We efficaciously extended the ansatz in the Riccati equation rational expansion technique to a new broad form and is used to attain some new exact wave solutions for the couple non-linear Drinfeld-Sokolov-Wilson (DSW) system. This system arises in water waves, quantum mechanics, fluid mechanics, biology, chemistry etc. Several of the attained solutions which is in the shape of rational solitary wave solutions and periodic wave solutions are entirely new and could be vital for researchers to appreciate. Certain selected solutions are graphically verified by precise values allocated to constant parameters. This technique with the current ansatz can be implemented with a broader range of applicability to handle various other forms of non-linear evolution systems (NLES).