Dynamic Tension Research Articles

Ball Milling Improves Physicochemical, Functionality, and Emulsification Characteristics of Insoluble Dietary Fiber from Polygonatum sibiricum.

The effects of ball milling on the physicochemical, functional, and emulsification characteristics of Polygonatum sibiricum insoluble dietary fiber (PIDF) were investigated. Through controlling milling time (4, 5, 6, 7, and 8 h), five PIDFs (PIDF-1, PIDF-2, PIDF-3, PIDF-4, and PIDF-5) were obtained. The results showed that ball milling effectively decreased the particle size and increased the zeta-potential of PIDF. Scanning electron microscope results revealed that PIDF-5 has a coarser microstructure. All PIDF samples had similar FTIR and XRD spectra. The functional properties of PIDF were all improved to varying degrees after ball milling. PIDF-3 had the highest water-holding capacity (5.12 g/g), oil-holding capacity (2.83 g/g), water-swelling capacity (3.83 mL/g), total phenol (8.12 mg/g), and total flavonoid (1.91 mg/g). PIDF-4 had the highest ion exchange capacity. Fat and glucose adsorption capacity were enhanced with ball milling time prolongation. PIDF-5 exhibited a contact angle of 88.7° and lower dynamic interfacial tension. Rheological results showed that PIDF-based emulsions had shear thinning and gel-like properties. PE-PIDF-5 emulsion had the smallest particle size and the highest zeta-potential value. PE-PIDF-5 was stable at pH 7 and high temperature. The findings of this study are of great significance to guide the utilization of the by-products of Polygonatum sibiricum.

Cucurbit[7]uril-Modified Nano SiO2 for Efficient Separation of Crude Oil Emulsions: Properties and Demulsification Mechanism.

Demulsification of crude oil emulsion is an obvious problem in the whole of petroleum engineering, which needs to be dealt with urgently. In this paper, a supramolecular material Cucurbit[7]uril-SiO2 (CB-SiO2) synthesized with excellent demulsification efficiency (DE) on O/W emulsion was synthesized by a simple thermal synthesis method. The microscopic morphology and structure were investigated through modern characterization techniques. Furthermore, its stability, dynamic interfacial tension (IFT), and wettability (three-phase contact angle (CA)) were systematically investigated, and the demulsification efficiency of different conditions on crude oil emulsion was also investigated. Reassuringly, these results showed that when the temperature was 70 °C, the demulsification dosage was close to 600 mg/L and remained unchanged for 90 min; the demulsification efficiency is 2.2 times compared with the unmodified material, up to 93.63%. In addition, a plausible demulsification mechanism was proposed, which is that CB-SiO2 can adsorb and disrupt the oil-water interface, leading to oil-water separation and promoting demulsification. It is a promising demulsification material for the oil industry demulsification.

Unraveling Early-Stage Dynamics of Cage-to-Covalent Organic Framework Transformation at Liquid-Liquid Interface.

Postsynthetic linker exchange (PLE) has emerged as an emerging synthetic strategy for constructing high-quality covalent organic frameworks (COFs) from preassembled entities such as linear polymers, amorphous networks, COFs, and porous organic cages by using the principles of dynamic covalent chemistry. The PLE strategy has recently been extended at the liquid-liquid interface to fabricate highly crystalline two-dimensional (2D)-COF membranes at a faster time scale (24 h). Examining the early stages of the interfacial PLE dynamics becomes essential to understanding the expedited COF growth process. In this regard, pendant drop tensiometry has been employed to probe the initial reaction dynamics of the imine cage-to-COF transformation through dynamic interfacial tension (IFT) measurements. The contrasting trends in IFT profiles between PLE-mediated (from cage) and direct COF synthesis (from parent monomers) are in qualitative agreement with the kinetics of bulk-scale interfacial polymerizations. Further, the distinct early-stage interfacial behaviors between the diverse synthetic routes have been experimentally demonstrated using tensiometry, optical microscopy, electron microscopy, and powder X-ray diffraction (PXRD) analysis. The pivotal role of in situ generated imine intermediates (ImIs) and the phenomenon of spontaneous emulsification toward accelerated interfacial COF growth process was delineated. The current study on deploying the pendant drop tensiometric technique to examine early-stage interfacial polymerization dynamics opens up a gripping avenue for mechanistic exploration in PLE-based COF synthesis. The generality of the developed methodology to study the initial COF growth kinetics was extended to a new interfacial PLE-mediated cage-to-COF transformation.

Droplet Microfluidic Method for Estimating the Dynamic Interfacial Tension of Ion-Crosslinked Sodium Alginate Microspheres.

The research focuses on optimizing the production of hydrogel microspheres using droplet microfluidics for pharmaceutical and bioengineering applications. A semiempirical method has been developed to predict the dynamic interfacial tension at the interface of ion-cross-linked sodium alginate microsphere-sunflower oil modified with glacial acetic acid and Tween 80 surfactant. These microspheres are produced in a small-scale coaxial device that is manufactured using affordable DLP/LCD 3D printing technology with a transparent photopolymer. The method was tested to design the minireactor in the device, which allows for the production of fully cross-linked microspheres that are ready for use at the output of the reactor without additional cross-linking steps in the microsphere collector. The mathematical expression for estimating the interfacial tension at the moment of formation of a hydrogel microsphere includes the Reynolds number for a two-phase liquid, the Ohnesorge number, and the surface tension at the liquid-air interface for continuous medium flow (modified oil). The reliability of the prediction is confirmed for continuous medium and dispersed phase flow rates of 0.8-3.2 and 0.01-0.08 mL/min, respectively. The evolution of the interfacial tension from the moment the microspheres formed and the estimated ultimate interfacial tension in a cross-linked hydrogel-modified oil system contributed to the reliable determination of the linear size of a minireactor. The ultimate interfacial tension of 76.5 ± 0.3 mN/m was determined using the Young-Laplace equation, which is based on measuring the surface free energy of the hydrogel as soft matter using the Owens-Wendt method. Additionally, the equilibrium static contact angle of the fully cross-linked hydrogel surface wetted with oil is measured using the sessile drop method. From a practical perspective, a method for optimizing and streamlining the high-tech manufacturing of cross-linked polymer microspheres and mini- and microchannel devices for use in bioengineering and pharmaceutical applications is suggested.

Experimental study on impact behaviour of normal strength mortar at cryogenic temperatures and after freeze-thaw cycles

Concrete structures employed for the storage of Liquefied Natural Gases (LNG) currently undergo temperature as low as −170 °C. These critical engineering structures may also experience dynamic loads such as impact or explosion during service life. Therefore, it is crucial to explore the mechanical response of concrete at intermediate to high strain rates together with low temperatures or cryogenic freeze-thaw (FT) cycles. This study presents experimental research into the combined effects of low temperatures and strain rate on normal strength mortar, providing a preliminary analysis of the dynamic performance of concrete at low and cryogenic temperatures. A Split Hopkinson Pressure Bar (SHPB) device was used to investigate the characteristics of dynamic compression (at strain rates of 40, 80, 120 and 160 s−1) and dynamic split tension (at strain rates of 20, 40, 60 and 80 s−1) of Normal Strength Mortar (NSM) at different low temperatures. In addition, the dynamic compression (at strain rates of 80, 130 and 180 s−1) after cryogenic FT cycles was also explored. The findings revealed that the failure pattern of NSM samples exposed to coupled low temperature or cryogenic FT cycles and high strain rate loading notably varied from that observed under room temperature condition. Both the dynamic compressive and split tensile strengths of NSM increased with the strain rates at all temperatures. At −160 °C, the dynamic compressive and splitting tensile strengths of NSM specimens were greater than those at room temperature (by 10.94 % and 28.29 %, respectively) and −70 °C (by 3.13 % and 4.12 %, respectively). Cryogenic freeze-thaw cycles evidently impacted the material static and dynamic performance. An empirical model was developed to predict the dynamic increase factors (DIFs) for both dynamic compression and splitting tensile strengths of NSM at low/cryogenic temperatures and after freeze-thaw cycles. Scanning electron microscopy (SEM) technique was performed to study and comprehend the microscopic processes and microstructural changes after FT cycles.

Demulsification of steam-assisted gravity drainage (SAGD) emulsions under high temperature and high pressure: Effects of emulsion breaker and reverse emulsion breaker dosages

Effective treatment of complex emulsions formed during steam-assisted gravity drainage (SAGD) production is crucial for oil/water separation and subsequent processing. However, it remains challenging due to the complexity of SAGD emulsions, and there are only very limited studies on demulsification under simulated SAGD conditions. This study systematically characterized the comprehensive properties of a fresh field SAGD emulsion with about 84.6 % water and 15.4 % bitumen, and then achieved effective demulsification under a simulated SAGD condition at 135 °C and 60 psi via adding a poly(ethylene oxide)-poly(propylene oxide) (PEO-PPO) copolymer (as a model emulsion breaker or EB) combined with a branched polyethylenimine (PEI, as a model reverse emulsion breaker or REB) in a bench-scale bottle test setup. The effects of EB and REB dosages on the demulsification of the SAGD emulsion were evaluated based on the properties of the separated phases. Dynamic interfacial tension, zeta potential, and coalescence time were measured to reveal the demulsification mechanisms of EB and REB. The highly interface-active EB facilitated oil dehydration by displacing the natural interface-active species at the interfaces, disrupting the rigid interfacial films and promoting water droplet coalescence, while the cationic REB aided water de-oiling by neutralizing oil droplet surface charges, disrupting the rigid interfacial films and promoting the approach and coalescence of oil droplets in aqueous media. This work has improved the understanding of SAGD emulsion characteristics, the effects of EB and REB dosages on the demulsification performance, and the underlying demulsification mechanisms in SAGD operations. The results provide useful insights for developing effective and cost-efficient chemical approaches to address challenging emulsion issues in oil production.

Reconceptualising Transparency in Journalism: Thinking Through Secrecy and PR Press Releases in News Cultures

ABSTRACT This article re-examines debates about transparency in journalism by using a sociological framework that analyses how transparency is held in a dynamic tension with secrecy. I use a specific empirical case study as the grounding for my analysis and then proceed to expand its scope to consider significant developments in transparency in the media. I take as my case study the relationship between UK journalists and public relations (PR) practitioners. Specifically, I analyse the ways in which press releases are shaped by PR practitioners, targeted at journalists, and are taken up by journalists in a UK news media context in which such “information subsidies” may be becoming ever more prevalent. Reframing transparency as one element in a compound phenomenon (the secrecy–transparency dynamic), I argue that practices of both transparency and secrecy are not merely situated within social contexts but are active in creating society and social relations. This approach pays close attention to how power operates in this shifting dynamic and offers new challenges for thinking about journalism’s role in society.

Gaining by losing: The daily living experience of international female doctoral students in Aotearoa New Zealand

ABSTRACT This Straussian grounded theory study explored how female doctoral students from South East Asia managed their daily occupations while studying in Aotearoa New Zealand. Twenty-three participants who were living or had lived in Auckland, one of Aotearoa New Zealand’s metropolitan cities, completed semi-structured, in-depth interviews on their experiences of occupation in that context. Data were also collected via participant observations. The analysis of data through open, axial, and selective coding yielded a substantive theory: Gaining by Losing , which entailed a three-stage process of Choosing to be International Students, Meeting Challenges, and Returning Transformed. Each stage was characterised as being in dynamic tension of initially exploring opportunities/making sacrifices, then encountering difficulties/making adjustments to daily occupations while studying, and ultimately living with their choice/experiencing changes. The findings revealed that temporarily moving to a city with a high cost of living elicited changes in the way they performed daily occupations, such as studying, cooking, shopping, caring for children, and so forth.

Cryogenic mechanical behavior and FCC → HCP phase transformation mechanism in a Si-added CrCoNi medium-entropy alloy under quasi-static and dynamic tension

The CrCoNiSi0.3 MEA exhibits excellent cryogenic mechanical properties upon both quasi-static and dynamic tension. Under quasi-static tension at cryogenic temperature, the engineering yield and ultimate tensile strengths (UTS) reach 980 MPa and 1800 MPa, respectively, with notable ductility (62 %). The product of UTS and total elongation (TE) is 111.6 GPa %, surpassing most cryogenic high strength-ductility alloys. The significant mechanical strength enhancement is attributed to the denser deformation twins (DTs), multiple twinning, and extensive face-centered-cubic to hexagonal-close-packed (HCP) phase transitions, resulting in a high work hardening capacity. Upon dynamic tension at cryogenic temperature, the strength and strain hardening are further improved, which originates from the thickening DTs and HCP sequence and localized plastic deformation. The effects of temperature and strain rate on phase transition are studied. It is proposed that there is a competing relationship between high strain rate and increased stacking fault energy (SFE) due to temperature rise. The coupling effect of cryogenic temperature and high strain rate inhibits phase transition due to the deformation inhomogeneity in CrCoNiSi0.3 MEA. The findings make a valuable contribution to understand the influence of temperature and strain rate on the mechanism of FCC-to-HCP phase transition.

Interfacial protein adsorption behavior can be connected across a wide range of timescales using the microfluidic EDGE (Edge-based droplet GEneration) tensiometer

HypothesisOur hypothesis is that dynamic interfacial tension values as measured by the partitioned-Edge-based Droplet GEneration (EDGE) tensiometry can be connected to those obtained with classical techniques, such as the automated drop tensiometer (ADT), expanding the range of timescales towards very short ones. ExperimentsOil-water and air–water interfaces are studied, with whey protein isolate solutions (WPI, 2.5 – 10 wt%) as the continuous phase. The dispersed phase consists of pure hexadecane or air. The EDGE tensiometer and ADT are used to measure the interfacial (surface) tension at various timescales. A comparative assessment is carried out to identify differences between protein concentrations as well as between oil–water and air–water interfaces. FindingsThe EDGE tensiometer can measure at timescales down to a few milliseconds and up to around 10 s, while the ADT provides dynamic interfacial tension values after at least one second from droplet injection and typically is used to also cover hours. The interfacial tension values measured with both techniques exhibit overlap, implying that the techniques provide consistent and complementary information. Unlike the ADT, the EDGE tensiometer distinguishes differences in protein adsorption dynamics at protein concentrations as high as 10 wt% (which is the highest concentration tested) at both oil–water and air–water interfaces.

Preparation of a low-temperature demulsifier derived from natural cottonseed oil

In this study, a low-temperature demulsifier (TEP-L) was synthesized by a simple method using polyethylene glycol 1000, and low-cost and readily accessible cottonseed oil as raw materials. The cottonseed oil was first hydrolyzed and then directly reacted with polyethylene glycol 1000 to obtain TEP-L. The chemical composition of TEP-L was determined by Fourier transform infrared spectroscopy (FT-IR) and nuclear magnetic resonance hydrogen spectroscopy (1H NMR). A comprehensive investigation was conducted to explore the demulsification performance of TEP-L in water-in-oil (W/O) emulsion. The investigation notably considered the effect of demulsifier dosage, temperature, settling time, pH value, and salinity on the demulsification process. The results demonstrated that the dehydration rate (DR) could reach 100 % with 1000 mg/L of TEP-L at 40 ℃ for 21 h, or a dosage of 500 mg/L at 60 ℃ for 240 min. Moreover, TEP-L exhibited a DR exceeding 90 % over a broad pH range of 8–12 and displayed remarkable resistance to salt. Characterization methods such as surface tension (SFT), dynamic interface tension (IFT), zeta potential, and optical microscopy observation were utilized to investigate the demulsification mechanisms.

Rock-like material under large diameter SHPB dynamic splitting tension: meso-damage mechanical behavior and stress wave propagation model

The mechanical behavior of splitting tensile damage and the law of stress wave propagation of rock-like materials (RLM) are of great significance to further reveal the dynamic disaster mechanism of the deep rock mass. The meso-damage mechanical behavior and stress wave propagation characteristics of RLM disks under impact splitting were studied by using a large diameter split Hopkinson pressure bar (SHPB). In terms of dynamic damage, the splitting tensile stress-compression strain curves of RLM disks obviously showed three stages of mechanical behavior evolution: initial elastic-plastic deformation, pre-peak plastic damage, and post-peak brittle fracture failure. The macro-damage of RLM disks increased with the increase of strain rate. The meso-tensile fracture was the result of both the initial meso-damage and the impact splitting meso-damage. The dynamic splitting damage variable defined based on the damage fracture energy can accurately describe the damage evolution characteristics of impact splitting on RLM disks. In the aspect of stress wave propagation, the peak value of transmission stress showed an advanced effect with the increase of incident stress wave. In the early stage (0–50 μs), the transmission stress wave ratio (σT/σI) increased with the increase of strain rate, while in the later stage (82–200 μs), the transmission stress wave ratio (σT/σI) decreased with the increase of strain rate. The stress wave propagation law in the process of impact splitting on RLM disks was clearly revealed based on the stress wave propagation model established by the one-dimensional elastic stress wave theory. Finally, the dynamic mechanical mechanism of splitting damage and fracture of RLM disks under different strain rates was discussed deeply.

Exploring the role of γ-Oryzanol on stabilization mechanism of Pickering emulsion gels loaded by α-Lactalbumin or β-Lactoglobulin via multiscale approaches

The research explored the role of γ-oryzanol (γs) on stabilization behavior of Pickering emulsion gels (PEGs) loaded by α-lactalbumin (α-LA) or β-lactoglobulin (β-LG), being analyzed by experimental and computer methods (molecular dynamic simulation, MD). Primarily, the average particle size of β-LG-γS was expressed 100.07% decrease over that of α-LA-γS. In addition, γs decreased the dynamic interfacial tension of two proteins with the order of β-LG < α-LA. Meanwhile, quartz crystal microbalance with dissipation proved that β-LG-γS exhibited higher adsorption mass and denser rigid interface layer than α-LA-γS. Moreover, the hydrophobic group of γS had electrostatic repulsion with polar water molecules in the aqueous phase, which spread to the oil phase. β-LG-γS had lower RMSD/Rg value and narrower fluctuation compared with α-LA-γS. This work strength the exploration of interfacial stabilization mechanism of whey protein-based PEGs, which enriched its theoretical research for industrial-scale production as the replacement of trans fat and cholesterol.

Investigation of Frequency-Dependent Characteristics of Wire Rope under Tension Based on Transfer Function Method

Wire rope is a complex structure made by twisting wires of various sizes in the longitudinal direction. It is used to support or move engineering structures and is subject to various tensions. Dynamic properties are important parameters to evaluate the resistance to bending deformation and vibration reduction of various structures. They are affected by the magnitude of tension. In this study, an experimental method for measuring the frequency-dependent characteristics of wire rope under tension is proposed. The study analyzed flexural wave propagation employing a vibration transfer function. Experimental results showed that the transfer function of wire rope under tension is affected by tension and bending stiffness. The Newton–Raphson method was employed to numerically measure wavenumbers of the wire rope. The bending stiffness and loss factor were determined from the wavenumbers. Changes in the bending stiffness and loss factor as the tension increased were explained by the dynamic behavior of the structure under tension. As the tension increased, the bending stiffness increased, and the loss factor decreased. Hysteresis analysis indicated that the energy dissipation of wire rope is greater than that of a steel beam due to the friction between the wires. Statistical analysis confirmed a significant correlation between dynamic characteristics and tension in wire rope.

Experimental study on dynamic direct tensile performances of steel fiber-reinforced RPC at high strain rates

Reactive power concrete (RPC) exhibits excellent mechanical properties, makes it great potential for applications. RPC has gained increasing attention in academic and engineering areas and has been used in fields such as anti-explosion engineering. The insufficient tensile strength of RPC is one of the critical reasons for its structural failure. Existing studies revealed that the strain rate effect of concrete under dynamic tension is stronger than that under dynamic compression. The existing research focuses either on dynamic splitting and spalling tests, or dynamic uniaxial tensile properties with a strain rate of 0–100/s, neither of which are representative of the effect of RPC subject to explosion. In addition, the study of the dynamic uniaxial tensile constitutive model of RPC has not been reported in the existing research. To solve the existing limitations, this study conducted dynamic direct tension tests on steel fiber-reinforced RPC with a predefined strain rate higher than 100 s−1 using a Split Hopkinson Tension Bar (SHTB) apparatus. RPC dumbbell-shaped samples, including plain RPC and steel fiber-reinforced RPC (SFRPC) with 1 % and 2 % fiber volumetric fractions, were tested at high strain rates of 98–528 s−1. Based on the test results of this study and those derived from existing publications, the relationship between dynamic direct tensile properties, steel fiber fraction, and strain rate was quantitatively analyzed, and corresponding empirical formulae were proposed. To meet the demand for numerical analysis on RPC structures subjected to explosive forces, a dynamic tensile stress-strain model for steel fiber-reinforced RPC considering steel fiber, strain rate, and dynamic toughness, was established.

Adsorption study on the formation of interfacial layers based on birch glucuronoxylans

Glucuronoxylans (GX), particularly crude fractions obtained by pressurized hot water extraction of birch wood, act as potent emulsifiers and stabilizers against physical separation and lipid oxidation. Herein, we studied the adsorption of GX on hydrophobic interfaces to correlate their multicomponent character towards the formation of interfacial layers in emulsions. Dynamic interfacial tension (DIFT) and quartz crystal microgravimetry with dissipation monitoring (QCM-D) were applied to various GX fractions and the results compared with those from cellulose-based emulsifiers. The roles of residual lignin and polysaccharides are discussed considering the formation of interfacial layers during emulsification. The DIFT of the different GXs reached quasi-equilibrium faster as the lignin concentration increased, implying a correlation between the rate of adsorption and the residual lignin content. The effect of NaCl addition was more pronounced in polysaccharide-rich fractions, indicating that the polysaccharide fraction modulated the effect of ionic strength. QCM-D showed that despite the fast adsorption exhibited by the lignin-rich GX extract in the DIFT curves, the adsorbed materials were lightweight, suggesting that the polysaccharide fraction built the bulk of the interfacial layer. These results provide a foundation towards understanding the role of GX in interfacial stabilization beyond traditional plant-based counterparts.

RETRACTED ARTICLE: Microwave-ultrasonic assisted extraction of lignin to synthesize new nano micellar organometallic surfactants for refining oily wastewater

In this work, a beneficial approach for efficient depolymerization of lignin and controllable product distribution is provided. Lignin, an abundant aromatic biopolymer, has the potential to produce various biofuels and chemical adsorption agents and is expected to benefit the future circular economy. Microwave-ultrasonic (MW/US) assisted efficient depolymerization of lignin affords some aromatic materials used in manufacturing the starting material to be investigated. Some nano organometallic surfactants (NOMS) based on Ni2+, Cu2+, Co2+, Fe3+, and Mn2+ besides 2-hydroxynaphth-sulphanilamide are synthesized to enhance oil recovery (EOR). In this work, the assessment of the NOMS’s efficiency was improving the heavy oil recovery via the study of the dynamic interfacial tension (IFT), contact angle, and chemical flooding scenarios. The NOMS-Ni2+ exhibited the maximum reduction of viscosity and yield values. Dropping the viscosity to 819.9, 659.89, and 499.9 Pa s from blank crude oil viscosity of 9978.8, 8005.6, and 5008.6 Pa s respectively at temperatures of 40, 60, and 80 °C was investigated. The reduction of τB values was obtained also by OMS-Ni2+. The minimum IFT was recorded against the Ni2+ derivatives (0.1 × 10–1 mN m−1). The complete wettability alteration was achieved with the NOMS-Ni2+ surfactant (ɵ ≅6.01).\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\cong 6.01).$$\\end{document} The flooding test has been steered in 3 sets using the sand-packed model as a porous media at surfactant concentrations (1, 1.5, 2 and 2.5%) at 50 °C and 499 psi as injection pressure. The best value (ORs) formed for NOMS-Ni2+ were 62, 81, 85.2, and 89% respectively as compared with other NOMS-M2+ at the same concentrations. The mechanism of alternating wettability was described in the text. The rheology of the used heavy crude oil was investigated under temperatures of 40, 60, and 80 °C.Graphical

Bottlebrush Block Copolymers at the Interface of Immiscible Liquids: Adsorption and Lateral Packing.

Amphiphilic bottlebrush block copolymers (BBCPs), having a hydrophilic bottlebrush polymer (BP) linked covalently to a hydrophobic BP, were found to segregate to liquid-liquid interfaces to minimize the free energy of the system. The key parameter influencing the outcome of the experiments is the ratio between the degree of polymerization of the backbone (NBB) and that of the side-chain brushes (NSC). Specifically, a spherical, star-like configuration results when NBB < NSC, while a cylindrical, bottlebrush-like shape is preferred when NBB > NSC. Dynamic interfacial tension (γ) and fluorescence recovery after photobleaching (FRAP) measurements show that the BBCP configuration influences the areal density and in-plane diffusion at the fluid interface. The characteristic relaxation times associated with BBCP adsorption (τA) and reorganization (τR) were determined by fitting time-dependent interfacial tension measurements to a sum of two exponential relaxation functions. Both τA and τR initially increased with NBB up to 92 repeat units, due to the larger hydrodynamic radius in solution and slower in-plane diffusivity, attributed to a shorter cross-sectional diameter of the side-chains near the block junction. This trend reversed at NBB = 190, with shorter τA and τR attributed to increased segregation strength and exposure of the bare water/toluene interface due to tilting and/or wiggling of the backbone chains, respectively. The adsorption energy barrier decreased with higher NBB, due to a reduced BBCP packing density at the fluid interface. This study provides fundamental insights into macromolecular assembly at fluid interfaces, as it pertains to unique bottlebrush block architectures.

Physical and mechanical properties of deflection-hardening hybrid fibre-reinforced recycled aggregate concrete

Recycled aggregate concrete (RAC) has been gaining a large interest in recent years due to the depletion of natural aggregates and environmental protection requirements. To improve the ductility of RAC for structural applications and to avoid corrosion risks involved with utilising steel fibres, this study proposes a deflection-hardening hybrid fibre-reinforced recycled aggregate concrete (FRRAC) by combining newly developed macro-basalt fibre (BF, 0.67 % by volume) and recycled macro-polypropylene fibre (PF, 0.67 % by volume). Its fresh, static and dynamic mechanical properties were investigated and compared with the mix containing macro-BF only (1.34 % by volume). A Ø 100 mm split Hopkinson pressure bar (SHPB) system was used to determine the dynamic mechanical properties in compression and tension. The hybrid FRRAC retained up to 90 % of its average first peak load at 3.5 mm crack width and showed better cracking bridging performance under dynamic splitting tension than the specimens with the same volume of macro-BF. Empirical formulae for dynamic increase factors and energy absorption capacities against varying strain rates have also been proposed for the newly developed hybrid FRRAC.

Investigation on dynamic behaviour of tin-lead welding spot of spacecraft circuit board

Spacecraft shall be subjected to mechanical environments such as mechanical shocks during loading, unloading and transportation, and the shocks shall be transmitted to the circuit boards inside. There are plenty of tin-lead spots on the circuit board as there are a large number inside the spacecraft. The dynamic behaviour of tin-lead welding spot determines the anti-impact and anti-fatigue properties of the circuit board, and therefore, it is essential to investigate the dynamic behaviour of tin-lead welding spot based on sufficient experiments and accurate simulation. In this research work, the dynamic uniaxial tension at five different strain rates (0.1/s, 1/s, 10/s, 100/s and 1000/s) were performed, the morphology of the fracture surface was examined and the alloy ingredient was analyzed. Furthermore, the finite element models (FEM) of both the tensile sample and the circuit board were developed based on the modified Darveaux model and the cohesive zone method. According to the experiments and the simulation of the uniaxial tensile samples, it was the mass ratio of the tin to the lead that govern the micro mechanical properties, and the modified Darveaux model could precisely describe the stress-strain response of the welding spot. As a result, the calculated results of the impacting dynamical behaviour of the circuit board are reasonable and helpful. The modified Darveaux model and the developed simulation approach could also be applied to other welding structures experiencing impulsive loads. The investigation shall provide research support for the mechanical environment analysis of spacecraft and other mechanical impact.