Desktop 3D Printer Research Articles

Influence of Chemical Pretreatment on the Mechanical, Chemical, and Interfacial Properties of 3D-Printed, Rice-Husk-Fiber-Reinforced Composites

This article explores using biomass, namely rice husks, as a reinforcement material in thermoplastic copolyester (TPC) composites. Rice husks were subjected to three chemical pretreatments: single-stage sulfuric acid hydrolysis, first-stage sulfuric acid hydrolysis followed by a second-stage methanesulfonic acid (MSA) treatment, and first-stage sulfuric acid hydrolysis followed by a second-stage sodium hydroxide alkali treatment. We studied the effects of these treatments on the rheological, thermal, interfacial, and mechanical properties of composites. The fibers were mixed with polymers at high shear rates and temperatures, and 3D-printed filaments were produced using a desktop 3D printer. The printed parts were analyzed using tensile tests, torque and viscosity measurements, and thermogravimetric analysis to obtain their mechanical, rheological, and thermal properties. SEM imaging was performed to understand the fiber–polymer interface and how it affects the other properties. The results showed that first-stage sulfuric acid hydrolysis followed by a second-stage pretreatment of the fibers with MSA showed better fiber–polymer adhesion and a 20.4% increase in stress at 5% strain, a 30% increase in stress at 50% strain, and a 22.6% increase in the elastic modulus as compared to untreated rice husk composites. These findings indicate that readily available and inexpensive rice husks have significant potential for use in natural fiber-reinforced composites when pretreated using dilute sulfuric acid followed by methane sulfonic acid hydrolysis.

Dermal and oral exposure risks to heavy metals from 3D printing metal-fill thermoplastics

Manufacturing advancements in polymer printing now allow for the addition of metal additives to thermoplastic feedstock up to 80–90 % by weight and subsequent printing on low-cost desktop 3D printers. Particles associated with metal additives are not chemically bound to the plastic polymer, meaning these particles can potentially migrate and become bioavailable. This study investigated the degree to which two human exposure pathways, oral (ingestion) and dermal (skin contact), are important exposure pathways for metals (copper, chromium, and tin) from metal-fill thermoplastics used in consumer fused filament fabrication (FFF). We found that dermal exposure to copper and bronze filaments presents the highest exposure risk due to chloride (Cl−) in synthetic sweat driving copper (Cu2+) release and dissolution. Chromium and tin were released as micron-sized particles < 24 μm in diameter with low bioaccessibility during simulated oral and dermal exposure scenarios, with potential to undergo dissolution in the gastrointestinal tract based on testing using synthetic stomach fluids. The rate of metal particle release increased by one to two orders of magnitude when thermoplastics were degraded under 1 year of simulated UV weathering. This calls into question the long-term suitability of biodegradable polymers such as PLA for use in metal-fill thermoplastics if they are designed not to be sintered. The greatest exposure risk appears to be from the raw filaments rather than the printed forms, with the former having higher metal release rates in water and synthetic body fluids for all but one filament type. For brittle feedstock that requires greater handling, as metal-fill thermoplastics can be, practices common in metal powder 3D printing such as wearing gloves and washing hands may adequately reduce metal exposure risks.

Cytotoxicity and Characterization of Ultrafine Particles from Desktop Three-Dimensional Printers with Multiple Filaments.

Previous research has indicated that ultrafine particles (UFPs, particles less than 100 nm) emitted from desktop three-dimensional (3D) printers exhibit cytotoxicity. However, only a limited number of particles from different filaments and their combinations have been tested for cytotoxicity. This study quantified the emissions of UFPs from a commercially available filament extrusion desktop 3D printer using three different filaments, including acrylonitrile butadiene Styrene (ABS), thermoplastic polyurethane (TPU), and polyethylene terephthalate glycol (PETG). In this study, controlled experiments were conducted where the particles emitted were used to expose cells grown in an air-liquid interface (ALI) system. The ALI exposures were utilized for in vitro characterization of particle mixtures, including UFPs from a 3D printer. Additionally, a lactate dehydrogenase (LDH) assay was used to evaluate the cytotoxic effects of these UFPs. A549 cells were exposed at the ALI to UFPs generated by an operational 3D printer for an average of 45 and 90 min. Twenty-four hours post-exposure, the cells were analyzed for percent cytotoxicity in a 24-well ALI insert (LDH assay). UFP exposure resulted in diminished cell viability, as evidenced by significantly increased LDH levels. The findings demonstrate that ABS has the most significant particle emission. ABS was the only filament that showed a significant difference compared to the high efficiency particulate arrestance (HEPA) following 90 min of exposure (p-value < 0.05). Both ABS and PETG exhibited a significant difference compared to the HEPA control after 45 min of exposure. A preliminary analysis of potential exposure to these products in a typical environment advises caution when operating multiple printer and filament combinations in poorly ventilated spaces or without combined gas and particle filtration systems.

Optimization of Revision Hip Arthroplasty Workflow by Means of Detailed Pre-Surgical Planning Using Computed Tomography Data, Open-Source Software and Three-Dimensional-Printed Models.

In revision hip arthroplasty (RHA), establishing the center of rotation (COR) can be technically challenging due to the acetabular bone destruction that is usually present, particularly in severe cases such as Paprosky type II and III defects. The aim of this study was to demonstrate the use of open-source medical image reconstruction software and low-cost 3D anatomical models in pre-surgical planning of RHA. A total of 10 patients, underwent RHA and were included in the study. Computed tomography (CT) scans were performed for all cases, before surgery and approximately 1 week after the procedure. The reconstruction of CT data, 3D virtual planning of the COR and positioning of acetabular cups, including their inclination and anteversion angles, was carried out using the free open source software platform 3D Slicer. In addition, anatomical models of the pelvis were built on a desktop 3D printer from polylactic acid (PLA). Preoperative and postoperative reconstructed imaging data were compared for each patient, and the position of the acetabular cups as well as the COR were evaluated for each case. Analysis of the pre- and post-op center of rotation position data indicated statistically insignificant differences for the location of the COR on the X-axis (1.5 mm, t = 0.5741, p = 0.5868) with a fairly strong correlation of the results (r = -0.672, p = 0.0982), whilst for the location of the COR in the Y and Z-axes, there was statistical dependence (Y axis, 4.7 mm, t = 3.168 and p = 0.0194; Z axis, 1.9 mm, t = 1.887 and p = 0.1081). A strong correlation for both axes was also observed (Y and Z) (Y-axis, r = 0.9438 and p = 0.0014; Z-axis, r = 0.8829 and p = 0.0084). Analysis of inclination angle values showed a statistically insignificant difference between mean values (3.9 degrees, t = 1.111, p = 0.3092) and a moderate correlation was found between mean values (r = -0.4042, p = 0.3685). Analysis of the anteversion angle showed a statistically insignificant difference between mean values (1.9 degrees, t = 0.8671, p = 0.4192), while a moderate correlation between mean values was found (r = -0.4782, p = 0.2777). Three-dimensional reconstruction software, together with low-cost anatomical models, are very effective tools for pre-surgical planning, which have great potential use in orthopedic surgery, particularly RHA. In up and in- and up and out-type defects, it is essential to establish a new COR and to identify three support points within the revision acetabulum in order to correctly position acetabular cups.

Effect of printing parameters on extrusion-based additive manufacturing using highly filled CuSn12 filament

Typical additive manufacturing (AM) processes for producing metal and ceramic parts are highly energy-consuming and expensive to install and maintain. On the other hand, material extrusion AM (MEAM) technologies are conventionally used to produce polymeric parts but only marginally to process metallic materials. A feasible alternative is to process polymeric filaments loaded with metal particles. Debinding and sintering processes are then required to join the metal particles and obtain the final parts. In recent years, highly filled metal filaments consisting of a polymer loaded with a high concentration of metal powder have been commercialized for this purpose. In this study, the printability of a commercial CuSn12 filament was investigated by evaluating the influence of the process parameters on the density, shrinkage, porosity, and mechanical properties of the additively manufactured samples using a low-cost desktop 3D printer. Parameters such as the flow rate and ironing had the greatest influence on the density of the green samples. The correct selection of these parameters may reduce shrinkage after sintering. Furthermore, the obtained bronze had a notable ultimate tensile strength (mean value of 107 MPa), high stiffness (E values range from 38 to 50 GPa), and a greater elongation at break (mean value of 13%) than that of cast bronze of the same CuSn12 type. In this case, the extrusion pattern and ironing had the most significant influence on the final mechanical performance. The study provides insights into the use of highly filled bronze filaments combined with MEAM to produce functional parts for engineering applications.

Comparative Analysis of Fused Deposition Modeling and Digital Light Processing Techniques for Dimensional Accuracy in Clear Aligner Manufacturing.

BACKGROUND This study aimed to compare fused deposition modeling (FDM) and digital light processing (DLP) techniques in terms of dimensional accuracy for printing dental models used for the manufacture of clear dental aligners. MATERIAL AND METHODS Based on the intraoral scan of an adult patient, a sequence of 10 aligner models was created using BlueSkyPlan4. The test models (n=30) were fabricated with 2 desktop 3D printers: (DLP) and (FDM) printers. Two groups of samples were created (digitized using a desktop optical scanner). To calculate trueness (n=20) and precision (n=10), printed models were compared to the source files (REF). REF, DLP, and FDM files were superimposed and converted to point clouds. The cloud-to-cloud distances were calculated using CloudCompare software. Using the same algorithm, distortions of models were measured. Data were analyzed using one-way ANOVA and Tukey's post hoc test. RESULTS Significant differences were found between the trueness and precision of DLP and FDM groups. The average calculated trueness of DLP and FDM was 0.096 mm (0.021) (P<0.001) and 0.063 mm (0.024) (P<0.001), respectively. The average calculated precision of DLP and FDM was 0.027 mm (0.003) (P<0.001) and 0.036 mm (0.003) (P<0.001), respectively. A widening (0.158 mmfor DLP and 0.093 mmfor FDM, P=0.05) and twisting (0.03 mmfor DLP and 0.043 mmfor FDM, P=0.05) of the printed models was observed. CONCLUSIONS Both printers had sufficient precision for aligner models manufacturing. FDM showed a higher trueness and this device can be applied as an alternative to DLP. Polymerization shrinkage is a significant factor in decreasing the trueness of DLP printers.

Evaluation of 3D Printed Burr Hole Simulation Models Using 8 Different Materials

3D printing is increasingly used to fabricate three-dimensional neurosurgical simulation models, making training more accessible and economical. 3D printing includes various technologies with different capabilities for reproducing human anatomy. This study evaluated different materials across a broad range of 3D printing technologies to identify the combination that most precisely represents the parietal region of the skull for burr hole simulation. Eight different materials (polyethylene terephthalate glycol, Tough PLA, FibreTuff, White Resin, BoneSTN, SkullSTN, polymide [PA12], glass-filled polyamide [PA12-GF]) across 4 different 3D printing processes (fused filament fabrication, stereolithography, material jetting, selective laser sintering) were produced as skull samples that fit into a larger head model derived from computed tomography imaging. Five neurosurgeons conducted burr holes on each sample while blinded to the details of manufacturing method and cost. Qualities of mechanical drilling, visual appearance, skull exterior, and skull interior (i.e., diploë) and overall opinion were documented, and a final ranking activity was performed along with a semistructured interview. The study found that 3D printed polyethylene terephthalate glycol (using fused filament fabrication) and White Resin (using stereolithography) were the best models to replicate the skull, surpassing advanced multimaterial samples from a Stratasys J750 Digital Anatomy Printer. The interior (e.g., infill) and exterior structures strongly influenced the overall ranking of samples. All neurosurgeons agreed that practical simulation with 3D printed models can play a vital role in neurosurgical training. The study findings reveal that widely accessible desktop 3D printers and materials can play a valuable role in neurosurgical training.

Open-Source Designs for Distributed Manufacturing of Low-Cost Customized Walkers

To improve accessibility, this article describes a static, four-legged walker that can be constructed from materials and fasteners commonly available from hardware stores coupled by open-source 3D-printed joints. The designs are described in detail, shared under an open-source license, and fabricated with a low-cost open-source desktop 3D printer and hand tools. The resulting device is loaded to failure to determine the maximum load that the design can safely support in both vertical and horizontal failure modes. The experimental results showed that the average vertical failure load capacity was 3680 ± 694.3 N, equivalent to 375.3 ± 70.8 kg of applied weight with the fractured location at the wood dowel handlebars. The average horizontal load capacity was 315.6 ± 49.4 N, equivalent to 32.2 ± 5.1 kg. The maximum weight capacity of a user of 187.1 ± 29.3 kg was obtained, which indicates that the open-source walker design can withstand the weight requirements of all genders with a 95% confidence interval that includes a safety factor of 1.8 when considering the lowest deviation weight capacity. The design has a cost at the bottom of the range of commercial walkers and reduces the mass compared to a commercial walker by 0.5 kg (19% reduction). It can be concluded that this open-source walker design can aid accessibility in low-resource settings.

Lap Shear Strength Assessment of Acetone Welded 3D-Printed ABS Polymer

Fused Deposition Modeling (FDM) is one of the most common polymer 3D printing technologies used in many applications today. However, limited volume capacity for 3D printing large parts or components is the usual downside of this technology, especially desktop 3D printers. Hence, to offset this limitation, the 3D-printed parts are often designed in multiple pieces and assembled after printing, which requires post-processing called cold welding. Such welds are also quite strong but not as strong as a single-piece print. Therefore, finding suitable parameters or settings that can provide substantial strength for cold-welded 3D-printed parts will be beneficial. This study aims to determine the failing behavior and shear strength of ABS FDM 3D-printed single-lap joint using ABS glue as adhesive. Specimens were printed with varying raster angles (+45o/-45o and 0o/90o) and layer thickness (290 μm, 190 μm, and 90 μm) to investigate the effects on the adhesion or shear strength and failure mode of the acetone welded 3D-printed joints. Results show that raster angle and layer thickness significantly affected the shear strength of acetone welded materials. Single-lap joint test sample printed with +45o/-45o raster angle reveals higher shear strength than specimens printed with 0o/90o raster angle. Results also indicated that the gaps between the raster and voids between adjacent filaments of 3D-printed parts affects the adhesion and failure mode of a single-lap joint.

AltPrint: new filling and slicing process planning based on deposited material with geometry variation

PurposeThis paper aims to address the development and implementation of “AltPrint,” a slicing algorithm based on a new filling process planning from a variation in the deposited material geometry. AltPrint enables changes in the extruded material flow toward local variations in stiffness. The technical feasibility evaluation was conducted experimentally by fused filament fabrication (FFF) process of snap-fit subjected to a mechanical cyclical test.Design/methodology/approachThe methodology is based on the estimation of the parameter E from the mathematical relationships among the variation of the material in the material flow, nozzle geometry and extrusion parameters. Calibration, validation and analysis of the printed specimens were divided into two moments, of which the first refers to the material responses (flexural and dynamic mechanical analysis) and the second involves the analysis of the printed components with localized flow properties (for estimating the response to cyclic loading). Finite element analysis assisted in the comparison of two snap-fit geometries, one traditional and one generated by AltPrint. Finally, three examples of compliant mechanisms were developed to demonstrate the potential of the algorithm in the generation of functional prototypes.FindingsThe contribution of AltPrint is the variable fill width integrated with the slicing software that varies the print parameters in different regions of the object. The alternative extrusion method based on material rate variation was conceived as an “open software” available in GitHub platform, hence, open manufacturing with initial focus on desktop 3D printer based on FFF. The slicing method provides deposited variable-width segments in an organized and replicable filling strategy, resulting in mechanical properties variations in specific regions of a part. It was implemented and evaluated experimentally and indicated potential applications in parts manufactured by the additive process based on extrusion, which requires local flexibilities.Originality/valueThis paper presents a new alternative method for application in an open additive manufacturing context, specifically for additive extrusion techniques that enable local variations in the material flow. Its potential for manufacturing functional parts, which require flexibility due to cyclic loading, was demonstrated by fabrication and experimental evaluations of parts made in acrylonitrile butadiene styrene filament. The changes proposed by AltPrint enable geometric modifications in the response of the printed parts. The proposed slicing and filling control of parameters is inserted in a context of design for additive manufacturing and shows great potential in the area of product design.

Primary Human Ligament Fibroblast Adhesion and Growth on 3D-Printed Scaffolds for Tissue Engineering Applications

The current gold standard technique for the treatment of anterior cruciate ligament (ACL) injury is reconstruction with a tendon autograft. These treatments have a relatively high failure and re-rupture rate and are associated with early-onset osteoarthritis, developing within two decades of injury. Furthermore, both autografting and allografting come with several drawbacks. Tissue engineering and additive manufacturing present exciting new opportunities to explore 3D scaffolds as graft substitutes. We previously showed that 3D-printed scaffolds using low-cost equipment are suitable for tissue engineering approaches to regenerative medicine. Here, we hypothesize that Lay-Fomm 60, a commercially available nanoporous elastomer, may be a viable tissue engineering candidate for an ACL graft substitute. We first printed nanoporous thermoplastic elastomer scaffolds using low-cost desktop 3D printers and determined the mechanical and morphological properties. We then tested the impact of different surface coatings on primary human ACL fibroblast adhesion, growth, and ligamentous matrix deposition in vitro. Our data suggest that poly-L-lysine-coated Lay-Fomm 60 scaffolds increased ligament fibroblast activity and matrix formation when compared to uncoated scaffolds but did not have a significant effect on cell attachment and proliferation. Therefore, uncoated 3D printed Lay-Fomm 60 scaffolds may be viable standalone scaffolds and warrant further research as ligament tissue engineering and reconstruction grafts.

Tuning mechanical properties of 3D printed composites with PLA:TPU programmable filaments

Polylactic acid (PLA) filament is widely used for desktop 3D printing purposes due to its exceptional mechanical properties such as high strength; however, its brittleness restricts its use for producing flexible objects. Thermoplastic polyurethane (TPU) filament which is also widely used for desktop 3D printing, on the other hand, is flexible and commonly used in printing compliant objects with relatively low load-bearing performance. This study investigates the ability to tune the mechanical properties of specimens that are printed using programmable filaments composed of PLA and TPU filaments with different volume ratios of PLA and TPU. Two types of PLA and TPU filament arrangements, i.e., series and parallel, are considered. The PLA:TPU programmable filaments are used to print dogbone specimens for tensile testing. In printing the dogbone specimens, the raster angle is varied, i.e., 0, 45, and 90° with respect to the transverse direction of the specimen. To examine their mechanical behaviors based on different PLA and TPU filament arrangements, compositions, and raster angles, tensile tests are conducted on both programmable filaments and dogbone specimens. This study demonstrates the ability to tune the mechanical properties of printed objects by designing programmable filaments and varying raster angles during printing.

Utilizing 3D printing to assist pre-procedure planning of transjugular intrahepatic portosystemic shunt (TIPS) procedures: a pilot study

Background3D (three-dimensional) printing has been adopted by the medical community in several ways, procedure planning being one example. This application of technology has been adopted by several subspecialties including interventional radiology, however the planning of transjugular intrahepatic portosystemic shunt (TIPS) placement has not yet been described. The impact of a 3D printed model on procedural measures such as procedure time, radiation exposure, intravascular contrast dosage, fluoroscopy time, and provider confidence has also not been reported.MethodsThis pilot study utilized a quasi-experimental design including patients who underwent TIPS. For the control group, retrospective data was collected on patients who received a TIPS prior to Oct 1, 2020. For the experimental group, patient-specific 3D printed models were integrated in the care of patients that received TIPS between Oct 1, 2020 and April 15, 2021. Data was collected on patient demographics and procedural measures. The interventionalists were surveyed on their confidence level and model usage following each procedure in the experimental group.Results3D printed models were created for six TIPS. Procedure time (p = 0.93), fluoroscopy time (p = 0.26), and intravascular contrast dosage (p = 0.75) did not have significant difference between groups. Mean radiation exposure was 808.8 mGy in the group with a model compared to 1731.7 mGy without, however this was also not statistically significant (p = 0.09). Out of 11 survey responses from interventionists, 10 reported “increased” or “significantly increased” confidence after reviewing the 3D printed model and all responded that the models were a valuable tool for trainees.Conclusions3D printed models of patient anatomy can consistently be made using consumer-level, desktop 3D printing technology. This study was not adequately powered to measure the impact that including 3D printed models in the planning of TIPS procedures may have on procedural measures. The majority of interventionists reported that patient-specific models were valuable tools for teaching trainees and that confidence levels increased as a result of model inclusion in procedure planning.

Tough, Resorbable Polycaprolactone‐Based Bimodal Networks for Vat Polymerization 3D Printing

AbstractVat polymerization allows for the accurate and fast fabrication of personalized implants and devices. While the technology advances rapidly and more materials become available, the fabrication of flexible yet tough resorbable materials for biomedical applications remains a challenge. Here, a formulation that can be 3D printed with high accuracy using vat polymerization, yielding materials that are tough, degradable, and non‐toxic is presented. This unique combination of properties is obtained by combining a long‐chain polycaprolactone macromonomer with a small molecule cross‐linker. A wide range of properties is achieved by tuning the ratio of these components. The use of benzyl alcohol as a non‐volatile, benign solvent enables fabrication on a low‐cost desktop 3D printer, with an exposure time of 8 s per 50‐micron layer. The 3D‐printed networks are tough and elastic with a tensile strength of 11 MPa at 116% elongation at break. Cells attach and proliferate on the networks with a viability of &gt;91%. The networks are fully degradable to soluble products. This new 3D printable material opens up a range of opportunities in biomedical engineering and personalized medicine.

Effects of powder properties on the 3D printing of BaTiO3 ceramic resins by stereolithography

Stereolithography is a layer-by-layer building fabrication technique enabling production of advanced ceramic 3D shapes that are not achievable by other methods. Critical parameters of stereolithography are associated with the preparation of a ceramic resin exhibiting suitable rheological and optical properties, as well as tunable curing property to achieve the desired level of resolution of complex 3D parts. However, tailoring the cure depth for each layer is challenging for functional ceramics due to their high refractive index giving increased light scattering. Here, the stereolithography 3D printing of BaTiO3 ceramic resins is investigated by employing a desktop 3D printer (λ = 405 nm) and a commercial base resin. The effects of two BaTiO3 powders with different size distributions (one micro-sized powder with grains in the range 1–20 µm, and one agglomerated nano-sized powder in the range 60–100 nm), on the viscosity and curing characteristics of the ceramic resins were investigated. It is shown that the nano-sized powder resulted in increased viscosity, increased scattering, and reduced cure depth compared to the micro-sized BaTiO3 ceramic resin. In general, the cure depth decreased with increasing ceramic loading. Successful prints were obtained for an overcuring of at least 40% between layers to assure good adherence between the layers. The printing properties of the ceramic resins from both powders were suitable for printing green parts with 50 µm layer thickness.

3D-printing of easily recyclable all-ceramic thick LiCoO2 electrodes with enhanced areal capacity for Li-ion batteries using a highly filled thermoplastic filament

In this work, the production of thick ceramic LiCoO2 (LCO) electrodes using a conventional desktop 3D-printing was developed as an alternative to conventional electrode manufacturing for Li-ion batteries. Firstly, the filament formulation, based on LCO powders and a sacrificial polymers blend, is optimized to achieve suitable features (viscosity, flexibility and mechanical consistency) to be used in the 3-D printing. Printing parameters were optimized to produce defect-free bodies with coin geometry (12 mm diameter and 230–850 µm thickness). Thermal debinding and sintering were studied in order to obtain all ceramic LCO electrodes with adequate porosity. The additive-free sintered electrodes (850 µm thickness) have enhanced areal and volumetric capacities (up to 28 mA·h·cm−2 and 354 mA·h·cm−3) due to their extremely high mass loading (up to 285 mg·cm−2). Thus, the Li//LCO half-cell delivered an energy density of 1310 W·h·L-1. The ceramic nature of the electrode permits the use of a thin film of paint gold as current collector, reducing considerably the polarization of thick electrodes. Thus, the whole manufacturing process developed in this work is a complete solvent-free method to produce tuneable shape electrodes with enhanced energy density, opening the door for the manufacturing of high-density batteries with complex geometries and good recyclable.

Study on long-term morphological stability of three-dimensional-printed photosensitive resin dental models

Objective: To study the long-term morphological stability of three-dimensional (3D) printed photosensitive resin dental models under natural light and dark conditions. Methods: Eighty sets of resin dental models were made by the desktop 3D printer from one digital standard model set, and randomly divided into two groups, namely natural light group (40 sets) and dark group (40 sets). All resin models were stored in sealed bags, with 4 model sets from each group randomly collected after 1, 3, 5, 7, 14, 21, 28, 40, 60, or 90 days of storage and 3D scanned using an optical model scanner. The root-mean-square error (RMSE) was calculated to represent the mean deviation of the difference between the digital standard model and the scanned resin model. Meanwhile, three linear indexes (the width between the canines, the width between the first molars, and the arch length) of the resin dental model were measured and compared with the corresponding values of the standard model. RMSE and the linear measurements between the digital standard model and the scanned resin models were compared between the natural light group and the dark group and among models from different time points. Results: Compared with the digital standard model, the RMSE values of 96.9% (155/160) resin dental models were less than 0.1 mm within 90-day storage. Also, at the same time point, there was no significant difference in the RMSE between the natural light group and the dark group (P>0.05). 75.0% (360/480) of the absolute values of the linear differences (differences in inter-canine width, intra-molar width, and arch length between the digital standard model and the scanned resin model) were within 0.2 mm, and about 0.1% (3/480) of the linear differences were greater than 0.5 mm, and all of the linear differences were within 0.6 mm. Conclusions: 3D-printed resin dental models can be stored stably under natural light and dark conditions for a long time.

Monitoring the liberation of volatile organic compounds during fused deposition modeling three dimensional printing using solid-phase microextraction coupled to gas chromatography/mass spectrometry

Three-dimensional (3D) printers have gained tremendous popularity and are being widely used in offices, laboratories, and private homes. Fused deposition modeling (FDM) is among the most commonly used mechanisms by desktop 3D printers in indoor settings and relies on the extrusion and deposition of heated thermoplastic filaments, resulting in the liberation of volatile organic compounds (VOCs). With the growing use of 3D printers, concerns regarding human health have risen as the exposure to VOCs may cause adverse health effects. Therefore, it is important to monitor VOC liberation during printing and to correlate it to filament composition. In this study, VOCs liberated with a desktop printer were measured by solid-phase microextraction (SPME) combined with gas chromatography/mass spectrometry (GC/MS). SPME fibers featuring sorbent coatings of varied polarity were chosen for the extraction of VOCs liberated from acrylonitrile butadiene styrene (ABS), tough polylactic acid, and copolyester+ (CPE+) filaments. It was found that for all three filaments tested, longer print times resulted in a greater number of extracted VOCs. The ABS filament liberated the most VOCs while the CPE+ filaments liberated the fewest VOCs. Through the use of hierarchical cluster analysis and principal component analysis, filaments as well as fibers could be differentiated based on the liberated VOCs. This study demonstrates that SPME is a promising tool to sample and extract VOCs liberated during 3D printing under non-equilibrium conditions and can be used to aid in tentative identification of the VOCs when coupled to gas chromatography-mass spectrometry.

Monitoring the Calibration of In-Office 3D Printers.

Most desktop 3D printers lack features that allow manual calibration of printer parameters. It is crucial to assess the accuracy of printing to minimize the margin of error and variance between each print. Therefore, this study aimed to develop a method for monitoring the calibration of in-office 3D printers. A calibration coupon was designed to have a tolerance and dimensions that define nominal geometry and allow the measurement of variances occurring in X−Y axes and curvature. Ten printing cycles were run on two stereolithography (SLA) 3D printers with two different resins. Additionally, the coupons were positioned in five positions on the build platform to assess errors caused by differences in positioning. Measurements were made on the X and Y axes. No statistical difference was noted between the coupons being printed in different positions on the build platform and between the two resins at both X and Y axes of measurement (p > 0.05). Desktop 3D printers currently lack a standardized calibration protocol, which provides a closed loop for design and manufacturing of printed parts. The coupon in this study will allow monitoring the calibration of desktop 3D printers to ensure high-quality printing.

Combined method for manufacturing of pattern equipment

The new method for manufacturing of wear-resistant patterns by printing a polyamide shell on a desktop 3D printer without heat chamber and heating the table, with further polystyrene and compound filling, is described. The patterns obtained by this method are successfully tested for foundry of Yaroslavl Electric Locomotive Repair Plant in the period of 2022—2023.