Durability Issues Research Articles

Long‐term Durability of Seawater Electrolysis for Hydrogen: From Catalysts to Systems

AbstractDirect electrochemical seawater splitting is a renewable, scalable, and potentially economic approach for green hydrogen production in environments where ultra‐pure water is not readily available. However, issues related to low durability caused by complex ions in seawater pose great challenges for its industrialization. In this review, a mechanistic analysis of durability issues of electrolytic seawater splitting is discussed. We critically analyze the development of seawater electrolysis and identify the durability challenges at both the anode and cathode. Particular emphasis is given to elucidating rational strategies for designing electrocatalysts/electrodes/interfaces with long lifetimes in realistic seawater including inducing passivating anion layers, preferential OH−adsorption, employing anti‐corrosion materials, fabricating protective layers, immobilizing Cl− on the surface of electrocatalysts, tailoring Cl− adsorption sites, inhibition of OH− binding to Mg2+ and Ca2+, inhibition of Mg and Ca hydroxide precipitation adherence, and co‐electrosynthesis of nano‐sized Mg hydroxides. Synthesis methods of electrocatalysts/electrodes and innovations in electrolyzer are also discussed. Furthermore, the prospects for developing seawater splitting technologies for clean hydrogen generation are summarized. We found that researchers have rethought the role of Cl− ions, as well as more attention to cathodic reaction and electrolyzers, which is conducive to accelerate the commercialization of seawater electrolysis.

Shear performance of perfobond leiste (PBL) connectors in engineered cementitious composites (ECC)

Substituting normal concrete with ductile Engineered Cementitious Composites (ECC) is a promising way to address the safety and durability issues caused by cracking in steel-concrete composite structures. To realize a synergistic deformation behavior between steel and ECC, Perfobond Leiste (PBL) shear connectors are preferred to be used owing to their superior shear resistance, shear stiffness, and excellent fatigue performance. This research comprehensively investigated the shear performance of PBL connectors in ECC through experimental, numerical, and analytical approaches. Firstly, the shear load-slip relationships of PBL connectors in ECC and concrete were studied through push-out tests of 36 H-shaped specimens. It indicated that the fracture of penetrating bars dominated the final failure of PBL connectors in ECC, whereas premature concrete spalling happened in concrete specimens. By establishing a refined finite element model, the parametric study was then conducted to clarify the influence of the compressive strength of ECC, hole diameter, penetrating bar diameter, and penetrated plate thickness on the shear characteristics of PBL connectors in ECC. Finally, an analytical model for predicting the shear carrying capacity of PBL connectors embedded in ECC was derived, matching well with the test results.

The LIFE SILENT project's approach to sustainable noise mitigation

The main objective of the LIFE SILENT PROJECT is the development of sustainable and eco-friendly solutions to mitigate noise in complex urban environments, where multiple and diverse noise sources, mainly roads and railways, coexist across densely populated areas. Mitigating noise in such environments generally excludes the use of solutions that might interfere with the urban context, such as noise barriers. This is mainly due to the proximity of receivers to the noise source, which reduces the visibility of the surroundings and air circulation, leading to microclimatic modifications and social opposition. This is why noise mitigation measures acting directly on the source are recommended, such as low-noise pavements for roads, and dampers, rail grinding, and silent brakes for railways. However, these solutions suffer from either durability issues or high implementation costs. Thus, an improvement is necessary. In the LIFE SILENT project, innovative and sustainable low-noise and long-lasting pavements, as well as low-height noise barriers will be developed and demonstrated in a real test environment. Additionally, procedures will be established to facilitate their synergistic implementation, providing transport infrastructure owners and managers with solid information to support their widespread adoption. In this paper, a general overview of the LIFE SILENT project is given.

Effect of High-Temperature Operation on Voltage Cycling Induced PEMFC Degradation: From Automotive Customer Drive Cycles to an Accelerated Stress Test

Degradation of the Pt catalyst during load cycling constitutes a major durability issue for proton exchange membrane fuel cells (PEMFCs) in automotive applications. In this study commercial 5 cm2 electrodes were exposed to 20 k voltage cycles between 0.6–0.9 VRHE at temperatures ranging from 75 to 120 °C. The electrochemical surface area (ECSA), the roughness factor (rf), and the oxygen transport resistance were investigated over the course of the test. The degradation was mainly governed by Pt agglomeration and was accelerated with increasing temperature. Interestingly, operation at high temperature (120 °C and 30% RH) caused the same ECSA loss as at standard conditions (90 °C and 90% RH), suggesting that when maintaining dry conditions high-temperature operation is not critical for the durability of the catalyst material. The experimental results were used to validate an existing 0D catalyst degradation model, which was then applied to an automotive customer drive cycle. The calculated degradation over the whole automotive lifetime (excluding startup shutdown and idle events) equals 20 k voltage cycles (0.6–0.9 V, 10 s hold time) at 90 °C and 30% RH, which provides a guideline for the assessment of the suitability of novel catalyst materials for automotive applications.

Enhanced Epoxy Composites Reinforced by 3D-Aligned Aluminum Borate Nanowhiskers.

Recently, the durability of high-performance and multifunctional portable electronic devices such as smartphones and tablets, has become an important issue. Electronic device housing, which protects internal components from external stimuli, such as vibration, shock, and electrical hazards, is essential for resolving durability issues. Therefore, the materials used for electronic device housing must possess good mechanical and electrical insulating properties. Herein, we propose a novel high-strength polymer nanocomposite based on 3D-aligned aluminum borate nanowhisker (ABOw) structures. ABOw was synthesized using a facile hydrothermal method, and 3D-aligned ABOw structures were fabricated using a freeze-casting process. The 3D-aligned ABOw/epoxy composites consist of repetitively layered structures, and the microstructures of these composites are controlled by the filler content. The developed 3D-aligned ABOw/epoxy composite had a compressive strength 56.72% higher than that of pure epoxy, indicating that it can provide high durability when applied as a protective material for portable electronic devices.

Discontinuity-enhanced icephobic surfaces for low ice adhesion

HypothesisPassive low ice-adhesion surfaces are frequently composed of soft materials; however, soft materials potentially present durability issues, which could be overcome by fabricating composite surfaces with patterned rigid and soft areas. Here we propose the innovative concept of discontinuity-enhanced icephobic surfaces, where the stress concentration at the edge between rigid and soft areas, i.e. where discontinuities in elasticity are located, facilitates ice detachment. ExperimentsComposite model surfaces were fabricated with controlled rigid-soft ratios and discontinuity line lengths. The ice adhesion values were measured while recording the ice/substrate interface, to unravel the underpinning ice detachment mechanism. The experiments were complemented by numerical simulations that provided a better understanding of the ice detachment mechanism. FindingsIt was found that when a surface contains rigid and soft areas, stress is concentrated at the edge between soft and hard areas, i.e. at the discontinuity line, rather than all over the soft or rigid areas. An unexpected non-unidirectional crack propagation was observed for the first time and elucidated. When rigid and deformable materials are present, the crack occurs on the discontinuity line and propagates first on rigid and then on soft areas. Moreover, it was demonstrated that an increase in discontinuities promotes crack initiation and leads to a reduction of ice adhesion.

Basalt fibers corrosion in concrete: New perspectives originating from computational modelling techniques employment

Most of engineering disciplines or research areas have recently witnessed strategic changes leading to formulation of new challenges and revision of existing activities. Promoting the environmental aspects to the highest priority level was mostly in common. Seeking for energy efficient solutions, concrete society has mentioned basalt as a promising candidate having a potential to replace steel in the future. The chemical disharmony between basalt and alkaline environment of concrete, however, represents the most challenging tasks that obstructs the replacement procedure due to durability issues. Since only 3.3 % of the research priorities in this area deals with the corrosion and degradation problems, while the mainstream (57.0 %) prefers determination of various material properties, this problem seems to be undervalued. Additionally, computational modelling approaches are surprisingly not applied as frequently (6.1 %) as in other disciplines, although they could provide the essential long-term research. Simplified methods therefore still dominate these estimations approaches. This paper therefore brings an overview on basalt fiber corrosion in concrete, while summarizing the most topical gaps slowing down the basalt application progress. Since these gaps originate mostly from the simplifications adopted, specific solutions are proposed respectively, exploiting the unique advantages and possibilities of computational modelling approaches that are omitted. The topicality as well as the potential of the advanced approach is demonstrated on a critical example dealing with corrosion analysis evaluation in a specific wall segment. Highlighting the differences between simplified- and advanced techniques outputs, the main findings are concluded, and the most topical gaps are identified.

Rapid Assessment of Sulfate Resistance in Mortar and Concrete.

Extensive research has been conducted on the sulfate attack of concrete structures; however, the need to adopt the use of more sustainable materials is driving a need for a quicker test method to assess sulfate resistance. This work presents accelerated methods that can reduce the time required for assessing the sulfate resistance of mixtures by 70%. Class F fly ash has historically been used in concrete mixtures to improve sulfate resistance. However, environmental considerations and the evolving energy industry have decreased its availability, requiring the identification of economically viable and environmentally friendly alternatives to fly ash. Another challenge in addressing sulfate attack durability issues in concrete is that the standard sulfate attack test (ASTM C1012) is time-consuming and designed for only standard mortars (not concrete mixtures). To expedite the testing process, accelerated testing methods for both mortar and concrete mixtures were adopted from previous work to further the development of the accelerated tests and to assess the feasibility of testing the sulfate resistance of mortar and concrete mixtures rapidly. This study also established criteria for interpreting sulfate resistance for each of the test methods used in this work. A total of 14 mortar mixtures and four concrete mixtures using two types of Portland cement (Type I and Type I/II) and various supplementary cementitious materials (SCMs) were evaluated in this study. The accelerated testing methods significantly reduced the evaluation time from 12 months to 21 days for mortar mixtures and from 6 months to 56 days for concrete mixtures. The proposed interpretation method for mortar accelerated test results showed acceptable consistency with the ACI 318-19 interpretations for ASTM C1012 results. The interpretation methods proposed for the two concrete sulfate attack tests demonstrated excellent consistency with the ASTM C1012 results from mortar mixtures with the same cementitious materials combinations. Metakaolin was shown to improve sulfate resistance for both mortar and concrete mixtures, while silica fume and natural pozzolan had a limited impact. Using 15% metakaolin in mortar or concrete mixtures with Type I/II cement provided the best sulfate resistance.

Evaluation of the effect of binder type and layer thickness on the performnce of open graded friction courses

To improve the long-term durability and functionality of open graded friction courses (OGFC), the Florida Department of Transportation (FDOT) investigated the use of a highly modified asphalt binder and increased thickness using Accelerated Pavement Testing (APT). A total of six test sections with combinations of two modified binder types (PG 76–22 and PG 82–22) and three lift thicknesses of 0.75 (19.05 mm), 1.25 (31.75 mm) and 2 (50.8) inches were constructed at FDOT’s APT facility. Accelerated loading was performed using a Heavy Vehicle Simulator (HVS) to evaluate the relative rutting performance of the test sections. Supplementary field and laboratory tests to evaluate tensile strength, Cantabro loss, field permeability, surface characteristics, and asphalt binder properties were also conducted. Test results indicated that the use of PG 82–22 polymer modified asphalt (PMA) binder may be beneficial to improve long-term durability of the OGFC. Thicker layers of OGFC were found to have considerably lower durability. It is recommended that the use of a highly modified PMA asphalt binder in OGFC layers be considered when raveling and other durability issues are of concern.

Experimental Study on the Bending Behavior of Precast Concrete Segmental Bridges with Continuous Rebars at Joints

Longitudinal ordinary rebars are discontinuous at the joints of precast concrete segmental bridges (PCSBs), which can open under tensile stresses induced by bending moments. This will lead to durability issues with the joints. To improve the bending properties of PCSBs, a novel joint type featuring continuous rebars was proposed in the present study. Three specimens were subjected to testing to examine the bending behavior of PCSBs using this new joint design compared to traditional joints. The crack propagation, structural deformation, joint opening width, strain in rebars, failure mode, stiffness, and flexural capacity were comprehensively investigated. The test results reveal that the continuous rebars effectively transferred bending normal stress between joints, ensuring full development of cracks in each beam segment. Effective control of joint opening width was also observed. Compared to traditional joints, the new joints exhibited a 29% to 33% increase in cracking load and a 32% increase in ultimate load. Failure in the continuous rebar joints was characterized by partial anchorage failure of the rebars along with localized concrete crushing in the top compression zone. Based on the test results, a computational method was proposed for calculating the cracking strength and flexural capacity of the new joints.

Investigating Additive Manufacturing Possibilities for an Unmanned Aerial Vehicle with Polymeric Materials.

Fused filament fabrication, also known as fused deposition modeling and 3D printing, is the most common additive manufacturing technology due to its cost-effectiveness and customization flexibility compared to existing alternatives. It may revolutionize unmanned aerial vehicle (UAV) design and fabrication. Therefore, this study hypothesizes the 3D printing possibility of UAV using a simple desktop printer and polymeric material. The extensive literature analysis identified the acceptable prototyping object and polymeric material. Thus, the research focuses on applying polylactic acid (PLA) in manufacturing the flying wing-type UAV and develops a fabrication concept to replicate arial vehicles initially produced from a mixture of expanded polystyrene and polyethylene. The material choice stems from PLA's non-toxicity, ease of fabrication, and cost-effectiveness. Alongside ordinary PLA, this study includes lightweight PLA to investigate the mechanical performance of this advanced material, which changes its density depending on the printing temperature. This proof-of-concept study explores the mechanical properties of printed parts of the wing prototype. It also considers the possibility of fragmentation in fabricated objects because of the limitations of printing space. The simplified bending tests identified significant reserves in the mechanical performance regarding the theoretical resistance of the material in the wing prototype, which proves the raised hypothesis and delivers the object for further optimization. Focusing on the mechanical resistance, this study ignored rheology and durability issues, which require additional investigations. Fabricating the wing of the exact geometry reveals acceptable precision of the 3D printing processes but highlights the problematic technology issues requiring further resolution.

Incorporation of Jute Fiber in Concrete: A Literature Review

Abstract: This systematic literature review delves into the incorporation of jute fiber as a reinforcement material in concrete, examining its benefits, challenges, and potential applications. Jute fiber, a natural and biodegradable material, presents an eco-friendly and cost-effective alternative to synthetic fibers commonly used in concrete reinforcement. The utilization of jute fibers in concrete not only enhances its mechanical properties but also promotes sustainable construction practices, addressing the growing need for environmentally responsible building materials. The review synthesizes existing research on the physical, mechanical, and durability properties of jute fiber-reinforced concrete (JFRC). It explores how the unique characteristics of jute fibers, such as their high tensile strength and low density, contribute to improved concrete performance, particularly in terms of tensile and flexural strength. The addition of jute fibers helps mitigate crack propagation and enhances the ductility of concrete, making it more resilient to dynamic loads. Despite these benefits, challenges such as the hydrophilic nature of jute fibers, which can lead to increased water absorption and potential durability issues, are also addressed. Various chemical treatments and surface modifications have been explored to improve the compatibility of jute fibers with the cement matrix and enhance the overall durability of JFRC

Longitudinal valvotomy of anterior leaflet for endoscopic transmitral myectomy for hypertrophic obstructive cardiomyopathy.

Transmitral myectomy for hypertrophic obstructive cardiomyopathy is compatible with minimally invasive surgery compared with traditional transaortic access. It has often been performed in conjunction with mitral valve replacement or temporary detachment of the anterior leaflet from its annulus. We present a novel approach: longitudinal incision at the midline of the anterior mitral leaflet for septal myectomy. The procedure is ideally conducted endoscopically or robotically through the right chest. Cardiopulmonary bypass is established in the usual manner. After cardioplegic arrest, the mitral valve is exposed, and the anterior mitral leaflet is incised longitudinally at the midline. Both parts of the leaflet are tentatively fixed to the atrial wall with sutures to keep them open. Using the look-up mode of a 30° scope, the right cusp of the aortic valve is observed. Myectomy is initiated close to the aortic annulus using the pure-cut mode of electrocautery and scissors, then extended apically as necessary. After myectomy, the anterior leaflet is reapproximated with interrupted sutures. This technique is simpler than the detachment of the anterior leaflet and does not require patch materials that could lead to durability issues for the reconstruction of the anterior leaflet.

Long-term Durability of Seawater Electrolysis for Hydrogen: From Catalysts to Systems.

Direct electrochemical seawater splitting is a renewable, scalable, and potentially economic approach for green hydrogen production. However, issues related to low durability caused by complex ions in seawater pose great challenges for its industrialization.In this review, a mechanistic analysis of durability issues of electrolytic seawater splitting is discussed.We critically analyze the development of seawater electrolysis and identify the durability challenges at both the anode and cathode. Particular emphasis is given to elucidating rational strategies for designing electrocatalysts/electrodes/interfaces with long lifetimes in realistic seawater including inducing passivating anion layers, preferential OH-adsorption, employing anti-corrosion materials, fabricating protective layers, immobilizing Cl- on the surface of electrocatalysts, tailoring Cl- adsorption sites, inhibiting binding of OH- to Mg2+ and Ca2+, inhibiting adherence of Mg and Ca hydroxide precipitation, and co-electrosynthesis of nano-sized Mg hydroxides. Synthesis methods of electrocatalysts/electrodes and innovations in electrolyzer are also discussed. Furthermore, the prospects for developing seawater splitting technologies for clean hydrogen generation are summarized. We found that researchers have changed the attitude towards Cl- ions from "hate" to accept to utilize, as well as more attention to cathodic reaction and electrolyzers, which is conducive to accelerate the commercialization of seawater electrolysis.

Identification of crack width behavior of one-way reinforced concrete slab structure at different steel reinforcement area

An evaluation study of crack limit states based on design codes and prior research is presented in this publication. Its main goal is to connect research findings to common design codes. Researchers continue to face a difficult dilemma when it comes to reinforced concrete structure fractures, particularly in one-way slab constructions where there is still significant damage and corrosion in the reinforcement because of cracks. Practitioners will find it easier to construct these structures and solve the slab durability issue if the proper formula is discovered. One can overcome reinforced concrete. A method for estimating the maximum fracture width formula in one-way reinforced concrete slabs with varying steel areas is suggested based on this research. Slabs use a variety of steel areas, including 1000 mm2, 1200 mm2, and 1400 mm2.The test specimens are the same length of 2 meters and have a slab width of 0.6 meters with steel reinforcement. Findings from a literature review of research codes and prediction formulas from earlier studies, namely wmax(prop)=1.5*10-2fsAs-0.4, indicate that the maximum crack width is not significantly influenced by steel area (As). Overall, the findings from the two methods used in this analysis match the suggested formula and the observed experimental testing. This data indicates that the maximum fracture width has been greatly lowered by increasing the steel Area (As) of the reinforced concrete slab, leading to the determination of the experimental formula, As a result, a unique approximation formula has been developed to assess the impact of steel area parameters for pure slabs on the maximum crack width formula for one-way reinforced concrete slabs. This crack width formula is only applicable to one-way slabs in practice.

Mechanistic insights into two-stage expansion of concrete under external sulfate attack

Despite extensive academic research on durability issues caused by sulfate attack, deterioration reasons and expansion mechanisms of concrete remain controversial, with descriptions of expansion development still focusing on phenomenological observations. The present study analyzes the macro-micro property changes of concrete and establishes a time-varying expansion prediction model considering environmental and material parameters. The micropore evolution in different pore categories is investigated, and the primary type and precipitation location of expansive products, as well as the expansion mechanism of concrete, are clarified. The results indicate the possibility of thaumasite sulfate attack (TSA) in concrete at low temperatures. The expansion development of concrete under sulfate attack can be divided into two stages: the expansion latency stage explained by crystallization pressure theory, and the significant expansion stage associated with volume increase theory. The expansion level at the inflection point of the expansion rate was solely related to the intrinsic micropore properties of concrete.

Preparation and Properties of Waterborne Polyurethane and SBS Composite-Modified Emulsified Asphalt

To address the issue of insufficient durability of traditional modified emulsified asphalt in the application of cold mix and cold paving anti-skid wear layers, this study utilizes cationic waterborne polyurethane (PU+) for composite modification to enhance adhesion and performance across a range of temperatures. Initially, composite-modified emulsified asphalt samples were prepared with varying dosages of PU+ according to a gradient method. Routine performance tests were conducted on the evaporated residues for analysis. Advanced rheological tests, including temperature sweep (TS), frequency sweep (FS), linear amplitude sweep (LAS), and multi-stress creep recovery (MSCR) tests, were performed using a dynamic shear rheometer (DSR). Surface free energy (SFE) tests were conducted with a fully automated surface tension meter (STM). A comprehensive evaluation of the high-temperature rheological properties, fatigue properties, adhesion properties, and water damage resistance of the modified emulsified asphalt residues was carried out. Chemical changes before and after modification were characterized using Fourier transform infrared spectroscopy (FTIR), and the distribution of polymers in the evaporated residue was observed using fluorescence microscopy (FM). The results demonstrated that cationic waterborne polyurethane significantly enhanced the fatigue and adhesion properties of SBS-modified emulsified asphalt, but it also weakened the water damage resistance of asphalt. MSCR tests revealed that the addition of cationic waterborne polyurethane might reduce the elastic recovery performance of modified asphalt, thereby weakening its resistance to rutting. Among the samples, the modified asphalt with a PU+ content of 6% exhibited good high-temperature shear resistance and elastic recovery performance, demonstrating the best anti-rutting performance.

Advancing Low-Cost Iron Redox Flow Batteries for Grid Storage

Iron-based redox flow batteries are promising and low-cost energy storage technologies for grid level showing the potential to meet DOE’s cost targets LCOS, $0.05/kWh due to its natural abundancy and eco friendliness. Iron deposition process has a parasitic hydrogen evaluation reaction (HER) controlling the storage capacity and efficiency. HER reaction imbalances the electrolyte composition and causes durability issues. Our present study shows how the performance of the iron flow battery can be increased by introducing advanced 3D electrodes and engineered electrolytes.This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344. Funding was provided by Lawrence Livermore National Laboratory Directed Research and Development (LDRD) Grant 22-DR-014. IM release number: LLNL-ABS-858432

Enhanced Capacity Retention Utilizing Hybrid Carbon Nanotube and Modified Separator in Li-Sulfur Batteries

Lithium-sulfur batteries (LiSBs) hold significant promise for high-energy storage; however, further concerted efforts are required to address challenges such as the shuttle effect, durability issues, and volume expansion to unlock their full potential. This study introduces an innovative approach to enhancing LiSBs' performance, involving the fabrication of a sulfur cathode using hybrid carbon nanotubes and modified separator. The modified separator exhibited high-rate capabilities, retaining over 80% capacity (~665 mAh/g) across 50 cycles. Cyclic voltammetry analysis indicated that the modified separator enhanced lithium-ion transportaion and a diffusion-controlled charge storage mechanism. Overall electrochemical performances suggest the potential of the proposed technique as an alternative for stabilizing LiSBs.

Direct Hydroquinone Fuel Cells

The Increasing interest and need to shift to sustainable energy give rise to the utilization of fuel cell technologies in various applications. The challenging task of hydrogen storage and transport led to the development of liquid hydrogen carriers (LHC) as fuels for direct LHC fuel cells, such as methanol in direct methanol fuel cells (DMFC). Although simpler to handle, most direct LHC fuel cells suffer from durability and price issues, derived from high catalysts’ loadings and by-products of the oxidation reaction of the fuel. Herein, we report on the development of direct hydroquinone fuel cells (DQFC) based on anthraquinone-2,7-disulfonic acid (AQDS) as an LHC. We have shown that DQFC can operate with continues flow of quinone as a hydrogen carrier, outperforming the incumbent state-of-the-art DMFC by a factor of three in peak power density, while completely removing the need for any catalyst at the anode. In addition, we demonstrate that the quinone can be charged with protons in the same system, making it a reversible fuel cell system. We optimized the operating conditions and will discuss the governing conditions to reach best performance.