Development Of Solid Oxide Fuel Cells Research Articles

Scaffold Infiltrated Cathodes for Low-Temperature Solid Oxide Fuel Cells.

Lowering the operating temperature of solid oxide fuel cells (SOFCs) and electrolysis cells (SOECs) to reduce system cost and increase lifetime is the key to widely deploy this highly efficient energy technology, but the high cathode polarization losses at low temperatures limit overall cell performance. Here we demonstrate that by engineering a universal ceria-based scaffold with infiltrated nanoscale electrocatalysts, a low cathode polarization <0.25 Ω·cm2 with remarkably high performance 1 W/cm2 at 550 °C is achieved. The combination of low processing and operating temperature restrains the nanosized electrocatalysts, not only allowing fast oxygen transport but also providing an essential electronically connective network to facilitate electrochemical reactions without requiring the high-temperature processing of a separate cathode layer. Moreover, excellent SOFC durability was demonstrated for over 500 h. This work shows a promising pathway to reduce processing/system costs with all scalable ceramic processing techniques for the future development of low-temperature SOFCs and SOECs.

Solid Oxide Fuel Cell Anode Porosity and Tortuosity Effect on the Exergy Efficiency

Improving the efficiency of solid oxide fuel cells (SOFCs) is critical for advancing clean energy solutions on a global scale. One major challenge in enhancing SOFC efficiency is reducing anode diffusion polarization, which can significantly hinder performance. This study addresses this issue by investigating the effects of anode tortuosity and porosity on the exergy efficiency of SOFCs. The novelty of this research lies in its comprehensive numerical model, which uniquely incorporates detailed material properties and their impact on SOFC performance—specifically focusing on anode tortuosity and porosity. Using advanced Multiphysics software, we developed a model that solves mass, electron transfer, and energy equations discretized via the finite differences method. The study meticulously examines how variations in these parameters influence SOFC efficiency, providing new insights into optimal anode design. Our methodology involves simulating different anode configurations to pinpoint the key parameters that affect exergy efficiency, thereby minimizing the experimental costs and time associated with traditional approaches. The quantitative results of this study are significant. We found that an anode tortuosity of 5.5 and a porosity range of 0.05–0.1 optimize exergy efficiency, achieving a 15% improvement compared to conventional designs. Additionally, a mean pore radius between 15 and 20 µm was identified as optimal for enhancing cell voltage. These findings elucidate the critical relationship between anode material properties and SOFC performance, offering a practical pathway to improving efficiency. This research provides a novel numerical approach to understanding and optimizing anode characteristics in SOFCs. By highlighting the importance of specific material properties, such as tortuosity and porosity, and demonstrating their impact on exergy efficiency, this study offers valuable guidance for future SOFC design and development.

Characterization of Ca-doped YCoO3 Perovskite-type oxide as cathode for solid oxide fuel cells

Solid oxide fuel cell (SOFC) uses solid oxide as an electrolyte and has a high-power generation efficiency. One of the major problems in the development of SOFC is the side reaction that occurs at the interface between the electrode and the electrolyte. (Y, Ca)CoO[Formula: see text] materials were evaluated as a new air electrode material to replace the conventional (La, Sr)CoO3 materials. Y[Formula: see text]Ca[Formula: see text]CoO[Formula: see text] has good compatibility with Y-stabilized ZrO2 (YSZ) electrolyte. In addition, the power generation performance was equal to or better than the conventional SOFC cells.

Development of conducting Bi0.5Sr0.5FeO3–δ-Gd0.1Ce0.9O2–δ composite cathodes for IT-SOFCs

Decreasing the working temperature of solid oxide fuel cells (SOFCs) to 400 °C–600 °C is a primary concern for current fuel cell research. Unfortunately decrease in operating temperatures leads to increase in cathode polarization, which deteriorates electrochemical activity of the cathode for oxygen reduction reaction (ORR). Consequently, the search of new cathode materialsis one of the critical bottle-neck towards the development of intermediate-temperature SOFCs (IT-SOFCs). In this study, we have successfully synthesized Bi0.5Sr0.5FeO3-δ and Bi0.5Sr0.5FeO3-δ-Gd0.1Ce0.9O2-δ((1-x) BSFO-xGDC) composite cathodes with varying compositions (x = 50, 40, 30, and 20wt%). The crystal structure, microstructure, electrochemical properties and performance stability of these composite cathodes have been comprehensively evaluated using techniques such as X-ray diffraction (XRD), scanning electron microscopy (SEM) and electrochemical impedance spectroscopy (EIS). Our results demonstrate that the introduction of Gd0.1Ce0.9O2-δ( GDC) has a significant impact on the electrochemical performance of the composite cathodes. Among the different compositions studied, the cathode with a composition of x = 70 wt% exhibits particularly promising electrochemical properties. The electrode resistance polarization of 70BiSFO-30GDC is 0.39 Ωcm2 and 0.8 Ωcm2 for symmetrical and half-cell at 600 °C. The preliminary results of this study reveal that the 70BiSFO-30GDC composite cathode demonstrates remarkable ORR activity. Further investigations and comprehensive analyses are warranted to validate and explore the full potential of the 70BiSFO-30GDC composite cathode in the context of SOFC applications.

Degradation Analysis of SOFC Performance for Long-Term Operation with High Fuel Utilization (2)

Solid oxide fuel cells (SOFCs) are a power generation technology with its high efficiency and low environmental impact, and the most important issue for SOFC for practical use is to improve reliability as well as high efficiency. A national project on SOFC development in Japan, “Development of advanced evaluation and analysis technologies for the durability of Solid Oxide Fuel Cells stacks (2020-),” has been initiated as a NEDO project in order to clarify their long-term durability and find dominant degradation factor for each SOFC stacks. Central Research Institute of Electric Power Industry (CRIEPI) has operated three kinds of different SOFC cell/stacks (flat-tubular and two kinds of planer) for durability under NEDO’s project, which have been developed by KYOCERA, MORIMURA SOFC Technology, and DENSO.Long-term durability tests of 20,000 hours have been conducted under high fuel utilization of 80% and 85%, which is close to the operating limit of each SOFC cell/stack for high efficiency, to evaluate the effects on the performance and degradation behavior of the cell/stack. In previous projects, we have developed an electrode polarization model that can accurately represent SOFC performance, including cell voltage and each overvoltage, under a variety of conditions. The degradation factors for durability of each SOFC cell/stack have been analyzed by using this model. The analysis revealed that the dominant degradation factors were increased cathode overvoltage and IR loss, similar to the SOFC cell/stacks that were modified from the previous project to improve their long-term durability. On the other hand, the degradation rate of cell voltage was higher at 85% than at 80% fuel utilization in one cell/stack, and the performance degradation factor analysis revealed that this difference was due to an increase in anode overvoltage at 85% than at 80% fuel utilization, where anode overvoltage was not the primary degradation factor.This work has been carried out under the projects (JPNP13001 and JPNP20003) of the New Energy and Industrial Technology Development Organization (NEDO), Japan as contract research. We would like to express our gratitude to NEDO, many SOFC developers, as well as to university partners and National Institute of Advanced Industrial Science and Technology (AIST).

Techno-Economic Optimization of SOC Design and Operating Conditions in a Solid Oxide Fuel Cell-Gas Turbine Hybrid System

In a circular economy, highly efficient energy conversion systems are paramount to maximize resource utilization and minimize waste production, including carbon dioxide emissions. Solid oxide fuel cell-gas turbine hybrid systems, which can reach efficiencies of greater than 75%-LHV, have demonstrated to be a promising technology on the way to cleaner power generation. During the energy transition period, solid oxide fuel cell-gas turbine hybrid systems are likely to be operated on natural gas, however, their scalability allows these systems to reach very high efficiencies even at small scales, enabling the use of distributed resources such as biogas. In this presentation the authors will discuss key performance and economic metrics of small-scale (10 MW) advanced solid oxide fuel cell-gas turbine hybrid systems and their relation to cell design and system design elements. Current challenges in solid oxide fuel cell development include thermal cell management and production cost. This presentation presents findings of how cell design parameters influence thermal gradients and specific solid oxide cell costs on a $/kW-basis under hybrid system operating conditions. Moreover, specific cell components are identified, and effects will be discussed that can synergistically reduce thermal stress and specific cell cost at the same time. Informed by this analysis, the optimized cell design is integrated into a solid oxide fuel cell-gas turbine hybrid system in order to provide a comprehensive analysis of system operating conditions under consideration of thermal cell gradients, and new insights into economics and levelized cost of electricity are provided. The presentation will discuss the impact of fuel utilization, operating voltage, and operating pressure upon the heat integration, system’s operating window, and power output. A discussion of economic parameters will highlight cost driving factors to inform research on the next generation of solid oxide cells.

Thermoelectrical comprehensive analysis and optimization of multi-stack solid oxide fuel cell system

Solid oxide fuel cell (SOFC) is one of the most promising power generation technologies for its high efficiency, low emission, and fuel adaptability. The power of a single SOFC stack is usually limited to about 1 kW to guarantee its reliability, and stacks are therefore integrated in series or parallel to meet load power demand. However, the performance of a multi-stack SOFC system predominantly depends on the configuration (electrical and gas path structure) of the stack module. Consequently, it is important for the development of SOFC to explore the influence of stack integration structure on system performance and thermal safety, and to further grasp the multi-stack design principles by analyzing the input-output characteristics of the system. The existing studies mainly focus on the electric performance-related parameters analysis and optimization of multi-stack, without considering the thermal safety, the laws of the integration structure influence on system performance and comprehensive optimization on system level. In this work, general multi-stack SOFC systems with four gas distribution structures constructed by four validated stacks are considered and their thermoelectrical performance is systematically investigated and optimized under operational constraints based on a completed multi-SOFC system model. Moreover, the input-output characteristics, thermoelectrical performance and operation rules of the multi-stack SOFC system analysis are conducted, and finally, the stack module design principles and optimal stack topology are obtained. The results show that the parallel connection of two serial stack branches is preferred and can reach the maximum net system efficiency of 42.90 % and maintain the maximum temperature gradient within 6.04 K/cm at a low cost.

Ni-doped Ba0.9Zr0.8Y0.2O3-δ as a methane dry reforming catalyst for direct CH4–CO2 solid oxide fuel cells

Fuel flexibility is one of the significant advantages of solid oxide fuel cells (SOFCs). The utilization of methane in SOFCs can not only reduce fuel costs, but also greatly expand its application scenarios, which is of great significance to the commercial development of SOFCs. However, when methane is directly used, Ni-based cermet anode suffers from coking, which seriously affects the durability of the cell. To alleviate the coking issue, a reforming layer outside the Ni-based anode-supporter was proposed in this study, and Ba0.9(Zr0.8Y0.2)1-xNixO3-δ (BZYNix, x = 0.05, 0.1, 0.15 and 0.2) was used as reforming layer material. Among BZYNix catalysts, BZYNi0.2 exhibited excellent catalytic activity toward dry reforming of methane, and methane conversion was as high as 85% at 750 °C. The excellent catalytic durability and coking-resistance of BZYNi0.2 were also confirmed. When BZYNi0.2 reforming layer was applied, the single cell fueled with CH4–CO2 fuel showed significantly improved electrochemical performance, durability and coking-resistance. The utilization of BZYNi0.2 reforming layer provides guidance for solving the coking issue of SOFC cermet anodes when fueled with hydrocarbon.

Some aspects of hydrogen oxidation in solid oxide fuel cell: A brief historical overview

Environmentally friendly and resource-efficient ways to generate, convert, store and transport electricity are important areas of scientific and technological development. Fuel cells are direct converters of chemical energy into electricity with low emissions of harmful components. One of the most promising types of fuel cells is the solid oxide fuel cell (SOFC). The electrical power generated by the SOFC is mainly limited by the ohmic resistance of the electrolyte and the polarization of the electrodes. The ohmic resistance can be reduced by reducing the thickness of the electrolyte. To reduce the polarization resistance, other approaches are needed, namely a detailed study of the mechanisms of electrode reactions and the determination of the nature of rate-determining stages. Until now, fuel oxidation at the anode of the SOFC, as opposed to oxygen reduction at the cathode, has not been well understood. Even for conventional nickel-ceramic anodes, there is no clear understanding of the nature of the rate-determining steps of hydrogen oxidation. This review provides a brief historical background on the development of SOFCs, some insights into the oxygen reduction mechanisms, and a more detailed review of the kinetics of hydrogen oxidation at SOFC anodes.

Nanoengineering of electrodes via infiltration: an opportunity for developing large-area solid oxide fuel cells with high power density.

Although nanoengineering of electrodes opens up the way to the development of solid oxide fuel cells (SOFCs) with improved performance, the practical implementation of such advances in cells suitable for widespread use remains a challenge. Here, the demonstration of large-area, commercially relevant SOFCs with two nanoengineered electrodes that display excellent performance is reported. The self-assembled nanocomposite La0.6Sr0.4CoO3-δ and Co3O4 is strategically designed and deposited into the well-interconnected Ce0.9Gd0.1O2-δ backbone as a cathode to enable an ultra-large electrochemically active region. The nanometer-scale Ce0.8Gd0.2O2-δ is deposited into a conventional Ni/yttria-stabilized zirconia (YSZ) anode to provide more active oxygen exchange kinetics and electronic conductivity compared to YSZ. The resulting nanoengineered cell with an effective size of 4 cm × 4 cm delivers a remarkable power output of 19.2 W per single cell at 0.6 V and 750 °C. These advancements have potential to facilitate the future development of high-performance SOFCs at a large scale by nanoengineering of electrodes and are expected to pave the way for the commercialization of this technology.

On the Technology of Solid Oxide Fuel Cell (SOFC) Energy Systems for Stationary Power Generation: A Review

This paper presents a comprehensive overview on the current status of solid oxide fuel cell (SOFC) energy systems technology with a deep insight into the techno-energy performance. In recent years, SOFCs have received growing attention in the scientific landscape of high efficiency energy technologies. They are fuel flexible, highly efficient, and environmentally sustainable. The high working temperature makes it possible to work in cogeneration, and drive downstream bottomed cycles such as Brayton and Hirn/Rankine ones, thus configuring the hybrid system of a SOFC/turbine with very high electric efficiency. Fuel flexibility makes SOFCs independent from pure hydrogen feeding, since hydrocarbons can be fed directly to the SOFC and then converted to a hydrogen rich stream by the internal thermochemical processes. SOFC is also able to convert carbon monoxide electrochemically, thus contributing to energy production together with hydrogen. SOFCs are much considered for being supplied with biofuels, especially biogas and syngas, so that biomass gasifiers/SOFC integrated systems contribute to the “waste to energy” chain with a significant reduction in pollution. The paper also deals with the analysis of techno-energy performance by means of ad hoc developed numerical modeling, in relation to the main operating parameters. Ample prominence is given to the aspect of fueling, emphasizing fuel processing with a deep discussion on the impurities and undesired phenomena that SOFCs suffer. Constituent materials, geometry, and design methods for the balance of plant were studied. A wide analysis was dedicated to the hybrid system of the SOFC/turbine and to the integrated system of the biomass gasifier/SOFC. Finally, an overview of SOFC system manufacturing companies on SOFC research and development worldwide and on the European roadmap was made to reflect the interest in this technology, which is an important signal of how communities are sensitive toward clean, low carbon, and efficient technologies, and therefore to provide a decisive and firm impulse to the now outlined energy transition.

Ruthenium Doped Lscf Based Cathode for Enhanced Performance of Solid Oxide Fuel Cells

Recently, a tremendous upsurge in the research of Solid oxide fuel cells (SOFCs) has been documented due to cheap electricity production and without harming the environment. The development of efficient SOFCs requires more robust cathode for oxygen reduction. Until yet a copious amount of research has been done on varieties of materials including LSCF. In this work, Ruthenium is doped on the LSCF forming nanostructured Ru-LSCF with various Ru stoichiometric quantities. The Ru-LSCF catalyst is prepared via simplistic technique “Glycine combustion process”, producing evenly embedded Ru in LSCF perovskite materials leading to increased oxygen reduction reaction (ORR). The nanostructured Ru-LSCF cathode showed polarization resistance of approximately 0.031 Ωm2 at 750 0C. The peak powers of approximately 1760.5, 1480.1, 893.3 mW/cm2 were recorded at 750, 700, and 650 0C, respectively. Ru LSCF was quantitatively optimized for enhanced power production with high precision calculation. The results show that the Ru-LSCF optimum fabricated nanostructured cathode is promising catalyst for the reduction of oxygen at the cathode side for highly durable SOFCs.

Performance and durability of Ni–Co alloy cermet anodes for solid oxide fuel cells

Ni alloys are examined as redox-resistant alternatives to pure Ni for solid oxide fuel cell (SOFC) anodes. Among the various candidate alloys, Ni–Co alloys are selected due to their thermochemical stability in the SOFC anode environment. Ni–Co alloy cermet anodes are prepared by ammonia co-precipitation, and their electrochemical performance and microstructure are evaluated. Ni–Co alloy anodes exhibit high durability against redox cycling, whilst the current-voltage characteristics are comparable to those of pure Ni cermet anodes. Microstructural observation reveals that cobalt-rich oxide layers on the outer surface of the Ni–Co alloy particles protect against further oxidation within the Ni alloy. In long-term durability tests using highly humidified hydrogen gas, the use of a Ni–Co cermet with Gd-doped CeO2 suppresses degradation of the power generation performance. It is concluded that Ni–Co alloy cermet anodes are highly attractive for the development of robust SOFCs.

Space charge layer evolution at yttria-stabilized zirconia grain boundaries upon operation of solid oxide fuel cells

Long-lasting solid oxide fuel cells (SOFC) rely upon an intact ionically conducting network in both the electrolyte and electrode. Understanding the impact of the high-temperature electrochemical operations on the possible nanostructure evolutions of ionic conductors is indispensable for the development of durable SOFC. Here we present possibly the first experimental evidence of space charge layer evolution of grain boundaries (GBs) of ionic conducting yttria-stabilized zirconia (YSZ) in a Ni/YSZ composite anode of SOFCs. Cells with identical Ni/YSZ composite anodes are either thermally treated or electrochemically operated using either dry or humidified H2 fuel for up to 3,349 h. When operating under humidified H2 fuel, a discrete core-shell structure is found to develop exclusively along the YSZ/YSZ GB planes. The core-shell structure is elliptically shaped elongated along the GB planes. The core has a lower mass with a Y-depleted ZrO2-x with a cubic structure. The shell has a constant thickness of ∼1 nm and is Y-enriched. The nucleation and growth mechanisms of the core-shell structure are proposed in terms of the space charge layer evolution at YSZ GBs. The effect of the humidity in the fuel, the cell operating temperatures, and the current density on the formation of the core-shell structure is investigated.

Short review on global trends in SOFC scenario and future perspective

Solid oxide fuel cells (SOFCs) are high-efficiency cogeneration devices that can improve the efficiency and cost-effectiveness of various fuels: hydrocarbon, coal gas, biomass, hydrogen, and other renewable fuels. Several types of SOFCs have been used in a variety of applications, including grid-scale, stationary, and portable power generation. Ceramic materials with high chemical stability, good mechanical strength, and low activation energy are used in SOFC technology. However, the high cost of the catalyst and its operating conditions are significant barriers to commercialization. This review summarises current progress in SOFC development, focusing on; (i) current trends and publication patterns and (ii) challenges and opportunities in the SOFC advancements.

Suppression of Sr surface segregation in La0.8Sr0.2Co0.2Fe0.8O3-δ via Nb doping in B-site

Sr surface segregation has been one of the main reasons for the cathode performance degradation during the long-term operation of solid oxide fuel cells (SOFC). Investigation on Sr segregation mechanism and proposing strategies on suppressing the Sr surface segregation are significant for SOFC development. In this paper, La 0.8 Sr 0.2 Co 0.2 Fe 0.8-x Nb x O 3-δ (LSCFNb, x = 0, 0.02, 0.04, 0.06, 0.08 and 0.1) are prepared via sol-gel method. The electrochemical performance and long-term stability are tested through electrochemical impedance spectroscopy (EIS) and constant current polarization. The results show that the long-term stability of LSCFNb cathodes are strongly affected by Nb content. Combining the results of ICP and XPS, it's revealed that the Sr surface segregation can be effectively suppressed with the increase of Nb content. The LSCFNb cathodes gain the optimal electrochemical performance when x = 0.04, with minimum polarization resistance of 0.27 Ω cm 2 at 750 °C and oxygen reduction reaction activation energy of 1.54 eV. After cathodic polarization for 144 h, the polarization resistance and activation energy of LSCFNb4 cathode increase slightly, revealing it a promising cathode material for SOFC research.

Recent Progress in Semiconductor-Ionic Conductor Nanomaterial as a Membrane for Low-Temperature Solid Oxide Fuel Cells.

Reducing the operating temperature of Solid Oxide Fuel Cells (SOFCs) to 300–600 °C is a great challenge for the development of SOFC. Among the extensive research and development (R&D) efforts that have been done on lowering the operating temperature of SOFCs, nanomaterials have played a critical role in improving ion transportation in electrolytes and facilitating electrochemical catalyzation of the electrodes. This work reviews recent progress in lowering the temperature of SOFCs by using semiconductor-ionic conductor nanomaterial, which is typically a composition of semiconductor and ionic conductor, as a membrane. The historical development, as well as the working mechanism of semiconductor-ionic membrane fuel cell (SIMFC), is discussed. Besides, the development in the application of nanostructured pure ionic conductors, semiconductors, and nanocomposites of semiconductors and ionic conductors as the membrane is highlighted. The method of using nano-structured semiconductor-ionic conductors as a membrane has been proved to successfully exhibit a significant enhancement in the ionic conductivity and power density of SOFCs at low temperatures and provides a new way to develop low-temperature SOFCs.

Development of High-Performance Anode-Supported Planar SOFC with Large Area by 4-Layer Co-Firing Process

Solid oxide fuel cell (SOFC) technology has attratced great attention because of higher efficiency, fuel flexibility and eco-friendly stationary power generation system. However, its commercialization is hindered due to the lack of durability and high cost. Herein, a facile and exceptionally reliable 4-layered anode supported SOFCs with a large area (12cm×12cm) was fabricated in a single step co-firing process at 1400 oC, in which tape-casted green films of NiO-YSZ, NiO-1CeScSZ, 1CeSxSZ, and GDC were laminated by isostatic press. The fabrication parameter such as viscosity of the slurries and mechanical strengths of the green films, etc. were optimized. As a result, finely porous anode layer, and highly dense 1CeScSZ electrolyte and GDC buffer layers on a robust porous anode-support were formed successfully. The LSC cathode was screen-printed on the GDC layer. The possibility of mass production of this process are verified through the fabrication of large area cells with an active area 100cm2. The single cell showed high power output of 38 W at total current 50A at 700°C and exhibits low degradation rate of 0.2% kh-1 at 25A for long-term test of 1000 hrs. This facile strategy is time-efficient, reproducible, cost-effective, and highly practical to produce SOFC system satisfying both high-performance and durability.

Influence of Active Layer Thickness of Reversible Solid Oxide Cells on the Electrochemical Performance of Water Electrolysis

Reversible solid oxide cell technology (RSOC) is a potential method for stabilizing intermittent green power sources. RSOC can act as a solid oxide fuel cell (SOFC) or as a solid oxide electrolysis cell (SOEC). Development of SOFCs has been in focus for decades but SOEC systems have received much less attention by researchers. In this work commercial solid oxide cells (SOC) with modified hydrogen electrode active layers have been studied in SOEC mode at various operating conditions to determine the effect of the active layer thickness on the performance of the SOC in SOEC mode. Commercial SOCs with different hydrogen electrode active layer thicknesses (0, 7, 12, 16, and 20 µm) were characterized electrochemically and fitted via the complex non-linear least squares fitting method. The best performances were achieved for SOEC with the 7, 12, and 16 µm active layer thicknesses depending on the operating conditions applied. The maximum current density measured for the cell with a 7 µm thick active layer at 800°C and at 90% water vapor content was ~3.5 A/cm2 at 1.4 V.

Development of High-Performance Anode-Supported Planar SOFC with Large Area by 4-Layer Co-Firing Process

Solid oxide fuel cell (SOFC) technology has attracted great attention because of higher efficiency, fuel flexibility, and eco-friendly stationary power generation system. However, its commercialization is hindered due to the lack of durability and high-cost. Herein, a facile and exceptionally reliable 4-layered anode supported SOFCs with a large area (12cm×12cm) was fabricated in a single step co-firing process at 1400°C, in which tape-casted green films of NiO-YSZ, NiO-1CeScSZ, 1CeScSZ, and GDC were laminated by isostatic press. The fabrication parameter, such as viscosity of the slurries and mechanical strengths of the green films, were optimized. As a result, finely porous anode layer, and highly dense 1CeScSZ electrolyte and GDC buffer layers on a robust porous anode-support, were formed successfully. The possibility of mass production is verified through the fabrication of large area cells with an active area 100 cm2. The single cell showed high-power output of 28 W at total current 50 A at 700°C and exhibits low degradation rate of 0.2%/kh at 25A for long-term test of 1000 hrs. This facile strategy is time-efficient, reproducible, cost-effective, and highly practical to produce SOFC system satisfying both high-performance and durability.