Considering the broad application prospect of high-strength steel (HSS) in engineering structure, and the limitations present in existing studies on interactive buckling of HSS welded thin-walled box-section long column, both test and finite element analysis were employed to investigate the interactive buckling behavior exhibited by 12 specimens fabricated from Q420–Q960 steels. The detailed analysis considered various aspects, including the failure mode, axial deformation, interaction of local and overall buckling deformation, and the ultimate bearing capacity. Observations revealed that the utilization rate of steel strength diminished with an escalation in both the plate width–thickness ratio and steel strength. An increase in the plate width–thickness ratio correlated with an earlier onset of local buckling, and the influence of steel strength was found to be negligible. More importantly, the limit of the plate width–thickness ratio for columns undergoing interactive buckling increased with a rise in column slenderness and decreased with an increase in steel strength. Taking into account the influence of column slenderness and steel strength, a novel calculation formula for determining the limit of the plate width–thickness ratio was derived. It is noteworthy that Eurocode 3 and JGJ/T 483–2020 were found too conservative for calculating the ultimate bearing capacity, while ANSI/AISC 360–22 was found suitable. Additionally, a calculation method for the ultimate bearing capacity of Q420–Q960 steel welded thin-walled H-section long column was proposed based on the direct strength method.