Design Ideas Research Articles

Multiple enhancement effects of dipoles within polyimide cathode promoting highly efficient energy storage of lithium-ion batteries

Polyimide (PI) has been recognized as a potential organic cathode for Li-ion batteries (LIBs) due to its programmable structural design, high theoretical capacity, and resource availability. However, the poor intrinsic electrical conductivity of PI means that PI-based cathodes of LIBs have inefficient energy storage performance, especially at high current densities. In this work, the molecular structure of PI is optimized to obtain a layer-stacked crystalline PI with significantly enhanced dipoles, denoted NT-B for the first time. The dipoles in this PI are induced by the electronegative carbonyl groups from the monomer biuret and further enhanced via a π-π layer stacking effect. This work is the first to verify that the co-directional dipole enhancement effect of biuret is surprisingly different from that of monomer urea. A series of ex-situ/in-situ and theoretical DFT simulations are carried out to understand the functional mechanism of such effects. The multiple enhancement effects of the dipoles synergistically promoting the generation of a strong built-in electric field (BIEF) within NT-B are proposed based on the results obtained. It is confirmed that this BIEF plays a significant role in accelerating electron transport, which enhances the electrochemical activity of LIB cathodes. This work provides a new idea for the structural design of high-performance PI cathodes for LIBs.

Superior initiator reactivity and electrochemical properties of In(OTf)3 over Sn(OTf)2 for 1,3-dioxolane based solid polymer electrolyte

The in-situ polymerization of 1,3-dioxolane (PDOL) in battery cells has attracted extensive attention, however, the differences of Lewis acid initiators on the DOL monomer conversion (C%) and electrochemical properties has been ignored. Here, it is demonstrated that compare with Sn(OTf)2 Lewis acid initiator, the gelation of DOL is achieved at the lower addition of In(OTf)3. By optimizing their content in the gelation process, their C% are comparable which are 95.7 % and 93.5 % for In(OTf)3 and Sn(OTf)2, respectively. However, the higher ionic conductivity (7.1 × 10−4 S cm−1 at room temperature), electrochemical window (~4.5 V) and Li+ transference number (0.42) are obtained for DOL initiated with In(OTf)3, due to its lower molecular weight which is helpful to the intermolecular Li+ transport along PDOL main chain; In addition, the Li/Li symmetrical cell of In(OTf)3 can be stably cycled for >500 h at 3 mA cm−2, with an over-potential of 178mv. The storage and cycling impedances of half cells further proves the stable interface of In(OTf)3 initiated DOL toward to lithium metal in comparison with those of Sn(OTf)2. Scanning electron microscopy results show a denser and thinner interface in the DOL catalyzed by In(OTf)3. Finally, the assembled Li/LiFePO4 battery delivers specific discharge capacity and capacity retention rates of 115.5mAh g−1 and 85 %, respectively after 300 cycles at 1C. Through the initiator selection, the DOL synthesis and electrochemical properties can be tuned, which further broadens the design idea of PDOL based solid polymer electrolyte.

Structural design of two types of composites with high resistance to atomic oxygen attack based on polyimide matrices: a molecular dynamics simulation study

Because of their exceptional properties, polyimide (PI) polymers are widely used in various types of spacecraft. However, in low Earth orbit, spacecraft using these polymers are susceptible to atomic oxygen (AO) erosion, which will cause them to lose their original performance. Covering the PI surface with a protective coating and adding fillers to the PI matrix are two traditional methods to improve the AO erosion resistance of PI. However, a single protective method does not provide a good protective effect and does not necessarily balance the relationship between the AO resistance of the composites and other properties, such as mechanical properties. The structural design of composites can perfectly solve such problems. Therefore, two kinds of AO-resistant materials based on the PI matrix are designed in this paper, one is a hybrid-filled composite with nano-silica filler and graphene filler, and the other is a double-layer coated composite based on the structural design of a traditional bulletproof vest. And the AO incidence simulation of these two types of materials was carried out using ReaxFF-based MD simulation. The results show that the mixed filling of graphene and nano-silica not only greatly improves the AO resistance of the PI matrix, but also greatly improves the tensile mechanical properties of the matrix by adjusting the appropriate mixing ratio. The structure of PI-Gr-SiO2 (The structures are PI, Gr and SiO2 from bottom up, respectively. SiO2 will be the first to take the impact of AO.) possesses excellent resistance to AO erosion, and at the end of 64 ps of AO erosion, the PI matrix did not suffer any damage. This paper provides a new idea of material structure design using the MD method, which provides a new approach to improve the AO erosion resistance of PI and is expected to design new composites adapted to a variety of extreme environments in the future.

Oral Patch/Film for Drug Delivery-Current Status and Future Prospects.

In recent years, there has been extensive research into drug delivery systems aimed at enhancing drug utilization while minimizing drug toxicities. Among these systems, oral patches/films have garnered significant attention due to their convenience, noninvasive administration, ability to bypass hepatic first-pass metabolism, thereby enhancing drug bioavailability, and their potential to ensure good compliance, particularly among special patient populations. In this review, from the perspective of the anatomical characteristics of the oral cavity and the advantages and difficulties of oral drug delivery, we illustrate the design ideas, manufacturing techniques, research methodologies, and the essential attributes of an ideal oral patch/film. Furthermore, the applications of oral patches/films in both localized and systemic drug delivery were discussed. Finally, we offer insights into the future prospects of the oral patch/film, aiming to provide valuable reference for the advancement of oral localized drug delivery systems.

Integrating machine and deep learning technologies in green buildings for enhanced energy efficiency and environmental sustainability

A green building (GB) is a design idea that integrates environmentally conscious technology and sustainable procedures throughout the building’s life cycle. However, because different green requirements and performances are integrated into the building design, the GB design procedure typically takes longer than conventional structures. Machine learning (ML) and other advanced artificial intelligence (AI), such as DL techniques, are frequently utilized to assist designers in completing their work more quickly and precisely. Therefore, this study aims to develop a GB design predictive model utilizing ML and DL techniques to optimize resource consumption, improve occupant comfort, and lessen the environmental effect of the built environment of the GB design process. A dataset ASHARE-884 is applied to the suggested models. An Exploratory Data Analysis (EDA) is applied, which involves cleaning, sorting, and converting the category data into numerical values utilizing label encoding. In data preprocessing, the Z-Score normalization technique is applied to normalize the data. After data analysis and preprocessing, preprocessed data is used as input for Machine learning (ML) such as RF, DT, and Extreme GB, and Stacking and Deep Learning (DL) such as GNN, LSTM, and RNN techniques for green building design to enhance environmental sustainability by addressing different criteria of the GB design process. The performance of the proposed models is assessed using different evaluation metrics such as accuracy, precision, recall and F1-score. The experiment results indicate that the proposed GNN and LSTM models function more accurately and efficiently than conventional DL techniques for environmental sustainability in green buildings.

Building energy consumption analysis and measures: a case study from an administration building in Chengdu, China

With the peak of carbon dioxide emissions and carbon neutrality, China is placing greater emphasis on energy expenditure. Office buildings occupy a prominent position in building energy consumption, which is one of the main energy consumption areas. Taking an administration building in Chengdu as an example, this article simulates the building energy consumption based on Design Builder software, examines the variables influencing energy consumption, and suggests energy-saving strategies combined with fresh ideas for sustainable architectural design. The results showed that the modeling building was a high-energy-consuming building, with an energy consumption of 724,857.59 kWh, and a unit area energy consumption of 288.17 kWh/m2 in Chengdu. For energy conservation and emission reduction, this article proposes the following three energy-saving measures. The first is to apply heat recovery technology for air conditioning systems. The second is photovoltaic glass, which provides partial electricity demand for buildings and reduces dependence on traditional energy sources. The third is roof greening, which utilizes the plants to purify the air and beautify the environment. The results showed that the heat recovery technology in air conditioning systems reduced the total energy consumption of buildings from 642144.04 kWh/m2 to 502937.83 kWh/m2, photovoltaic glass reduced 552243.87 kWh/m2, and roof greening reduced to 635947.35 kWh/m2. All of these have good energy-saving and emission reduction effects. The above three strategies not only help reduce building energy consumption, but also provide substantial support for China to achieve carbon neutrality.

On the Integration and Application of New Media Technology and Advertising Design

In the new era, the rapid development of new media technology has injected new vitality and new impetus into advertising design. Realizing the integration of new media technology and advertising design can innovate advertising design ideas, improve advertising design effects, meet diversified advertising design needs, expand advertising communication channels, and promote the sustainable development of advertising design industry. Starting from new media technology, this paper analyzes the advantages brought by new media technology to advertising design, and discusses the specific application of new media technology and advertising design in combination with the actual situation, so as to provide reference and reference for advertising designers.

Multifunctional Adaptable Injectable TiN-Based Hydrogels for Antitumor and Antidrug-Resistant Bacterial Therapy.

The close relationship between bacteria and tumors has recently attracted increasing attention, and an increasing number of resources are being invested in the research and development of biomedical materials designed for the treatment of both. In this study, prefabricated TiN nanodots (NDs) and Fe(CO)5 nanoparticles are combined into sodium alginate (ALG) hydrogels to create a biomedical material for the topical treatment of breast cancer and subcutaneous abscesses, and a pseudocatalytic hydrogel with intrinsic photothermal and antibacterial activities is synthesized. TiN+Fe(CO)5+ALG hydrogels are used to determine the ability of Fe(CO)5 to promote CO production. Moreover, TiN NDs catalyze the production of reactive oxygen species (ROS) from hydrogen peroxide in tumor microenvironments and exhibit excellent photothermal conversion properties. After local injection of the TiN+Fe(CO)5+ALG hydrogel into subcutaneous tumors and subcutaneous abscesses, and two-zone near-infrared (NIR-II) irradiation, tumor cells and methicillin-resistant Staphylococcus aureus are effectively removed by the hydrogel, the mouse epidermis exhibiting complete recovery within 8 d, indicating that this hydrogel exhibits better antibacterial efficacy than the small-molecule antibiotic penicillin. This study demonstrates the potential of novel hydrogels for antitumor and antimicrobial combination therapy and aims to provide design ideas for the research and development of multifunctional antitumor and antimicrobial drug combinations.

A leaf-like photothermal evaporator with enhanced thermal conduction in reversed solar-driven desalination for efficient freshwater harvest

Solar-driven desalination has received tremendous attention due to its utilization of renewable solar energy, minimized carbon footprint, and simple installation. However, the traditional solar evaporator has the disadvantages of damaged light absorption and low heat transfer efficiency. In this work, a leaf-like photothermal evaporator (LPE) is designed by integrating the functions of light-to-heat conversion, water transport and evaporation, and vapor discharge. The photothermal layer is made of graphene oxide reduced by tannic acid, which shows a full–spectrum optical absorption as high as 94 % and achieves a strong combination with the water transport-evaporation layer thereby improving the heat conduction. Due to the chemical and mechanical bonding between tannic acid and cellulose, the temperature difference between the photothermal layer and the water transport-evaporation layer was reduced by 33 %. In addition, the water transport-evaporation layer adopts a Janus structure, which makes the water transport-evaporation layer thinner, thereby reducing the heat loss during the water transporting process, and provides a hydrophobic surface with good resistance of salt precipitation. By combing with an aluminum-made invert-structured condenser, a reversed solar-driven desalination (RSDD) system is proposed, whose water collecting rate is greatly improved to be 1.007 kg m−2 h−1. A freshwater collection efficiency as high as 80 % is almost the highest value of a single-stage solar distiller. Besides, a single-stage solar distiller with four LPEs in parallel is made and applied in the outdoor desalination. This work proposes a design idea for a new type of solar distillation system, which will play a role in response to the water crisis.

MULTI-USER INTERACTION FOR LIVING ROOM FURNITURE LAYOUT DESIGN IN HANDHELD AUGMENTED REALITY

Augmented Reality (AR) is the most recent popular technology that was developed in many fields. Development of AR is important for living room furniture layout design due to the high expectation of clients for testing design outcomes. Being able to think in three dimensions (3D) and visualizing projects is also a great importance for interior designers. Besides, the interior designer is difficult to collaborate with the clients for collecting furniture layout design ideas by referring the 2D furniture layout. Therefore, this study aims to introduce a multi-user interaction system for living room furniture layout design using handheld AR. The objectives of this study are; firstly, study multi-user interaction for living room furniture layout design in handheld AR. Secondly, develop handheld AR research prototype and multi-user interaction for living room furniture layout design and lastly, to integrate the handheld AR research prototype with multi-user interaction for living room furniture layout design. This study implements and combines the AR living room furniture layout design with multi-user interaction. This study also evaluates the research prototype based on the usability and user acceptance testing. The testing results showed the research prototype works properly. The respondents were overall satisfied with the research prototype and agreed that this research prototype is very interesting, creative and useful for collaborating with multi-user to design the living room furniture layout. This study has successfully established multi-user interaction for living room furniture layout design in handheld AR.

Biomimetic design and impact simulation of Al2O3/Al composite armor based on armadillo shell

The advancement of lightweight protective armors holds critical importance for enhancing the maneuverability and combat capabilities of helicopters. Leveraging insights from bionics, it provides a new idea for high-performance armor design. In this study, a new type of composite armor was designed by referring to the structural characteristics of hard phase-protection, soft phase-buffering of unitization armadillo shell. Through the numerical study, the anti-ballistic performance of armor with varying thickness ratios of the dense ceramic layer to the interpenetrating layer is obtained, and the influence of different structures of armor on the anti-ballistic performance is analyzed. The results show that compared with the traditional laminated composite armor, the Al2O3/Al biomimetic composite armor not only improves the separation phenomenon caused by wave impedance mismatch, but also greatly improves the speed drop in resisting high-speed and penetrating bullets. When the thickness ratio is 2:1, the armor has higher ballistic protection performance.

Revealing the Effect of Anion Regulation in NiCo2X4 (X = O, S, Se, Te) on Photoassisted Methanol Electrocatalytic Oxidation.

Designing nonprecious metal anode catalysts for photoassisted direct methanol fuel cells (PDMFCs) remains a challenge. As a semiconductor catalyst with a spinel structure, NiCo2O4 has good methanol catalytic oxidation activity and photocatalytic activity, making it a highly promising anode non-noble metal catalyst for PDMFCs. However, compared with the noble metal catalyst, the photoelectrocatalytic activity remained to be improved. In this report, an anion regulation strategy was adopted to improve the photoassisted methanol electrocatalytic activity. Using a CoNi-Aspartic (CoNi-Asp) nanorod as the precursor, the anion-regulated NiCo2X4 (X = O, S, Se, Te) was prepared by oxidation, sulfuration, selenization, and telluridation reactions. The regulation of anions and their effects on the electronic structure, intermediate product, and photoelectric catalytic performance of NiCo2X4 (X= O, S, Se, Te) was systematically discussed. Photoelectrochemical characterization and adsorption energy of •OH revealing the volcano-like correlation between the anion in NiCo2X4 (X = O, S, Se, Te) and their photoelectrocatalytic performance. The narrowest band gap (2.239 eV), the highest •OH adsorption energy (-3.32 eV), and the highest ratio of Co3+/Co2+ (2.19) ensure the best photoelectric catalytic performance of NiCo2S4, under the visible light irradiation, the photoresponse current density was 1.9 A g-1, the current density at 0.6 V was up to 21.9 A g-1. After 9 h of stability testing, the current retention rate was 80%. This report sheds an idea for the rational design of non-noble anode catalysts for PDMFCs.

Eco-friendly sustainable fluorescent coal-based carbon dots as a highly selective probe for Cu2+detection

Carbon dots as fluorescent probes exhibit brilliant sensitivity and selectivity in copper ion detection, which greatly depends on their microstructure. Herein, a mild oxidation method was adopted to tailor the organic macromolecules of coal and its derivatives for preparing coal-based carbon dots. Such coal-based carbon dots comprise a carbonaceous center dominated by sp2 microcrystalline carbon, surface defects formed by sp3 amorphous carbon, and oxygen/nitrogen-containing functional groups. The coal-based humic acid-based carbon dots (HA-CDs) exhibit high dispersity (∼7.6 nm), high sp2 microcrystalline carbon (61.73 %), abundant carboxyl groups (2.09 %), hydroxy groups (8.93 %), and pyridinic nitrogen (1.06 %). Due to their unique microstructure, the HA-CDs in aqueous solutions exhibit prominent fluorescence stability under different pH conditions and show superior selectivity and sensitivity to Cu2+ even in the existence of other metal ions. Within the concentration range of 0–40 µmol/L, the fluorescence intensity of HA-CDs linearly correlates with the concentration of Cu2+. The limit of detection is 0.014 µmol/L, allowing for tracing the Cu2+ concentration in flowing water. This work affords a novel idea for the microstructure design of high-sensitivity carbon dots for Cu2+ detection in the water environment.

Electrodeposition transition layer induced Cu/PPr hybrids

The high-performance metal-plastic hybrids have been widely applied in lightweight manufacturing. In this work, microstructures were prepared on the copper plate (Cu) surface using an electrodeposition process. Afterward, this microstructure was used to join with the pentatricopeptide repeats (PPr) to obtain Cu/PPr hybrids. The effect of electrodeposition process parameters on surface morphology was explored. The polyacrylic acid (PAA) content had the most significant effect on the surface morphology, and an increase in PAA content resulted in a shift from a lamellar to a granular structure. When the PAA content was 5 g/L, electrodeposition time was 300 s and the current density was 25 mA/cm2, the transition layer on the Cu surface was optimized, the roughness reached 164 nm, and the contact angle decreased to 2.41°. Meanwhile, the effect of molding temperature on the strength of the hybrids was explored, and the joining strength of the hybrids reached a maximum of 13.45 MPa when the temperature was 270 °C, which is 73.5 % of the strength of the PPr matrix. Further elevation of the molding temperature failed in the transition layer due to oxidation. The joining strength of the hybrids relies solely on the mechanical interlocking ability of the interface. The Cu/PPr hybrids provide design ideas for the practical production of copper-plastic composite pipes.

Donor-acceptor type of triazine-based conjugated organic polymers with excellent charge separation for efficient photocatalytic production of hydrogen peroxide

Hydrogen peroxide (H2O2) was widely utilized as an environmentally friendly and efficient chemical in various fields. The photocatalytic production of H2O2 using conjugated organic polymers as photocatalysts is promising. However, conjugated organic polymers have limited applications due to the high recombination rate of photogenerated carriers, poor electron mobility rate, and long synthesis time. Herein, we rapidly prepared a novel triazine-based conjugated organic polymer (CTP-TT) for efficient photocatalytic production of H2O2 using a facile sonochemical method. The H2O2 photosynthesis rate of CTP-TT reached 3383 μmol · g−1·h−1 in pure water without the addition of sacrificial agents. The experimental and characterization results confirmed that CTP-TT possessed dual H2O2 production pathways of 2e− oxygen reduction reaction (ORR) and 2e− water oxidation reaction, with 2e− ORR dominating. The theoretical calculations indicated that the excellent charge separation efficiency of CTP-TT was due to its unique donor–acceptor structure. This study provides novel design ideas for improving the photocatalytic performance of conjugated organic polymers, which is expected to promote the development of photocatalytic production of H2O2 applications and the rational design and preparation of organic semiconductor photocatalysts.

Adjustable stereo path design method based on pin-sculpture acoustic topological insulator with Z-dislocation defect immunity

The field of topological protected wave engineering, inspired by quantum mechanics, has generated significant interest. Acoustic analogs of electronic topological insulators provide new opportunities for manipulating sound propagation with unconventional acoustic edge modes that are immune to backscattering. Numerous reports have been published on the design of two-dimensional acoustic topological insulators (ATIs). However, the sound path of a two-dimensional design is simple, and its ability to control sound waves is limited. On the other hand, the design of 3D ATIs is relatively complex, making it difficult to manufacture and limiting its versatility. Based on the design idea of the 2D ATIs, inspired by the art named 3D pin-sculpture, an adjustable structure of a finite size consisting of spindle-shaped units with a variable cross section is designed to realize flexible path transformation. Furthermore, unlike two-dimensional structural defects, such as cavities and disorder, the analysis of vertical dislocation defects in finite-sized structures allows for the design of local sound propagation along the z-direction, providing a concept for constructing a stereo path. The designed structure also serves two functions: acoustic switch and delay. This idea offers an alternative approach to designing complex sound transmission paths.

Boosting peroxymonosulfate activation via Fe–Cu bimetallic hollow nanoreactor derived from copper smelting slag for efficient degradation of organics: The dual role of Cu

Valorization of iron-rich metallurgical slags in the construction of Fenton-like catalysts has an appealing potential from the perspective of sustainable development. For the first time, copper smelting slag (CSS) was utilized as the precursor to synthesize hollow sea urchin-like Fe–Cu nanoreactors (Cu1.5Fe1Si) to activate peroxymonosulfate (PMS) for chlortetracycline hydrochloride (CTC) degradation. The hyper-channels and nano-sized cavities were formed in the catalysts owing to the induction and modification of Cu, not only promoting the in-situ growth of silicates and the formation of cavities due to the etching of SiO2 microspheres, but also resulting the generation of nanotubes through the distortion and rotation of the nanosheets. It was found that 100 % CTC degradation rate can be achieved within 10 min for Cu1.5Fe1Si, 75 times higher than that of Cu0Fe1Si (0.0024 up to 0.18 M−1‧min−1). The unique nanoconfined microenvironment structure could enrich reactants in the catalyst cavities, prolong the residence time of molecules, and increase the utilization efficiency of active species. Density functional theory (DFT) calculations show that Cu1.5Fe1Si has strong adsorption energy and excellent electron transport capacity for PMS, and Fe-Fe sites are mainly responsible for the activation of PMS, while Cu assists in accelerating the Fe(II)/Fe(Ⅲ) cycle and promotes the catalytic efficiency. The excellent mineralization rate (83.32 % within 10 min) and efficient treatment of CTC in consecutive trials corroborated the high activity and stability of the Cu1.5Fe1Si. This work provides a new idea for the rational design of solid waste-based eco-friendly functional materials, aiming at consolidating their practical application in advanced wastewater treatment.

Construction of g-C3N4@Bi-MOF@BiOCl double Z-type heterojunctions for photodegradation of antibiotics under visible light irradiation: Mechanism, pathway, and toxicity assessment

In this study, flower-like microspheres dispersed double Z-type heterojunction g-C3N4@Bi-MOF@BiOCl photocatalysts were prepared using Bi-MOF as the structural template. The photocatalyst showed good degradation ability for both tetracycline antibiotics under simulated sunlight irradiation, as well as stable recyclability and total organic carbon mineralization (TOC). This excellent photocatalytic activity was mainly attributed to the formation of double Z-type heterojunctions that accelerated charge separation and transfer and drove stronger redox capacity. In addition, the effects of conditions such as catalyst dosage, initial concentration of tetracycline hydrochloride (TC) and initial pH (3–11) value of the solution on the photocatalytic reaction were investigated. The results of free radical trapping experiments and ESR analyses indicated that O2−, h+ and OH were the active free radicals that could not be neglected for the degradation of tetracycline hydrochloride (TC), and a possible degradation mechanism was further proposed. Finally, the possible pathways for degradation of the intermediates were rationally deduced by gas chromatography (GC–MS) and evaluated by ecotoxicity analysis based on the utilization rate (T.E.S.T.) of the intermediates produced. This study provides an effective idea for the rational design and synthesis of highly efficient dual Z-type photocatalysts for antibiotic contamination in water-polluted environments.

Integrating Course and Certificate Teaching: Practical Exploration of Enhancing English Vocational Skills under the “1+X” Certificate System

This article explores the implementation path of the “1+X” certificate system in vocational college English teaching, specifically how to integrate VETS (Vocational English Test System) level examination teaching with daily teaching. The article analyzes the current situation and dilemmas of course-certificate integration teaching, including the separation of teaching content, the lack of practical ability among teachers and the absence of a unified teaching plan. Subsequently, it proposes the characteristics and design ideas of course-certificate integration teaching, emphasizing the role of the course in cultivating compound talents. A specific case demonstrates how to integrate “Advanced International English for Vocational Colleges” with the VETS primary tutorial to enhance students’ language skills, vocational skills and international perspective and shape the correct professional concepts.

Creative-Rational Tensions in Game Development

In this paper, we discuss an ethnographic field study conducted with a single 8-person development team operating within an established indie game company located in Copenhagen, Denmark, to explore how members of a development team – in this case mainly programmers and designers – coordinate their design ideas and development processes. In a view that accepts “the heterogeneity of production logics within the games industry” (Kerr 2017, 76), our study of a single company in Denmark contributes new insights on organized and managed team creativity by adding to this pool of varying forms of development. The paper inquires and develops a perspective to analyse collaborative game-making within a studio workplace. We explore two formats of game development team meetings, Sprint Reviews and Sprint Retrospectives, to understand the ways in which teams work together to balance ‘creative-rational tensions’ (Tschang 2007) between given expectations and deadlines as well as personal expressive interests.