Thermally regenerative batteries (TRB) can combine with an electrodeposition cell (EC) to develop a hybrid system (TRB-EC) for low-grade waste heat disposal and Cu2+ recovery from wastewater. To improve the Cu2+ removal efficiency in EC, a vertically placed reactor and gradient porous electrodes are proposed to remiss ammonia crossover and enhance power generation in TRB. The vertically placed reactor effectively reduced the NH3 concentration difference on the both side of anion exchange membrane, inhibiting NH3 transmembrane transport. Moreover, the gradient porous anode is used to adjust the physical and chemical distribution in anode chamber. The results indicate that the maximum power density of 14.6 W/m−2 is obtained in a TRB employing the gradient porous electrodes (the pore order is large-middle-small scale), which is 22 % better than that of electrodes with uniform-size pores. Through the strategy of flow catholyte, the maximum power density can be further increased to 19.4 W/m−2 and the cathodic coulombic efficiency is improved to 92.7 %. Due to above optimal design, the Cu2+ removal efficiency of the hybrid system can reach an impressive value of 98.4 % (87.7 % in TRBs and 10.7 % in EC), showing a promising method of heat waste and Cu2+ disposal.
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