A novel citric acid-activated Lablab purpureus husk is proposed to remove crystal violet (CV) and sunset yellow (SY) by column chromatographic elution in a cost-effective way. The adsorbent was characterized by Scanning Electron Microscopy (SEM) and the images supported the adsorptive nature of the material. The experiments were carried out on a chromatographic column by homogenously packing the pre-wetted adsorbent into the column and eluting the dye solution through it. The effects of initial dye concentration, adsorbent dose, pH, contact time, and flow rate were optimized. The efficient removal of up to 300 and 4400 µg/mL of CV and SY, respectively, was observed. The pH range of 4-5 for CV and >4 for SY were found effective. The flow rate was optimized at 1 ml/min. The contact time was found less than 10 minutes. The adsorbent was successfully removed 96.62% and 99.62% of CV and SY, respectively. The Freundlich and Langmuir adsorption isotherm studies were carried out to interpret the interaction between the adsorbate and adsorbent. These models are instrumental in optimizing and scaling up the adsorption process for practical and industrial applications. The experimental data for the adsorption of CV and SY fitted well with the Freundlich isotherm, and the kinetic study of both CV and SY fitted well with the pseudo-second-order reaction.
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