The resource theory of superposition is a generalization of coherence theory. A rigorous framework for quantifying superposition of linear independent states has been given by previous studies. In this paper, the optimal superposition enhancement of a mixed state is studied. Based on the l1 measure of superposition the optimal superposition enhancement value of a mixed state can be obtained under the stochastic diagonal superposition-free operations(or incomplete diagonal superposition-free operations). In addition, the optimal probability corresponding to the optimal superposition enhancement value of a mixed state is also discussed. The results show that although the superposition-free operations can decrease the superposition of a state, the superposition enhancement of a state is possible, a single mixed state can be probabilistically transformed into another state with higher superposition than before by superposition-free operations. These studies will give us a better understanding of the superposition manipulation and the resource theory of superposition.