Diesel Exhaust Research Articles

Atmospheric aerosol chemistry and source apportionment of PM10 using stable carbon isotopes and PMF modelling during fireworks over Hyderabad, southern India

This study examined the influence of fireworks on atmospheric aerosols over the Southern Indian city of Hyderabad during festival of Diwali using mass closure, stable carbon isotopes and the EPA-PMF model. Identification of chemical species in day and night time aerosol samples for 2019 and 2020 Diwali weeks showed increased concentrations of NH4+, NO3−, SO42−, K+, organic carbon (OC), Ba, Pb and Li, which were considered as tracers for fireworks. PM10 source apportionment was done using inorganic (trace elements, major ions) and carbonaceous (organic and elemental carbon; OC & EC) constituents, along with stable isotopic compositions of TC and EC. K+/Na+ ∼1 and K+nss/OC > 0.5 indicated contribution from fireworks. High NO3−, NH4+, Na+, Cl− and SO42− suggested the presence of deliquescent salts NaCl, NH4NO3 and (NH4)2SO4. TAE/TCE >1 suggested H+ exclusion, indicating possible presence of H2SO4 and NH4HSO4 in the aerosols. Ba, Pb, Sb, Sr and Fe increased by 305 (87), 12 (11), 12 (3), 3 (2) and 3 (4) times on Diwali nights, compared to pre-Diwali of 2019 (2020), and are considered as metallic tracers of fireworks. δ13CTC and δ13CEC in aerosols closely resembled that of diesel and C3 plant burning emissions, with meagre contribution from firecrackers during Diwali period. The δ13CEC was relatively depleted than δ13CTC and δ13COC. For both years, δ13COC-EC (δ13COC - δ13CEC) were positive, suggesting photochemical aging of aerosols during long-range transport, while for pre-Diwali 2019 and post-Diwali 2020, δ13COC-EC were negative with high OC/EC ratio, implying secondary organic aerosols formation. High toluene during Diwali week contributed to fresh SOA formation, which reacted with precursor 12C, leading to 13C depletions. Eight-factored EPA-PMF source apportionment indicated highest contribution from residue/waste burning, followed by marine/dust soil and fireworks, while least was contributed from solid fuel/coal combustion.

On the impact of using nanoparticles type additives on the altering of diesel fuel jet characteristics

Even though diesel-powered passenger cars and light-duty vehicles may not be sold in the European Union by 2035, possibly in most other countries will be. Truck diesel engines will remain in use after 2035 because electric trucks are not a viable alternative for goods transportation. This involves continuing research and development on diesel engines to reduce their pollutant emissions. Alternative (renewable) fuels with combustion improvers can diminish emissions at the source. Nanoparticle-based additives can enhance the efficiency and emissions of diesel engines through their intense catalytic activity and by improving the fuel injection process. However, their effect on the injection process has not been well tested and published in the dedicated literature. The use of nanoparticles mixed in small fractions with original diesel fuel influences the physicochemical properties of the fuel as well as the formation of fuel jets inside the combustion chamber. This research focuses on the opportunity of using different diesel fuel blends mixed with combustion improver additives such as MWCNT and CeO2 nanoparticles. In this sense, a simulation investigation was conducted using the AVL BOOST Hydsim software. The physicochemical properties of fuels were used to assess the macroscopic characteristics of the fuel spray, such as penetration, spray cone angle, and Sauter mean diameter. When increasing the nanoparticle dosage, the penetration and spray cone angle values are decreasing, while the Sauter mean diameter values are increasing. This tendency is present for both nanoparticle types considered.

A techno-economic analysis of diesel exhaust injection into mine tailings for carbon sequestration

The environmental impact of off-grid mines in remote, cold climates is significantly intensified by their dependence on fossil fuels for power and heating. A promising solution lies in the potential to capture and permanently store carbon within mine tailings, thus allowing the mining industry to take a leading role in carbon removal initiatives and provide sustainable solutions. This study explores energy-optimal design scenarios for flue gas injection into mine waste to capture carbon. The approach involves installing perforated pipes within dry stack tailings. The established reduced-order model in this research serves as a novel tool for decision-making, aiding in the selection of an appropriate perforation scheme for the injection pipes embedded in the tailings. A cost analysis is also performed to assess the financial viability of the proposed concept under different operating parameters. Operational expenses, particularly energy costs, are found to be influenced by the permeability of the tailings. In instances of lower permeabilities, larger injection pipes are required. The findings indicate that achieving viable operating costs for sequestering one tonne of carbon dioxide hinges on amenable pipe sizing and engineering. Additionally, the study estimates that maintaining a reasonable level (around 1%) between the power being decarbonized and the power required for the carbon sequestration operation is crucial.

Toxicity of particles derived from combustion of Ethiopian traditional biomass fuels in human bronchial and macrophage-like cells

The combustion of traditional fuels in low-income countries, including those in sub-Saharan Africa, leads to extensive indoor particle exposure. Yet, the related health consequences in this context are understudied. This study aimed to evaluate the in vitro toxicity of combustion-derived particles relevant for Sub-Saharan household environments. Particles (< 2.5 µm) were collected using a high-volume sampler during combustion of traditional Ethiopian biomass fuels: cow dung, eucalyptus wood and eucalyptus charcoal. Diesel exhaust particles (DEP, NIST 2975) served as reference particles. The highest levels of particle-bound polycyclic aromatic hydrocarbons (PAHs) were found in wood (3219 ng/mg), followed by dung (618 ng/mg), charcoal (136 ng/mg) and DEP (118 ng/mg) (GC–MS). BEAS-2B bronchial epithelial cells and THP-1 derived macrophages were exposed to particle suspensions (1–150 µg/mL) for 24 h. All particles induced concentration-dependent genotoxicity (comet assay) but no pro-inflammatory cytokine release in epithelial cells, whereas dung and wood particles also induced concentration-dependent cytotoxicity (Alamar Blue). Only wood particles induced concentration-dependent cytotoxicity and genotoxicity in macrophage-like cells, while dung particles were unique at increasing secretion of pro-inflammatory cytokines (IL-6, IL-8, TNF-α). In summary, particles derived from combustion of less energy dense fuels like dung and wood had a higher PAH content and were more cytotoxic in epithelial cells. In addition, the least energy dense and cheapest fuel, dung, also induced pro-inflammatory effects in macrophage-like cells. These findings highlight the influence of fuel type on the toxic profile of the emitted particles and warrant further research to understand and mitigate health effects of indoor air pollution.

Investigations of carbon and particulate matter emissions of diesel engine using tertiary fuel

The development of modern world reveals that the world is facing an energy crisis due to the depletion of fossil fuel reserves. Biodiesel is renewable bioenergy made from vegetable oils, microalgae oil, and animal fats. The study involved adding 3,000 parts per million (ppm) of clove oil as an additive to the biodiesel. An endurance test was then conducted on a Compression Ignition (CI) engine for a duration of 100 hours, using three different fuel samples: pure diesel fuel (D100), a blend of 30% biodiesel and 70% diesel fuel (B30), and a blend of biodiesel with 3,000 ppm of clove oil (3000 ppm). The study analysed the effects of the fuel samples on carbon emissions from a CI engine. The results show that carbon monoxide (1.69%) is reduced in B30 and (7.49%) is reduced in CL3000 ppm. Carbon dioxide (7.97%) in B30 and 12.59% in CL3000 ppm are also reduced. Further particulate diesel engine emissions using biodiesel and clove oil-blend fuel samples were investigated. It was found that PM emissions were reduced when using clove oil-blend fuel.

Cobalt chromite nanoparticle effects on kapok diesel emulsion performance and emission characteristics at various injection pressures

AbstractAlternative fuels derived from vegetable oil have great potential as diesel fuel replacements in the transportation and manufacturing sectors. The aim of this study is to use cobalt chromite nanoparticles as a fuel additive with biodiesel in engine and to experimentally investigate the influence of injection pressure on combustion parameters. As an addition, cobalt chromite nanoparticles are used with biodiesel made from kapok oil, which is blended with mineral diesel at a ratio of 20:80. The engine is operated at various injection pressures (200–260 bar) and with an 80 ppm nanoparticle concentration. The results have shown that the increased injection pressure caused by the use of nanoparticles enhances engine combustion properties, such as the peak pressure and the rate of heat release. The main purpose of this research was to investigate the effects of a CoCr2O4 + KME20 mix on a CI engine, with the hope of improving engine performance characteristics. This investigation examines the effects of varying test fuel injection pressures. The increased injection pressure of CoCr2O4 + KME20 resulted in better performance and combustion. The 240‐bar IP was shown to be superior to lower IPs because of its greater penetration length and more uniform formation. The IP rating of 240 bar represented a significant improvement over competing products with respect to emission controls. In addition to reducing our reliance on fossil fuels, this also prevents harmful chemicals from being released into the air.

A novel free-air diesel and ozone enrichment (FADOE) research platform

Air pollution is an escalating concern in the modern world, posing substantial threats to ecosystem processes. While the importance of comprehending the impact of pollutants on natural environments is evident, conducting rigorous field-based experiments presents formidable challenges. Elevating pollutant concentrations within open air environments in a controlled manner is complex. Nonetheless, such real-world experiments are invaluable for revealing the genuine influence of air pollutants on ecosystems and their functioning. Field-scale measurements have emerged as a pivotal avenue for advancing our understanding of the interactions between air pollutants and the natural world, providing unique insights into ecosystem dynamics, including critical processes like pollination and natural pest regulation. In atmospheric and ecological research, free-air exposure systems have proven effective in elevating carbon dioxide (CO2) and ozone (O3) concentrations, facilitating the exploration of their ecological consequences. Yet, nitrogen oxides (NOx), a class of pollutants with significant ecological and atmospheric relevance, have largely eluded field-based ecological investigations. This paper introduces the recently developed FADOE (Free-Air Diesel and Ozone Enrichment) platform, which allows the elevation of O3 and diesel exhaust (including NOx) within a field-scale context. Comprehensive information on the system's design, construction, and performance data from the 2023 summer season is presented.•Air pollution and ecosystem functioning•Elevated ozone and nitrogen oxides (NOx)•Free-air exposure systems for field scale measurements.

Evaluation of Orthotrichum lyellii moss as a biomonitor of diesel exhaust

Exhaust from diesel combustion engines is an important contributor to urban air pollution and poses significant risk to human health. Diesel exhaust contains a chemical class known as nitrated polycyclic aromatic hydrocarbons (nitro-PAHs) and is enriched in 1-nitropyrene (1-NP), which has the potential to serve as a marker of diesel exhaust. The isomeric nitro-PAHs 2-nitropyrene (2-NP) and 2-nitrofluoranthene (2-NFL) are secondary pollutants arising from photochemical oxidation of pyrene and fluoranthene, respectively. Like other important air toxics, there is not extensive monitoring of nitro-PAHs, leading to gaps in knowledge about relative exposures and urban hotspots. Epiphytic moss absorbs water, nutrients, and pollutants from the atmosphere and may hold potential as an effective biomonitor for nitro-PAHs. In this study we investigate the suitability of Orthotrichum lyellii as a biomonitor of diesel exhaust by analyzing samples of the moss for 1-NP, 2-NP, and 2-NFL in the Seattle, WA metropolitan area. Samples were collected from rural parks, urban parks, residential, and commercial/industrial areas (N = 22 locations) and exhibited increasing concentrations across these land types. Sampling and laboratory method performance varied by nitro-PAH, but was generally good. We observed moderate to moderately strong correlation between 1-NP and select geographic variables, including summer normalized difference vegetation index (NDVI) within 250 m (r = −0.88, R2 = 0.77), percent impervious surface within 50 m (r = 0.83, R2 = 0.70), percent high development land use within 500 m (r = 0.77, R2 = 0.60), and distance to nearest secondary and connecting road (r = −0.75, R2 = 0.56). The relationships between 2-NP and 2-NFL and the geographic variables were generally weaker. Our results suggest O. lyellii is a promising biomonitor of diesel exhaust, specifically for 1-NP. To our knowledge this pilot study is the first to evaluate using moss concentrations of nitro-PAHs as biomonitors of diesel exhaust.

Differential pulmonary toxicity and autoantibody formation in genetically distinct mouse strains following combined exposure to silica and diesel exhaust particles

BackgroundInhalation of airborne particulate matter, such as silica and diesel exhaust particles, poses serious long-term respiratory and systemic health risks. Silica exposure can lead to silicosis and systemic autoimmune diseases, while DEP exposure is linked to asthma and cancer. Combined exposure to silica and DEP, common in mining, may have more severe effects. This study investigates the separate and combined effects of occupational-level silica and ambient-level DEP on lung injury, inflammation, and autoantibody formation in two genetically distinct mouse strains, thereby aiming at understanding the interplay between genetic susceptibility, particulate exposure, and disease outcomes. Silica and diesel exhaust particles were administered to mice via oropharyngeal aspiration. Assessments of lung injury and host response included in vivo lung micro-computed tomography, lung function tests, bronchoalveolar lavage fluid analysis including inflammatory cytokines and antinuclear antibodies, and histopathology with particle colocalization.ResultsThe findings highlight the distinct effects of silica and diesel exhaust particles (DEP) on lung injury, inflammation, and autoantibody formation in C57BL/6J and NOD/ShiLtJ mice. Silica exposure elicited a well-established inflammatory response marked by inflammatory infiltrates, release of cytokines, and chemokines, alongside mild fibrosis, indicated by collagen deposition in the lungs of both C57BL/6J and NOD/ShilLtJ mice. Notably, these strains exhibited divergent responses in terms of respiratory function and lung volumes, as assessed through micro-computed tomography. Additionally, silica exposure induced airway hyperreactivity and elevated antinuclear antibody levels in bronchoalveolar lavage fluid, particularly prominent in NOD/ShiLtJ mice. Moreover, antinuclear antibodies correlated with extent of lung inflammation in NOD/ShiLTJ mice. Lung tissue analysis revealed DEP loaded macrophages and co-localization of silica and DEP particles. However, aside from contributing to airway hyperreactivity specifically in NOD/ShiLtJ mice, the ambient-level DEP did not significantly amplify the effects induced by silica. There was no evidence of synergistic or additive interaction between these specific doses of silica and DEP in inducing lung damage or inflammation in either of the mouse strains.ConclusionMouse strain variations exerted a substantial influence on the development of silica induced lung alterations. Furthermore, the additional impact of ambient-level DEP on these silica-induced effects was minimal.

Enhancement of SO2 resistance and hydrothermal stability of Cu-SAPO-34 via Al2O3 coating for NOx selective catalytic reduction with NH3 in diesel exhaust

Cu-based zeolites are one kind of efficient catalyst in the selective catalytic reduction of NOx with NH3 (NH3-SCR) in diesel exhaust, but the SO2 resistance and hydrothermal stability of the catalyst need to be improved. Herein, in this work, a series of Al2O3-coated Cu-SAPO-34 catalysts were prepared by chemical liquid deposition (CLD) to enhance the SO2 resistance and hydrothermal stability simultaneous. The optimal Al2O3-coated Cu-SAPO-34 catalyst showed >90 % NO conversion at 180–500 °C, and presented significant enhanced SO2 resistance and hydrothermal stability in comparison to the uncoated Cu-SAPO-34 catalyst. It was found that the Al2O3 shell served as the sacrificial layer, reacted with SO2, which could limit the competitive adsorption between SO2 and NO on the Cu-SAPO-34, and reduce the formation of sulfate species. Moreover, the Al2O3 shell also limited the aggregation of Cu species and enhanced the stability of the catalysts during hydrothermal aging. This work provides a facile method for construction of efficient practical NH3-SCR catalysts.

An Estimate of the NOX Emissions of Euro 6 Diesel Passenger Cars with Manipulated Emission Control Systems

The motivation for conducting this research stems from the increasingly applied manipulations of emission control systems (ECSs), especially those in diesel passenger cars (PCs). The study aimed to investigate the influence of manipulations of exhaust gas recirculation (EGR) valves and a diesel exhaust fluid (DEF)-dosing system on the nitrogen oxide (NOX) emissions of a Euro 6 diesel vehicle and, through the quantification of vehicles with manipulated ECSs, estimate the emissions of Euro 6 diesel PCs. Portable emissions measurement system (PEMS) measurements were performed on a Euro 6 diesel vehicle at a constant speed and on real driving emission (RDE) routes. The speed-dependent functions of the NOX hot emission factor (EF) were calculated for seven different scenarios. The results showed that the NOX EFs for the worst-case scenarios were more than two orders of magnitude higher than those where all ECSs were active. Applying the calculated EFs and the survey answers on the percentage of manipulated PCs to the Croatian Euro 6 diesel PC fleet, the results showed that the emission levels were up to 46.3% higher than the emissions calculated by the official computer program COPERT v5.6.5, with a tendency towards significantly higher values. The main conclusion is that vehicle manufacturers, policymakers, and the general public need to be informed about the enormous damage that in-use vehicles with manipulated ECSs cause to the environment and human health, in order to prevent such actions.

Diesel exhaust and respiratory dust exposure in miners and chronic obstructive pulmonary disease (COPD) mortality in DEMS II

BackgroundDiesel exhaust and respirable dust exposures in the mining industry have not been studied in depth with respect to non-malignant respiratory disease including chronic obstructive pulmonary disease (COPD), with most available evidence coming from other settings. ObjectivesTo assess the relationship between occupational diesel exhaust and respirable dust exposures and COPD mortality, while addressing issues of survivor bias in exposed miners. MethodsThe study population consisted of 11,817 male workers from the Diesel Exhaust in Miners Study II, followed from 1947 to 2015, with 279 observed COPD deaths. We fit Cox proportional hazards models for the relationship between respirable elemental carbon (REC) and respirable dust (RD) exposure and COPD mortality. To address healthy worker survivor bias, we leveraged the parametric g-formula to assess effects of hypothetical interventions on both exposures. ResultsCox models yielded elevated estimates for the associations between average intensity of REC and RD and COPD mortality, with hazard ratios (HR) corresponding to an interquartile range width increase in exposure of 1.46 (95 % confidence interval (CI): 1.12, 1.91) and 1.20 (95 % CI: 0.96, 1.49), respectively for each exposure. HRs for cumulative exposures were negative for both REC and RD. Based on results from the parametric g-formula, the risk ratio (RR) for COPD mortality comparing risk under an intervention eliminating REC to the observed risk was 0.85 (95 % CI: 0.55, 1.06), equivalent to an attributable risk of 15 %. The corresponding RR comparing risk under an intervention eliminating RD to the observed risk was 0.93 (95 % CI: 0.56, 1.31). ConclusionsOur findings, based on data from a cohort of nonmetal miners, are suggestive of an increased risk of COPD mortality associated with REC and RD, as well as evidence of survivor bias in this population leading to negative associations between cumulative exposures and COPD mortality in traditional regression analysis.

Investigating sources and health risk assessment of n-alkanes in atmospheric wet deposition in Indo-Gangetic Plain

The present study determines the levels of n-alkanes in atmospheric wet deposition at an urban site in the Indo-Gangetic Plain, Delhi, during monsoon and non-monsoon periods in 2021. The n-alkane homologs (C10–C33) were determined in wet deposition, which included wet-only and bulk samples. The average total n-alkanes were found to be 56.0 ± 16.7 and 439.4 ± 150.8 μg/L in wet-only samples, whereas, 149.6 ± 46.4 and 454.9 ± 108.4 μg/L in bulk samples during monsoon and non-monsoon periods, respectively. The low molecular weight n-alkanes (C10–C25) exhibited no odd-even predominance in wet-only and bulk depositions during monsoon and non-monsoon periods. However, the high molecular weight n-alkanes (>C25) showed odd-even predominance during the non-monsoon period. The molecular distribution patterns of n-alkanes indicated possible emissions from bacteria, fossil-fuel combustion, direct volatilization of unburnt fuels, biogenic sources, and other anthropogenic activities. A health risk assessment for n-alkanes revealed the higher susceptibility of children via dermal and oral exposure. The Hazard Index for the exposure of n-alkanes through atmospheric wet deposition was <1, i.e., within the acceptable limit. The Carbon Preference Index (CPI) and wax n-alkanes (WNA)%, supported the prevalence of mixed emission sources with higher contributions from anthropogenic activities. Five sources of n-alkanes were identified using the positive matrix factorization (PMF) model, i.e., gasoline vehicles + fuel evaporation, biogenic, biogenic + diesel exhaust, road dust, and mixed, contributing ∼30 %, 11 %, 26 %, 17 %, and 16 % respectively. The Concentration Weighted Trajectory (CWT) analysis revealed that n-alkanes in wet-only and bulk samples were contributed by different local, regional, and long-range transport of air pollutants.

Neurodegenerative effects of air pollutant Particles: Biological mechanisms implicated for Early-Onset Alzheimer’s disease

BackgroundSporadic Alzheimer’s disease (AD) occurs in 99% of all cases and can be influenced by air pollution such as diesel emissions and more recently, an iron oxide particle, magnetite, detected in the brains of AD patients. However, a mechanistic link between air pollutants and AD development remains elusive. AimTo study the development of AD-relevant pathological effects induced by air pollutant particle exposures and their mechanistic links, in wild-type and AD-predisposed models. MethodsC57BL/6 (n = 37) and APP/PS1 transgenic (n = 38) mice (age 13 weeks) were exposed to model pollutant iron-based particle (Fe0–Fe3O4, dTEM = 493 ± 133 nm), hydrocarbon-based diesel combustion particle (43 ± 9 nm) and magnetite (Fe3O4, 153 ± 43 nm) particles (66 µg/20 µL/third day) for 4 months, and were assessed for behavioural changes, neuronal cell loss, amyloid-beta (Aβ) plaque, immune response and oxidative stress-biomarkers. Neuroblastoma SHSY5Y (differentiated) cells were exposed to the particles (100 μg/ml) for 24 h, with assessments on immune response biomarkers and reactive oxygen species generation. ResultsPollutant particle-exposure led to increased anxiety and stress levels in wild-type mice and short-term memory impairment in AD-prone mice. Neuronal cell loss was shown in the hippocampal and somatosensory cortex, with increased detection of Aβ plaque, the latter only in the AD-predisposed mice, with the wild-type not genetically disposed to form the plaque. The particle exposures however, increased AD-relevant immune system responses, including inflammation, in both strains of mice. Exposures also stimulated oxidative stress, although only observed in wild-type mice. The in vitro studies complemented the immune response and oxidative stress observations. ConclusionsThis study provides insights into the mechanistic links between inflammation and oxidative stress to pollutant particle-induced AD pathologies, with magnetite apparently inducing the most pathological effects. No exacerbation of the effects was observed in the AD-predisposed model when compared to the wild-type, indicating a particle-induced neurodegeneration that is independent of disease state.

Experimental study of peripheral fuel injection for higher performance in diesel engines

In conventional diesel combustion (CDC), a centrally located multi-hole injector supplies fuel radially outwards. This study introduces and explores the concept of peripheral fuel injection (PeFI) to supply fuel from multiple locations on top of the combustion chamber using several single-hole injectors. The PeFI concept is designed to eliminate flame-wall and jet-wall interactions, and, ideally, to produce independent flames without any interference. PeFI is also intended to increase air entrainment in the near field and thus, reduce equivalence ratio at the lift-off length and subsequent soot formation. PeFI reduces wall heat transfer compared to CDC although this feature is not considered in the present study. The two methods of fuel injection are compared in a non-reacting optical chamber via high-speed imaging of the jets. N-heptane fuel at 1500 bar supply pressures is injected into a test chamber filled with nitrogen at engine relevant ambient densities of 23.0 and 18.5 kg/m3. Four configurations are trialed including a six-hole central injector and six, single-hole PeFI injectors with holes oriented at a layout angle, defined as the angle between the center of the fuel jet and chamber radius, of 0°, 15°, and 30°. Flow visualizations show jet-to-jet interactions at small layout angles for PeFI, but little to no jet-to-jet (or jet-wall) interference as the layout angle increases to 30°. Image analysis reveals that PeFI provides faster rate of injection, longer jet penetration length, greater width near the jet tip, and larger jet volume compared to those for the central injector. Overall, results demonstrate the potential of PeFI to simultaneously improve fuel efficiency and reduce emissions in diesel engines.

Emission inventory of heavy metals from on-road vehicles in Xiamen, China, from 2015 to 2060

Reducing vehicle emissions to improve air quality has been widely adopted by policy makers. However, insufficient attention has been paid to non-exhaust particulate matter (PM) and the associated heavy metals (HMs) from on-road vehicles, which can cause adverse health effects. In this study, emission inventories of PM2.5 and PM10 and the associated HMs from on-road vehicles in Xiamen, China, were established from 2015 to 2060 under a business-as-usual scenario. In the base year 2021, the total emissions of HMs associated with primary PM2.5 and PM10 were 1.88 × 104 kg and 3.96 × 104 kg, respectively, with the dominant contributions from brake wear and road surface wear. The emissions of HMs were overwhelmingly dominated by light-duty passenger cars and heavy-duty trucks. Fe, Ba, Zn, Cu, Mn, and Ti together accounted for about 97% of the total HMs. High-density emission areas were concentrated in urban centers. From 2015 to 2060, an increasing trend in total HMs emissions was observed due to the superimposed effect of decreasing diesel exhaust and increasing non-exhaust brake wear and road wear. However, the trends of the individual HMs were different from each other. The U-shaped distribution patterns of the relative cancer and non-cancer risks of HMs were observed between 2015 and 2060. Vehicle electrification alone is not enough to effectively reduce the potential health risk of vehicle-related HMs in the future. Reducing HMs from brake wear should be encouraged to use in electric vehicle. Uncertainties in the emissions of HMs were quantified using the Monte Carlo simulation.

Investigation of the effect of different structure parameters and operating factors on the integrated exhaust aftertreatment system for diesel engines and parameter importance analysis

With diesel emission regulations growing more stringent, it is important to study the effect of different structure parameters and operating factors on the integrated aftertreatment system consisting of diesel oxidation catalyst (DOC), catalytic diesel particulate filter (CDPF) and selective catalytic reduction (SCR) during the design and optimization of the aftertreatment system. In this paper, a simulation model capable of exploring the interaction between the aftertreatment components was developed based on some relevant reaction mechanism, and the model accuracy was verified well using the experiment data. Then the effect of different parameters on the overall performance of the aftertreatment system was analyzed qualitatively. Finally, the importance score of each parameter was determined quantitatively based on Latin Hypercubic Sampling method and Random Forests algorithm. The results showed that larger diameter or larger cell density in DOC could improve the aftertreatment performance effectively. The increase in the wall thickness of each component had a negative impact on the aftertreatment system, except for CDPF wall thickness, which improved the filtration efficiency for particular matter (PM). When total aftertreatment length was fixed, high conversion efficiencies for carbon monoxide (CO) and total hydrocarbons (THC) were distributed in the region with large DOC length ratio, and NOx conversion efficiency was affected simultaneously by the length ratio of DOC, CDPF and SCR. An increase in CDPF length ratio and a decrease in DOC and SCR length ratios could contribute to the reduction of total pressure drop. Finally, Random Forests algorithm provided a good identification of the importance score of each parameter. DOC length and diameter played a dominant role in CO and THC conversion. The aftertreatment diameter had higher effect on NOx conversion efficiency than SCR length and PM filtration efficiency was mainly affected by DOC and CDPF length. Based on these qualitative and quantitative results, a design strategy for the integrated aftertreatment system was proposed, which provided some ideas for improving aftertreatment performance.

Benefits of diesel emission regulations: Evidence from the World's largest low emission zone

We examined the impact of diesel emission regulations on air quality, land prices, and infant health in the Tokyo metropolitan area. The results reveal that as air pollution concentrations improved, land prices increased more in areas with higher diesel vehicle traffic, even after controlling for non-regulated vehicle traffic. In contrast, the concentrations of non-regulated air pollutants were unaffected. Estimates based on the hedonic approach show that the benefit of air quality improvement in the metropolitan area is about 14 times the cost. Improved air quality also improved infant health. The improvement in infant mortality with a one-unit improvement in suspended particulate matter was similar in magnitude to published results from the United States.

Inter-annual trends of ultrafine particles in urban Europe

Ultrafine particles (UFP, those with diameters ≤ 100 nm), have been reported to potentially penetrate deeply into the respiratory system, translocate through the alveoli, and affect various organs, potentially correlating with increased mortality. The aim of this study is to assess long-term trends (5–11 years) in mostly urban UFP concentrations based on measurements of particle number size distributions (PNSD). Additionally, concentrations of other pollutants and meteorological variables were evaluated to support the interpretations. PNSD datasets from 12 urban background (UB), 5 traffic (TR), 3 suburban background (SUB) and 1 regional background (RB) sites in 15 European cities and 1 in the USA were evaluated. The non-parametric Theil-Sen’s method was used to detect monotonic trends. Meta-analyses were carried out to assess the overall trends and those for different environments. The results showed significant decreases in NO, NO2, BC, CO, and particle concentrations in the Aitken (25–100 nm) and the Accumulation (100–800 nm) modes, suggesting a positive impact of the implementation of EURO 5/V and 6/VI vehicle standards on European air quality. The growing use of Diesel Particle Filters (DPFs) might also have clearly reduced exhaust emissions of BC, PM, and the Aitken and Accumulation mode particles. However, as reported by prior studies, there remains an issue of poor control of Nucleation mode particles (smaller than 25 nm), which are not fully reduced with current DPFs, without emission controls for semi-volatile organic compounds, and might have different origins than road traffic. Thus, contrasting trends for Nucleation mode particles were obtained across the cities studied. This mode also affected the UFP and total PNC trends because of the high proportion of Nucleation mode particles in both concentration ranges. It was also found that the urban temperature increasing trends might have also influenced those of PNC, Nucleation and Aitken modes.

Biogas intake pressure and port air swirl optimization to enhance the diesel RCCI engine characteristics for low environmental emissions

Exhaust emission and combustion control in RCCI (reactivity-controlled compression ignition) focused mainly on the direct-injected fuel parameters, urging to investigate the advantages of port-fuel intake parameters. The engine was modified for port injection of Biogas at the valve and RCCI mode. The influence of port swirl ratio (PSR, 0 – 80%) and biogas injection pressure (BIP, 1 – 4 bar) on the diesel RCCI combustion and emissions was tested and optimized at varied loads and 1600 rpm in a port injection at the valve (PIVE) approach. Established kinetic mechanisms were combined with multi-objective optimization to further investigate, predict, and analyze emissions occurrence and trade-offs for reduced environmental impacts. The results show that the radiation absorption triggered by increased CO2 lowers combustion temperature, resulting in prolonged ignition. Setting the airflow to swirl lowers the in-cylinder pressure at elevated BIP while raising the heat generated across the BIPs. Increasing the PSR slows the combustion while BIP speeds up the process. BIP and PSR show great trade-off reduction ability among all emission parameters. The optimum unburned hydrocarbon, nitrogen oxide, particulate, and carbon monoxide emissions for the injection at the valve were found to be 109.58, 0.577, and 2.336 ppm, and 0.103%, respectively, at low-load, low-BIP, and high-PSR. The emissions were lowered by 6.58, 91.26, 80.65, and 13.45% compared to the premixed RCCI mode, respectively. Therefore, introducing low-pressure biogas amid high swirling air at the valve elevates the in-cylinder condition while lowering the emissions, mitigating their environmental implications.