Device Capacitance Research Articles

Facile synthesis of MWCNT hexagonal needles grown on interconnected honeycombs like MnCo2O4/MnO2 nanoporous electrode for high-performance asymmetric supercapacitor

The construction of a honeycomb-like structure composed of MnCo2O4/MnO2was effectively achieved using a combination of hydrothermal processing and heat treatment. The whole surface of the MnCo2O4/MnO2 honeycomb is coated with neatly arranged hexagonal nano needles made of MWCNT, leading to a substantial enhancement in the specific surface area. At 1 A/g, the supercapacitor electrode composed of MnCo2O4/MnO2@MWCNT composite exhibited an exceptional specific capacitance of around 1539 F/g. Furthermore, it maintained approximately 95.5 % of its capacity even after undergoing 10,000 cycles. The asymmetric capacitor device, with MnCo2O4/MnO2@MWCNT and AC electrode, has a power density of 1537.8 W kg−1 and an energy density of 48.78 Wh kg−1. The MnCo2O4/MnO2composite exhibits exceptional rate performance, significant capacitance, and excellent cycle performance due to the synergistic effect between MnCo2O4/MnO2 and MWCNT, as well as the high specific surface area and unique structure. Consequently, it presents a viable option for the advancement of high-efficiency electrochemical super capacitors in the next generation.

Selective electro-capacitive deionization of Yb(III) by nanospherical N-doped carbon supported nickel‑iron bimetallic oxide, nitride and phosphide

The separation of rare earth elements from the mining waste water is highly important but still facing challenge. In this study, three different porous composite electrode materials were well-designed by decorating the nickel‑iron bimetallic oxide, nitride or phosphide onto nitrogen-doped carbon nanosphere, respectively (termed as NiFeO@NC, NiFeN@NC and NiFeP@NC), and utilized in capacitive deionization device for electrosorption of Yb(III) from water under the low-voltage electric field. The characterization and electrochemical results indicated that the incorporation of N or P atom lead to the reduced specific surface area and the enhanced electrochemical properties (i.e., larger specific capacitance, lower charge transfer resistance). In addition, NiFeN@NC and NiFeP@NC exhibited the excellent electrosorption capacities of Yb(III) with 105.24 mg·g−1 and 90.31 mg·g−1, respectively, under conditions of a flow rate of 20 mL·min−1, a voltage of 1.2 V, and pH of 5.0, which was extremely higher than NiFeO@NC (i.e., 50.7 mg·g−1). Moreover, all these three materials also demonstrated the remarkable electrosorption selectivity of Yb(III) from the mixed solution, and the robust durability with over 90 % of initial capacities after ten consecutive electrosorption-desorption cycles. Furthermore, the XPS characterizations and electrosorption results revealed that the electrosorption mechanism mainly depended on the synergistic effects of intrinsic Faraday redox reaction, electric double layer capacitance and active binding sites. Therefore, this work provided a feasible strategy for the separation of rare earth elements from aqueous solution, and the prospective applications related to the recovery of rare earth elements from mining wastes or spent permanent magnets in future life.

Research of the Primary Electric Energy Storage System of a Traction Photovoltaic Module

Purpose. The main idea of the work is that the electric energy generated by photovoltaic installations is supplied in small parts to capacitive energy storage devices of low power, and then these «portions» of energy are supplied to one common, so-called traction storage device. The research is aimed at obtaining time diagrams of current and voltage changes in the proposed system. Methodology. A review of the world literature on the topic of work was conducted. The basis of this research is the analysis of transient processes in the electrical circuits of the system during the transfer of energy from the photovoltaic module to the traction capacitor under the influence of various control signals: series, parallel, combined. The main research method is computer simulation. The Scilab software environment was used to simulate the operation of the electric energy storage system. Findings. The relevance of the research and development of a primary electric energy storage system using a traction photovoltaic module has been proved. The key mathematical dependencies between the parameters of the constituent elements of electrical circuits are established. The structure of a site with electric energy storage with traction photovoltaic modules and a converter-pulse signal unit is proposed. The graphical characteristics of transient processes that occurred during the transfer of energy from low-power capacitive elements to a high-power capacitive element (traction capacitor) were obtained. Originality. For the first time, graphical dependences of energy transfer between system elements were obtained, which allows for a reasonable choice of the parameters of these elements. Also, for the first time, time dependencies describing the law of control of the process of energy transfer between system links were obtained, which will allow determining the rational modes of its operation. Practical value. The results of the research open up new opportunities in the research field in the development of large-scale experimental models of the maglev path structure in the case of the introduction of a system of distributed primary energy storage in a traction photovoltaic module.

Enhanced buoyancy and propulsion in 3D printed swimming micro-robots based on a hydrophobic nano-fibrillated cellulose aerogel and porous lead-free piezoelectric ceramics

This paper provides the first demonstration of additively manufactured swimming micro-robots which combine a hydrophobic nanofibrillated cellulose aerogel, to provide long-term buoyancy, with a low acoustic impedance porous piezoelectric ceramic for improved propulsion. The hydrophobic nanocellulose aerogel is shown to exhibit a high and stable contact angle that was maintained for extended periods of time, which facilitates long-term and stable buoyancy of the micro-robot. To quantify the benefits of introducing porosity into the active piezoelectric element, a new analysis model was developed to inform material design and maximize the acoustic propulsion force. Detailed characterisation and modelling of the swimming robots demonstrated that a swimming robot based on a lead-free porous Ba0.85Ca0.15Zr0.1Ti0.9O3 (BCZT) ceramic exhibited a higher acoustic radiation propulsion force and a faster swimming speed compared to a robot fabricated using a dense ceramic element. These benefits were associated with the lower elastic modulus, density and acoustic impedance of the porous piezoelectric material. The lower dielectric constant, reduced device capacitance, and lower resonant frequency of the porous piezoelectric element also significantly reduced the driving current and power requirements of the robot. This work therefore provides new insights on the impact of hydrophobic and acoustically matched piezoelectric materials on the performance of swimming micro-robots, and successfully demonstrates the use of porosity to improve acoustic impedance matching of resonant piezoelectric devices, such as micro-robots and ultrasonic transducers.

Space charge-induced capacitance recovery in blue quantum dot light-emitting diodes

In this work, we report the capacitance recovery behavior in the blue quantum dot light-emitting diode (QLED) by capacitance–voltage (C–V) characterizations. A comprehensive study of the C–V, dC/dV–V, and current density–voltage characteristics of pristine and shelf-aged devices suggests that capacitance recovery is associated with space charge-induced charge accumulation. At lower temperatures, the capacitance recovery in the shelf-aged device is efficiently suppressed due to the difficulty in building up the space charge, which supports our argument. Moreover, the capacitance recovery behavior of QLED only happens at low frequencies (a few hundred hertz), which is related to the time constant for charge accumulation at the selected voltage. Our work shows the effect of space charge on device capacitance and enriches the comprehension of carrier processes in QLED under AC measurement.

The effect of temperature variation on the transient response of RF PIN diode limiters for very high frequency applications

AbstractThis work presents the effect of temperature change on the capacitance of silicon PIN diodes and the resulting change in performance of RF limiters at very high frequency (VHF). Device temperatures were varied between −25 ºC and 100 ºC, with small‐signal parameters (including device capacitance) extracted at regular temperature increments and bias voltages from −20 Vdc to +3 Vdc using a multi‐bias parameter extraction method. It was found that the junction capacitance of the four PIN diodes under investigation increases with temperature, as expected from carrier lifetime behaviour, while results also confirmed prior observations of an inverse relationship between forward‐biased series resistance and temperature. Devices were subsequently tested in two different limiter topologies through high‐power transient measurements. It was found that the combination of increased capacitance and decreased resistance with increasing temperature increases the transient spike leakage and decreases the flat leakage of a limiter. It was also concluded that, for VHF, an anti‐parallel topology provides the best performance over a wide range of temperatures.

Liquid metal interface mechanochemistry disentangles energy density and biaxial stretchability tradeoff in composite capacitor film

Dielectric polymer composites for film capacitors have advanced significantly in recent decades, yet their practical implementation in industrial-scale, thin-film processing faces challenges, particularly due to limited biaxial stretchability. Here, we introduce a mechanochemical solution that applies liquid metal onto rigid dielectric fillers (e.g. boron nitride), dramatically transforming polymer-filler interface characteristics. This approach significantly reduces modulus mismatch and stress concentration at the interface region, enabling polypropylene composites to achieve biaxial stretching ratio up to 450 × 450%. Furthermore, liquid metal integration enhances boron nitride’s dielectric polarization while maintaining inherent insulation, producing high-dielectric-constant, low-loss films. These films, only microns thick yet quasi square meters in area, achieve a 55% increase in energy density over commercial biaxially-oriented polypropylene (from 2.9 to 4.5 J cm−3 at 550 MV/m), keeping 90% discharge efficiency. Coupled with improved thermal conductivity, durability, and device capacitance, this distinctive interface engineering approach makes these composites promising for high-performance film capacitors.

Single, binary, and ternary nanocomposite electrodes of reduced graphene oxide@polyaniline@Co-Prussian analog for supercapacitors

The present work includes fabrication of a binary and ternary and composites of reduced graphene oxide (RGO), Polyaniline (Pani), and cobalt Prussian blue analog (Co-PA) for high performance supercapacitor. The materials were characterized using XRD, SEM, FT-IR, and BET techniques. The results confirm the formation of the desired nanocomposites. The electrochemical properties were evaluated in three electrode configuration using CV, CCD and EIS methods. The ternary composite of RGO@Pani@Co-PA showed better electrochemical properties than that obtained from the binary composites as well as their constituent components. The ternary-based sample had a specific capacitance of 490 Fg-1 at a current density of 1 A g-1 and a minimal capacitance loss of 93.9% after 3000 electric cycles. The ternary composites' remarkable electrochemical performance has been attributed to their well-thought-out, distinctive architecture, which offers a substantial surface area and promotes synergistic effects among the other ingredients. The ternary RGO@Pani@Co-PA composite was used as the anode electrode (positive) and activated carbon as the cathode (negative) materials in the assembly of the asymmetric supercapacitor (ASC) device. Over a wide potential window of 2 V, the fabricated ASC had a remarkable specific energy of 58.9 Wh kg-1 at a specific power of 9210 W kg-1 and 88.5% device capacitance stability after 5000 cycles of charge/discharge.

Analysis of seismic damage mechanism of capacitor

Abstract A high voltage shunt capacitor bank is very important for the normal operation of the power system, especially for the UHVDC transmission in long distance large capacity transmission, and power system networking has an important role. Therefore, its performance response under earthquakes is one of the key concerns. Through the fine finite element simulation modeling of the actual capacitor, the sine beat wave, and the actual earthquake input, the dynamic characteristics and the response index under the earthquake are studied. The results show that the stiffness in the x direction of the capacitor assembly is greater than that in the y direction. The weak position of the model is the root and top of the end insulator and the middle insulator. Under the action of different working conditions, such as X - and Y-El Centro waves, the maximum stress response of the root of the end insulator of the capacitor device is 4.98 MPa, and the safety factor is 3.51, which meets the requirement greater than 1.67.

Wind conversion systems effects on power grid and ability of thyristor controlled series capacitor and static synchronous series compensator devices for dynamic performance enhancing

Wind conversion systems effects on power grid and ability of thyristor controlled series capacitor and static synchronous series compensator devices for dynamic performance enhancing

A self-integration via dual-active mode structural-SC-TENG energy device for electrochemical energy storage and triboelectric energy harvesting

The structural supercapacitor with triboelectric nanogenerator (structural-SC-TENG) is a remarkable integrated energy device utilized for clean energy storage and harvesting. Here, we demonstrated the structural-SC-TENG device based on a multifunctional storage and harvester using dual-functional MoO3 grown on a carbon cloth electrode (CC) via hydrothermal technique and physiochemical characterization revealed the formation of an orthorhombic phase of MoO3. The FE-SEM morphological analysis confirms that the cubes-like peals were uniformly decorated on the CC surface in an upward and downward direction. The dual-functional MoO3 grown on the CC electrode was used for the construction of the supercapacitor and TENG device which will act as a charge-storing electrode in the supercapacitor and charge-sharing electrode in TENG. The constructed MoO3 SSC provides an excellent device capacitance of 97.86 F g−1, energy density of 40.50 Wh kg−1, and a high-power density of 28,125 W kg−1 with remarkable cyclic life modeled/predicted via time series analysis (TSA) technique. On the other side, the TENG device constructed using MoO3 on CC as the positive electrode (confirmed through KPFM analysis) and PDMS as the negative electrode exhibited a better electrical response with a high voltage and current of 55 V and 0.19 μA and delivered a peak power of 4.17 μW. This type of integrated device is splendid and possibly be used for self-powered sensors, smart IoTs, self-charging power systems, low-power electronics, and various indoor/outdoor environments.

Percolation-Triggered Negative Permittivity in Nano Carbon Powder/Polyvinylidene Fluoride Composites.

Percolating composites exhibiting negative permittivity have garnered considerable attention due to their promising applications in the realm of electromagnetic shielding, innovative capacitance devices, coil-less inductors, etc. Nano carbon powder/polyvinylidene fluoride (CP/PVDF) percolating composites were fabricated that exhibit Drude-type negative-permittivity behavior upon reaching the CP percolation threshold. This phenomenon is attributed to the formation of a plasmonic state within the interconnected CP network, enabling the delocalization of electrons under the alternating electric field. Furthermore, a significant (nearly two orders of magnitude) increase in the conductivity of sample is observed at a CP content of 12.5 wt%. This abrupt change coincides with the percolation phenomenon, suggesting a transition in the conduction mechanism. To elucidate this behavior, comprehensive analyses of the phase composition, microstructure, AC conductivity, and relative permittivity were performed. Additionally, the sample containing 5 wt% CP exhibits a remarkably high permittivity of 31.5, accompanied by a relatively low dielectric loss (tanδ < 0.2). The findings expand the potential applications of PVDF, while the fabricated percolating composites hold promise for electromagnetic shielding, antennas, and other electromagnetic devices.

(Invited) Ferroelectric Nonvolatile Capacitive Synapse for Charge Domain Compute-in-Memory

The rise of Artificial Intelligence has led to an increased demand for computing hardware which can handle data intensive tasks in an energy efficient manner. Compute-in-memory architecture which combines information processing and data storage at the same location and specializes in Multiply-and-Accumulate (MAC) operation has emerged as an attractive candidate to meet this demand. Non-volatile capacitive (nvCAP) devices are investigated to realize the synaptic devices to enable CIM in charge-domain-computing. Charge-domain-CIM works as follows: The synaptic weights of a neural network are stored as the capacitance state of the nvCAP device in a crossbar array. The input of the neural network is applied as voltages to the crossbar array, and the resulting charges are summed up as the MAC operation. The nvCAP synaptic devices also provides benefits over traditional resistive synapses such as: only static power consumption, negligible sneaky current, suppressed read-disturb due to small-signal-read out. Recently, the Ferroelectric Field Effect Transistor (FeFET) has been demonstrated to operate in nvCAP mode, with S-D terminal of the FET shorted and Body-Floating. Here, the Field Effect Transistor part exhibits a gate voltage-dependent capacitance behavior, where the high capacitance originates from the transistor gate area, while the low capacitance originates from the overlap region between the gate oxide and source-drain region of FET. The ferroelectric layer part introduces a lateral shift in the C-V curve of FET, leading to either a high (CON) or low capacitance (COFF) state at 0V that can be tuned by an applied electric field. The CON/COFF ratio of the device can be designed as-per the application by increasing the channel area and reducing the overlap length. For a robust and consistent performance in CIM, reliability aspects of ferroelectric nvCAP are investigated. The FeFET in nvCAP mode demonstrates an initial endurance of 106 Program-Erase cycles while maintaining the ON/OFF >5. It is found that a CV sweep performed on the device help recover the performance. By performing repeated endurance-recovery operation, a recovered endurance of 108 cycles is achieved. The nvCAP device demonstrates memory retention of at least 1 day @85C for all fresh, fatigued and recovered states of the device. The nvCAP device also shows multi-level-cell capabilities for atleast 4 levels by changing the Program voltages. Figure 1

Equivalent circuit fitting method for microwave characterisation of low-k dielectric thin films

Abstract A new equivalent circuit fitting analysis scheme is proposed to analyse the measured data of test structures originally developed to characterise high-κ dielectrics at frequencies up to 5 GHz (Zhengxiang et al 1998 IEEE Trans. Electron Devices 45 1811–6). It is compared to an extension of the analysis which can be used for high-κ dielectrics at up to 50 GHz (Rundqvist et al 2004 Integr. Ferroelectr. 60 1–19). The proposed scheme focuses on the accurate characterisation of low-κ dielectrics, which exhibit greater sensitivity to various parasitics. The scheme utilises the same concentric capacitor devices and measurement setup as the original method, maintaining the advantage of ease in fabrication of the original approach. The physical model employed in the analysis step of the original method, which tended to overestimate the dielectric permittivity, has been enhanced by incorporating fringing fields and a parasitic gap capacitance as circuit elements. The accuracy of the new approach is validated using experimental data, demonstrating its ability to more accurately determine the dielectric permittivity compared to the original method.

Modeling of Nanomaterials for Supercapacitors: Beyond Carbon Electrodes.

Capacitive storage devices allow for fast charge and discharge cycles, making them the perfect complements to batteries for high power applications. Many materials display interesting capacitive properties when they are put in contact with ionic solutions despite their very different structures and (surface) reactivity. Among them, nanocarbons are the most important for practical applications, but many nanomaterials have recently emerged, such as conductive metal-organic frameworks, 2D materials, and a wide variety of metal oxides. These heterogeneous and complex electrode materials are difficult to model with conventional approaches. However, the development of computational methods, the incorporation of machine learning techniques, and the increasing power in high performance computing now allow us to tackle these types of systems. In this Review, we summarize the current efforts in this direction. We show that depending on the nature of the materials and of the charging mechanisms, different methods, or combinations of them, can provide desirable atomic-scale insight on the interactions at play. We mainly focus on two important aspects: (i) the study of ion adsorption in complex nanoporous materials, which require the extension of constant potential molecular dynamics to multicomponent systems, and (ii) the characterization of Faradaic processes in pseudocapacitors, that involves the use of electronic structure-based methods. We also discuss how recently developed simulation methods will allow bridges to be made between double-layer capacitors and pseudocapacitors for future high power electricity storage devices.

Harmonic voltage measurement based on capacitive equipment dielectric equivalent model and responding current

Abstract With the increasing proportion of new energy and the power electronic equipment in the power grid, accurate measurement of harmonic voltage has become increasingly important for power quality monitoring. In order to solve the problem of high-precision measurement of harmonic voltage in the power grid, this manuscript proposes a high-precision harmonic voltage measurement method based on the dielectric equivalent model (DEM) of capacitive equipment and its responding current. Based on DEM, a voltage-current transfer function of the capacitive device is established, and harmonic voltage is reconstructed with the responding current. Considering the dielectric relaxation characteristics of capacitive device other than a pure capacitor model, this manuscript analyzes the fitting performance of different equivalent capacitance models and improves the traditional pure capacitance model to a more suitable DEM for harmonic voltage reconstruction. The DEM parameters of capacitive devices are obtained through the frequency domain spectroscopy (FDS) and intelligent parameter identification algorithms, which improved the measurement accuracy of harmonic voltage and reduced computational complexity. The harmonic voltage testing platform is established to test the simulated high-voltage harmonics and the harmonic voltage of the actual grid voltage. The results show that the proposed harmonic voltage measurement method can meet the high-precision reconstruction of harmonic voltage in the frequency range of 50~2500Hz, and the system testing error with sensors is less than 2%. The testing accuracy is higher than traditional voltage transformers and testing systems based on pure capacitance models.

Capacitive Neuromodulation via Material-Based Passive Interaction: Efficacy in Motor Function Improvement in Parkinson Disease.

A non-invasive and non-pharmacological approach is evaluated for the proprioceptive and postural improvement of PD subjects. The authors evaluated the effectiveness of a class I medical device according to EU regulation 745/2017 designed to develop the mechanism of action based on the modulation of action potentials, which occurs in prevalent pathways of the afferent peripheral nervous system efferent in subjects with spasticity. The present observational study, structured in a double-blind randomized manner, therefore, had the main aim of evaluating the ability of the device to improve on the motor and proprioceptive function of PD patients. This study was based on the instrumented gait analysis performed according to the Timed Up and Go (TUG) test procedure, as well as using a fall risk assessment in accordance with the Berg Balance Scale (BBS) procedures. This study involved 25 participants in the active group (no placebo) and 25 in the non-active group (placebo), the latter to whom non-functional devices were applied, but in every respect identical to the functional devices applied to the 25 patients in the no placebo group. Data analysis was conducted using statistical methodologies for statistics, the statistical significance of the results for the observed samples and the interdependence between the measured variables. The study of the mechanism of action based on the remodulation of action potentials was preliminary conducted through numerical modeling of the Hodgkin-Huxley axon, modified by introducing the influence of the capacitive device applied in clinical tests into the validated model to target the dielectric properties of materials constituting the passive sensor. The use of the neuromodulation device promises observable improvements in motor function among PD patients, including increased limb mobility and greater postural stability.

Uniform, Fully Connected, High-Quality Monocrystalline Freestanding Perovskite Oxide Films Fabricated from Recyclable Substrates.

Releasing epitaxial perovskite oxide films from their native oxide substrates produces high quality, 2D-material-like monocrystalline freestanding oxide membranes, as potential key components for the next-generation electronic devices. Two major obstacles still limit their practical applications: macroscopic material defects (mainly cracks) that lowers uniformity and yield, and the high cost of the consumed oxide substrates. Here, a two-step film transfer method and a substrate recycling method enable repetitive fabrication of millimeter-scale, fully-connected freestanding oxide films of various chemical compositions from the same substrates; arrays of capacitor and resistor devices based on these oxides transferred on silicon indicate high uniformity, low sample-to-sample variation, and satisfactory electrical connectivity. The two-step transfer suppresses crack formation by avoiding buckling-delamination-type relaxation of epitaxial strain, and the key point to achieve substrate reuse is to remove the residual Al species bonded to the substrate surfaces. The mitigation of such long-lasting issues in freestanding oxide fabrication techniques may eventually pave roads toward future industrial-grade devices, as well as enabling many research opportunities in fundamental physics.

Low-frequency capacitor with hopping electrical conductivity of the working substance (on the example of a-Si:H)

We propose a structural and electrical schemes of a capacitor based on a 3 μm thick a-Si:H (amorphous hydrogenated silicon) layer separated from the metal plates by 0.3 μm thick dielectric layers of SiO2 (silicon dioxide). We consider room temperatures (T ≈ 300 K) when in the absence of illumination for a-Si:H the hopping mechanism of electron migration via point defects of the structure prevails. For such a capacitor, the dependencies of the capacitance on the frequency of the measuring signal ω/2π in the range from 0.1 to 300 Hz are calculated for the a-Si:H layer with stationary hopping electrical conductivity σdc ≈ 1 ∙ 10−10 (Ohm ∙ cm)−1. It is assumed that there is no end-to-end electron transfer between the a-Si:H layer, dielectric layers and capacitor plates in the small-signal mode of capacitance measurement. It is shown that the real part of the capacitance of the capacitor decreases with increasing angular frequency ω, and the imaginary part is negative and depends non-monotonically on ω. The decrease in the real part of the device capacitance to the geometric capacitance of the series-connected oxide layers and the a-Si:H layer with increasing ω is due to a decrease in the electrical resistance of the capacitor. As a result, with increasing ω, the imaginary part of the capacitance is shunted by the hopping electrical conductivity of the capacitor. The phase shift for a sinusoidal electrical signal supplied to the capacitor is determined depending on the frequency ω/2π in the range of 0.1–300 Hz for the values of electrical conductivities of the hydrogenated amorphous silicon layer σdc ≈ 1 ∙ 10−11, 1 ∙ 10−10, and 1 ∙ 10−9 (Ohm ∙ cm)−1 at the temperature 300 K. With an increase in the electrical conductivity σdc of the a-Si:H layer, the minimum absolute value of the phase shift angle (≈65°) shifts to the high- frequency region (from 1 to 100 Hz). The proposed low-frequency capacitor can find application in electrical circuits for detecting low-frequency electrical signals for the purposes of biomedicine.

Ferroelectric and Relaxor-Ferroelectric Phases Coexisting Boosts Energy Storage Performance in (Bi0.5Na0.5)TiO3-Based Ceramics.

With the intensification of the energy crisis, it is urgent to vigorously develop new environment-friendly energy storage materials. In this work, coexisting ferroelectric and relaxor-ferroelectric phases at a nanoscale were constructed in Sr(Zn1/3Nb2/3)O3 (SZN)-modified (Bi0.5Na0.5)0.94Ba0.06TiO3 (BNBT) ceramics, simultaneously contributing to large polarization and breakdown electric field and giving rise to a superior energy storage performance. Herein, a high recoverable energy density (Wrec) of 5.0 J/cm3 with a conversion efficiency of 82% at 370 kV/cm, a practical discharged energy density (Wd) of 1.74 J/cm3 at 230 kV/cm, a large power density (PD) of 157.84 MW/cm3, and an ultrafast discharge speed (t0.9) of 40 ns were achieved in the 0.85BNBT-0.15SZN ceramics characterized by the coexistence of a rhombohedral-tetragonal phase (ferroelectric state) and a pseudo-cubic phase (relaxor-ferroelectric state). Furthermore, the 0.85BNBT-0.15SZN ceramics also exhibited excellent temperature stability (25-120 °C) and cycling stability (104 cycles) of their energy storage properties. These results demonstrate the great application potential of 0.85BNBT-0.15SZN ceramics in capacitive pulse energy storage devices.