Eco-friendly Packaging Materials Research Articles

An In-depth Analysis of Fashion Merchandise Packaging: Evaluating Environmental Awareness and Challenges among Consumers and Retail Managers in Nairobi City County, Kenya

Recently, the Government of Kenya implemented a ban on single-use plastic and imposed strict regulations on environmental sustainability for packaging. This has led to challenges for consumers and fashion retail managers in Nairobi City County as they adapt to new packaging innovations from manufacturers. A study was conducted to assess the level of environmental awareness among consumers and fashion retail managers regarding fashion merchandize packaging. The study also aimed to identify the packaging challenges faced by both consumers and fashion retail managers in fashion retail outlets. The results of the study are intended to assist consumers, fashion retail managers, and the Kenyan government in standardizing eco-friendly packaging materials and providing training on proper disposal methods to ensure a clean environment.

Value addition of mango kernel for development and characterization of starch with starch nanoparticles for packaging applications

The present research was conducted to explore the potential of mango kernel starch from the Chaunsa variety to develop starch and starch nanoparticles (SNPs) based films. The investigation included starch isolation from mango kernel followed by the preparation of SNPs by acid hydrolysis and a thorough examination of various physicochemical properties for film formation. The properties of SNPs were found to be distinctly different from those of native starch. SNPs exhibited an aggregated form with an irregular surface, whereas native starch had an oval and elongated shape with a smooth surface. X-ray diffraction (XRD) analysis confirmed that the starch type in SNPs was of the A-type. Additionally, the pasting properties of SNPs were minimal due to the acid hydrolysis process. SNP-based composite film was developed with (5 %) SNP concentration added. This successful incorporation of SNPs enhanced biodegradability, with complete degradation occurring within three weeks. Moreover, the composite films displayed increased burst strength, measuring 1303.51 ± 73.7 g, and lower water vapor transmission rates (WVTR) at (7.40 ± 0.50) × 10−3 g per square meter per second and reduced water solubility at 35.32 ± 3.0 %. This development represents a significant advancement in the field of eco-friendly packaging materials.

A strategy to prolong cheese shelf-life: Laminated films of bacterial cellulose and chitosan loaded with grape bagasse antioxidant extract for effective lipid oxidation delay

This study presents an innovative approach to developing bioactive composite films for food packaging applications. Laminated films composed of bacterial cellulose (BC) and chitosan were enriched with grape bagasse extract (GE) and glycerol. GE provides antioxidant capacity. Glycerol was added as plasticizer. The formulations were systematically varied to assess their mechanical and thermal properties. The assembly of the films demonstrated robust interaction between components, resulting in enhanced mechanical strength. Tensile tests revealed that GE and glycerol concentrations significantly influenced the tensile strength and elongation properties Films were obtained with Tensile Strength values that ranged between 16.92 and 32.71 MPa, but with an increase of up to 4 times in the percentage of elongation (from 2.33 to 8.63%) compared to films without GE. Puncture tests indicated that the incorporation of GE and glycerol played pivotal roles in improving puncture resistance. Predictive models were developed for better understanding. The laminated films were applied as separators for Havarti cheese, demonstrating their ability to mitigate lipid oxidation and maintaining antioxidant properties during storage. After 60 days of cheese storage, 67.3% decrease in the lipid oxidation was obtained. The findings suggest that laminated BC-chitosan films enriched with GE and glycerol could serve as effective, eco-friendly packaging materials with enhanced mechanical strength and antioxidant functionality for extending the shelf life of food products.

Mechanically robust carboxymethyl cellulose/graphene oxide composite cross-linked by polyetherimide for fruits packaging and preservation system

Modulating the interactions between biopolymer matrix and nanofillers highly determined the mechanical performances of composite packaging materials. Herein, we innovatively proposed a sort of eco-friendly and mechanically robust carboxymethyl cellulose/graphene oxide/tannic acid/polyetherimide (CMC/GO/TA/PEI, CGTP) composite by employing PEI as cross-linker and TA as proton donor. The amidation reaction between -NH2 and -COOH chemically connected the CMC/GO, CMC/CMC and GO/GO and the physical interaction (e.g. hydrogen bonds and molecular entanglements) was beneficial to form dense structures. The chemical/physical bonds among polymers and nanofillers contributed to dissipate the external energy. The toughness was effectively reinforced from 1.68 MJ/m3 for CGTP0 to 4.63 MJ/m3 for CGTP1.0. Furthermore, the CGTP1.0 composite film also delivered improved gas (moisture and oxygen) barriers, UV protection and antimicrobial features. Originating from these merits, the shelf life of fresh fruits (e.g. strawberries, blueberries and cherry tomatoes) was prolonged at least 5 days under ambient conditions when the packaging box was covered by the fabricated CGTP1.0 film. Our findings not only provided a facial strategy to reinforce the interactions between biopolymer matrix and nanofillers, but also boosted the development of eco-friendly packaging materials with robust structures in the area of food packaging.

Fine extraction of cellulose from corn straw and the application for eco-friendly packaging films enhanced with polyvinyl alcohol

Biomass materials substituting for petroleum-based polymers occupy an important position in achieving sustainable development. Cellulose, a typical biomass material, stands out as the primary choice for producing eco-friendly packaging materials. However, it is still a challenge to efficiently utilize cellulose from waste biomass materials in practice. Herein, cellulose-based films were prepared by pretreating waste corn straw, separating straw husk, straw pith and straw leaf, and extracting cellulose through alkali and sodium chlorite treatment to improve its mechanical properties using the cross-linked polyvinyl alcohol (PVA) method in this work. The prepared composite films were characterized by Fourier transform infrared spectrometer (FTIR), X-ray diffraction instrument (XRD), Scanning electron microscopy (SEM), Thermogravimetric (TG) and mechanical properties. The results indicated that corn straw husk exhibited the highest cellulose content of 31.67 wt%, and obtained husk cellulose had the highest crystallinity of 52.5 %. Compared to corn straw, the crystallinity of husk cellulose, pith cellulose and leaf cellulose increased by 19.5 %, 16.4 % and 44.1 %, respectively. Husk cellulose/PVA composite films were the most thermally stable, with a maximum weight loss temperature of 346.8 °C. In addition, the husk cellulose/PVA composite film had the best tensile strength of 37 MPa. Meanwhile, the composite films had good UV shielding, low water vapor transmission rate and biodegradability. Therefore, this work provides a fine utilization route of waste corn straw, and as-prepared cellulose based films have potential application in eco-friendly packaging materials.

Corn cob nanocellulose packaging for increasing the shelf life of food products

Studies were carried out to develop eco-friendly Packaging material for the extended shelf-life of food products. The current study sought to improve the coated bioactive film's hydrophobicity and antimicrobial properties by preparing active packaging based on biodegradable Poly Lactic Acid (PLA) containing 1 wt% Nanocellulose (NC) and various loadings of essential oil-prepared nanocomposites. Nanocellulose (NC) from Maize Cob was used as filler in the synthesis of nanopolymers enriched with Thyme oil, Cinnamon oil, clove oil, and Rosemary oil. Characterization of nanopolymer-coated bags and their effect on enhancing the shelf-life of food products in different temperature conditions was also studied. The fabricated nanocomposite and nanocellulose were characterized using FTIR, SEM, XRD, Contact angle, TGA, and Tensile mechanical properties. The fabricated nanocomposite-coated paper cum bag shows good hydrophobic properties as well as antimicrobial and insecticidal properties. The results showed that adding essential oils and dispersing nanocellulose to the PLA matrix strengthened its mechanical qualities as well as its efficacy for biodegradation and antimicrobial properties. The current work provides extremely promising materials for future applications in food packaging applications using sustainable nanocomposite-based biodegradable and antimicrobial coated paper cum bags.

Towards Greener Packaging: Tapioca Starch-Based Biocomposites with Siam Weed Extract and Flax Seed Gel as Sustainable Antibacterial Packaging Material

This paper delves into the development of biocomposite (BC) packaging material from tapioca starch (TS), flax seed gel (FS), and Siam weed (SW) extract, considering the increased demand for sustainable, eco-friendly packaging materials. The BCs—BC1 (40 mL), BC2 (80 mL), and BC3 (120 mL), prepared by varying the concentration of SW—were subjected to morphological, structure, thermal, and optical characterisations. The BC with a fragmented, agglomerated morphology shows cellulosic peaks in the X-ray diffraction pattern, indicating the C-type crystalline structure in TS. Thermogravimetric analysis confirmed the BC’s safe use up to 300 °C, with a minimal 40% weight loss. Differential scanning calorimetry plots identified heat absorption during gelatinisation, with an endothermic peak at 300 °C marking a phase transition. The Fourier transform infrared (FTIR) and UV–visible spectra revealed functional groups that attribute antibacterial potential to the BC. The optical analyses show greater absorption and fewer emissions, resulting in the increased enthalpy responsible for the microbial activities. Antibacterial studies demonstrated BC2’s efficacy against Staphylococcus aureus, while the stability against humidity and the minimal weight loss underscored the BC’s robust thermal stability. FTIR spectra of post-heating at 80 °C confirmed the structural integrity, positioning the BC as a promising material for eco-friendly packaging solutions.

가치-신념-규범(VBN) 모델에 기반한 밀키트 소비자의 친환경 의사결정과정 이해

With the significant growth of the meal kit market, environmental pollution problems caused by meal kit packaging materials are also emerging. Meal kit companies are pressured by society to use more eco-friendly packaging materials. However, doing so would only increase the production costs and sales prices, if consumers turn a blind eye to it. Therefore, for meal kit companies, it is necessary to understand the antecedents to consumers' eco-friendly behavior intentions and react accordingly. For this reason, this study used the VBN model to examine the decision-making process of meal kit consumers that leads from value beliefs and personal norms to eco-friendly behavioral intentions. In addition, the mediating roles of emotional factors (predicted guilt and pride) in the process were considered. To address the research objectives, a survey was conducted amongst adult men and women who purchased meal kits and plan to purchase them in the future. A total of 300 responses were collected from July 11 to 13, 2023. Among them, 249 (83.0%) suitable responses were analyzed. Descriptive statistics analysis and structural equation modeling analysis were performed using SPSS and AMOS programs. The analysis results are as follows. First, the values of meal kit consumers had significant effects on outcome perception, responsibility attribution, individual norms, and purchase intentions. Second, there were significant mediating effects of anticipated guilt and pride in the relationship between personal norms and the intentions to purchase eco-friendly meal kits. The analysis results emphasized the importance of values, beliefs, personal norms, and anticipated emotions in strengthening the eco-friendly behavioral intentions of meal kit consumers. It is suggested that meal kit companies should invest in monitoring and managing consumers' ecological values, personal norms, and emotional factors at the marketing level.

Potential use of plant leaves and sheath as food packaging materials in tackling plastic pollution: A Review

Plastic pollution, mainly due to single-use food packaging materials, has become a drastic environmental issue around the world. As a consequence of their accumulation, naturally balanced ecosystems may undergo various types of vulnerabilities, and eventually, it may lead to the annihilation of flora, and fauna. Hence, there is an urgent need to find alternative ways of packaging food with environmentally friendly materials. Currently, there are considerable numbers of research being done to prove that biodegradable packaging materials can be produced from plant leaves and sheaths. However, the large-scale production and application of eco-friendly packaging materials is still a challenge and more studies are further required to accomplish it. Hence, this review is done to identify initiatives made in the field of biodegradable packaging material and directs them towards practical application. In the end, it proves that there is a huge potential to produce biodegradable packaging materials from plant sources economically.

Enhancing Paper Packaging's Wet Strength Using the Synergy between Chitosan and Nanofibrillated Cellulose Additives.

The demand for eco-friendly packaging materials has urged researchers to look for alternatives to petroleum-based polymers. In this regard, paper-based products have turned out to be a promising choice; however, their weak resistance to water has limited their application. The use of various additives to enhance paper's moisture resistance is a common practice. However, considering the growing global agenda for sustainable development, the search for new bio-based paper additives has become increasingly important. This study investigated the potential synergistic impact of the addition of nanofibrillated cellulose (NFC) and chitosan additives (CHIT) to different fiber combinations to improve paper's properties, in particular, their wet strength. The efficacy of the additive application order was examined and was found to be crucial in achieving the desired outcomes. The results showed that incorporating CHIT after NFC enhanced the paper's tensile and burst indicators, as well as the paper stretch in the dry state, by 35-70%, 35-55%, and 20-35%, respectively. In addition, the tensile index and stretch in the wet state improved 9-13 times and 2.5-5.5 times over, respectively. The air permeability decreased 2.5-12 times over. These findings demonstrate that the sequential addition of the NFC and CHIT additives yield a greater enhancement of paper's properties than using each additive separately.

Impact of Nanoclays Addition on Chickpea (Cicer arietinum L.) Flour Film Properties.

Chickpea flour is an affordable natural blend of starch, proteins, and lipids, which can create films with suitable properties as an eco-friendly packaging material. Nanoclays' incorporation into natural biopolymers enhances the barrier properties of the resulting nanocomposites, so they could improve the properties of flour films. The objective of this work was to assess the influence of three types of nanoclays (halloysite, bentonite, and Cloisite 20A) at two concentrations on the characteristics of chickpea flour films. In general terms, when the lowest dose (5%) was added, no or very slight significant differences with the control were observed in most parameters, except for thermal stability and opacity, which increased, and solubility, which decreased. At the highest concentration (10%), films containing any of the nanoclays demonstrated greater thermal stability, opacity, and rigidity while being less soluble than those without nanofillers. Bentonite exhibited superior film structure distribution compared to other nanoclays. At the highest concentration, it had the most significant impact on modifying the properties of chickpea flour films, increasing their tensile and puncture strengths while decreasing elasticity and water vapor permeability. The incorporation of nanoclays into chickpea flour films could be a useful technique to enhance their properties.

Sustainable lignin nanoparticles from coconut fiber waste for enhancing multifunctional properties of macroalgae biofilms

Multifunctional and sustainable packaging biofilms felicitous to changeable conditions are in large demand as substitutes to petroleum-derived synthetic films. Macroalgae with noticeable film-formation, abundant, low-cost, and edible properties is a promising bioresource for sustainable and eco-friendly packaging materials. However, the poor hydrophobicity and mechanical properties of sustainable macroalgae biofilms seriously impede their practical applications. Herein, lignin nanoparticles (LNPs) produced by a sustainable approach from black liquor of coconut fiber waste were incorporated in the macroalgae matrix to improve the water tolerance and mechanical characteristics of the biofilms. The effect of different LNPs loadings on the performance of biofilms, such as physical, morphological, surface roughness, structural, water resistance, mechanical, and thermal behaviors, were systematically evaluated and found to be considerably improved. Biofilm with 6 % LNPs presented the optimum enhancement in most ultimate performances. The optimized biofilm exhibited great hydrophobic features with a water contact angle of over 100° and high enhancement in the tensile strength of >60 %. This study proposes a facile and sustainable approach for designing and developing LNPs-macroalgae biofilms with excellent and multifunctional properties for sustainable high-performance packaging materials.

Chitosan Films with Caffeine and Propolis as Promising and Ecofriendly Packaging Materials

This study addresses challenges faced by the packaging industry in finding suitable natural and biodegradable materials that can replace plastics while preserving the superior quality and freshness of the items contained within. Chitosan, a biodegradable natural polymer, shows great potential as a matrix for ecofriendly and biodegradable composite materials. In the present study, bioactive substances such as caffeine (CAF) and propolis extract (EP) were used for the enhancement of the bioactivity of chitosan-based films. Two acidic solvents, acetic acid and citric acid, were used to produce chitosan films. The study examined the antioxidant capabilities of the solutions used for film formation; similarly, the characteristics of the resultant films were also examined, encompassing antimicrobial, barrier, and mechanical characteristics. The findings suggested that the use of additives exhibiting antioxidant activity, such as CAF and EP in the chitosan matrix can be an effective method to counteract oxidative stress in food packaging. The study also showed that films produced with citric acid exhibit antimicrobial activity against many strains of bacteria, including foodborne pathogens. In addition, the antimicrobial activity of chitosan/citric acid film can be increased by adding CAF and EP. The results confirmed that both the additives and the acids used affect the mechanical and barrier features of the obtained chitosan-based films. This study suggests that chitosan films supplemented with natural bioactive substances have the potential to serve as viable replacements for traditional plastics in the packaging sector.

Effect of a Composite Alginate/Grape Pomace Extract Packaging Material for Improving Meat Storage.

The development of food packaging materials that reduce the production of plastic, preserving at the same time the quality of food, is a topic of great interest today for the scientific community. Therefore, this article aims to report the effectiveness of an eco-friendly packaging material based on alginic acid and grape pomace extract from Vitis vinifera L. (winemaking by-products) for storing red meat in a domestic refrigerator. Specifically, biogenic amines are considered "sentinels" of the putrefactive processes, and their presence was thus monitored. For this purpose, an experimental analytical protocol based on the use of solid-phase microextraction coupled with gas chromatography-mass spectrometry was developed during this work for the determination of six biogenic amines (butylamine, cadaverine, isobutylamine, isopentylamine, putrescine, and tyramine). Moreover, by combining the analytical results with those of pH and weight loss measurements, differential scanning calorimetry, and microbiological analysis, it was proved that the studied materials could be proposed as an alternative packaging material for storing foods of animal origin, thus lowering the environmental impact according to sustainability principles.

Effect of Chitosan Variation in Starch and Cellulose Based Biofoam

Styrofoam’s using as packaging is increasing. Styrofoam is difficult to decompose so alternatives such as biofoam are needed. This study explores the creation of eco-friendly packaging material by varying cellulose (0%, 3%, 5%, and 7%) and chitosan concentrations (0%, 2%, 4%, 6%, 8%, and 10%) in biofoam, aiming to replace non-biodegradable Styrofoam. Production is carried out by delignifying sugarcane bagasse and corn cobs with 10% NaOH, making tofu pulp starch and biofoam. The research focuses on tensile strength, absorption capacity, biodegradation, and morphology of the biofoam. Results indicate that chitosan concentration affects water absorption and biodegradation, while cellulose impacts tensile strength. The findings highlight the potential of biofoam made from tofu dregs, corn cobs, and sugar cane bagasse, offering a promising alternative to Styrofoam

Thermoplastic starch biocomposites reinforced with hemp shives obtained via extrusion

Biodegradable and sustainable materials are becoming increasingly important in response to environmental concerns associated with traditional petroleum-based plastics. The objective of this study was to assess the feasibility and efficiency of incorporating hemp shives as a filler in thermoplastic wheat starch, aimed at promoting environmental sustainability and reducing reliance on non-renewable resources. The biocomposites, prepared by extrusion, consisted of pure starch, different hemp shives concentrations (10%, 20%, 30%, 40%, 50%, and 70%), with water and glycerol as plasticizers. The results revealed that the incorporation of shives notably enhanced the mechanical properties of the biocomposite, reaching an optimal performance at 40% shives concentration (resulting in a maximum tensile strength of 11.5 MPa and Young’s modulus of 1621 MPa). In this concentration, ESEM images unveiled robust adhesion between hemp shives and the matrix, indicating starch penetration into the shives' parenchymatous cells. At higher concentrations, however, the resulted high pressures during extrusion collapsed the shive cells, impairing their adhesion with starch and reducing the biocomposite strength. The hemp shives addition reduced the water uptake, thereby enhancing the dimensional stability. Conclusively, this study offers pivotal insights into the development and characteristics of starch/hemp shives biocomposites, with structure-process-properties relationships, suggesting their potential applicability in the creation of eco-friendly packaging materials and small objects, presenting a viable alternative to traditional materials.

Effect of cellulose nanofiber-montmorillonite hybrid filler on the melt blending of thermoplastic starch composites

This study investigated the impact of cellulose nanofibers (CNFs) on montmorillonites (MMTs) exfoliation within thermoplastic starch (TPS) nanocomposites during the melt blending process. TPS nanocomposite films were manufactured using an internal mixer with a controlled ratio of CNFs and MMTs to evaluate the effect of individual and hybrid fillers on the material interactions and characteristics of the TPS composites. The incorporation of hybrid fillers resulted in notable enhancements in torque values and rheological properties, suggesting interactions between the starch, CNFs, and MMTs. The degree of MMT intercalation, obtained via X-ray diffraction analysis, decreased with the addition of CNFs, indicating that CNFs positively impacted MMT exfoliation. Scanning electron microscopy (SEM) images of cryo- and tensile-fractured samples highlighted the effectiveness of CNFs in facilitating MMT exfoliation and reinforcing interactions between the MMTs and TPS matrix. These interactions enhanced the tensile strength and Young's modulus by up to 95.8 % and 278.2 %, respectively, with a 1:1 weight ratio of CNFs to MMTs. Additionally, well-dispersed MMTs within the TPS matrix caused passivation and created tortuous paths, improving the water contact angle and decreasing the water vapor sorption. These synergistic effects of the hybrid filler, achieved through a melt blending process, indicate the potential use of TPS nanocomposites as an eco-friendly packaging material.

Cultivating Consumer Choices: Exploring the Impact of Product Packaging Design on Purchasing Behavior in the Food Processing Industry of Metro Baguio (MBLISTTDA)

This study investigates the influence of product packaging design on consumer purchasing behavior within the food processing industry of Metro Baguio, comprising Baguio City and its contiguous municipalities. The research aims to identify the specific packaging elements that significantly impact consumer purchasing decisions and examine the effects of various packaging attributes on consumers' choices in this region. The study encompasses packaging color, typography, visuals and mascots, and packaging format as key elements of interest. The significance of this study lies in its potential to elevate consumer perceived value of products through innovative packaging design and technology adoption within Metro Baguio's food processing sector. By embracing contemporary packaging practices, local food entrepreneurs can enhance their products' marketability and consumer impact. Using a descriptive research design and quantitative analysis, data was collected through a structured visual questionnaire. The findings highlight the preference for visually engaging packaging designs, particularly those incorporating mascots and emotive visuals. Positive responses to packaging colors emphasize their role in creating favorable impressions. The study also underscores the importance of transparent and accurate product information and visuals' influence on purchase intent. To optimize packaging's impact, local food processing businesses are encouraged to collaborate with young designers to create emotionally resonant packaging designs. Modern designs that resonate with the current generation can enhance emotional engagement, leading to stronger brand-consumer relationships, increased product desirability, and higher sales. Additionally, market research should inform packaging color choices to align with consumer emotions and cultural associations. Providing transparent and accurate information on packaging fosters trust while visually engaging images to enhance visibility and purchase intent. Prioritizing safe and eco-friendly packaging materials reflects consumer values and enhances brand perception and sustainability efforts.

How APTMS Acts as a Bridge to Enhance the Compatibility of the Interface between the Hydrophilic Poly(vinyl alcohol) Film and the Hydrophobic Stearic Acid Coating.

The hydrophobic modification of poly(vinyl alcohol) (PVA) film as a biodegradable packaging material has received significant attention in recent research. Despite the use of stearic acid (SA) as a coating for the PVA film, a challenge persists due to the poor compatibility between SA and PVA. This study addressed the aforementioned issue by utilizing (3-aminopropyl)trimethoxysilane (APTMS) as a bridging agent to establish a connection between the hydrophilic PVA film and the hydrophobic SA coating through hydrogen bonding and chemical reactions. First, SEM and EDS analyses confirmed the enhanced interfacial compatibility between the SA coating and the PVA film. Subsequently, the results from 1H NMR, FTIR, and XPS experiments presented evidence of hydrogen bonding and chemical reactions among APTMS, SA, and the PVA film. Interestingly, the PVA-APTMS-SA film demonstrated a contact angle of 120.77°, a water absorption of 7.81%, and a water vapor transmission rate of 8.69 g/m2/h. Furthermore, such a composite film displayed exceptional adhesion performance, requiring detachment stresses of 9.86 ± 0.91 and 6.17 ± 0.75 MPa when tested on glass and marble surfaces, respectively. In conclusion, the PVA-APTMS-SA film exhibited significant potential in extending the freshness of fresh-cut apples, making it a promising eco-friendly packaging material for food preservation.

Bionanocomposites films applied as active and smart food packaging: A review

AbstractFood packaging is used worldwide and is a common technique for protecting food safety and quality while increasing shelf life. Environmental issues caused by using polymers in packaging derived from petroleum are becoming more significant and more well‐known. Interest in ecofriendly packaging materials made of renewable resources (biopolymers) has steadily increased, particularly for temporary and throw‐away packaging applications. However, biopolymers frequently have poor processability, poor mechanical, and poor barrier characteristics, restricting their industrial application and scalable manufacturing. Researchers have created bionanocomposites with improved packaging qualities like antibacterial function, mechanical toughness, optical clarity, and gas and water barrier properties to overcome these restrictions. This review seeks to inform readers about recent advances in active food packaging that use biopolymers and bionanocomposite materials. The difficulties and possibilities presented by such resources for the food packaging sector have been examined. This review is timely given the recent spike in interest in research projects both in academia and industry seeking to create a new group of materials for packaging based on biopolymer for food with potential uses elsewhere.