AdS black holes show richer transition behaviors in extended phase space by assuming the cosmological constant and its conjugate quantity to behave like thermodynamic pressure and thermodynamic volume. We study the extended thermodynamics of charged dilatonic AdS black holes in a class of Einstein–Maxwell-dilaton theories that can be embedded in gauged supergravities in various dimensions. We find that the transition behaviors of higher dimensional dilatonic AdS black holes are different from the four dimensional counterparts, and new transition behaviors emerge in higher dimensions. First, there exists a standard Van der Waals transition only in a five dimensional dilatonic AdS black hole with two equal charges. Second, there emerges a new phase transition branch in negative pressure region in six and seven dimensional dilatonic black holes with two equal charges. Third, there emerge transition behaviors in higher dimensional black hole with single charge cases, which are absent in four dimensions.