The present study attempts to characterize the time-dependent three-dimensional hydrodynamics in a stirred tank reactor using computational fluid dynamics (CFD). The rotating propellers produce a complex, unsteady, three-dimensional turbulent flow field. This results in efficient mixing and is therefore widely used in various process engineering applications. The time-dependent turbulent single-phase flow is computed using large eddy simulation, relying on the sliding mesh approach. The unresolved subgrid scales are treated using the Smagorinsky-Lilly model. The dominant coherent flow structures are characterized in the entire three-dimensional computational domain using the 3D proper orthogonal decomposition (POD) technique. The design of the propeller is evaluated in a separate POD analysis in a rotating frame which encloses the propeller. The most energetic POD modes characterize the organized large scale structures, the so-called coherent flow structures, while the higher modes correspond to the small-scale disorganized turbulence. It was found that the dynamics of the main flow structures can be reconstructed using only 3 modes corresponding to 98% of the overall energy in the entire 3D inner rotating domain and 21 modes are necessary for the same amount of energy in the outer stationary region.Furthermore, the macro instability (MI) was characterized by monitoring the velocity in more than 1 million computational cells, as well as using FFT analyses of the three-dimensional POD temporal coefficients. In the outer stationary domain, both approaches showed characteristic frequencies around one-eighth and one-fifth of the blade passage frequency.
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