High-Performance Computing (HiPC) systems routinely employ multi/many – core processors. Specifically, dual – core processors find many applications in pervasive computing devices. Dual–core processors employ buffers for queueing the incoming jobs. Traditionally, the queues at the processors are assumed to be independent and the queueing system is analyzed in equilibrium for tractability purposes. Queues are modeled using Continuous Time Markov Chains (CTMC's) and the equilibrium performance measures are determined to analyze as well as design the queueing systems. In most interesting cases, the incoming jobs are routed to the queues using the Join the Shortest Queue (JSQ) policy. Thus, with such an adaptive routing algorithm, the two queues are evidently coupled and are not statistically independent. Hence traditional equilibrium performance evaluation doesn't provide realistic performance measures. In this research paper, the two queues associated with buffers in dual-core processors are considered to be coupled. The Coupled Queues are modeled using a Quasi – Birth – and – Death (QBD) process. Using traditional results related to QBD processes, equilibrium performance measures are determined. More interestingly, we demonstrate the tractability of the computation of transient probability distribution of a QBD process. In the research literature, transient analysis of the QBD process was shown to be tractable in the Laplace transform domain. But in this research paper, we prove that the matrix exponential eQt arising in transient analysis (where Q is the generator matrix of the QBD process) can be computed directly in the time domain rendering efficient transient analysis of QBD process. Using the transient probability mass function of queue length, estimation of transient performance measures such as expected queue length, average delay, and tail distribution can be determined. Further, optimal adaptive routing algorithms for coupled queues can be designed.