Lithium-ion batteries are prone to risks with fire hazard due to the possibility of thermal runaway propagation. During battery product development and subsequent safety tests for design validation and safety certification, the thermal runaway onset is triggered by various test methods such as nail penetration, thermal ramp, or external short circuit. This failure initiation method affects the amount of heat contributions and the composition of gas generations. This study1 compares two such trigger methods, by external heating and by using a thermally activated internal short circuit device (ISCD). The effects of the trigger method on total heat generation are experimentally investigated within 18650 cylindrical cells at single cell level as well as at multiple cell configuration level.During thermal abuse conditions, it is known that internal short circuits occur before thermal runaway, but this joule heating does not contribute much to heat generation2. But during internal short circuits initiating at lower temperatures, joule heating plays a major role in thermal runaway process. Previous modeling studies have enhanced our understanding of the role of multiple physical processes during thermal runaway3-4. In this study we use a combination of models and experiments to characterize battery safety in terms of abuse tolerance, severity of thermal runaway and propagation. The severity of failure was observed to be worse for cells with ISC devices at single cell level whereas quite opposite results were observed at multiple cell configuration level. A preliminary numerical analysis was performed to better understand the battery safety performance with respect to thermal runaway trigger methods and heat transfer conditions. Mallarapu, A., Sunderlin, N., Boovaragavan, V., Tamashiro, M., Peabody, C., Pelloux-gervais, T., Li, X., Sizikov, 2024, Effects of Trigger Method on Fire Propagation during the Thermal Runaway Process in Li-ion Batteries, Journal of The Electrochemical Society, 171 040514Ren, D., Feng, X., Liu, L., Hsu, H., Lu, L., Wang, L., He, X., Ouyang, M., 2021, Investigating the relationship between internal short circuit and thermal runaway of lithium-ion batteries under thermal abuse condition, Energy Storage Materials 34, 563–573Feng, X., He, X., Ouyang, M., Wang, L., Lu, L., Ren, D., Santhanagopalan, S., 2018, An electrochemical-thermal coupled overcharge-to-thermal-runaway model for lithium ion battery, Journal of The Electrochemical Society, 165 A3748Coman, P. T., Darcy, E. C., Veje, C. T., White, R. E., 2017. “Modelling Li-Ion cell thermal runaway triggered by an internal short circuit device using an efficiency factor and arrhenius formulations.” Journal of The Electrochemical Society, 164 A587
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