflow distribution uniformity of the earth to air heat exchanger, while it acted observably on the thermal performance. In addition, humid air in a small diameter pipe tended to condense more easily. Humidity and condensation should be taken into consideration for the design of earth to air heat exchangers in greenhouses during engineering applications.

Experimental study on acoustic condensation fog elimination in traveling wave tube

Acoustic condensation artificial fog elimination has the advantages of wide application range, good economy, flexible and controllable operation area, and does not affect traffic operation. The characteristics of the fog, the frequency and intensity of the acting sound waves have an important influence on the effect of condensation and fog elimination. This paper studies the influence of the frequency of fog on the microscopic particle size distribution and the change of light transmission in the process of fog elimination from both theoretical and experimental aspects. The research results show that for natural fog conditions with low concentration, the time of pure sound wave action takes several minutes to tens of minutes. Under the condition of high-concentration artificial fog, the anti-fog time can be shortened to tens of seconds. Simulations and experiments have both confirmed that sound waves can significantly promote fog elimination, and there is an optimal frequency between 200Hz-700Hz.

Effect of Nonlinear Elasticity on the Swelling Behaviors of Highly Swollen Polyelectrolyte Gels.

Polyelectrolyte gels exhibit swelling behaviors that are dependent on the external environment. The swelling behaviors of highly charged polyelectrolyte gels can be well explained using the Flory–Rehner model combined with the Gibbs–Donnan effect and Manning’s counterion condensation effect (the FRGDM model). This study investigated the swelling properties of a series of model polyelectrolyte gels, namely tetra-polyacrylic acid-polyethylene glycol gels (Tetra-PAA-PEG gels), and determined the applicability of the FRGDM model. The swelling ratio (Vs/V0) was well reproduced by the FRGDM model in the moderate swelling regime (Vs/V0 < 10). However, in the high swelling regime (Vs/V0 > 10), the FRGDM model is approx. 1.6 times larger than the experimental results. When we introduced the finite extensibility to the elastic free energy in the FRGDM model, the swelling behavior was successfully reproduced even in the high swelling regime. Our results reveal that finite extensibility is one of the factors determining the swelling equilibrium of highly charged polyelectrolyte gels. The modified FRGDM model reproduces well the swelling behavior of a wide range of polyelectrolyte gels.

A zero-dimensional view of atmospheric degradation of levoglucosan (LEVCHEM_v1) using numerical chamber simulations

Abstract. Here, we developed a zero-dimensional (0-D) modeling framework (LEVCHEM_v1) to provide insights into the atmospheric degradation of a key tracer emitted during biomass burning – levoglucosan (LEV), while additionally exploring its effects on the dynamics of secondary organic aerosols (SOA) and other gases. For this, we updated existing chemical mechanisms (homogeneous gas-phase chemistry and heterogeneous chemistry) in the BOXMOXv1.7 model to include the chemical degradation of LEV and its intermediary degradation products in both phases (gas and aerosol). In addition, we added a gas-particle partitioning mechanism to the model to account for the effect of evaporation and condensation on the phase-specific concentrations of LEV and its degradation products. Comparison of simulation results with measurements from various chamber experiments (spanning summer and winter conditions) show that the degradation timescale of LEV varied by phase, with gas-phase degradation occurring over ∼1.5–5 d and aerosol-phase degradation occurring over ∼8–36 h. These relatively short timescales suggest that most of the initial LEV concentration can be lost chemically or deposited locally before being transported regionally. We varied the heterogeneous reaction rate constant in a sensitivity analysis (for summer conditions only) and found that longer degradation timescales of LEV are possible, particularly in the aerosol phase (7 d), implying that some LEV may be transported regionally. The multiphase chemical degradation of LEV has effects on SOA and other gases. Several first- or second-generation products resulted from its degradation; most of the products include one or two carbonyl groups, one product contains a nitrate group, and a few products show the cleavage of C−C bonds. The relative importance of the products varies depending on the phase and the timing of the maximum concentration achieved during the simulation. Our estimated secondary organic aerosol SOA yields (4 %–32 %) reveal that conversion of LEV to secondary products is significant and occurs rapidly in the studied scenarios. LEV degradation affected other gases by increasing the concentrations of radicals and decreasing those of reactive nitrogen species. Decreases of the mixing ratios of nitrogen oxides appear to drive a more rapid increase in ozone compared with changes in volatile organic compounds levels. An important next step to confirm longer degradation timescales will be to extend the evaluation of the modeled LEV degradation beyond 3–6 h by using more extensive data from chambers and, possibly, from fire plumes. The mechanism developed here can be used in chemical transport models applied to fire plumes to trace LEV and its degradation products from source to deposition, to assess their atmospheric implications and to answer questions relevant to fire tracing, carbon and nitrogen cycling, and climate.

Thermo-Structural Analysis of Steam Turbine Startup With and Without Integrated Prewarming System Using Hot Air

Abstract Motivated by the urgent need for flexibility and startup capability improvements of conventional power plants in addition to extending their life cycle, General Electric provides its customers with a product to prewarm steam turbines using hot air. In this paper, the transient thermal and structural analyses of a 19-stage intermediate pressure (IP) steam turbine in various startup operating modes are discussed in detail. The presented research is based on previous investigations and utilizes a hybrid finite element method (HFEM—numerical FEM and analytical) approach to efficiently determine the time-dependent temperature distribution in the components of the steam turbine. The simulation strategy of the HFEM model applies various analytical correlations to describe heat transfer in the turbine channel. These are developed by means of extensive unsteady multistage conjugate heat transfer (CHT) simulations for both startup turbine operation with steam and prewarming operation with hot air. Moreover, the complex numerical setup of the HFEM model also considers the thermal contact resistance (TCR) on the surfaces between vane and casing as well as blades and rotor. Prior to the analysis of other turbine startup operating modes, the typical startup turbine process is calculated and validated against an experimental data as a benchmark for subsequent analysis. In addition to heat transfer correlations, the simulation of a turbine startup from cold state uses an innovative analytic pressure model to allow for a consideration of condensation effects during first phase of startup procedure. Finally, the presented thermal investigation focuses on the comparison of transient temperature fields in the turbine for different startup scenarios after prewarming with hot air and provides the subsequent structural investigation with required boundary conditions. As a result, the values of the highest stress are numerically determined and compared to the values obtained by means of cold startup simulation. The final evaluation clearly displays the technical potential and the benefits of the prewarming concept.

A Review of Research on Dropwise Condensation Heat Transfer

Dropwise condensation is considered to be an effective method of enhancing heat transfer due to its high heat transfer performance. However, because the effect of dropwise condensation is affected by many complex factors, there is no systematic review summarized on the law of dropwise condensation heat transfer by scholars. In this paper, the main methods and problems of promoting dropwise condensation were reviewed based on the dropwise condensation mechanism and theoretical model. The three different hypotheses about the mechanism of dropwise condensation and the heat transfer model of dropwise condensation based on the hypothesis of nucleation sites were summarized. The methods for promoting dropwise condensation and the problems that influence dropwise condensation heat transfer are introduced in this paper. The research showed that many researchers focused on how the surface fabricated forms dropwise condensation rather than whether it enhances heat transfer. In this paper, we point out that the droplet shedding rate is the key to enhancing dropwise condensation heat transfer. Much more research on droplet formation mechanisms and theoretical models of different surfaces is supposed to be carried out in the future.