Dynamic Thermal Properties Research Articles

SiO2 aerogel modified aggregates: Preparation, heat resistance and improvement mechanism

Modification of natural aggregates using SiO2 aerogel solution can not only radically reduce the rutting disease of asphalt pavement, but also avoid the problems of poor heat-resistant performance, mechanical strength and durability of ordinary heat-resistant aggregates. The effects of SiO2 aerogel solution type, modification method and SiO2 aerogel solution dosage on the thermal resistance and adhesion properties of SiO2 aerogel-modified aggregates (SM-Agg) were explored by orthogonal tests. Based on scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS) and infrared thermography, the surface micromorphology, elemental composition and dynamic thermal resistance properties of natural aggregate and SM-Agg were analyzed, respectively. The results showed that Both SiO2 aerogel solution type and dosage significantly affect the evaluation indexes and the modification of natural aggregates by soaking method using ZN-S type SiO2 aerogel solution with 15 % of the aggregate mass could obtain SM-Agg with good heat resistance and adhesion properties. The surface of SM-Agg was covered with a “gel layer” containing uniform and densely distributed SiO2 aerogel particles. The temperature of the top surface of the 18.3-mm-thick SM-Agg specimen gradually changed from 2.2°C higher than that of the natural aggregate to about 1.8°C lower than that of the natural aggregate within 60 min of heating at 55°C. The “gel layer” containing SiO2 aerogel particles forms one or more layers of three-dimensional heat-blocking mesh on the aggregate surface, which dramatically reduces the heat transfer area, prolongs the heat transfer path within the specimen, and increases the heat-reflecting capacity of the aggregate surface.

Controllable fabrication of shape memory epoxy resin filament by polymerization-melting-mixing-drawing process and performance regulation

ABSTRACT This work controlled the polymerization reaction, melting, and mixing processing of a mixture including epoxy resin and polyethylene glycol (PEG) by a pulverizer, to effectively develop high-performance shape memory epoxy/PEG (EPP) filaments. The process parameters of polymerization-melting-mixing-drawing were determined through the extrusion force investigation. The results showed that EPP mixtures could be developed into filaments through polymerization-melting-mixing-drawing process, reducing the spinning temperature and filament diameter from 300°C and 31 mm to 235°C and 13 mm, respectively. The Fourier transform infrared spectra confirmed the complete polymerization of epoxy resin and the stable existence of PEG. EPP filaments developed through the polymerization-melting-mixing-drawing process have exhibited controllable dynamic thermal mechanical properties and Tg, excellent shape recovery effects, and adjustable stimulus temperature. This work developed shape memory EPP filaments through a polymerization-melting-mixing-drawing process, with controllable spinnability and adjustable stimulus temperature, providing a reference for high-performance filament fabrication and process optimization.

Centrifugal Compressor Surge in Closed Loop Systems: Initial Modelling and Comparison with Experiments

Abstract Heat pumps are expected to play a primary role in electrification of thermal users in the residential and industrial sectors. Dynamic compressors are widely used in large size heat pumps, thanks to their industrial replicability, compact size, affordable costs, and good performance in terms of efficiency and low acoustic emissions. The instability, which may occur in a compressor installed in closed loop cycle such as in a heat pump, is quite different from the classic open loop configuration involving dynamic compressors. This is mainly due to the complexity of the compressor instability mechanism coupled to a vapor compression system connected with two- phase heat exchangers, having different thermal and fluid dynamic capacitance properties, under a physical feedback loop. The aim of this paper is to investigate the behaviour of a dynamic compressor installed in an innovative heat pump prototype, of laboratory scale, under stable and unstable conditions. A preliminary simple dynamic model of the compression system consisting of a radial compressor, condenser and evaporator, is developed to represent the heat pump compression system, which can capture the unstable behaviour. The evaporator and condenser are modelled using empirical correlations. The preliminary validation of the dynamic model results is done through a dedicated experimental campaign, under different operating conditions. Results show the complexity of the interaction between the centrifugal compressor and the heat pump loop, discerning the different contributions to the time-dependent response of the system, prompting the necessity of a detailed model in the next step of the work.

Experimental dynamic thermal properties determination of EPDM/NBR panels with a shape stabilized Phase Change Material based on summer daily temperatures of four cities in Italy

In this work, the evaluation of E-PCM panels based on an elastomeric matrix containing a shape-stabilized paraffinic phase change material with a melting point of 28 °C was carried in a climatic chamber, simulating the summer daily temperature profile of four geographical locations in Italy at different latitudes. The characterization, carried out on testing boxes insulated using the E-PCM panels, allowed the determination of the delay (time lag) and of the dampening (decrement factor) in the propagation of the heat wave when passing from the outer to the inner surface of the walls; the results were correlated to two important parameters, the characteristic admittance and the heat capacity. From the difference between the heat fluxes on the outer and inner surface of the panels it was also possible to quantify the amount of stored energy and to do a comparison with a reference insulating panel (aerogel). Aerogel panels, despite the low thermal conductivity but due to the limited heat capacity and characteristic admittance, were unable to provide an effective insulation during summer conditions while E-PCM panels led to excellent outcomes. Results showed that with a peak of 33 °C in the external temperature, the phase change material limited the internal one at 27 °C with a maximum delay in the peak temperature of 6 h, an overall decrement factor of 0.4, time lag of 3 h and stored energy of 740 kJ/m2 per day. Finally, also the influence of the testing speed on the response of the E-PCM was evaluated through repetition of heating/cooling cycles in the temperature range 19–35 °C, highlighting the necessity of improving the thermal conductivity of the system in case of fast-response applications (cycle length < 3.5 h) and/or to optimize the PCM amount in the panel depending on the energy to be absorbed.

Preparation of Hydrophobic Modified Silica with Si69 and Its Reinforcing Mechanical Properties in Natural Rubber.

The inherent large number of hydroxyl groups of silica poses strong hydrophilicity, resulting in poor dispersibility in the natural rubber matrix. Here, the silica's surface was hydrophobically modified with [3-(triethoxysiliconyl) propyl] tetrasulfide (Si69) to improve the dispersibility and reinforce the mechanical properties of silica/natural rubber composites. The structure and morphology of modified silica were characterized by Fourier infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), X-ray electron spectroscopy (XPS), nuclear magnetic resonance spectroscopy and the contact angle. Further, the mechanical properties, dynamic mechanical properties and morphology of silica/natural rubber composites were studied with a universal electronic tension machine, dynamic thermal mechanical properties analyzer (DMA) and scanning electron microscope (SEM). The experimental results show that the Si69 was successfully grafted onto the surface of silica, thereby significantly improving the water contact angle (a 158.6% increase) and enhancing the mechanical properties of modified silica/natural rubber composites.

Simulating Brownian motion in thermally fluctuating viscoelastic fluids by using the smoothed profile method

To investigate the Brownian motion of individual particles suspended in viscoelastic fluids, the stochastic smoothed profile method (SPm) for direct numerical simulation is developed by extending deterministic SPm for suspensions in viscoelastic media. To simulate viscoelastic flow driven by thermal fluctuations in the suspending medium, the random stress in the fluid momentum equation as well as the random driving force for the conformation tensor in the Oldroyd-B model are incorporated according to the fluctuating hydrodynamics and fluctuating viscoelasticity formalisms. The thermal equilibrium and dynamical properties calculated by using numerical simulations successfully reproduce the analytic predictions, validating the direct simulation for the coupled fluctuating Navier–Stokes and Oldroyd-B equations and for the coupling between the stochastic viscoelastic medium and individual particles. As an application of the stochastic SPm, we investigate finite system-size effects under periodic boundary conditions (PBCs) on the passive microrheological relationship between the mean-square displacement (MSD) of a Brownian particle and the medium's dynamic modulus. Comparing the modulus that was microrheologically calculated from the MSD with the input modulus reveals that the effect of periodic image cell interaction appears not only in the long-time diffusive regime but also in the short-time region. A frequency-dependent finite system-size correction is implemented by phenomenologically extending the long-time diffusive regime correction, allowing passive microrheology analysis under PBCs. This result can be directly applied to other mesoscale numerical simulations including coarse-grained molecular dynamics and dissipative particle dynamics simulations.

A Multifunctional Approach to Optimizing Woven Fabrics for Thermal Protective Clothing

This paper presents a detailed exploration of the development and characterization of multifunctional dual-purpose woven fabrics for thermal protective clothing. Through this research, 69 woven fabric prototypes have been carefully designed and produced, integrating various raw materials, yarn, and woven fabric construction parameters, with the aim of optimizing thermal protection properties while ensuring comfort and durability. The analysis led to the identification of two optimal woven fabric samples, which, upon further testing, exhibited exceptional dimensional stability, crease recovery, tear resistance, as well as abrasion and water resistance. Furthermore, the thermal properties were evaluated, demonstrating exceptional flame resistance, limited heat transmission, and high thermal insulation. Additionally, the study evaluated dynamic thermal properties, contact conductive heat transfer, air permeability, water vapour resistance, and thermal resistance of two clothing systems constructed from selected woven fabrics. Statistical analysis confirms significant differences between clothing systems, highlighting the influence of yarn composition and fabric structure on thermal performance and comfort, where one system exhibits better thermal insulation characteristics suitable for colder environments while the other excels in breathability for warmer climates. The developed woven fabrics meet high standards for protective clothing against heat and flame, surpassing currently available comparable woven fabrics on the market in terms of efficacy and performance. This research provides insights into the intricate balance between protection, comfort, and durability of woven fabrics, contributing to advancements in protective textile technology.

Thermal Properties and Dynamic Rheological Characterization of Dioscorea Starch Gels.

Yam (Dioscorea. sp.) is an edible starchy tuber with potential for being a commercial source of starch for industrial purposes, but yam starch is underutilized. The dynamic oscillatory and thermal properties of yam starches from sixteen varieties each of Dioscorea. rotundata, Dioscora. alata, Dioscorea. bulbifera and one variety of Dioscorea. dumetorum from Nigeria were studied to determine their potential for industrial utilization. The storage modulus, loss modulus, damping factor and complex viscosity as a function of frequency (ω) of the dioscorea gels, as well as the onset temperature (To), peak gelatinization temperature (Tp), end of gelatinization (TC), and gelatinization enthalpy of the starches were determined by standard procedures. Results showed that all the dioscorea starches showed a typical elastic behavior with the magnitude of G' greater than G″ while tan δ < 1 in all varieties. Thus, the starch gels were more elastic than viscous. All the starch gels exhibited shear thinning characteristics and showed frequency (ω) independence characteristics of weak gels. D. rotundata varieties had the lowest ∆Hgel, while D. bulbifera varieties had the highest. The diversity of the visco-elastic and thermal properties of the yam starch gels from different varieties and species can be an advantage in their utilization in both food and non-food industries.

Numerical research on the thermal characteristics and mechanical properties of a molten-salt single tank storage system

Single-tank thermal storage systems are an effective solution for enhancing the stability and continuity of solar power plants. The thermal characteristics and safety of the cycling process are essential indicators of single-tank performance. In this study, an integrated model of the finite volume method (FVM) and finite element method (FEM) is established for a molten-salt single tank system with a composite wall, and the effects of operating parameters and structural parameters on the cyclic dynamic thermal and mechanical characteristics are investigated. Our findings indicate that increasing the inlet flow rate reduces the heat storage capacity and increases thermal efficiency, while increasing the equivalent stress on the tank wall. However, increasing the inlet/outlet temperature difference enhances the thermal efficiency and the wall equivalent stress and reduces the heat storage capacity. Additionally, a reduction in the solid particle diameters improves the dynamic thermal properties of a single tank, and the thermal efficiency increases from 92.1 % to 94.1 % when the particle diameter decreases from 0.05 m to 0.01 m. In a composite wall structure, increasing the firebrick thickness improves the thermal efficiency and mechanical properties of the tank, while increasing the steel shell thickness improves the stress concentration on the tank wall. Therefore, to improve the thermal efficiency of a single tank and guarantee its security, the inlet flow rate and inlet/outlet temperature differences should be controlled within a certain range. Furthermore, the diameters of solid particles should be reduced, the thickness of the firebrick should be increased and the thickness of the steel shell layer should be controlled within a certain range.

Assessing the dynamic thermal performance of prefabricated wall panels in extreme hot weather conditions

Given the potential for extreme weather conditions to cause significant damage to both property and human life, it is imperative to take action to mitigate the impact of such events. Buildings as one of the main shelters of peoples’ lives become critical to study. Especially, building envelopes components that seal the buildings and act as a barrier between indoor and outdoor environments are imperative to evaluate their thermal performance. Moreover, the incorporation of prefabricated wall panels can play a pivotal role in addressing challenges associated with extreme weather conditions due to their capacity to enhance structural resilience, accelerate construction, and encourage sustainable practices. While prefabricated construction has been shown to offer significant advantages in energy conservation, low-carbon emission, and environmental protection, its thermal performance remains uncertain when subjected to significant temperature fluctuations. Therefore, the objective of this paper is to evaluate the dynamic thermal performance of a prefabricated wall panel under extreme weather conditions. Accordingly, a prefabricated wall panel was tested in an environmental chamber, simulating a heat wave that occurred in Chicago in July 2012. The metrics of Decrement factor (DF) and Time lag (TL) were used to measure the dynamic thermal properties. The results show DF of 0.07 and TL of 8 h indicating when considering thickness as a factor, the tested wall panel exhibits superior dynamic thermal performance compared to the other wall panels from the literature. This study provides valuable insights into the impact of building materials and design on energy efficiency and indoor thermal comfort.

Electronic, elastic, optic, thermal dynamic, and thermoelectric properties of the half-Heusler compounds ZrCoBi and TiCoBi

Electronic, elastic, optic, thermal dynamic, and thermoelectric properties of the half-Heusler compounds ZrCoBi and TiCoBi

Effect of the alumina micro-particle sizes on the thermal conductivity and dynamic mechanical property of epoxy resin.

Epoxy thermal conductive adhesives with high thermal conductivity and dynamic mechanical properties are important thermally conductive materials for fabricating highly integrated electronic devices. In this paper, micro-Al2O3 is used as a thermally conductive filler for the epoxy resin composite and investigated the effect of micron-sized alumina particle size on the thermal conductivity and dynamic mechanical property of epoxy resin by the transient planar hot plate method and DMA (Dynamic mechanical analysis). The experimental results show that with the same amount of alumina filling, the thermal conductivity and Tg (glass transition temperature) of epoxy/Al2O3 composite material decrease with the increase of alumina particle size. The maximum thermal conductivity of the composite material is 0.679 (W/mK), while the energy storage modulus of epoxy/Al2O3 composite material increases with the increase of alumina particle size, and the maximum energy storage modulus of the composite material is 160MPa. Compared with pure epoxy resin, the thermal conductivity and energy storage modulus have increased by 2.7 and 3.2 times, respectively. The epoxy/Al2O3 composite was applied to the COB (Chips On Board) type LED package, and the substrate temperature of the LED dropped to the lowest after 1.5 hours of operation using EP-A5 composite, and the temperature was stabilized at 38.2°C, indicating that the addition of 5-micron alumina composite has the best heat dissipation in the COB type LED package. These results are critical for the implementation of particulate-filled polymer composites in practical applications because relaxed material specifications and handling procedures can be incorporated in production environments to improve efficiency.

Underground hydrogen storage: A recovery prediction using pore network modeling and machine learning

Understanding the hydrogen-brine transport properties and the hydrogen trapping rate (i.e., ratio of residual hydrogen saturation after recovery to initial hydrogen saturation) is critical to the site selection for underground hydrogen storage (UHS). In this study, a three-dimensional pore network model (PNM) was used to simulate hydrogen-brine two phase flow in various porous media, including sandstone, carbonate, and sand packs. Surface contact angles measured from previous experiments were used to study the influence of the wettability on hydrogen transport in porous media. Many studies have investigated the impact of these factors on carbon dioxide sequestration. However, because of the difference in the thermal dynamic properties of the fluids and the purpose of UHS and carbon dioxide sequestration, it is still essential to analyze the UHS performance under the different rock and fluid properties. PNM simulations showed that a relatively larger contact angle with low water affinity was more suitable for UHS due to its low hydrogen trapping rate. Two machine learning methods, the least square fitting and the support vector machine (SVM), were developed to classify the ability of a rock to trap hydrogen and to predict hydrogen trapping rates. Hydrogen trapping rates simulated using the PNM were used as the training data in the machine learning models. The SVM classified rock samples into two groups which had high hydrogen trapping rates (>50 %) and low hydrogen trapping rates (<50 %). The machine learning results showed that rock samples with a low ratio of pore size to throat size and high pore connectivity (i.e., average number of throats connected to a given pore) were favorable for a low hydrogen trapping rate. This study illustrated that the impact of both rock surface wettability and pore structural geometry should be accounted for when evaluating a hydrogen-brine two-fluid system in porous media. This work is the first study that combined PNM simulation with machine learning to investigate the influence of rock surface wettability and pore structure features on the hydrogen trapping rate, which will provide insights into site selections and decision making in large-scale UHS projects.

Analysis of amplitude and frequency-dependent scaling behavior of dynamic hysteresis loop and thermal properties of BaZr0.05Ti0.95O3 ceramic

In this work, single-phase BaZr0.05Ti0.95O3 (BZT) ceramic was prepared through a conventional solid-state reaction route. The structural identity was analyzed by X-ray diffraction (XRD) and Rietveld refinement, which reveals the single-phase perovskite structure of the synthesized sample having an orthorhombic structure and space group Amm2. Scanning electron microscope (SEM) study gives an idea about the well-dense grains with clear grain boundaries of the BZT sample. Frequency and amplitude-dependent Polarization-Electric field (P-E) and Strain-Electric field (S-E) loops were studied. The parameters like remnant polarization (Ec), coercive field (Pr), loop area (<A>), energy storage efficiency (η), field-induced maximum strain (Smax) and inverse piezoelectric coefficient (d33*) were calculated. The scaling behavior of the hysteresis loops area as a function of frequency and field strength is studied. The thermal conductivity and thermal diffusivity as a function of temperature were investigated.

The stability, electronic, thermal, and optical properties of silver halide (AgX: X = F, Cl, Br, and I) semiconductors: Ab-initio study

The structural properties, mechanical and dynamic stability, electronic, thermal and optical properties of silver halide AgX (X = F, Cl, Br, and I) compounds in the rock-salt phase within GGA and HSE approximations have been studied. The calculations are performed using the QUANTUM-ESPRESSO package which is based on the density functional theory (DFT) and the pseudo-potential method. The calculated elasticity parameters illustrated that the rock-salt phase complies with the mechanical stability conditions at ambient pressure. Based on the results of the mechanical calculations, it can be concluded that AgI is more rigid than other silver halide compounds, while the AgF compound is more malleable than other silver halide compounds. Also, against other examined silver halides, the AgI compound has an isotropic nature. The phonon scattering diagram has proved the dynamic stability of silver halide compounds in the studied rock-salt phase. Evaluation of the electronic results indicates that silver halide compounds in both GGA and HSE approximations have an indirect bandgap in the L−Γ path. In comparison to GGA, the HSE calculation improves the amount of bandgap toward a better agreement with experimental results. At room temperature, the hole mobility of silver halides is much less than the electron mobility. The decreasing trend of the effective mass of electrons in silver halides with the atomic radius of halide in the rock-salt phase leads to a faster carrier transfer rate in AgI, AgBr, AgCl, and AgF compounds, respectively. Moreover, by increasing the atomic radius of halide atom X, the Debye temperature θD and stiffness decrease, and inversely the heat capacity Cv increases. The increasing entropy relative to temperature refers to the endothermic properties of silver halide compounds. In both GGA and HSE approximations, the AgF compound has the highest absorption coefficient peak with the maximum optical absorption in the ultraviolet regime of the electromagnetic spectrum. The absorption coefficients of the silver halide compounds are of the order of 105 cm−1 which is comparable to the absorption coefficient of silicon crystals. The latter property along with a high stability and high electron mobility, makes silver halides attractive photocatalytic materials in the NaCl structure.

Study of main factors influencing unsteady-state temperature drop in oil tank storage under dynamic thermal environment coupling

With the increasing oil demand, the construction of oil energy reserves in China needs to be further strengthened. However, given that there has been no research on the main influencing factors of crude oil temperature drop in storage tanks under actual dynamically changing environments, this paper considers the influence of dynamic thermal environment and internal crude oil physical properties on the fluctuating changes in crude oil temperature. A theoretical model of the unsteady-state temperature drop heat transfer process is developed from a three-dimensional perspective. According to the temperature drop variation law of crude oil storage tank under the coupling effect of various heat transfer modes such as external forced convection, thermal radiation, and internal natural convection, the external dynamic thermal environment influence zone, the internal crude oil physical property influence zone, and the intermediate transition zone of the tank are proposed. And the multiple non-linear regression method is used to quantitatively characterize the influence of external ambient temperature, solar radiation, wind speed, internal crude oil density, viscosity, and specific heat capacity on the temperature drop of crude oil in each influencing zone. The results of this paper not only quantitatively explain the main influencing factors of the oil temperature drop in the top, wall, and bottom regions of the tank, but also provide a theoretical reference for oil security reserves under a dynamic thermal environment.

Dynamic mechanical and thermal properties of Flax/bio-phenolic/epoxy reinforced hybrid composites

ObjectivesThe influence of flax fibre loading on the dynamic thermal and mechanical characteristics of composites was investigated in this work. MethodsFlax composites were fabricated at 30 (F-30), 40(F-40) and 50(F-50) wt% fibre loading. As a control, a bio-phenolic/epoxy polymer blend (P-20) containing 20% bio-phenolic was made. ResultsThe findings suggest that the incorporation of flax into the composites led to an enhancement in the dynamic mechanical properties of the experimental sample. The glass transition temperature (Tg) was identified via dynamic mechanical analysis to be between 60 °C and 85 °C. Aside from that, the cole–cole plot revealed a heterogeneous mixture of fabricated samples, with strong fibre-to-matrix adhesion. Thermogravimetric analysis (TGA) showed adding flax to the composite reduces thermal stability. ConclusionsWith the integration of flax as reinforcement, it could be asserted that the composites' dynamic mechanical properties improved while their thermal stability reduced.

Dynamic Rheological, Thermal, and Structural Properties of Starch from Modified Cassava Flour (MOCAF) with Two Cultivars of Cassava

The objectives of this study were to investigate alteration in the starch properties of modified cassava flour from two different local cassava cultivars from Indonesia at different fermentation times, provide structural information for starch molecules, and characterize the dynamic rheological and thermal properties. Resistant starch, non-resistant starch, and total starch levels in the cassava cultivars were also evaluated. Changes in the starch properties of Cimanggu and Kaspro (local cultivars of cassavas from Indonesia) were compared following different fermentation times (0, 12, and 24 hours). The properties of starch from modified cassava flour were influenced by the fermentation time, although both cassava varieties showed the same general characteristics. Their levels of resistant starch, non-resistant starch, and total starch were 33.28% to 51.74%, 20.51% to 23.72%, and 53.81% to 72.25% (g/100 g dry sample), respectively. The starch granules for the non-fermented samples were oval, polygonal, and round shapes; however, during fermentation, the starch granules became more porous and developed cracks of various sizes. The starches of both varieties showed an onset temperature between 67.85 and 70.17 °C, a peak temperature of 69.33 °C to 71.62 °C, and an end set temperature of 68.62 °C to 70.95 °C, with enthalpy values ranging from 1.25 mJ/mg to 1.74 mJ/mg.

The Aging Behavior and Life Prediction of CFRP Rods under a Hygrothermal Environment.

Carbon fiber-reinforced polymer (CFRP) composites have been widely used in civil engineering structures due to their excellent mechanical and durability properties. The harsh service environment of civil engineering leads to significant degradation of the thermal and mechanical performances of CFRP, which then reduces its service reliability, service safety, and life. Research on the durability of CFRP is urgently needed to understand the long-term performance degradation mechanism. In the present study, the hygrothermal aging behavior of CFRP rods was investigated experimentally through immersion in distilled water for 360 days. The water absorption and diffusion behavior, the evolution rules of short beam shear strength (SBSS), and dynamic thermal mechanical properties were obtained to investigate the hygrothermal resistance of CFRP rods. The research results show that the water absorption behavior conforms to Fick's model. The ingression of water molecules leads to a significant decrease in SBSS and glass transition temperature (Tg). This is attributed to the plasticization effect of the resin matrix and interfacial debonding. Furthermore, the Arrhenius equation was used to predict the long-term life of SBSS in the actual service environment based on the time-temperature equivalence theory, obtaining a stable strength retention of SBSS of 72.78%, which was meaningful to provide a design guideline for the long-term durability of CFRP rods.

Optimising The Mixing Ratio of Hybrid Nanofluids Based on Their Thermal Conductivity and Dynamic Viscosity Properties Using Design of Experiment Method

The hybrid nanofluid's synergetic effect is proportional to the mixing ratio. However, the One Factor at A Time (OFAT) method only displays the optimised mixing ratio when the mixing ratio used in the respective experiments is specified. Thus, the purpose of this study is to optimise the nanoparticle mixing ratio using Design of Experiment (DOE) in Design Expert 11 to cover the entire range of mixing ratios with the fewest experiments possible. The prepared hybrid nanofluid comprises Titanium Dioxide (TiO2) and Graphene Nanoplatelets (GNP) at a concentration of 0.3vol%, a mixing ratio ranging from 1:9 to 9:1, and temperature ranging from 30oC to 60oC. However, the DOE method generates only 1:9, 1:1, and 9:1 mixing ratios. ANOVA analysis was used to generate a model for thermal conductivity. Additionally, the optimisation results indicate that a mixing ratio of 1:4 (TiO2-GNP) and a temperature of 40oC are the optimised parameters. The difference between the measured and predicted thermal conductivity values was less than 5%.