Direct Laser Ablation Research Articles

Femtosecond laser-induced plasma-assisted backward deposition of robustly adherent porous carbon films on glass substrates

The simple and rapid production and transfer of high-quality carbon materials are crucial for the flexible and efficient fabrication of carbon-based electronic devices. Recently, a laser-assisted transfer method combining laser-induced carbonization and transfer printing was demonstrated for the one-step preparation and transfer of patterned laser-induced carbon films to transparent substrates. However, this method is limited by insufficient robustness and weak adhesion of the carbon film post-transfer. Herein, we developed a non-contact laser-induced plasma-assisted deposition method to deposit robustly adherent porous carbon films on glass substrates. By well-adjusting the laser parameters and inserting spacers with adjustable thickness, laser-induced plasma ablation replaced direct laser ablation during femtosecond laser scanning of the substrate-polyimide-carrier sandwich structure, resulting in micro-channels with a carbon-glass recast layer instead of easily peelable flakes on the glass substrate. This hierarchical structure significantly enhances the adhesion between the laser-induced carbon film and the glass substrate, ensuring outstanding stability of the deposited carbon film under various adhesion tests. Furthermore, compared to carbon films prepared by the laser-assisted transfer method, the obtained carbon films are hydrophilic, low-resistance, and porous, facilitating the fabrication of energy storage devices. To demonstrate its practical application, a planar carbon-based micro-supercapacitor was fabricated on glass, exhibiting excellent electrochemical and cycling performance.

Quantitative Measurement of Multiple Elements in Micro‐Quantities of Crude Oil Using In Situ Analysis by Laser Ablation‐ICP‐MS

Multi‐element quantification in small amounts of material and in situ measurements at the micrometre scale are essential aspects of geological sample investigation. A direct and rapid simultaneous multi‐elemental determination of metals in crude oil samples was carried out by combining direct laser ablation of the oil inserted in silica capillaries with inductively coupled plasma‐mass spectrometry. The accuracy of LA‐ICP‐MS determination was demonstrated by analysing CONOSTAN reference material oils, certified for multiple elements, and by comparing LA‐ICP‐MS measurement results with those obtained by ICP‐OES using microwave‐assisted sample digestion. The results obtained by both methods were in agreement with certified values. The LA‐ICP‐MS method showed an adequate precision with a mean relative standard deviation of less than 10% for multi‐element determination, and was sufficiently sensitive to determine the majority of elements. LA‐ICP‐MS was also applied to the determination of elements in crude oils of different origins. LA‐ICP‐MS is a good alternative method allowing the determination of elements in organic fluids (oil and bitumen) in shorter times, involving less material consumption, smaller test portion size and with higher throughput compared with protocols using, for instance, sample digestion. It validates the possible application of metal analysis in hydrocarbon‐containing fluid inclusions for metallogenic purposes.

Coating-assisted picosecond laser ablation for microstructure fabrication of SiC ceramics

Silicon carbide (SiC) ceramics have emerged as critical materials in the production of high-precision components. Ultrafast laser processing is deemed the optimal technique for micro-nano manufacturing of SiC. However, the permanent deposition layer induced by laser ablation can critically impact the precision of the component. In this work, a coating-assisted picosecond laser ablation (CAPLA) method was proposed, in which sacrificial photoresist coating was utilized to improve surface quality without efficiency loss. The coating serves to prevent the uncooled plasma from contacting with the substrate, thereby preventing the formation of a permanent deposition layer. By comparing the CAPLA method with laser direct ablation, the influence of laser parameters and photoresist coating characteristics on the deposition layer was investigated systematically. A processed surface devoid of deposition layers can be achieved by CAPLA with low pulse energy and a high number of scans. The uniformity is critical to ensure the transmission of the laser beam, and a larger thickness can improve the processing efficiency by increasing the limit of pulse energy capacity. Pin arrays and vacuum grooves for SiC ceramic vacuum chucks were fabricated to demonstrate the superiority of the CAPLA method. These results suggest that this method can be a novel and promising approach for high-precision component manufacturing.

Development of a facile, versatile and scalable fabrication approach of solid, coated, and dissolving microneedle devices for transdermal drug delivery applications

Nowadays, microneedles as novel transdermal delivery systems are interested in scientists for biomedical applications. This work aims to present a Cascade Microneedle Molding Technique (CMMT) for the reusable fabrication of polydimethylsiloxane (PDMS) molds to produce microneedle devices. To produce a positive master mold from epoxy resin, a negative PDMS mold was first fabricated. PDMS can be molded, and microneedles can be fabricated using this epoxy mold in a scalable and cost-effective manner. These molds were used to manufacture solid, coated, and dissolving microneedles, which were characterized comprehensively. Microneedle morphology and geometry were evaluated using Scanning Electron Microscopy (SEM). The mechanical integrity and ability to insert the microneedle device into the skin were assessed using compression strength analysis and force-displacement measurements. Drug penetration through animal skin was evaluated for Rhodamine B (RhB) loaded microneedles. The depth of needle insertion was also visualized using histological analysis while the spatial distribution of released cargo was determined by using confocal microscopy. Taken together, CMMT offers a simple, rapid, cost-effective, and scalable method for mass-producing microneedles with remarkable properties compared to direct 3D printing or laser ablation.

THz active modulation device by electric field turned modulation characteristics of titanium sulfide nanofilm device

AbstractAn effective approach to manipulate terahertz (THz) waves involves the utilization of a device structure. In this particular investigation, we have successfully fabricated a SnS2 nanofilm device using femtosecond laser direct ablation. The passive and active polarization‐sensitive characteristics of the SnS2 nanofilm device were examined within the THz frequency range, employing different line spaces of 500, 600, and 700 μm. The combination of the device effect and SnS2 absorption led to an enhanced passive polarization modulation. Moreover, when an external electric field was applied to the SnS2 nanofilm device along the device line, persistent switching and linear modulation of THz wave transmission were observed. These findings indicate that the integration of material properties and device structure in this SnS2 device renders it highly suitable for applications in ultrafast THz switches, filters, and modulation devices.

Polarization sensitive electronically tuned microgroove array THz active modulator

The 6G technology has identified the frequency range of 0.1 to 1 THz as the communication band, with a particular focus on ultrafast modulation and multi-dimensional resolution coding technology. To advance the applications of THz photonics, there is a critical need for high-performance active optoelectronic THz devices. One potential solution involves the utilization of electrically controlled semi-metallic based THz modulators, which can provide suitable modulation depth and a wide modulation bandwidth. In this research, a semi-metallic TiS2 nanofilm device was developed using femtosecond laser direct ablation. The combination of structural effects and TiS2 absorption has significantly improved active modulation. These findings indicate that TiS2-based devices are well-suited for applications in THz photonics.

Design of "green" plasmonic nanocomposites with multi-band blue emission for ultrafast laser hyperthermia.

Although non-toxic nanoscale materials are widely employed for different healthcare applications, their performance is still considerably limited. In this paper, various approaches using the environmentally friendly ultrafast laser processing were employed to remodel IV group semiconductor nanostructures and synthesize highly-stable (ξ-potential is up to -47 mV) colloidal solutions of plasmonic (525 nm) nanocomposites with a strong size-dependent chemical content. All nanocomposites exhibited a remarkable lamp-excited multi-band blue emission centred at around 420 nm that is considerably (∼10-fold for Au-SiC) stronger than from nanocomposites prepared by the laser co-fragmentation technique. The latter formed a greater quantity of smaller narrowly dispersed (∼4 nm for Au-Si) plasmonic nanostructures compared to the direct laser ablation method. Moreover, it led to a greater number of semiconductor elements (∼1.7-fold for Au-Ge) in the nanocomposites, which was correlated with lower (∼30%) electrical conductivity. Aqueous colloidal solutions revealed a greater degree (∼80%) of the femtosecond laser-induced heating for all nanocomposites formed by direct laser ablation. These findings highlight the peculiarities of the applied laser processing approaches and considerably facilitate the design of specific multi-modal plasmonic-fluorescence (biosensing, bioimaging, hyperthermia) nanocomposites with a required performance that significantly expands the application area of semiconductor nanostructures.

High-quality and efficient large-area copper removal utilizing laser-induced active mechanical peeling

Large-area copper layer removal is one of the essential processes in manufacturing printed circuit boards (PCB) and frequency selective surfaces (FSS). However, laser direct ablation (LDA) with one-step scanning is challenging in resolving excessive substrate damage and material residue. Here, this study proposes a laser scanning strategy based on the laser-induced active mechanical peeling (LIAMP) effect generated by resin decomposition. This scanning strategy allows the removal of large-area copper layers from FR-4 copper-clad laminates (FR-4 CCL) in one-step scanning without additional manual intervention. During the removal process, the resin decomposition in the laser-irradiated area provides the mechanical tearing force, while the resin decomposition in the laser-unirradiated area reduces the interfacial adhesion force and provides recoil pressure. By optimizing scanning parameters to control the laser energy deposition, the substrate damage and copper residue can be effectively avoided. In our work, the maximum removal efficiency with different energy densities, pulse duration, and repetition frequency are 31.8 mm2/ms, 30.25 mm2/ms, and 82.8 mm2/ms, respectively. Compared with the reported copper removal using laser direct write lithography technology combined with wet chemical etching (LDWL+WCE) and LDA, the efficiency improved by 8.3 times and 66 times. Predictably, the laser scanning strategy and the peeling mechanism are simple and controllable, which have potential in electronics, communications, and aerospace.

A comparative investigation on micro-channel by using direct laser ablation and liquid-assisted laser ablation on zirconia

In this work, direct laser ablation (DLA), liquid-assisted laser ablation in water (LALA-W) and in ethanol (LALA-E) is applied to fabricate single micro-channels on the zirconia ceramic by using a picosecond laser. To assess the machining ability of them, micro-channels fabricated are characterized and compared the differences in morphology, geometric profile, chemical and phase composition. The morphological results indicate that both LALA-E and DLA can fabricate microchannel with obvious recast layer and cracks, and LALA-W can fabricate microchannel with a porous surface, and almost no recast layer and cracks. The results of geometric characteristics show that LALA-W can fabricated micro-channels with “U” shape profile with 52.74% enhancement in depth compared to that “V” shape by DLA and LALA-E. The XPS results demonstrate that LALA-W can exhibit the smallest oxygen vacancies with 50.01% than that of LDA 53.81% and LALA-E 54.56%. For XRD results, after machining by all three processes, the zirconia ceramic undergoes the tetragonal→monoclinic phase transformation, resulting in an increase in monoclinic phase. While LALA-W exhibits the smallest increase in monoclinic phase from 9.9% to 12.7%, and has the most tetragonal phase content of 58.8%.

Randomized whispering-gallery-mode microdisk laser arrays via cavity deformations for anti-counterfeiting labels

Optical physical unclonable functions (PUFs) have emerged as a promising strategy for effective and unbreakable anti-counterfeiting. However, the unpredictable spatial distribution and broadband spectra of most optical PUFs complicate efficient and accurate verification in practical anti-counterfeiting applications. Here, we propose an optical PUF-based anti-counterfeiting label from perovskite microlaser arrays, where randomness is introduced through vapor-induced microcavity deformation. The initial perovskite microdisk laser arrays with regular positions and uniform sizes are fabricated by femtosecond laser direct ablation. By introducing vapor fumigation to induce random deformations in each microlaser cavity, a laser array with completely uneven excitation thresholds and narrow-linewidth lasing signals is obtained. As a proof of concept, we demonstrated that the post-treated laser array can provide fixed-point and random lasing signals to facilitate information encoding. Furthermore, different emission states of the lasing signal can be achieved by altering the pump energy density to reflect higher capacity information. A threefold PUF (excited under three pump power densities) with a resolution of 5×5 pixels exhibits a high encoding capacity (1.43×1045), making it a promising candidate to achieve efficient authentication and high security with anti-counterfeiting labels.

High aspect ratio sapphire micromachining by ultraviolet laser‐induced plasma‐assisted ablation (LIPAA)

AbstractThe ultraviolet laser‐induced plasma‐assisted ablation performed in this article can attain deep and high‐quality engravings in sapphire without necessitating volatile solutions or expensive equipment such as high‐power ultrashort‐pulsed lasers. The dominant mechanism of ablation is discovered to be from the direct ablation of excited sapphire surfaces and not from the plasma generated from the target material. Only an initial deposition from the target is needed to initiate the direct ablation. Note that 20‐µm wide, 30‐µm deep channel and hole features with a surface roughness (Sa) of .65 µm are achieved at an etching rate of .3 µm per pulse without the need for extensive cleaning. Engravings can reach up to 150‐µm depths at a maximum tapering angle of 5° until the shrinking absorbent surface vanishes, and 500‐µm wide 430‐µm deep topside through‐cutting is achieved. This study characterizes the morphology of direct laser ablation of transient absorbent sapphire surfaces. This method demonstrates the potential for the low‐cost rapid engraving of high aspect ratio features in transparent sapphire substrates.

Hybrid Multiphase Fresnel Lenses on Silicon Wafers for Terahertz Frequencies

The hybrid multi-phase Fresnel lenses (H-MPFLs) were developed on silicon (Si) wafer at the selected frequency of 585 GHz. For this reason, the design of a standard MPFL was modified thoroughly in various outer zone areas in order to reduce complexity and manufacturing time of the diffractive optical elements (DOEs) by employing the direct laser ablation (DLA) processes. The phase offset was found by a precise control over the phase shift of incoming radiation in steps of π/12, revealing its optimal value to be of +π/4 independently on the hybridization order of the lens, the focusing gain of which was found to be up to 10 % higher than that achieved with a standard design MPFL. The numerical modeling data were confirmed by experiments demonstrating the effective THz beam focusing with H-MPFL samples to the diffraction limited spot size. Proposed development procedure can be further modified by scaling the hybrid lens design to other frequencies with different zone numbers and/or by employing other materials suitable for THz photonics integration on-chip with the semiconductor devices.

Tungsten oxide nanoparticle and aggregate formation through direct femtosecond laser ablation in air

In this work, we report the generation of tungsten oxide (WO3) nanoparticles and aggregate structures through direct femtosecond laser ablation in air. The nanoparticle morphology is studied utilizing Raman spectroscopy and TEM analysis, showing the generation of nanorods in the monoclinic phase with an average width and length of 70 and 168 nm, respectively. A range of laser fluences (0.8 to 4.2 J/cm 2) were during the ablation process, demonstrating control over the spread and density of the aggregate structures. Moreover, through variation of the laser spot size we demonstrate controlled aggregate formation, creating structures ranging from a high-density web-like structure with high area coverage to longer wire-like structures with lengths above 100μm.

Native Mass Spectrometry and Collision-Induced Unfolding of Laser-Ablated Proteins.

Infrared laser ablation sample transfer (LAST) was used to collect samples from solid surfaces for mass spectrometry under native spray conditions. Native mass spectrometry was utilized to probe the charge states and collision-induced unfolding (CIU) characteristics of bovine serum albumin (BSA), bovine hemoglobin (BHb), and jack-bean concanavalin A (ConA) via direct injection electrospray, after liquid extraction surface sampling, and after LAST. Each protein was deposited from solution on solid surfaces and laser-ablated for off-line analysis or sampled for online analysis. It was found that the protein ion gas-phase charge-state distributions were comparable for direct infusion, liquid extraction, and laser ablation experiments. Moreover, calculated average collision cross section (CCS) values from direct injection, liquid extraction, and laser ablation experiments were consistent with previously reported literature values. Additionally, an equivalent number of mobility features and conformational turnovers were identified from unfolding pathways from all three methods for all charge states of each protein analyzed in this work. The presented work suggests that laser ablation yields intact proteins (BSA, BHb, and ConA), is compatible with native mass spectrometry, and could be suitable for spatially resolved interrogation of unfolding pathways of proteins.

Bioinspired superwetting surfaces for fog harvesting fabricated by picosecond laser direct ablation

Bioinspired superwetting surfaces for fog harvesting fabricated by picosecond laser direct ablation

Direct Laser Ablation of Glasses with Low Surface Roughness Using Femtosecond UV Laser Pulses

Direct Laser Ablation of Glasses with Low Surface Roughness Using Femtosecond UV Laser Pulses

Cavitation bubble removal by surfactants in Laser-Induced Plasma Micromachining

The Laser-Induced Plasma Micromachining (LIPMM) process results in higher material removal rates, lower heat affected areas, and is less influenced by materials properties in comparison to direct laser ablation. Despite these improved benefits, cavitation bubbles generated during the process that reflect, refract, and scatter the laser beam pose a challenge for processing materials in precision engineering applications. This work reports an effective solution to remove surface bubbles in LIPMM using surfactants. The force of repulsion between the surfactant molecules aids the buoyancy force in the bubbles to overcome the surface tension which causes the bubbles to detach from the surface.

Anisotropy of material removal during laser-induced plasma assisted ablation of sapphire

Sapphire crystals have a special lattice structure, which causes anisotropy in their processing quality due to anisotropy of the physical and mechanical properties. Laser-induced plasma assisted ablation (LIPAA) is a new processing technology used to process transparent, hard, and brittle materials. LIPAA is regarded as a photoelectric composite processing method that makes the material removal and surface generation mechanisms more complicated. In this study, a surface generated by LIPAA processing showed much higher quality than a surface generated by direct laser ablation. Moreover, LIPAA has the advantage of a lower etching energy threshold than that of infrared laser direct ablation. Infrared laser-induced plasma assisted ablation was performed on different sapphire crystal orientations to explore the influence of anisotropy on LIPAA processing. The LIPAA material removal rates for different sapphire planes were presented and compared with results for direct laser ablation-focused ion beam (FIB) processing. The results showed that thermal removal was most dominant during LIPAA processing of sapphire. The material removal rate was highest in the [10 1‾ 0] direction and lowest in the [112‾ 0] direction.

Fabrication of hierarchical structures on titanium alloy surfaces by nanosecond laser for wettability modification

Titanium alloy is widely used in aerospace industry due to its low density, high specific strength and high-temperature resistance. To broaden its application scope, superhydrophobicity of titanium alloy is required in certain situations, such as self-cleaning and anti-icing. In this study, direct nanosecond laser ablation was applied to fabricate distinct pits with hierarchical structures on titanium alloy substrates, followed with chemical treatment to modify the wettability of the surfaces. The effects of laser processing parameters on surface morphology and surface wettability were explored systematically. Results show that, increasing the number of scans improves the depth of the pits and the accumulation of the micro-nano structures around the craters. The scanning space mainly affects the overlap of the heat affected zones, and hence the distribution of the laser-induced hierarchical structures. The wettability of a laser processed surface is determined by both surface roughness and surface chemistry, and the solid fraction of the rough surface is regulated by the number of scans as well as the scanning space. Moreover, superhydrophobic surfaces are obtained on the laser processed titanium alloy after chemical treatment, which has great potential for the as-mentioned applications.

A Soft Evaporation and Ionization Technique for Mass Spectrometric Analysis and Bio-Imaging of Metal Ions in Plants Based on Metal-Iodide Cluster Ionization.

Protonation/deprotonation is the well-recognized mass spectrometric mechanism in matrix-assisted laser desorption ionization of organic molecules but not for metal ions with different oxidation states. We describe herein a soft evaporation and ionization technique for metal ions based on iodination/de-iodination in metal-iodide cluster ionization (MICI). It is not only able to determine identities and oxidation states of metal ions but also reveal spatial distributions and isotope ratios in response to physiological or environmental changes. A long chain alcohol 1-tetradecanol with no functional groups that can absorb laser irradiation was used to cover and prevent samples from direct laser ablation. Upon the irradiation of the third harmonic Nd3+:YAG (355 nm, 3 ns), iohexol containing three covalently bonded iodine atoms instantly generates negative iodide ions that can quantitatively form clusters with at least 14 essential metal ions present in plants. The detection limits vary with different metal ions down to low fmol. MICI eliminates the atomization process that obscures metal charges in inductively coupled plasma mass spectrometry. Because only metal ions can be iodinated with iohexol, interferences from the abundant organic molecules of plants that are confronted by secondary ion mass spectrometry (SIMS) are also greatly decreased.