Dominant Product Research Articles

Effects of a Carboxyl Group on the Products, Mechanism, and Kinetics of the OH Radical-Initiated Oxidation of 3-Butenoic Acid Under Low NOx Conditions.

Concentrations of nitrogen oxides (NOx) in the U.S. have decreased so much in the last few decades that the oxidation of volatile organic compounds (VOCs), which plays a critical role in the formation of ozone and fine particles, now often occurs in urban areas under conditions that are historically associated with remote rural locations. As a result, alkylperoxy radicals (RO2•), which are key intermediates in VOC oxidation, can react with NO, HO2, and RO2• radicals, and isomerize. In this study, we primarily investigated the products, mechanism, and kinetics of the OH radical-initiated oxidation of 3-butenoic acid under conditions where the dominant products of a similar reaction of 1-pentene were hydroxy-hydroperoxides formed through RO2• + HO2 reactions. 3-Butenoic acid has some structural properties that made it ideally suited for this study, which was conducted in an environmental chamber using iodide chemical ionization mass spectrometry and authentic standards. The major reaction products were oxo-propanoic acid, hydroxyoxo-butanoic acid, dihydroxy-butanoic acid, and dihydroxy-dicarboxybutyl-peroxide (a ROOR dimer) formed with measured molar yields of 0.74, 0.09, 0.08, and 0.03 for a total molar yield of 0.94 that effectively achieved a mole balance. Unlike in the 1-pentene reaction, reaction of the dominant RO2• radical with HO2 led almost solely to formation of oxo-propanoic acid + formaldehyde + OH + HO2, apparently due to hydrogen bonding involving the carboxyl group in the ROO-OOH intermediate complex. Similar hydrogen bonding in the ROO-OOR complex was likely responsible for the formation of the peroxide dimer and the exceptional speed of RO2• + RO2• reactions, which were competitive with RO2• + HO2 reactions and were calculated from measurements and kinetics modeling to occur with a rate constant ≥3 × 10-11 cm3 molecule-1 s-1 that may approach the collision limit value of about 5 × 10-10 cm3 molecule-1 s-1. The results of the study demonstrate that functional groups can have dramatic effects on the atmospheric chemistry of VOCs.

Toward Scalable Synthesis of Mo2C/MoNi4 Heterojunction Catalysts on Ni Mesh via Laser Radiation for Efficient H2 Production in Alkaline Electrolysis

AbstractThe alkaline electrolysis is the dominant production method for hydrogen since non‐noble Ni metals can be used as catalysts. The low activity of the commercial nickel mesh (NM) electrodes remains a considerable obstacle to reducing energy consumption for water splitting. Conducting surface modification on commercial NM is a promising tactic to improve the hydrog enevolution reaction (HER) intrinsic activity of NM catalysts. Herein, Mo2C/MoNi4 heterojunction coating on the NM substrate via a laser Radiation strategy is designed. The results indicate that the Mo2C8.5/MoNi4/NM delivers an extremely low overpotential to trigger HER (η10 = 49.5 mV) processes and maintains a stable overpotential for 100 h in alkaline media. The experimental and theoretical calculations reveal that the downshifted d‐band center of Ni in MoNi4 caused by two‐phase heterojunction can regulate the free energy of reactive intermediates adsorption & desorption, thereby accelerating the entire HER process. This work will open up an avenue for developing highly efficient Ni‐based heterostructured electrocatalysts for commercial HER electrode application.

Measurement of inclusive and differential cross sections of single top quark production in association with a W boson in proton-proton collisions at s = 13.6 TeV

The first measurement of the inclusive and normalised differential cross sections of single top quark production in association with a W boson in proton-proton collisions at a centre-of-mass energy of 13.6 TeV is presented. The data were recorded with the CMS detector at the LHC in 2022, and correspond to an integrated luminosity of 34.7 fb−1. The analysed events contain one muon and one electron in the final state. For the inclusive measurement, multivariate discriminants exploiting the kinematic properties of the events are used to separate the signal from the dominant top quark-antiquark production background. A cross section of 82.3±2.1stat−9.7+9.9syst±3.3lumi pb is obtained, consistent with the predictions of the standard model. A fiducial region is defined according to the detector acceptance to perform the differential measurements. The resulting differential distributions are unfolded to particle level and show good agreement with the predictions at next-to-leading order in perturbative quantum chromodynamics.

CO2 conversion products in α and γ modes of radio frequency capacitively coupled plasma

Radio Frequency Capacitively Coupled Plasma (RF-CCP) exhibits excellent spatial uniformity, high stability, and the capability to generate plasma over large areas, making it highly promising for applications in CO2 resource utilization in space environments. This study investigates the CO2 conversion products under two typical discharge modes (α and γ modes) of RF-CCP and their product selectivity under Martian nominal pressure. The results indicate that the optical emission spectra in both α and γ modes contain CO2+, O, and CO spectral bands/lines. The overall spectral line intensity is enhanced in the γ mode compared to the α mode, indicating a higher electron density and ionization degree in the γ mode. The key product, CO, is primarily generated through electron collisions with CO2, while O2 is produced via the dissociative recombination of electrons with CO2+. After the transition from α to γ mode, the content of CO2 decreases, but the concentrations of electrons and CO2+ increase significantly. This results in CO being the dominant product in the α mode, while in the γ mode, the overall abundance of products is higher and there is a greater selectivity for O2. Therefore, by controlling the discharge mode of RF-CCP, it is possible to achieve targeted regulation of the CO2 conversion products.

Assessing Dominant Production Systems in the Eastern Amazon Forest

The expansion of agricultural frontiers in the Amazon region poses a significant threat to forest conservation and biodiversity persistence. This study focuses on Pará state, Brazil, aiming to identify and characterize the predominant production systems by combining remote sensing data and landscape structure metrics. A rule-based classification tree algorithm is applied to classify hexagonal cells based on land cover, deforestation patterns, and distance from dairy facilities. The results reveal three dominant production systems: Natural Region, Non-Intensive Beef, and Initial Front, with livestock production being prominent. The analysis indicates that there is a correlation between the productive area and deforestation, emphasizing the role of agriculture as a driver of forest loss. Moreover, road networks significantly influence production system spatial distribution, highlighting the importance of infrastructure in land use dynamics. The Shannon diversity index reveals that areas with production systems exhibit greater diversity in land use and land cover classes, reflecting a wider range of modifications. In contrast, natural vegetation areas show lower Shannon values, suggesting that these areas are more intact and are less affected by human activities. These findings underscore the urgent need for sustainable development policies that will mitigate threats to forest resilience and biodiversity in Pará state.

Key enzymatic activities and metabolic pathway dynamics in acidogenic fermentation of food waste: Impact of pH and organic loading rate.

Acidogenic fermentation was an effective technology to recover volatile fatty acids (VFAs) ethanol and lactic acid from food wastes (FW) as bioresources. However, the impact of process controls on key functional enzymes and metabolic pathways has been inadequately understood. In this study, the metabolite distribution, key functional enzymes and metabolic pathways were completely elucidated using 16S rRNA gene high-throughput sequencing combined with PICRUSt2. Results demonstrated pH significantly affected fermentation types by influencing key enzyme activities, while organic loading rate (OLR) primarily affected the yield without altering metabolic pathway. The maximum VFAs production was achieved at pH 6.0 and OLR of 15.0g-VS/L/d as a result of Glycolysis and Pyruvate Metabolism were enhanced. Meanwhile, butyric acid was always dominant product, attributed to the enhanced activity of butyryl-CoA dehydrogenasedue. Furthermore, Lactobacillus enrichment and lactate dehydrogenase upregulation promoted lactate-type fermentation under without pH control (3.8), resulting in an average yield of lactic acid was 7.84g/L. When the pH was raised from 3.8 to 5.0,downregulation of lactate dehydrogenase and upregulation of acetate kinase shifted the fermentation to acetate-type. This study provides a deeper understanding of how does process controls influence the metabolic pathways and key functional enzymes.

Exploring Mg-Sn Alloys as Electrocatalysts for CO2 Electroreduction

Tin is one of the most selective electrocatalysts for CO2 reduction (CO2RR), mostly thanks to its poor activity towards the hydrogen evolution reaction (HER). Still, Sn electrodes are limited by their very high overpotential. We decided to investigate the electrochemical CO2RR catalytic activity of tin-magnesium alloys that can be easily obtained by thermal annealing from the elemental metallic powders. We found that the alloys exhibit a slightly improved activity in activity and selectivity towards CO2RR with formate as dominant product according to electrochemical and chemical analysis. Post-mortem characterization confirmed that this effect is not due to the alloys performance, but to Sn re-structuration. Most of the Mg is leached from the alloy into the electrolyte during CO2RR, leaving a highly porous Sn structure. These changes in morphology and surface area as triggered by Mg leaching, appear to be at the origin of the enhanced electrocatalytic performance.

Pressure-dependent kinetic analysis of the N2H3 potential energy surface.

The pressure-dependent reactions on the N2H3 potential energy surface (PES) have been investigated using CCSD(T)-F12/aug-cc-pVTZ-F12//B2PLYP-D3/aug-cc-pVTZ. This study expands the N2H3 PES beyond the previous literature by incorporating a newly identified isomer, NH3N, along with additional bimolecular reaction channels associated with this isomer, namely NNH + H2 and H2NN(S) + H. Rate coefficients for all relevant pressure-dependent reactions, including well-skipping pathways, are predicted using a combination of ab initio transition state theory and master equation simulations. The dominant product of the NH2 + NH(T) recombination is N2H2 + H, while at high pressures and low temperatures, N2H3 formation becomes significant. Similarly, collisions involving H2NN(S) + H predominantly produce N2H2 + H. Secondary reactions such as H2NN(S) + H ⇌ NNH + H2 and H2NN(S) + H ⇌ NH2 + NH(T) are found to play a significant role at high temperatures across all examined pressures, while H2NN(S) + H ⇌ NH3N becomes prominent only at high pressures. Notably, none of these four H2NN(S) reactions have been included with pressure-dependent rate coefficients in previous NH3 oxidation models. The rate coefficients reported here provide valuable insights for modeling the combustion of ammonia, hydrazine, and their derivatives in diverse environments.

Don't forget the trans: double bond isomerism radical-acetylene growth reactions affect the primary stages of PAH and soot formation.

In combustion, acetylene is a key species in molecular-weight growth reactions that form polycyclic aromatic hydrocarbons (PAHs) and ultimately soot particles. Radical addition to acetylene generates a vinyl radical intermediate, which has both trans and cis isomers. This isomerism can lead to profound changes in product distributions that are as yet insufficiently investigated. Herein, we explore acetylene addition to substituted trans-vinyl radicals, including potential rearrangement to cis structures, for eight combustion-related hydrocarbon radicals calculated using a composite method (G3X-K). Of these eight systems, the phenyl trans- and cis-Bittner-Howard HACA (hydrogen abstraction, C2H2 Addition) process, where acetylene successively adds to a phenyl radical via a β-styryl intermediate, is simulated using a unified Master Equation model. Including the trans-Bittner-Howard pathway changes the products significantly at all simulated temperatures (550-1800 K) and pressures (5.33 × 102-107 Pa), relative to a cis-only model. Typically, naphthalene remains the dominant product, but its abundance decreases at higher temperatures and pressures. For example, at 1200 K and 105 Pa, its branching ratio decreases from 78.5% to 62.9% when the trans pathway is included. At higher temperatures this decrease corresponds to the formation of alternative C10H8 isomers, including the cis product benzofulvene with 8% maximum abundance at 1200 K and 5.33 × 102 Pa, and E-2-ethynyl-1-phenylethylene, a trans product with 26% maximum abundance at 1800 K, with little pressure dependence. At higher pressures, our model predicts a range of C10H9 radicals, including resonance-stabilised radicals (RSRs). The impact of trans-vinyl radical chemistry in reactive environments means that they are essential to accurately describe combustion reactions and inhibit soot formation.

Artificial Intelligence and Gender: Examining Identities in The Alara X Sample

This study is about gender-based changes that may occur with artificial intelligence technology. The connection between social change and technology is not a recent phenomenon. Comte illustrates this change through the evolution of knowledge and shifts in human thought. Anne Balsamo (1995) opposes the claim that the material body has lost its validity in our scientific culture in her study examining how the body is gendered in its interaction with new corporal technologies. Balsamo, who provides abundant evidence that the techno-body has always been gendered and racially marked, prepares the ground for a renewed relationship of feminists with contemporary technological narratives. In this context, how the physical world continues while recreating women with virtual characters based on gender approaches will be examined. In this study, first, body theories will be addressed within the scope of the posthuman. Second, how virtual characters occur in social media environments will be evaluated. Finally, Turkish influencer and talk show host Alara X will be examined in terms of her internal and external aspects within the entirety of both human and non-human elements In this study, which claims to connect the cultural formation of women's identities in virtual environments with dominant cultural production forms while making sense of it, it has been concluded that the female body is instrumentalized in power relations through consumption, communication, control mechanisms, and information technologies.

Mildly acidic pH boosts up CO2 conversion to isobutyrate in H2 driven gas fermentation system.

As a greenhouse gas, massive carbon dioxide (CO2) has been generated due to organic matter degradation in wastewater treatment processes. Microbial gas fermentation offers a promising approach to capture CO2 and generate various valuable chemicals. However, limited studies have achieved branched or medium-chain fatty acids production via gas fermentation. This study reported the production of isobutyrate and hexanoate by feeding H2 and CO2 into membrane biofilm reactors (MBfRs). The gas fermentation product in the reactor with neutral pH (pH of 7) was dominated by acetate (accounting for 90 % of the product spectrum), whereas a mildly acidic pH (pH of 6) resulted in isobutyrate and hexanoate as the dominant products, with a selectivity of 57 % and 42 %, respectively. Notably, a remarkably high concentration of isobutyrate (266 mmol C/L) was produced in the reactor with pH of 6. Subsequent batch test results suggest that the isobutyrate production in this study is coupled with acetogenesis and ethanol-driven chain elongation processes, rather than via methanol-driven chain elongation reported previously. High-throughput 16S rRNA gene amplicon sequencing revealed that the microbial community under neutral pH was dominated by acetate-producing homoacetogens Acetobacterium. By contrast, a mildly acidic pH promoted the community shifting towards chain elongation microorganisms, dominated by Clostridium sensu stricto 12, Oscillibacter and Caproiciproducens. Collectively, this study demonstrates the significant role of mildly acidic pH in boosting up bioisomerization and chain elongation in gas fermentation systems, thus triggering isobutyrate and hexanoate production. The findings highlight gas fermentation as a new green alternative route for generating highly valuable isobutyrate and hexanoate.

Evaluation of texture, sensory, and fillet color traits in channel catfish (Ictalurus punctatus), blue catfish (Ictalurus furcatus), and the hybrid catfish (channel catfish ♀ × blue catfish ♂)

AbstractDespite catfish being the dominant freshwater aquaculture product in the United States, catfish texture and sensory evaluation are understudied compared with other aquaculture species, and very few studies have been conducted to evaluate these traits in catfish. Texture, sensory, carcass yield, flavor, visceral fat deposition, gonadal development, and fillet color analyses were conducted on four size classes, small (<0.68 kg), medium (0.68–0.92 kg), large (0.93–1.75 kg), and extra‐large (>1.75 kg), for channel catfish (n = 456) (Ictalurus punctatus), blue catfish (n = 78) (I. furcatus), and hybrid catfish (n = 195) (channel catfish ♀ × blue catfish ♂). Within genetic type comparisons indicated that the texture traits, hardness, and chewiness and the sensory trait toughness increased with increasing size in hybrid catfish and channel catfish but were the most pronounced in channel catfish. Overall, channel catfish had the firmest fillets based on several attributes. Blue catfish were found to have differences among texture traits between the extra‐large size class and the three remaining size classes, but overall size had less of an effect compared with the channel catfish and hybrid catfish. A trend of paternal predominance was observed as the hybrid catfish was more similar to the blue catfish than the channel catfish. Hybrid catfish had the highest fillet percentage. This study is the first large‐scale analysis of texture and sensory traits within two catfish species and their interspecific hybrid at different sizes and highlights the differences in commercially important texture and sensory traits.

Glycosylase Pretreatment with Chemical Labeling-Assisted HPLC-MS/MS: An Ultrasensitive and Reliable Strategy for Quantification of 8-Oxo-7,8-dihydro-2'-deoxyguanosine in Genomic DNA.

8-Oxo-7,8-dihydro-2'-deoxyguanosine (dOG), the dominant oxidative product of 2'-deoxyguanosine (dG) under high levels of reactive oxygen species, usually serves as a biomarker for oxidative stress and a risk assessment factor for various diseases. Due to the extremely low abundance of dOG and the susceptibility of dOG detection to the interference of spurious oxidation, research on related biological processes is limited by insufficient sensitivity and specificity. In this work, an ultrasensitive and reliable approach for genome-wide dOG quantification was developed through chemical labeling-assisted high-performance liquid chromatography-tandem mass spectrometry with the introduction of glycosylase pretreatment. Upon derivatization by a novel labeling reagent rhodamine B ethylenediamine, the detection sensitivity of dOG was enhanced by 100-fold, and the detection limit was as low as 25 amol, which was superior to those of reported mass spectrometry-based methods. Potassium ferricyanide, as a single-electron oxidant, was shown to possess strong selectivity for dOG versus dG, improving the labeling specificity and reducing the interference from dG. The spurious oxidation during sample pretreatment was systematically explored and minimized, and a control assay of glycosylase pretreatment was proposed to further improve the quantitative accuracy of dOG. Precise quantification of endogenous dOG in different cells was achieved with less than 500 ng of genomic DNA. This method was successfully applied to the assessment of the overall level of oxidative damage under the treatment of glycosylase inhibitors, potentially contributing to the exploration of the complex role of dOG in physiological status and disease phenotype.

Electrocatalytic CO Reduction to Produce Long‐chain Products Through Fischer‐Tropsch Pathway

AbstractElectrocatalytic CO reduction (COR) is a promising approach for converting C1 feedstock into valuable multi‐carbon fuels using renewable electricity. At ambient temperature, COR, particularly on Cu‐based catalysts, typically produces C2 chemicals as the dominant products, with long‐chain hydrocarbons containing more than five carbon atoms rarely forming. In contrast, Fischer‐Tropsch synthesis (FTS), a thermocatalytic process converting CO and H2, selectively generates long‐chain hydrocarbons. In this study, we utilized Ru nanoparticles for electrochemical COR under elevated conditions (423 K and 2.8 MPa). Long‐chain products with up to 21 carbon atoms were detected, achieving a Faradaic efficiency of 32 % and a weight selectivity of 65 % for C5+ products. We propose an FTS‐like pathway for this electrocatalytic process. Unlike thermocatalytic FTS, where adsorbed H atoms form via H2 dissociation, in this electrocatalytic version, the H atoms are generated through the Volmer reaction from water. Subsequently, the chemisorbed and activated CO species are hydrogenated, forming CHx intermediates that propagate into long‐chain products.

Change in Alloy Composition and Manufacturing Technology of Bronze Vessels Excavated from Archaeological Site

The purpose of this study is to analyze the components and observe the microstructure of 98 bronze vessels excavated from the Korean Peninsula, where such vessels were widely used, to identify the alloy composition and manufacturing process of bronze artifacts by period. In addition, we attempted to confirm the changing processes of bronze manufacturing technology by reviewing previous studies. The analysis results showed that the bronzeware of the Unified Silla period was mainly produced using a Cu-Sn binary alloy containing 20-26 wt% Sn, which was cast and slowly cooled. Also, most bronze vessels from the Goryeo dynasty were made of a Cu-Sn binary alloy, with an Sn content of 20–24 wt%. In the microstructure, a twinned α phase and β(M) phase were observed, indicating that the container was manufactured using the casting–hot forging–quenching process. Bronze vessels from the Joseon dynasty were made using a binary alloy of Cu-Sn and a ternary alloy of Cu-Sn-Pb. In order to confirm the changes in bronze manufacturing technology over time, we investigated the alloy composition and microstructure of a total of 295 vessels, including previous studies, and were able to confirm the dominant production technology for each period. During the Unified Silla period, the shape of the container was made by casting using a Cu-Sn binary alloy, and the process was completed through slow cooling or quenching. During the Goryeo Dynasty, vessels were made using a Cu-Sn binary alloy through a process of casting, hot forging, and quenching, or by casting a Cu-Sn-Pb ternary alloy into a vessel shape and then slowly cooling it. And in the Joseon Dynasty, the use of ternary alloys of Cu-Sn-Pb increased.

Pyrolysis kinetics and reaction mechanism of waste medical masks by sectional heating process

The COVID-19 epidemic has led to a significant upsurge in the accumulation of waste medical masks. This work focuses on the detailed examination of waste medical masks’ pyrolysis kinetic and reaction mechanism, employing a sectional heating process. The degradation properties were analyzed via thermal gravimetric analysis and pyrolysis reactor. The comprehensive kinetic process was studied using model-free and model-fitting methods, which determined the apparent activation energy and pre-exponential factor. The calculated average value for these parameters was 221.32 kJ/mol and 2.6 × 1014 min−1, respectively. The pyrolysis process was carried out at three distinct temperatures: 380, 470, and 490 ℃, corresponding to the initial peak degradation rate and final degradation temperatures determined by TGA results. The total yield of oil, gas and tar was 88.6 %, 11.3 % and 0.1 %, respectively. The identification and quantification of pyrolysis products were achieved through GC–MS and FTIR. It was observed that higher pyrolysis temperature facilitated the generation of alkanes and hydrocarbons with lower carbon chain lengths in oil products and propylene monomers in gas products. The dominant pyrolysis products in oil under 380 ℃, 470 ℃ and 490 ℃ were C20, C20 and C12 with the yield of 36.17 %, 48.96 % and 43.35 %, respectively. And the corresponding dominant products in gas all were propylene with the yield of 34.74 %, 53.02 % and 54.55 %, respectively. Furthermore, a reaction mechanism was postulated to elucidate the pyrolysis process under varying temperature conditions.

Supercritical water co-gasification of waste R134a and plastics to produce valuable chemicals and fuels: ReaxFF reactive molecular dynamic simulation

Supercritical water gasification of waste hydrofluorocarbon refrigerants was an effective treatment technology, but there is a problem of high yield of fluorine-containing products with complex types. Plastic has the potential to provide sufficient H atoms as hydrogen donor to facilitate defluorination of fluorine-containing products. In this study, ReaxFF reactive molecular dynamic simulation and density functional theory calculation were used to investigate the supercritical water co-gasification (SCWCG) mechanism of R134a and low-density polyethylene (LDPE). The results showed that the decomposition of LDPE was the initial reaction of SCWCG, the generated radicals promoted the dissociation of R134a and H2O. The dominant SCWCG products were valuable hydrocarbons, H2, CO and HF. The present of LDPE promoted the defluorination reaction of fluorine-containing products from the dissociation of R134a, reduced the yield of fluorine-containing products, and greatly promoted the yields of H2, HF, CO and hydrocarbon products. 99% of F atoms in R134a can be converted to HF, which indicated that plastics participating in supercritical water gasification of R134a has excellent defluorination effect. This study provided an efficient and potential route to conduct waste HFC refrigerants into valuable chemicals and fuels.

Implementation of the Sugeno Fuzzy Method in a Firefighting Robot Prototype with an All-Wheel Drive System

The purpose of this study is how to implement the Fuzzy Sugeno method to a fire-fighting robot prototype with all wheel drive system. Resculpts by transferring academic input to specific fields of knowledge, as many problems have become increasingly adaptable due to technology or the growth of AI, which is fast becoming the dominant productivity tool. Fuzzy method is a mathematical method used to overcome the problems of small uncertainties and imprecision. The first prototype of the fire-fighting robot which will be able to use all-wheel drive system is meant to mitigate the risk of large fire and to detect as soon as possible. Observational results verify that the Robot prototype follows its intended workflow as well as can complete its mission to both detect and eliminate fire hazards. The speed of the wheel is controlled on three levels slow (0 RPM), moderate (50 RPM), and fast (100 RPM) using Fuzzy Sugeno method. Also, in response time is set by using Fuzzy Sugeno method which is set to 1 second, 2 seconds, and 3 seconds

Precision prediction of a democratic up-family philic KSVZ axion model at the LHC

In this work, we study the SU(2)L singlet complex scalar extended KSVZ model that, in addition to providing a natural solution to the strong-CP problem, furnishes two components of dark matter that satisfy observer relic density without fine-tuning the model’s parameters. A colored vector-like quark (VLQ) is naturally present in the KSVZ axion model, providing a rich dark matter and collider phenomenology. In this extended model, scalar dark matter interacts with the Standard Model up-type quarks (up, charm, top) through VLQ. We explore the possibility of democratic Yukawa interaction of the VLQ with all up-type quarks and scalar dark matter candidate. We also employ next-to-leading order NLO-QCD correction on dominant production channels for VLQ pair production to study a unique search at the LHC, generating a pair of boosted tops with sizeable missing transverse momentum. Such corrections are significant and reduce factorization and renormalization scale uncertainties substantially. The NLO fixed order results are matched with the Pythia8 parton shower. After being pair-produced, each VLQ decays into a dark matter and a top quark. We conducted a multivariate analysis using jet substructure variables of boosted top fatjets with a significant missing transverse momentum signal. This analysis allows us to explore a substantial parameter space of this model at the 14 TeV LHC.

Intermediate-regulated dynamic restructuring at Ag-Cu biphasic interface enables selective CO2 electroreduction to C2+ fuels

A bimetallic heterostructure has been shown effective to enhance the multi-carbon (C2+) product selectivity in CO2 electroreduction. Clarifying the interfacial structure under electrolysis and its decisive role in the pathway selection are crucial, yet challenging. Here, we conceive a well-defined Ag-Cu biphasic heterostructure to understand the interfacial structure-steered product selectivity: The Cu-rich interface prefers ethylene, while the dominant product switch to alcohols with an increasing Ag fraction, and finally to CO as Ag occupying the main surface. We unravel a *CO intermediate-regulated interfacial restructuring, and observe abundant of Cu atoms migrating onto the neighboring Ag surface under a locally high *CO concentration. The evolving structure alters the oxyphilic characteristic at the interface, which profoundly determines the hydrogenation energetics of CO2 and ultimately, the dominant C2+ product. This work explicitly links the evolving interfacial structure with distinct C2+ pathway, formulating design guidelines for bimetallic electrocatalysts with selectively enhanced C2+ yields.