Destruction Efficiency Research Articles

Low-Temperature Oxidation Pathways are Critical to Thermal Incineration of PFAS-Laden Materials

With growing desire to destroy per- and poly-fluoroalkyl substances (PFAS) now known to be detrimental to human health, a sound understanding of fluorocarbon combustion chemistry is important to efficient thermal destruction within incinerators. While most fluorocarbon combustion models and the sets of reactions contained within them were originally developed for the high temperatures encountered in flame suppression applications, they have often been used to assess PFAS destruction in incinerators, which emphasize a lower range of temperatures. We present results that demonstrate that low-temperature fluorocarbon oxidation pathways—not yet known to play a role in fluorocarbon combustion—impact key incinerator performance metrics, including: PFAS surrogate mole fractions, products of incomplete destruction, and waste destruction efficiencies. The results further point to the utility of NO as a potential additive. The present results show the influence of these pathways for CF3O2, for which some data are available, but analogous pathways would also occur for other fluoroalkylperoxy radicals, for which little is known. The results demonstrate the need for future work to identify and characterize low-temperature pathways more generally, consider such pathways in kinetic model development, and experimentally probe intermediate temperature conditions to better understand, design, and control thermal destruction technologies for improved PFAS management.

Study on the Destruction and Removal Efficiency (DRE) of Perfluorinated Compound Gases Used in Semiconductor and Display Processes in Korea: DRE and Uncertainty by Scrubber Type

In Republic of Korea, plasma scrubbers are a common technology employed in the semiconductor and display industries. However, there are numerous other types of scrubbers in use. The Intergovernmental Panel on Climate Change (IPCC) does not provide destruction and removal efficiencies (DREs) specific to individual scrubbers, only DREs specific to greenhouse gases, which makes it challenging to consider the specific effects of different types of scrubbers. The semiconductor and display industries in Korea represent a significant market share and are experiencing a steady increase in emissions, underscoring the need for research on GHG-reducing DREs to effectively manage these emissions. In this study, data on Tier 3 DREs developed based on measurements from companies subject to GHG management were collected. The findings indicated that C3F8 gas exhibited a comparable performance to the 2019 IPCC G/L (guideline) for plasma and combustion wet scrubbers, although it surpassed the 2006 IPCC G/L value. The catalytic scrubbers exhibited values that were comparable to the 2006 IPCC G/L, but lower than the 2019 IPCC G/L. The uncertainties were minimal for c-C4F8 gases, both in the absence of consideration of the scrubber type and when each scrubber type was taken into account. In contrast, the uncertainties associated with CF4 gases were relatively high, depending on the scrubber type. Although there are differences between the greenhouse gases in question, failing to take the type of scrubber into account could result in under- or overestimates of certain emissions. Therefore, it would be beneficial to develop coefficients that take this into account, particularly where information on scrubbers by gas type is available.

Enhanced methylene blue degradation and miniralization through activated persulfate coupled with magnetic field

In this work, for the first time, the effectiveness of the degradation and mineralization process of methylene blue) MB) was investigated using activated persulfate (PS) with a magnetic field. The effect of various operating parameters, including pH, PS (5–20 mg/L), intensity of the magnetic field (1–4 A), initial concentration of methylene blue dye (25–100 mg/L), and contact time (30–120 min), was evaluated. Process optimization was conducted via the Taguchi model, and the optimal values of these factors were found to be pH = 5, PS = 10 mg/L, MFs = 4 A, reaction time = 30 min, and the initial concentration of methylene blue dye = 50 mg/L. Under optimal conditions, the methylene blue removal efficiency and TOC destruction efficiency reached 91.8% and 88%, respectively. The kinetics of the process followed pseudo-second order (R2 = 0.9723). According to the promising results of the research, the efficiency of dye purification using a magnetic field has increased by about three times compared to the state without this factor. It can be suggested that this system be used as a wastewater treatment process for the textile industry to reduce the toxicity of wastewater and total organic carbon (TOC).

Exergetic characterization of flat plate solar collector using genetic algorithm

With the rapid advancement of technology, the global demand for energy is increasing exponentially. It is crucial to focus on energy conservation and conversion across all sectors. This study conducted a second law or exergy analysis on a solar water heating system to uncover hidden losses during the process. To optimize exergetic efficiency, a genetic algorithm was employed to control the overall loss coefficient of a solar flat plate collector. Four decision variables were used in the genetic algorithm—heat flux rate, glass cover temperatures at the inlet and exit, and collector plate temperature to minimize the overall loss coefficient. Energy efficiency, entropy generation, and exergy destruction were estimated for various mass flow rates using thermodynamic equilibrium equations. Exergy correlations were developed concerning mass flow rate (0.001–0.009 kg/s), inlet temperature (300 K–360 K), collector plate area (1–10 m²), incident solar energy (400–900 W/m²), optical efficiency (0.4%–1%), and ambient temperature (300–315 K) under a range of initial conditions. It was found that exergy efficiency slightly increased (0.01%–0.08%) over a 12-h period. Although this increase is small, it can significantly contribute to energy conservation over the long term. The genetic algorithm predicted the minimum loss coefficient occurring during peak hours (12–14 p.m.) with respect to four decision variables. The results of this study were compared with existing literature and showed good agreement. In addition to the exergy analysis, an uncertainty error analysis was performed to assess the reliability and accuracy of the experimental measurements and computational predictions. By quantifying these uncertainties, the study ensured that the reported enhancements in exergy efficiency and the optimization results obtained through the genetic algorithm are robust and credible. This rigorous error analysis adds confidence to the findings, highlighting the potential for improved energy conservation in solar water heating systems.

IMPLEMENTASI ALGORITMA BLOWFISH PADA SISTEM MANAJEMEN SURAT DENGAN PENDEKATAN RATIONAL UNIFIED PROCESS YANG RAMAH LINGKUNGAN

In many organizations, including the Institut Teknologi Perusahaan Listrik Negara (ITPLN), letter management and organization is very important. This process is often resource-intensive and time-consuming. With the advancement of information technology, a secure digital system can help optimize letter management. The implementation of Blowfish cryptographic algorithm for encryption of important data on letter stored in a digital-based letter management system is the subject of this research. This method lowers the potential for eavesdropping and data theft. In the development process of this system, the Rational Unified Process (RUP) methodology takes the principle of green computing, which helps improve the efficiency of environmental destruction. The system adopts a paperless office paradigm, addresses the issue of operational inefficiencies, and safeguards sensitive data. The Blowfish algorithm prevents irresponsible people from compromising the database. This research produces a secure letter management information system using blowfish algorithm and developed using RUP that is environmentally friendly in contribution to the efficiency of environmental destruction caused by software development. Keywords: Blowfish Algorithm, Rational Unified Process, Data Security, Letter Management, Eco-Friendly Software

Thermodynamic analysis of an advanced adiabatic compressed air energy storage system integrated with a high-temperature thermal energy storage and an Organic Rankine Cycle

Advanced adiabatic compressed air energy storage (AA-CAES) system has drawn great attention owing to its large-scale energy storage capacity, long lifespan, and environmental friendliness. However, the performance of the air turbine during the discharging process is limited by the low temperature of the compression heat. Thus, this study proposes an integrated AA-CAES system incorporating high-temperature thermal energy storage and an Organic Rankine Cycle (ORC). The high-temperature thermal energy storage is introduced to heat the discharging compressed air to enhance the air turbine performance, and the Organic Rankine Cycle is integrated to utilize the waste heat. Notably, two preheaters are deployed in a special tandem to recover the heat from the air exiting the turbine and the water exiting the hot water tank, respectively. This paper develops a thermodynamic model to simulate the proposed system, assessing the effects of heat storage temperature, ambient temperature, and inlet conditions of the air turbine on performance metrics, including exergy efficiency and exergy destruction. The simulation results indicate that, compared to thermal oil and Hitec salt, employing solar salt as the heat storage medium for the solar thermal collection and storage unit yields the best performance. The energy storage efficiency, roundtrip efficiency, exergy efficiency, exergy conversion coefficient, and energy storage density of this system are 115.6 %, 65.7 %, 78 %, 79.4 %, and 5.51 kWh/m3, respectively. Exergy analysis reveals that the exergy efficiency of interheaters (IH) is the lowest at 76.7 %, while air turbines (ATBs) exhibit the highest exergy efficiency at 91.2 %. Moreover, due to the irreversible processes of compression, expansion, and throttling, ATBS, compressors, and throttle valves collectively contribute to an exergy destruction rate as high as 79.2 %. The parameter analysis demonstrates that low ambient temperature, high inlet temperature, and high inlet pressure of the air turbine enhance energy storage performance.

Mineralization of fluoropolymers from combustion in a pilot plant under representative european municipal and hazardous waste combustor conditions

The goal of this study was to provide data to support mineralization of fluoropolymer waste and insignificant generation of PFAS as products of incomplete combustion (PIC) during incineration of fluoropolymer applications at their end-of-life. Destruction efficiency is not an acceptable metric to indicate mineralization and therefore we need to look for and measure products of incomplete destruction. A mixed sample of fluoropolymers representing 80% of commercial fluoropolymers was combusted at conditions representative of municipal and industrial waste incinerators operating in EU. State-of-the-art emission sampling and analytical methods (UPLC-MS/MS, GC-MS) were used for identifying and quantifying those PFAS whose standards were available. Statistical analysis of the results confirmed non-detect to negligible levels of PFAS evidencing mineralization of fluoropolymers.

Enhancing energy efficiency: Design and simulation of air fractionation unit integrated through LNG cold energy and two‐stage organic Rankine cycles

AbstractThe study explores air separation processes, proposing an innovative design incorporating liquid natural gas (LNG)'s two‐stage Rankine cycles to address traditional approaches' complexity and energy intensity. Significant wastage of energy during air compression in standard units is recuperated for liquefied natural gas regasification, with a focus on enhancing cold energy recovery, emphasizing cryogenic LNG advantages. Aspen HYSYS (12.1) is used for process modelling and simulation evaluating a combined two‐stage Rankine cycle integrated into air separation. Specific energy requirements for high‐purity oxygen and nitrogen production are reduced to 0.38 and 0.12 kWh/kg, respectively. The integrated Rankine cycle generates 4456.32 kW, which is sufficient for air separation process. Exergy destruction and component efficiency are explored and parametric optimization, revealing LNG variables' significant impact. Economic analysis indicates a fair 5.25‐year payback period. This approach aligns with sustainability goals, providing a compelling efficiency‐enhancing option for the LNG sector.

Catalytic Heaters at Oil and Gas Sites May be a Significant yet Overlooked Seasonal Source of Methane Emissions.

Successful reduction of oil and gas sector methane emissions to meet near-zero intensity targets requires the identification and mitigation of all possible sources. One potentially important source is catalytic heaters, which have largely escaped attention in regulatory and mitigation efforts despite being ubiquitous at upstream production sites in cold climate regions. This study reports direct in situ measurements of the exhaust streams of 38 natural gas-fired catalytic heaters at upstream production sites in British Columbia, Canada. All heaters in the sample showed consistently poor methane conversion with mean destruction efficiencies of 61 ± 5% while releasing 235 [+31/-28] g of methane per cubic meter of fuel. Although individual units are generally small methane sources (mean of 0.28 ± 0.04 kg/h), their prevalence means they could represent 6% of the total provincial upstream methane inventory and as an aggregate methane source could be 5× more significant than abandoned wells. Notably, these heaters are seasonal sources whose emissions would be missed in measurement campaigns occurring solely in summer months. However, additional measurements from a small number of heat medium burners demonstrate that, where feasible, methane emissions can be reduced by approximately 425× by replacing catalytic heaters with centralized heat systems.

Fabrication of a reusable carbon quantum dots (CQDs) modified nanocomposite with enhanced visible light photocatalytic activity

In awareness of industrial dye wastewater, carbon quantum dots (CQDs) and cobalt zinc ferrite (CZF) nanocomposites were synthesised for the making of carbon quantum dots coated cobalt zinc ferrite (CZF@CQDs) nanophotocatalyst using oxidative polymerization reaction. The results of TEM, zeta potential value, and FTIR confirm highly dispersed 1–4 nm particles with the − 45.7 mV carboxylic functionalized surface of CQDs. The results of the synthesised CZF@CQDs photocatalyst showed an average particle size of ~ 15 nm according to TEM, SEM, and XRD. The photocatalyst showed a 1.20 eV band gap, which followed the perfect visible light irradiation. TGA and DTA revealed the good thermal stability of the nanophotocatalyst. VSM was carried out, and the saturation magnetisations for CZF and CZF@CQDs were 42.44 and 36.14 emu/g, respectively. A multipoint study determined the BET-specific surface area of the CZF@CQDs photocatalyst to be 149.87 m2/g. Under visible light irradiation, the final CZF@CQDs nanophotocatalyst demonstrated remarkable efficiency (~ 95% within 25 min) in the photocatalytic destruction of Reactive Blue 222 (RB 222) and Reactive Yellow 145 (RY 145) dyes, as well as mechanical stability and recyclability. Even after the recycling of the degradation study, the nanophotocatalyst efficiency (~ 82%, 7th cycles) was predominantly maintained. The effects of several parameters were also investigated, including initial dye concentration, nanophotocatalyst concentration, CQD content, initial pH of the dye solution, and reaction kinetics. Degradation study data follow the first-order reaction rate (R2 > 0.93). Finally, a simple and low-cost synthesis approach, rapid degradation, and outstanding stability of the CQD-coated CZF nanophotocatalyst should make it a potential photocatalyst for dye wastewater treatment.

Vegetation restoration in the coarse‐textured soil area is more conducive to the accumulation of Fe‐associated C

Abstract Vegetation restoration has an important effect on soil carbon (C) pool dynamics. Highly stable iron (Fe)‐associated C is an important component of the soil C pool and it plays a crucial role in the soil C cycle. However, a knowledge gap remains regarding the existence of Fe‐associated C variation during vegetation restoration. Herein, 0–60 cm soil samples of cropland, grassland, shrubland and forestland from three soil types (loam, loess and sandy soils) were collected to explore the response of Fe‐associated C to vegetation restoration. The results showed that soil Fe‐associated C proportion in the study area ranged from 2.2% to 26.3%. Surface soil (0–20 cm) Fe‐associated C content in loess and sandy soils increased following vegetation restoration, but decreased in loam soil. The accumulation efficiency of soil Fe‐associated C during vegetation restoration was higher in coarser soils. Moreover, the Fe‐associated C content and proportion of forestland with a higher soil organic matter (SOM) pool were the highest among the land use types. Vegetation restoration affects soil Fe‐associated C in two different ways: (1) increasing the SOM and dissolved organic C and improving the efficiency of C and Fe binding to promote the accumulation of Fe‐associated C; (2) decreasing the total soil Fe content, reducing the trivalent iron (Fe(III)) to bivalent iron (Fe(II)) and breaking the binding of C and Fe to decrease soil Fe‐associated C content, and these two different ways were found in all three soil types. Additionally, higher SOM accumulation efficiency and less root destruction caused by vegetation restoration in coarse soils resulted in a higher Fe‐associated C accumulation efficiency. Synthesis and applications. Vegetation and soil type strongly regulated the effects of vegetation restoration on soil Fe‐associated C. Forestlands may be the optimum vegetation type to provide soil C sequestration benefits, effectively increasing soil C pool and maximising Fe‐associated C content. This study has addressed the knowledge gap regarding the effects of vegetation restoration on soil Fe‐associated C and provides scientific basis for a better understanding of the soil C cycle and developing scientific vegetation restoration measures.

Performance Evaluation of Novel Advanced Recompression Absorption Refrigeration Systems Equipped with Ejector and Vapor Injection Technology

The absorption refrigeration cycle (ARC) faces challenges considering its decreased working pressure and COP. By integrating Recompression technology (RAC) into ARC, these issues are partly addressed. To address these inefficiencies, in this study, ejector and vapor injection techniques are incorporated into refrigerant side of the RAC cycle, resulting in the development of advanced systems: Refrigerant ejector enhanced recompression absorption cycle (RE-RAC) and Vapor injection enhanced recompression absorption cycle (VI-RAC). Key metrics assessed are 1st and 2nd law efficiency, system exergy destruction rate, compressor load, and generator heat requirements. Conclusively, under analogous operating conditions, RE-RAC and VI-RAC demonstrate a substantial improvement in COP, achieving 76 % and 63 % enhancements, respectively, over the standard RAC system. Compared to the conventional solution ejector-based SE-RAC, these systems show performance increases of 28 % and 19 %, respectively. The findings also highlight the sensitivity of these systems to parameters such as generator temperature and pressure, evaporator temperature, absorber temperature, evaporator recovery and normal pressure ratio. At higher evaporator temperature and lower generator temperature, the performance of these systems as well as enhancement of RE-RAC over VI-RAC is higher observed. The optimal value of generator pressure and recovery pressure ratio for maximum efficiency and minimum total exergy destruction rate is also dependent upon these. At a generator temperature of 67 °C and an evaporator temperature of 8 °C, RE-RAC exhibits a 35 % higher COP compared to VI-RAC. However, at −10 °C evaporator temperature, changes in external generator heat input and compressor work reduce the COP enhancement to 5 %.

CO2 emission reduction by geothermal-driven CCHP tailored with turbine bleeding and regeneration CHP; economic/multi-aspect comparative analysis with GA-based optimization

The current research compares a geothermal-driven combined cooling, heating, and power generation cycle (B–CCHP) and a modified version using turbine bleeding and regeneration process named the TBR-CCHP cycle. These cycles incorporate organic Rankine systems, an ejector cooling system, and a heat pump system. The procedure of this study entails (i) introduction of an innovative CCHP setup, (ii) structural modification of the devised cycle, (iii) evaluation based on thermodynamic laws, (iv) optimization through GA, (v) sensitivity (vi) evaluation of the design parameters, Profitability assessment. The results indicate that the TBR-CCHP system achieves the most significant energy and exergy efficiencies with values of 87.83 % and 70.29 %, respectively. The system demonstrates heating load, cooling load, net electricity production, and total exergy destruction values of 80.38 kW, 24.26 kW, 34.44 kW, and 22.32 kW, respectively. Through optimization using genetic algorithm, improvements in energetic efficiency, exergetic efficiency, and overall energy destruction of 7.93 %, 25.53 %, and 34.83 % are seen in the B–CCHP system, and 7.37 %, 19.87 %, and 33.43 % in the TBR-CCHP system. The study reveals that in the TBR-CCHP system, the compressor is identified as the primary source of irreversibility, with reduced irreversibility during optimization. A comprehensive examination of critical parameters of the cycles indicates the significance of optimizing the generator pressure. Also, the payback period in the modified system is reduced to 6.72 years compared to the base cycle, which has a value of 8.43 years.

Modification of crystalline graphitic carbon nitride for improve efficiency in photocatalytic destruction of volatile organic compounds (VOCs) under visible light irradiation

In this study, we show that the use of a mixture of melamine and oxalic acid during the synthesis of acid-treated crystalline graphitic carbon nitride samples significantly enhances its photocatalytic activity in VOCs destruction processes. The rate of photocatalytic ethanol destruction with the participation of modified crystalline graphitic carbon nitride obtained under optimal conditions is 67.1 μmol h−1, which is almost twice higher than sample synthesized in the absence of oxalic acid, and is two orders of magnitude higher than the activity of bulk g–C3N4. The synthesized materials were characterized using XRD, FT-IR, UV–Vis, PL, SEM, and EDXA methods. The high activity of the modified carbon nitride samples is attributed to increased light absorption in the visible region of the spectrum and better crystallinity, which can lead to more efficient separation and transport of photogenerated charges. To our knowledge, the effect of the simultaneous use of melamine and oxalic acid for obtaining acid-treated crystalline graphitic carbon nitride is, shown for the first time.

The role of specific energy consumption in a heat recovery system for cassava starch production using an integrated agro-industrial system

BackgroundReducing energy consumption and greenhouse gas emissions is a crucial issue in the cassava starch processing industry. In this study, the integrated system combining livestock, cassava cultivation and cassava production in the same area leads to both a zero emission goal and economic efficiency, a typical example of an effective agro-industrial symbiosis. A heat exchange/recovery system was applied including the economizer, heat exchanger tank, biogas tank, and boiler. The economizer attached to the boiler’s chimney transfers heat from exhaust gases for pre-heating feed water entering the boiler. The biogas tank recovers energy from the wastewater of starch production and livestock, and the generated biogas was used as fuel for the boiler.ResultsThe energy and exergy efficiency, energy losses, and exergy destruction for the heat recovery system were analyzed. The specific energy consumption was used to evaluate the overall energy efficiency for a cassava starch factory with a capacity of 20 tons/day. The results show that there is a high potential to recycle waste into energy in the cassava starch industry. The total energy saving and reduced greenhouse gas emissions per year of the cassava starch factory were 0.054%/year and 123,564 kgCO2/per year, respectively.ConclusionsCassava starch factories can save energy and reduce emissions when applying a heat recovery system in the integrated agro-industrial system. Excess heat from the production was used for evaporating (removal of) NH3 in wastewater flow from the biogas tank, and for heating the biogas system to enhance the efficiency of methane production. A biochar filter was attached to the economizer for adsorption of released ammonium, and the biochar after adsorption was combined with sludge from the biogas tank to produce a solid biofertilizer.

Effects of air to fuel ratio on parameters of combustor used for gas turbine engines: Applications of turbojet, turbofan, turboprop and turboshaft

Combustors of gas turbine engines have generally the highest irreversibility due to the combustion process. Therefore, to observe influence of air to fuel ratio (AFR) on combustor performance is of high importance. In this study, thermodynamic laws are employed to separately determine adiabatic flame temperature (AFT), entropy production, exergy destruction and exergy efficiency of combustor for turbojet (TJ), turbofan (TF), turboprop (TP) and turboshaft (TS) where variables are AFR, combustor inlet temperature (CIT) and combustor pressure ratio (CPR). In this regard, the higher the AFR, the lower the adiabatic flame temperature, however the higher the entropy production for related combustor. Similarly, increasing AFR leads to raise exergy destruction, thereby lowering exergy efficiency. On the other hand, as CIT increases, exergy efficiency of the combustor improves whereas slight effects of CPR on the combustor metrics are observed. Namely, due to variation of AFR, exergy destruction of combustor changes between 0.512 MW and 0.825 MW for TJ, between 1.807 MW and 2.735 MW for TS, between 28.38 MW and 40.49 MW for TF and between 3.102 MW and 4.564 MW for TP. Moreover, exergy efficiency of combustor changes between 59% and 73% for TJ, between 70% and 77% for TS, between 78% and 81% for TF and between 75% and 79% for TP engine through the determined AFR and CIT ranges. These findings indicate that combustor of each gas turbine engine demonstrates different behavior according to the mentioned variables and exergy efficiency of combustor depends on finding the optimum points of combustor variables.

Design, simulation and investigation of the tri-generation process of fresh water, power and biogas using solar thermal energy and sewage sludge

To address the high demand for energy and fresh water, the effect of global warming and pollution generated by fossil fuels consumption needs to be minimized and replaced with alternative renewable energy. Hybrid renewable energy systems using solar energy and biomass will become more crucial. In this study a new design for continuous production process of power, biogas and fresh water is proposed. The challenge of the present research is to use different sources for energy production from renewable resources simultaneously including solar and biomass to produce power, fuel and fresh water, using 4-stage Multi Effect Distillation (MED) for desalination of seawater. To cope with constant and stable energy production required for renewable solar power plants at night, due to lack of sunlight, co-consumption of hybrid solar and biomass feedstocks is considered in this paper. The associated challenge is discussed by the assessments of Solar Heat transfer fluid (SHTF), Sewage sludge flowrates, biogas production, output waste stream of gasification reactor, power and fresh water production using ASPEN Plus software. The sensitivity analysis was performed to demonstrate the viability of the designed process and the resulting products. The gasification process produced 76.8586 tonh syngas (CO and H2). Also, 34.547 MW of power with about 783 m3h of fresh water were produced with the overall exergy efficiency of 35.51 %, 52.260 MW exergy destruction and desalination efficiency of 52 %. Only 25 MW of solar power were necessary due to proper energy recovery throughout the entire process. The productivity of fresh water production was 50 %. 38908 m2 of Parabolic trough collector (PTC) was needed to supply required solar energy during day light hours. It was revealed that the hybridization of solar & biomass energy resources for producing power, fresh water, and biogas could be a sustainable approach to cope with the increasing demand for fresh water, electricity, and fuel.

Blast wave interaction during explosive detonation in a variable cross-sectional charge

Purpose. The research aims to assess the efficiency and performance of solid media destruction in directed blasting of a charge with variable cross-sectional shape. Methods. Numerical modelling of the blast wave interaction process is performed using the finite element method based on the Euler-Lagrange algorithm. The Johns-Wilkins-Lee equation of state is used to determine the pressure-volume dependences of medium destruction. Assessment of solid medium destruction mechanism during a directed blasting of a charge with variable cross-sectional shape is carried out based on polarization-optical method on models made of optically active material. Findings. Experimental studies of solid medium destruction by the action of directed blasting with a variable cross-section charge made it possible to determine the direction of blast wave propagation and its amplitude in stress wave, influencing the intensity of radial crack network formation in superposition areas, and directed perpendicularly to explosive cavity. At the same time, the average peak pressure in collision zone of two shock waves in centre of spherical cavity is approximately 1.48 and 1.84 times higher than that in weakly blast-loaded areas. It has been found that when two shock waves collide and superimpose on each other, the intensity of their impact increases. Moreover, the shock wave velocity in collision zone is higher than that of the radial shock wave. Originality. It has been determined that the maximum pressure values on the explosive cavity wall at the initiation points sharply increase and then gradually stabilize as the blast stress waves propagate and have an arbitrary distribution pattern. Three areas should be considered: not superimposed, weakly superimposed, and strongly superimposed. At each point of detonation, the pressure on explosive cavity wall will be minimal, while in the charge centre in the spherical insert zone, on the contrary, it will be maximal. In this case, the pressure in the central superposition area is about 2.84 times greater than at the initiation ends, and the nature of distribution changes according to a linear dependence. Practical implications. The performed research findings can serve as a basis for development of effective parameters of resource-saving methods for stripping hard rocks of complex structure in the conditions of ore mines.

Biofilm microenvironment-activated multimodal therapy nanoplatform for effective anti-bacterial treatment and wound healing

Antimicrobial drug development faces challenges from bacterial resistance, biofilms, and excessive inflammation. Here, we design an intelligent nanoplatform utilizing mesoporous silica nanoparticles doped with copper ions for loading copper sulfide (DM/Cu2+-CuS). The mesoporous silica doped with tetrasulfide bonds responds to the biofilm microenvironment (BME), releasing Cu2+ions, CuS along with hydrogen sulfide (H2S) gas. The release of hydrogen sulfide within 72 h reached 793.5 µM, significantly higher than that observed with conventional small molecule donors. H2S induces macrophages polarization towards the M2 phenotype, reducing inflammation and synergistically accelerating endothelial cell proliferation and migration with Cu2+ions. In addition, H2S disrupts extracellular DNA within biofilms, synergistically photothermal enhanced peroxidase-like activity of CuS to effectively eradicate biofilms. Remarkably, DM-mediated consumption of endogenous glutathione enhances the anti-biofilm activity of H2S and improves oxygen species (ROS) destruction efficiency. The combination of photothermal therapy (PTT), chemodynamic therapy (CDT), and gas treatment achieves sterilization rates of 99.3 % and 99.6 % against Staphylococcus aureus (S. aureus) and Escherichia coli (E. coli), respectively, in vitro under 808 nm laser irradiation. Additionally, in vivo experiments demonstrate a significant biosafety and antibacterial potential. In summary, the H2S donor developed in this study exhibits enhanced biocompatibility and controlled release properties. By integrating BME-responsive gas therapy with antibacterial ions, PTT and CDT, a synergistic multimodal strategy is proposed to offer new therapeutic approaches for wound healing. Statement of significanceThe advanced DMOS/Cu2+-CuS (DMCC) multimodal therapeutic nanoplatform has been developed for the treatment of drug-resistant bacterial wound infections and has exhibited enhanced therapeutic efficacy through the synergistic effects of photothermal therapy, chemodynamic therapy, Cu2+ions, and H2S. The DMCC exhibited exceptional biocompatibility and could release CuS, Cu2+, and H2S in response to elevated concentrations of glutathione within the biofilm microenvironment. H2S effectively disrupted the biofilm structure. Meanwhile, peroxidase activity of CuS combined with GSH-mediated reduction of Cu2+ to Cu+ generated abundant hydroxyl radicals under acidic conditions, leading to efficient eradication of pathogenic bacteria. Furthermore, both H2S and Cu2+ could modulate M2 macrophages polarization and regulate immune microenvironment dynamics. These strategies collectively provided a novel approach for developing antibacterial nanomedical platforms.

Co-pyrolysis of fly ash with sewage sludge for PCDD/F removal.

Fly ash generated from municipal waste incineration (MWI) contains various toxic substances, and it has to be properly treated before disposal or reuse. Water washing and thermal pyrolysis can improve the destruction efficiency of PCDD/Fs in fly ash generated from municipal solid waste incinerators. Since sulfur oxides and nitrogen compounds generated by the heating of the sewage sludge poison the catalytic active sites for PCDD/Fs formation on fly ash surface, co-pyrolysis of fly ash with sewage sludge effectively inhibits precursor formation and de novo synthesis reaction, resulting in the great reduction of PCDD/F formation. The results of the pyrolysis at 350 °C show that the PCDD/Fs removal efficiencies based on mass concentration are over 99%. The results at 350 °C of different reaction times show that the reaction time of 10 min is sufficient to reach the European End of Waste criteria (≤ 20 pg TEQ/g) when the ratio of fly ash/sewage sludge is controlled at 1:1.