Double Color Research Articles

Design of High-Secure Digital/Optical Double Color Image Encryption Assisted by 9D Chaos and DnCNN

With the rapid development of multimedia technology, securing the transfer of images becomes an urgent matter. Therefore, designing a high-speed/secure system for color images is a real challenge. A nine-dimensional (9D) chaotic-based digital/optical encryption schem is proposed for double-color images in this paper. The scheme consists of cascaded digital and optical encryption parts. The nine chaotic sequences are grouped into three sets, where each set is responsible for encryption one of the RGB channels independently. One of them controls the fusion, XOR operation, and scrambling-based digital part. The other two sets are used for controlling the optical part by constructing two independent chaotic phase masks in the optical Fourier transforms domain. A denoising convolution neural network (DnCNN) is designed to enhance the robustness of the decrypted images against the Gaussian noise. The simulation results prove the robustness of the proposed scheme as the entropy factor reaches an average of 7.997 for the encrypted color lena-baboon images with an infinite peak signal-to-noise ratio (PSNR) for the decrypted images. The designed DnCNN operates efficiently with the proposed encryption scheme as it enhances the performance against the Gaussian noise, where the PSNR of the decrypted Lena image is enhanced from 27.01 dB to 32.56 dB after applying the DnCNN.

P‐261: Late‐News Poster: Highly Efficient Color Conversion Layers Using Organic Nano‐dots

In this study, we report color conversion layers (CCLs) developed by new organic nano‐dots (ONDs). These ONDs, comprised of organic fluorescent materials and surfactant molecules, offer unique advantages such as tunable optical properties, high (100%) photoluminescence quantum yield (PLQY), and narrow (25‐35 nm) full‐width at half‐maximum (FWHM). Compared to the inorganic (InP) reference CCLs, OND CCLs exhibit almost double (80‐85%) color conversion efficiencies with good photo and thermal stability.

Innentitelbild: Reconfigurable Photonic Crystal Reversibly Exhibiting Single and Double Structural Colors (Angew. Chem. 52/2023)

Innentitelbild: Reconfigurable Photonic Crystal Reversibly Exhibiting Single and Double Structural Colors (Angew. Chem. 52/2023)

Inside Cover: Reconfigurable Photonic Crystal Reversibly Exhibiting Single and Double Structural Colors (Angew. Chem. Int. Ed. 52/2023)

Inside Cover: Reconfigurable Photonic Crystal Reversibly Exhibiting Single and Double Structural Colors (Angew. Chem. Int. Ed. 52/2023)

Reconfigurable Photonic Crystal Reversibly Exhibiting Single and Double Structural Colors

AbstractUnlike absorption‐based colors of dyes and pigments, reflection‐based colors of photonic crystals, so called “structural colors”, are responsive to external stimuli, but can remain unfaded for over ten million years, and therefore regarded as a next‐generation coloring mechanism. However, it is a challenge to rationally design the spectra of structural colors, where one structure gives only one reflection peak defined by Bragg's law, unlike those of absorption‐based colors. Here, we report a reconfigurable photonic crystal that exhibits single‐peak and double‐peak structural colors. This photonic crystal is composed of a colloidal nanosheet in water, which spontaneously adopts a layered structure with single periodicity (407 nm). After a temperature‐gradient treatment, the photonic crystal segregates into two regions with shrunken (385 nm) and expanded (448 nm) periodicities, and thus exhibits double reflection peaks that are blue‐ and red‐shifted from the original one, respectively. Notably, the transition between the single‐peak and double‐peak states is reversible.

Reconfigurable Photonic Crystal Reversibly Exhibiting Single and Double Structural Colors.

Unlike absorption-based colors of dyes and pigments, reflection-based colors of photonic crystals, so called "structural colors", are responsive to external stimuli, but can remain unfaded for over ten million years, and therefore regarded as a next-generation coloring mechanism. However, it is a challenge to rationally design the spectra of structural colors, where one structure gives only one reflection peak defined by Bragg's law, unlike those of absorption-based colors. Here, we report a reconfigurable photonic crystal that exhibits single-peak and double-peak structural colors. This photonic crystal is composed of a colloidal nanosheet in water, which spontaneously adopts a layered structure with single periodicity (407 nm). After a temperature-gradient treatment, the photonic crystal segregates into two regions with shrunken (385 nm) and expanded (448 nm) periodicities, and thus exhibits double reflection peaks that are blue- and red-shifted from the original one, respectively. Notably, the transition between the single-peak and double-peak states is reversible.

Versatile Double Bandgap Photonic Crystals of High Color Saturation.

Double bandgap photonic crystals (PCs) exhibit significant potential for applications in various color display-related fields. However, they show low color saturation and inadequate color modulation capabilities. This study presents a viable approach to the fabrication of double bandgap photonic inks diffracting typical secondary colors and other composite colors by simply mixing two photonic nanochains (PNCs) of different primary colors as pigments in an appropriate percentage following the conventional RGB color matching method. In this approach, the PNCs are magnetically responsive and display three primary colors that can be synthesized by combining hydrogen bond-guided and magnetic field (H)-assisted template polymerization. The as-prepared double bandgap photonic inks present high color saturation due to the fixed and narrow full-width at half-maxima of the parent PNCs with a suitable chain length. Furthermore, they can be used to easily produce a flexible double bandgap PC film by embedding the PNCs into a gel, such as polyacrylamide, facilitating fast steady display performance without the requirement of an external magnetic field. This research not only presents the unique advantages of PNCs in constructing multi-bandgap PCs but also establishes the feasibility of utilizing PNCs in practical applications within the fields of anti-counterfeiting and flexible wearable devices.

Red-Light-Photosensitized NO Release and Its Monitoring in Cancer Cells with Biodegradable Polymeric Nanoparticles.

The role of nitric oxide (NO) as an "unconventional" therapeutic and the strict dependence of biological effects on its concentration require the generation of NO with precise spatiotemporal control. The development of precursors and strategies to activate NO release by excitation in the so-called "therapeutic window" with highly biocompatible and tissue-penetrating red light is desirable and challenging. Herein, we demonstrate that one-photon red-light excitation of Verteporfin, a clinically approved photosensitizer (PS) for photodynamic therapy, activates NO release, in a catalytic fashion, from an otherwise blue-light activatable NO photodonor (NOPD) with an improvement of about 300 nm toward longer and more biocompatible wavelengths. Steady-state and time-resolved spectroscopic and photochemical studies combined with theoretical calculations account for an NO photorelease photosensitized by the lowest triplet state of the PS. In view of biological applications, the water-insoluble PS and NOPD have been co-entrapped within water-dispersible, biodegradable polymeric nanoparticles (NPs) of mPEG-b-PCL (about 84 nm in diameter), where the red-light activation of NO release takes place even more effectively than in an organic solvent solution and almost independently by the presence of oxygen. Moreover, the ideal spectroscopic prerequisites and the restricted environment of the NPs permit the green-fluorescent co-product formed concomitantly to NO photorelease to communicate with the PS via Förster resonance energy transfer. This leads to an enhancement of the typical red emission of the PS offering the possibility of a double color optical reporter useful for the real-time monitoring of the NO release through fluorescence techniques. The suitability of this strategy applied to the polymeric NPs as potential nanotherapeutics was evaluated through biological tests performed by using HepG2 hepatocarcinoma and A375 melanoma cancer cell lines. Fluorescence investigation in cells and cell viability experiments demonstrates the occurrence of the NO release under one-photon red-light illumination also in the biological environment. This confirms that the adopted strategy provides a valuable tool for generating NO from an already available NOPD, otherwise activatable with the poorly biocompatible blue light, without requiring any chemical modification and the use of sophisticated irradiation sources.

Simple synthesis of Bi3+ and Fe3+ co-doped Cs2Ag0.6Na0.4InCl6 double perovskite and its dual emission mechanism

The lead-free double perovskite with low toxicity and good performance stability has attracted much attention in optoelectronic device applications. But their photoluminescence quantum yields (PLQY) are low, which limits their applications. Co-doping and alloying are the most valuable methods to improve its PLQY and stability. In this study, we successfully synthesized Bi3+ and Fe3+ co-doped Cs2Ag0.6Na0.4InCl6 double perovskite using the hydrothermal method, and the emission mechanism was further investigated. Under UV-light excitation, the Cs2Ag0.6Na0.4InCl6: Bi3+/Fe3+ shows dual emission. This emission results from the modification effect of self-trapped exciton (STE) formation, and Fe3+ induces longer wavelength emission. By changing the doping contents of Bi3+ and Fe3+, the revolution of double perovskite color from yellow to orange-red can be observed, and its PLQY is up to 39.95%. The studies of the PL emission mechanism reveal that energy transfer occurs between the STE and Fe3+, and different doping contents can affect this transfer mechanism. This work has implications for producing double perovskite for optoelectronic semiconductors and provides direction for designing new lead-free double perovskites.

Double Color Image Visual Encryption Based on Digital Chaos and Compressed Sensing

Image encryption is an effective way to protect images in secure transmission or storage. In this paper, we propose a novel double color image visual encryption algorithm based on the improved Chebyshev map (ICM) and compressed sensing. Firstly, a new nonlinear term is introduced into the classical one-dimensional Chebyshev map, and then the ICM is used to generate the secret code stream for the encryption algorithm. Next, the key-controlled sensing measurement matrices are constructed through the ICM, and they are used to compress the integer wavelet coefficients of two plain images. Subsequently, the compressed images are dislocated by dislocation matrices and diffused by an ICM-generated diffusion matrix, respectively. Finally, the encrypted images are embedded into the carrier image using the least significant bit embedding algorithm. Experimental results demonstrate that the proposed method has good visual safety, large key space, and high key sensitivity.

Imaging flow cytometry-based multiplex FISH for three IGH translocations in multiple myeloma

Three types of chromosomal translocations, t(4;14)(p16;q32), t(14;16)(q32;q23), and t(11;14)(q13;q32), are associated with prognosis and the decision making of therapeutic strategy for multiple myeloma (MM). In this study, we developed a new diagnostic modality of the multiplex FISH in immunophenotyped cells in suspension (Immunophenotyped-Suspension-Multiplex (ISM)-FISH). For the ISM-FISH, we first subject cells in suspension to the immunostaining by anti-CD138 antibody and, then, to the hybridization with four different FISH probes for genes of IGH, FGFR3, MAF, and CCND1 tagged by different fluorescence in suspension. Then, cells are analyzed by the imaging flow cytometry MI-1000 combined with the FISH spot counting tool. By this system of the ISM-FISH, we can simultaneously examine the three chromosomal translocations, i.e, t(4;14), t(14;16), and t(11;14), in CD138-positive tumor cells in more than 2.5 × 104 nucleated cells with the sensitivity at least up to 1%, possibly up to 0.1%. The experiments on bone marrow nucleated cells (BMNCs) from 70 patients with MM or monoclonal gammopathy of undetermined significance demonstrated the promising qualitative diagnostic ability in detecting t(11;14), t(4;14), and t(14;16) of our ISM-FISH, which was more sensitive compared with standard double-color (DC) FISH examining 200 interphase cells with its best sensitivity up to 1.0%. Moreover, the ISM-FISH showed a positive concordance of 96.6% and negative concordance of 98.8% with standard DC-FISH examining 1000 interphase cells. In conclusion, the ISM-FISH is a rapid and reliable diagnostic tool for the simultaneous examination of three critically important IGH translocations, which may promote risk-adapted individualized therapy in MM.

Detecting Double JPEG Compressed Color Images via an Improved Approach

Detecting double Joint Photographic Experts Group (JPEG) compression for color images is vital in the field of image forensics. In previous researches, there have been various approaches to detecting double JPEG compression with different quantization matrices. However, the detection of double JPEG color images with the same quantization matrix is still a challenging task. An effective detection approach to extract features is proposed in this paper by combining traditional analysis with Convolutional Neural Networks (CNN). On the one hand, the number of nonzero pixels and the sum of pixel values of color space conversion error are provided with 12-dimensional features through experiments. On the other hand, the rounding error, the truncation error and the quantization coefficient matrix are used to generate a total of 128-dimensional features via a specially designed CNN. In such a CNN, convolutional layers with fixed kernel of and Dropout layers are adopted to prevent overfitting of the model, and an average pooling layer is used to extract local characteristics. In this approach, the Support Vector Machine (SVM) classifier is applied to distinguish whether a given color image is primarily or secondarily compressed. The approach is also suitable for the case when customized needs are considered. The experimental results show that the proposed approach is more effective than some existing ones when the compression quality factors are low.

Unexpectedly High Prevalence of iAMP21 in Children with Acute Lymphoblastic Leukemia in Mexico: A Report from the "Mexico in Alliance with St. Jude” (MAS) Collaborative Group

Keywords: acute lymphoblastic leukemia, intra-amplification of chromosome 21, genetic characterization. Mexico in Alliance with St. Jude (MAS) has carried out a multi-center collaboration for children with acute lymphoblastic leukemia (ALL) in Mexico since 2019. The "Bridge Project” has granted access to diagnostic tests that allow genetic characterization of children with ALL in participating centers. The Molecular Genetics Laboratory of Hospital Infantil Teleton de Oncologia (HITO) serves as the referral laboratory. 253 newly diagnosed ALL patients from 5 hospitals in Mexico have utilized a comprehensive diagnostic panel that includes cytogenetic and molecular tests to identify relevant abnormalities. iAMP21 is recognized by the 2017 World Health Organization (WHO) Classification of Tumors of Hematopoietic and Lymphoid Tissues as a characteristic genetic alteration of B-lineage Leukemia/Lymphoma, with a reported incidence of up to 2-5%. It involves amplification of the RUNX1 gene and/or duplication of chromosome 21 dup(21q), and defines a relatively new cytogenetic subgroup in B-lineage ALL with poor prognosis, derived from the genetic instability of chromosome 21.The heterogeneity of iAMP21 contributes to the difficulty in its detection with the sole use of conventional cytogenetic techniques, rendering Fluorescent In Situ Hybridization (FISH) as a better strategy for the distinction between iAMP21 (amplification in tandem) and the sporadic gain of copies of the RUNX1 gene. METHODS: We performed a comprehensive diagnostic panel for 253 patients with ALL; the FISH B-cell lymphoid panel included (KMT2A, ETV6 (TEL)/RUNX1 (AML1), BCR/ ABL, E2A/(TCF3)/(PBX1) and the T-cell lymphoid panel included (MLL, BCR / ABL, E2A / (TCF3) / (PBX1), TLX1, TLX3, CDKN2A and TRA / D). Diagnosis of iAMP21 was made using the interphase FISH technique with the LSI ETV6/RUNX1 (Vysis®) double color double fusion probe (Abbott Molecular®, Ill), and Cytocell probe (OGT Company®, NY). A finding of ≥ 5 RUNX1 gene signals in interphase FISH and/or more than 3 signals within chromosome 21 was considered positive for the identification of iAMP21. Samples were processed according to the specifications to the AGT Cytogenetics Laboratory Manual. FISH analysis was performed by analyzing 200 interphase cells. When ETV6/ RUNX1 probes are used, samples of patients carrying iAMP21 usually show two normal copies of the ETV6 signal and multiple RUNX1 signals (three or more additional signals) and are negative for the ETV6-RUNX1 fusion gene. RESULTS: Among 253 patients with ALL, 233 cases were of lineage B (92%) and 20 (8%) were of lineage T. FISH was reported negative in 57 (23%) and positive in 185 (73%) cases, 11 results were not available (4.3%). We detected iAMP21 in 28 (11%); these cases were classified as high risk. We also report t(12;21) in 41 (16%), MLL gene disruption t(4;11) in 10 (4%), t(1;19) in 14 (6%), and t(9;22) in 7 (3%); 75 (30%) patients had nonspecific genetic gains. The T lineage showed CDKN2A del(9)(p21) in 6 (2.5%) and TRA/D(14)(q11.2) rearrangement in 4 (1.7%) cases. CONCLUSION: Our experience shows that FISH analysis with the ETV6/RUNX1 probe is useful for identifying iAMP21, a chromosomal abnormality with prognostic significance. Genetic risk factors in the Hispanic population that adversely impact survival in Latin America are not yet fully identified. The Molecular genetic analysis and the fluorescence in situ hybridization (FISH) technique are the basic methods used to detect the presence of the most common genetic abnormalities, the presence or absence of which has an impact on the patient's classification into the appropriate risk group. Our findings from this cohort point to an increased prevalence of iAMP21 in ALL patients in Mexico. We will soon incorporate gene sequencing to the diagnostic panel and improve the characterization of these patients. Figure 1View largeDownload PPTFigure 1View largeDownload PPT Close modal

A Novel Combined Double Binary Turbo Coding and Color Shift Keying Technique for Flicker Mitigation in Multi Carrier Visible Light Communications

Although radio frequency (RF) systems have been developed at a level that can operate almost within theoretical limits in terms of spectral efficiency due to increasing demands, the RF spectrum allocated for wireless mobile communication has started to fill up rapidly and become insufficient. Visible light communication (VLC), one of the optical wireless communication systems, stands out as a promising technology that can be an alternative to RF technology in some application areas and can help meet the demands by playing a complementary role in some application areas. However, VLC systems face the flickering problem. In this study, it is proposed to combine the double binary Turbo coding (DBTC) technique with color shift keying (CSK) modulation, which does not have a flickering problem, as a solution to the flicker problem of VLC systems. The proposed combined DBTC-CSK method is tested on optical OFDM systems from multi-carrier wireless communication systems. Monte-Carlo simulations are performed to verify the performance of the proposed DBTC-CSK-OFDM system in terms of bit-error-rate (BER) over AWGN channel, single-path optical LOS channel and multi-path optical channel. According to the simulation results it is observed that, DBTC-CSK-OFDM system has better BER performance than that of RS–CC coded CSK-OFDM and un-coded CSK-OFDM systems, providing 5.5 dB and 14 dB SNR gain at multi-path optical channel environments, respectively.

Determining the ideal initial printing colorants in electrophotography by the discrete gradation trajectories

The accuracy and repeatability of the color reproduction in print is determined by the fine‐tuning of the tone reproduction curves of the basic printing colorants (most often this is CMYK). However, the diversity of manufacturers of printing equipment and dyes introduces an element of significant uncertainty about color uniformity. In addition, the traditional approach does not take into account the effect of hue change when applying the original dyes, as well as the nonlinearity of the hue rise in high‐ and low‐density areas. Determining the color of base colorants that produces the most uniform tone change is an important engineering challenge. Previously, there was no scientific basis for such calculations. We recently proposed an alternative color correction model based on gradation trajectories as an analogue of gradation curves in the CIE Lab space. We have also described the extension of the approach to double color overlay (gradation surfaces) and its analytical and discrete implications. The trajectories are the geodetic lines on gradation surfaces. In this paper, we propose using the gradation trajectories to determine “ideal” or “true” initial printing dyes for electrophotography. To simplify calculations, natural color discretization in digital printing is used.

Influence of Aqueous Phase Composition on Double Emulsion Stability and Colour Retention of Encapsulated Anthocyanins.

Water-in-oil-in-water (W1/O/W2) emulsions (double emulsions) have often been used for the encapsulation of bioactive compounds such as anthocyanins. Instability of both anthocyanins and double emulsions creates a need for a tailored composition of the aqueous phase. In this work, double emulsions with a gelled internal water phase were produced and monitored over a 20-day storage period. The effect of the electrolyte phase composition (varying electrolyte components, including adipic acid, citric acid, and varying concentration of potassium chloride (KCl)) on anthocyanin and double emulsion stability was analysed using colour analysis, droplet sizing, and emulsion rheology. The effect of electrolytes on colour retention was shown to differ between the primary W1/O emulsion and the secondary W1/O/W2 emulsion. Furthermore, droplet size analysis and emulsion rheology highlighted significant differences in the stability and structural behaviour of the emulsions as a function of electrolyte composition. In terms of colour retention and emulsion stability, a citrate-buffered system performed best. The results of this study highlight the importance of strict control of aqueous phase constituents to prevent anthocyanin degradation and maximise double emulsion stability. Additional experiments analysed the effect of pectin chemistry on the anthocyanin colour retention and leakage, finding no conclusive difference between the unmodified and amidated pectin.

Single Excited Dual Band Luminescent Hybrid Carbon Dots-Terbium Chelate Nanothermometer.

The report introduces hybrid polyelectrolyte-stabilized colloids combining blue and green-emitting building blocks, which are citrate carbon dots (CDs) and [TbL]+ chelate complexes with 1,3-diketonate derivatives of calix[4]arene. The joint incorporation of green and blue-emitting blocks into the polysodium polystyrenesulfonate (PSS) aggregates is carried out through the solvent-exchange synthetic technique. The coordinative binding between Tb3+ centers and CD surface groups in initial DMF solutions both facilitates joint incorporation of [TbL]+ complexes and the CDs into the PSS-based nanobeads and affects fluorescence properties of [TbL]+ complexes and CDs, as well as their ability for temperature sensing. The variation of the synthetic conditions is represented herein as a tool for tuning the fluorescent response of the blue and green-emitting blocks upon heating and cooling. The revealed regularities enable developing either dual-band luminescent colloids for monitoring temperature changes within 25–50 °C through double color emission or transforming the colloids into ratiometric temperature sensors via simple concentration variation of [TbL]+ and CDs in the initial DMF solution. Novel hybrid carbon dots-terbium chelate PSS-based nanoplatform opens an avenue for a new generation of sensitive and customizable single excited dual-band nanothermometers.

A high-efficiency blind watermarking algorithm for double color image using Walsh Hadamard transform

A high-efficiency blind watermarking algorithm for double color image using Walsh Hadamard transform

Double color image encryption based on fractional order discrete improved Henon map and Rubik’s cube transform

A double color image encryption method based on DNA (deoxyribonucleic acid) computation and chaos is proposed. Differently from the conventional algorithms, double color images are encrypted at the same time so that we can save information of each other, which makes the encryption more safe and reliable. In addition, a new chaotic fractional order (FO) discrete improved Henon map (FODIHM) is proposed as a pseudo-random number generator. To ensure the plain-image sensitivity of the encryption algorithm, the initial value of FODIHM is calculated from the hash value of the color image (SHA-256) and from the three additional keys entered by the user. Furthermore, a Rubik’s cube transform scrambles the pixels in each color component of the two images. Then, each pixel in each color component of the two images is diffused by means of different DNA coding rules. Finally, the CAT transform, based on FO discrete Logistic map and the classic XOR, is used to further improve the security performance. The key space size of the proposed algorithm is of order 10135, which is about 30 orders of magnitude higher than those available in the literature. The information entropies are 7.9974 and 7.9973, which are very close to the ideal entropy value of 8. The values of the unified average changing intensity (NPCI) are 99.630 and 99.623, while the number of pixels change rate (UACR) are 33.473 and 33.553, which are also close to the ideal NPCR and UACR value of 99.6094 and 33.4635, respectively. The numerical results and security analysis prove that the algorithm has good resistance to several classic attacks.

A Blueprint for the Milky Way’s Stellar Populations. II. Improved Isochrone Calibration in the SDSS and Pan-STARRS Photometric Systems

Abstract We improve the identification and isolation of individual stellar populations in the Galactic halo based on an updated set of empirically calibrated stellar isochrones in the Sloan Digital Sky Survey and Pan-STARRS 1 photometric systems. Along the Galactic prime meridian (l = 0° and 180°), where proper motions and parallaxes from Gaia DR2 can be used to compute rotational velocities of stars in the rest frame of the Milky Way, we use the observed double color–magnitude sequences of stars having large transverse motions, which are mostly attributed to groups of stars in the metal-poor halo and the thick disk with halo-like kinematics, respectively. The Gaia sequences directly constrain color–magnitude relations of model colors, and help to improve our previous calibration using Galactic star clusters. Based on these updated sets of stellar isochrones, we confirm earlier results on the presence of distinct groups of stars in the metallicity versus rotational-velocity plane, and find that the distribution of the most metal-poor ([Fe/H] < −2) stars in our sample can be modeled using two separate groups on prograde and retrograde orbits, respectively. At 4–6 kpc from the Galactic plane, we find approximately equal proportions of the Splashed Disk, and the metal-rich (〈[Fe/H]〉 ∼ −1.6) and metal-poor (〈[Fe/H]〉 ∼ −2.5) halos on prograde orbits. The Gaia–Sausage–Enceladus, the metal-weak thick disk, and the retrograde halo structure(s) (〈[Fe/H]〉 ∼ −2.2) constitute approximately 10% of the rest of the stellar populations at these distances.