Deposition Process Research Articles

Microstructure and mechanical property improvement of concurrent wire-powder feeding laser melting deposition Ti-6Al-4V via TiC addition

Wire-feed laser metal deposition (LMD-W) offers a high deposition rate and low cost, making it an effective solution for reducing costs and enhancing efficiency in manufacturing large-scale titanium aerospace components. Currently, the material used for LMD-W is typically a single alloy wire, which limits the flexibility and functionality of manufacturing composite materials. This work employed a novel concurrent wire-powder feeding laser metal deposition (LMD-WP) process to manufacture TiC/Ti-6Al-4V composite. In the LMD-WP method, Ti-6Al-4V wire was fed laterally, while TiC particles were delivered coaxially. Only 1.0 wt% TiC particles were added to prevent excessive TiC, which could cause stress concentration and increase crack sensitivity. The microstructure and mechanical properties of Ti-6Al-4V alloy and TiC/Ti-6Al-4V composite were investigated. The results indicate that with coaxial TiC particle addition, the α-Ti in TiC/Ti-6Al-4V is noticeably refined. Additionally, in situ TiC acts as heterogeneous nucleation sites, restricting α-Ti growth and reducing its aspect ratio. Furthermore, TiC particles weakened the α-Ti texture in the (0001) and (11–20) directions. Moreover, adding TiC particles significantly enhanced tensile strength, with the yield strength reaching 950 MPa and the ultimate tensile strength reaching 1048 MPa. Compared to Ti-6Al-4V alloy fabricated by LMD-W, this represents an increase of 11.25% and 10.72%, respectively. The improvement in tensile properties is principally ascribed to grain boundary strengthening, Orowan strengthening and dislocation density strengthening. This work introduces an innovative approach and abundant data for the additive manufacturing of TiC/Ti-6Al-4V composite with high efficiency and low cost.

Heat and mass transport micropolar Maxwell and Williamson nanofluids flow past a perpendicular cylinder using combined convective flow

The current study aims to investigate the heat and mass transport characteristics of micropolar Maxwell and Williamson nanofluids flowing past a perpendicular cylinder under the influence of combined convective flow using the Buongiorno nanofluid model. The objective is to analyze the axisymmetric flow of these nanofluids around an orthogonal cylinder, highlighting the effects of various physical parameters on temperature profiles and velocity distributions. Maple 23 software was employed to solve the coupled nonlinear differential equations derived from appropriate similarity transformations. The numerical results are presented in tabular and graphical form to show the impacts of key parameters on the selected micropolar nanofluids. The significant outcomes show that the skin friction coefficient, as well as the Nusselt and Sherwood numbers, increase along the axial direction, indicating enhanced heat and mass transfer capabilities. Additionally, the study emphasizes the roles of micro polarity, relaxation time, and viscoelastic properties in modulating these transfer processes. These findings have significant implications for applications in biomechanics, polymer manufacturing, aerosol deposition, and thermal treatment processes, offering valuable insights for future research and industrial practices.

Low-modal-crosstalk doped-fiber amplifiers in few-mode-fiber-based systems

Independent light propagation through one or multiple modes is commonly considered as a basic demand for mode manipulation in few-mode fiber (FMF)- or multimode fiber (MMF)-based optical systems such as transmission links, optical fiber lasers, or distributed optical fiber sensors. However, the insertion of doped-fiber amplifiers always kills the entire effort by inducing significant modal crosstalk. In this paper, we propose the design of doped-fiber amplifiers in FMF-based systems adopting identical multiple-ring-core (MRC) index profiles for both passive and doped fibers to achieve low modal crosstalk. We develop the direct-glass-transition (DGT) modified chemical vapor deposition (MCVD) processing for precise fabrication of few-mode erbium-doped fibers (FM-EDFs) with MRC profiles of both refractive index and erbium-ion doping distribution. Then, a few-mode erbium-doped-fiber amplifier (FM-EDFA) with a maximum gain of 26.08 dB and differential modal gain (DMG) of 2.3 dB is realized based on fabricated FM-EDF matched with a transmission FMF supporting four linearly polarized (LP) modes. With the insertion of the FM-EDFA, 60 + 60 km simultaneous LP01/LP11/LP21/LP02 transmission without inter-modal multiple-input multiple-output digital signal processing (MIMO-DSP) is successfully demonstrated. The proposed design of low-modal-crosstalk doped-fiber amplifiers provides, to our knowledge, new insights into mode manipulation methods in various applications.

Effect of deposition regime transition on the properties of Al:ZnO transparent conducting oxide layer by radio frequency magnetron sputtering system

High-quality zinc oxide thin films doped with aluminium adatoms have effectively been fabricated on pristine soda-lime silica glass substrates via radio frequency magnetron sputtering system. The deposition temperature was varied to explore the impact of deposition regime transition of as-deposited Al:ZnO thin films on their performance as transparent conducting oxide layers. In particular, the depositions were conducted at room temperature, 100 °C, 200 °C, and 300 °C, allowing for a comprehensive assessment of the resulting films. The Raman spectra depicted the modulation of Raman bands in correlation with the deposition regime transition, illustrating the impact of thermal induction on various properties of the as-deposited aluminium-doped zinc oxide thin films. Atomic force microscopy reveals the transformation from nearly spherical to elongated shape structure was obtained as the deposition process shifted from kinetic limited to thermodynamic limited regimes. The phase analysis and grazing incident of x-ray diffractometer disclose a single crystal orientation has been achieved at thermodynamic limited regime. However, two different crystal planes were predominant comparing between the surface and structural of as-deposited aluminium-doped zinc oxide thin films. It is also evident that a highly transparent with low lattice strain and better carrier concentrations of as-deposited aluminium-doped zinc oxide thin films were realized at thermodynamic limited regimes.

Experimental study and parameter optimization of laser wire additive manufacturing of titanium alloy

In the single-pass multilayer deposition process of laser wire additive manufacturing, variations in process parameters significantly influence the morphology of the deposited layer. This study experimentally investigates how the main process parameters (laser power, scanning speed, and wire feeding speed) affect the morphology of the deposited layer. It was found that each parameter has distinct effects on the geometrical morphology of deposition. Simultaneously, aiming to enhance the surface topography of the deposited layer and its bonding with the substrate, three optimization objectives are defined. An optimization model is then constructed using experimental data to refine the process parameters. The optimal parameters are determined through experimentation, resulting in significant enhancement of the deposited layer’s topography.

Formation mechanisms of multiple Si/graphene nanocomposites through underwater pulsed discharge using different wire arrangements

Si/graphene nanocomposite is regarded as an advanced lithium-ion anode material, attributable to its advantageous microstructure and exceptionally high theoretical specific capacity. This study demonstrates a novel approach for the preparation of Si/graphene nanocomposites, achieved through the pulsed discharge method employing graphite and Si strips as precursors. We devised two distinct “one-step” synthetic routes through pulsed discharge of different wire arrangements. The characterization results of the obtained samples unveiled the presence of Si/graphene composite and Si@carbon layer composite. In addition, the formation mechanisms of Si/graphene nanocomposites have been proposed, different wire arrangements lead to the different energy deposition processes, inducing different robust mechanical and thermal effects on the products. The formed Si clusters either deposit on the surface of exfoliated graphene or become encapsulated within curling graphitic layers, forming a core@shell structure. This work not only presents a straightforward and innovative approach for synthesizing Si/graphene nanocomposites but also contributes valuable insights into the underlying mechanisms governing their formation.

Tribological properties under dry and lubricated sliding conditions of TiSiN and AlTiCrN coatings deposited on gray cast iron

In internal combustion engines, the majority of friction losses and wear occur between the cylinder liners and piston rings. Hard coatings applied to cylinder liners can increase the efficiency of internal combustion engines by improving tribological properties. The gray cast iron cylinder liner was coated with TiSiN and AlTiCrN employing the cathodic arc deposition process. The coatings were examined using nanoindentation tests, scratch tests, an optical profilometer, a scanning electron microscope, an X-ray diffractometer, and energy dispersive analysis to assess their hardness, adhesion, and structural characteristics. The reciprocating test was carried out to assess the coatings' wear and friction characteristics under lubricated and dry sliding with a ball at varying normal loads. The hardness of the TiSiN and AlTiCrN coatings was 45 GPa and 18 GPa, respectively. The cohesion strength, adhesion strength, and crack propagation resistance of AlTiCrN coating were approximately 2, 1.3 and 2.5 times higher than those of TiSiN coating, respectively. Both coatings exhibited remarkable wear performance at high normal loads. Under dry sliding conditions at 25 N normal load, the wear rate of AlTiCrN and TiSiN coatings were nearly 33 and 20 times, respectively, lower than the uncoated substrate. Under dry sliding conditions, the TiSiN coating exhibited the lowest wear rate at low normal loads (5 N and 15 N), while the AlTiCrN coating performed best at high normal loads (25 N). In lubricated sliding conditions, the AlTiCrN coating consistently showed the lowest wear rate across all normal loads.

Optical tomography by laser line scanning and digital twinning for in-process inspection of lattice structures in material extrusion

One of the challenges of manufacturing hollow parts featuring internal lattice structures by using material extrusion is to achieve geometric accuracy of the internal geometries. In this work a solution for in-process geometric inspection and monitoring is presented, based on combining on-machine part measurement by laser line scanning and digital twinning. In the solution, a laser line scanner is used to acquire a two-dimensional map of material and void distribution within the deposited layer. Layer inspection is carried out by comparing the 2D map with a reference one obtained by simulating the deposition process (digital twin of the layer); discrepancies are automatically identified and quantified. The evolution of anomalies across layers can be tracked by vertically stacking both layer measurements and 2D digital twins and by investigating the resulting 3D voxel models. The models are updated after the fabrication of each new layer, to allow geometric monitoring over time. The proposed inspection and monitoring solution is particularly suitable for hollow parts and/or lattice or otherwise reticular internal structures, which would otherwise be inaccessible when using conventional measurement methods on the final part.

The role of zinc addition on the microstructural evolution and mechanical properties of wire-arc directed energy deposited Mg-Gd-Y-(Zn)-Zr alloys

Wire-arc directed energy deposition (WA-DED) demonstrates significant potential in the rapid and free forming of high-strength magnesium rare-earth (Mg-RE) alloys. This highlights a growing demand for tailored wire alloy compositions to promote engineering applications of this technology. In this work, the role of zinc addition on WA-DED processed Mg-Gd-Y based alloys has been thoroughly investigated by utilizing Mg-6Gd-3Y-0.5Zr (wt.%, GW63K) and Mg-6Gd-3Y-0.5Zn-0.5Zr (wt.%, GWZ631K) alloy wires as model materials. The microstructure evolution of these two alloys during deposition and heat treatment is revealed by multi-scale microstructure characterization techniques. The influences of Zn addition on mechanical properties of these deposited alloys are investigated comparatively. Obtained results indicate that addition of Zn element into Mg-Gd-Y based alloys promotes phase transformation between eutectic phases and long period stacking order (LPSO) phases during the WA-DED deposition process owing to the multiple thermal cycling. More importantly, the addition of Zn element increases the tendency of solidification shrinkage of the deposited metal. During high-temperature solid solution treatment, the presence of Zn is conducive to improving the thermal stability of the as-deposited grain boundaries and thus suppressing grain coarsening. After optimized T6 treatments, the strength of GW63K alloys increases to 374±7MPa, and is obviously higher than that (315±6MPa) of GWZ631K alloys. The addition of Zn element weakens the precipitation strengthening effect. This can be attributed to the formation of LPSO phases, which consumes a substantial amount of RE elements, and in turn decreases the density of aging precipitated nanoscale β´ phases. This work promotes the understanding of the non-equilibrium solidified microstructure evolution of multi-component Mg-RE alloys and guides the optimization of alloy composition of WA-DED specific wire materials.

Investigating laser beam shadowing and powder particle dynamics in directed energy deposition through high-fidelity modelling and high-speed imaging

Laser beam shadowing in directed energy deposition process occurs when in-flight powder particles partially block the laser beam, preventing it from fully reaching the melt pool. This blockage alters the beam's profile, introducing spatio-temporal randomness in heat transfer to the melt pool and affecting its stability. This study utilizes a novel high-fidelity multiphysics model to quantitatively analyze gas-powder stream dynamics and laser-particle interactions. It specifically focuses on dynamic variations in laser beam shadowing, attenuation, and reflection of the laser beam radiant energy, along with powder particles temperature prediction from in-flight heating, accounting for multiple reflection phenomena. Gas-particle dynamics is modeled using a fully coupled CFD-DEM approach, while laser-particle in-flight interactions are predicted using a ray-tracing-based photon discretization method. Modeling predicted that interactions between the laser beam and the in-flight powder stream could result in energy losses up to approximately 70 % due to shadowing and attenuation. The study comprehensively explored the spatio-temporal variations in the attenuated laser beam profile, revealing significant deviations from its initial Gaussian profile and substantial stochasticity and randomness over time. To confirm the modeling results and correlate computational predictions with experimental data, high-speed visible imaging of the powder stream, both with and without the melt pool, along with laser beam attenuation measurements using a photodiode system, were conducted. The model's predictions of particle velocity and laser beam attenuation characteristics aligned with the results from these experiments. Modeling and high-speed imaging demonstrated that in-flight heating caused some particles to melt and few others to reach the vaporization threshold. High-speed imaging further validated these numerical findings by examining the interaction of heated particles with the melt pool across different phases (solid, liquid, and partially vaporized). A significant observation was the increased velocities of partially vaporized particles due to recoil pressure from selective vaporization, which led to the formation of deep craters in the melt pool resulting from high-speed impact.

Enhanced hydrogen gas sensing performance with Ag-doped WO3 thin film

The paper reports the fabrication of a device, based on the thin film of Ag-doped WO3 nanoparticles, to enhance the hydrogen gas sensing performance. The synthesis of thin films of pristine and Ag-doped WO3 nanoparticles were carried out using the single-step hydrothermal method, followed by the spin coating deposition process. The characterization of the samples was carried out with XRD, FESEM, TEM, FTIR and UV–vis spectroscopy. The consistent pattern observed from the microstructure analysis of data from XRD, UV–vis spectrometer and FTIR validates effective incorporation of Ag into the WO₃ structure. The XRD patterns confirmed the formation of the monoclinic phase of WO3 nanoparticles. The crystallite size and the value of band gap decreased on increasing the Ag doping percentage in WO3. This reduction with Ag-doping could be attributed to the proper substitution of the W with Ag due to their similar sizes. The gas sensing performances of the fabricated sensing devices were analyzed by exposing different concentrations of hydrogen gas ranging from 12.5 ppm to 75 ppm. The device based on the thin film of Ag-doped WO3 performed much better than the device based on the thin film of pristine WO3 nanoparticles. The device with 4% Ag-doped WO3 showed the best sensor response of 98 % for 75 ppm H2 gas concentration with response and recovery time of 76 and 100 s, respectively at 100 °C. The improved response of the device with Ag doping compared to the pristine device could be attributed to the better charge transfer, more defect creation, and the ability of Ag to work as a catalyst to make reaction kinetics faster. The selectivity of the device was tested using the oxidizing and reducing gasses of NO2, H2, and NH3 at 100 °C for 75 ppm gas concentration. The recorded response of the device for NO2, H2, NH3 were 38%, 98%, and 43%, respectively.

Polymer assisted deposition of YIG thin films with thickness control for spintronics applications

The use of magnetic garnets in new technologies such as spintronic devices requires fine-structured thin films. Classical fabrication techniques for these materials, typically physical vapor deposition methods, lead to excellent magnetic behavior. However, availability and scalability for potential applications are well restricted. In this study, we propose an innovative approach to fabricating Yttrium Iron Garnet thin films with precise thickness control achieved through iterative layer deposition via a chemical synthesis route. Remarkably, the iterative deposition process results in films exhibiting exceptional crystallinity. Magnetic characterization provides saturation magnetization and coercivity values on par with those reported in literature, summed to narrow ferromagnetic resonance lines. Therefore, in this work we demonstrate the viability of polymer assisted deposition as a promising alternative thinking about scalability to conventional deposition techniques for this material. Notably, our findings reveal energy conversion efficiencies comparable to those achieved with materials synthesized via physical vapor deposition methods.

High temperature deformation behaviour and recrystallization mechanism of TiC/Ti6Al4V gradient material fabricated by laser directed energy deposition

Metal-ceramic gradient materials are of considerable interest due to their unique capability to integrate the ductility of metals with the mechanical strength and high-temperature resistance of ceramics, thereby reducing the risk of cracking induced by thermal stress. In this article, TiC/Ti6Al4V gradient materials were prepared through the laser directed energy deposition (LDED) process. Subsequently, high-temperature compression tests were performed at various temperatures to investigate the deformation behaviour and recrystallization mechanism of the gradient materials. The Zener-Holomon constitutive equation was then used to calculate the gradient material at 750–900 °C and 0.001–0.1 s−1 to obtain a deformation activation energy of 362.36 KJ·mol−1. The EBSD was used to analyze the microstructural evolution of the gradient material. The results indicate a significant reduction in the average grain size of the specimens after high-temperature compression, and a more random crystal orientation due to the occurrence of dynamic recrystallisation (DRX). The primary softening mechanism of TiC/Ti6Al4V gradient materials is discontinuous dynamic recrystallisation, with TiC primarily affecting the nucleation of discontinuous dynamic recrystallisation (DDRX) and the subsequent grain growth. The nucleation becomes easier with increasing TiC content. However, the TiC hinders the migration of grain boundaries, resulting in a smaller DDRX grain size. After high-temperature compression, the main slip system of the crystal is converted from Pri to Bas. Pyr is difficult to activate due to its high critical resolved shear stress.

Advancing Metallic Lithium Anodes: A Review of Interface Design, Electrolyte Innovation, and Performance Enhancement Strategies.

Lithium (Li) metal is one of the most promising anode materials for next-generation, high-energy, Li-based batteries due to its exceptionally high specific capacity and low reduction potential. Nonetheless, intrinsic challenges such as detrimental interfacial reactions, significant volume expansion, and dendritic growth present considerable obstacles to its practical application. This review comprehensively summarizes various recent strategies for the modification and protection of metallic lithium anodes, offering insight into the latest advancements in electrode enhancement, electrolyte innovation, and interfacial design, as well as theoretical simulations related to the above. One notable trend is the optimization of electrolytes to suppress dendrite formation and enhance the stability of the electrode-electrolyte interface. This has been achieved through the development of new electrolytes with higher ionic conductivity and better compatibility with Li metal. Furthermore, significant progress has been made in the design and synthesis of novel Li metal composite anodes. These composite anodes, incorporating various additives such as polymers, ceramic particles, and carbon nanotubes, exhibit improved cycling stability and safety compared to pure Li metal. Research has used simulation computing, machine learning, and other methods to achieve electrochemical mechanics modeling and multi-field simulation in order to analyze and predict non-uniform lithium deposition processes and control factors. In-depth investigations into the electrochemical reactions, interfacial chemistry, and physical properties of these electrodes have provided valuable insights into their design and optimization. It systematically encapsulates the state-of-the-art developments in anode protection and delineates prospective trajectories for the technology's industrial evolution. This review aims to provide a detailed overview of the latest strategies for enhancing metallic lithium anodes in lithium-ion batteries, addressing the primary challenges and suggesting future directions for industrial advancement.

The influence of self-assembled particle layer on particle collision properties

Interactions between particle and particle layers are fundamental in modeling deposition processes. The complex mechanical behaviors of these layers pose significant challenges in precisely predicting the rebound characteristics of incident particle, especially at the micron and nanoscale. Very few related experimental studies have been reported in this area. To better control the structure of particle layers and offer a path to more systematic research, this study introduces the particle self-assembly method, combined with high-speed imaging technology, to investigate the influence of particle monolayer, their diameters, and impact velocity on critical capture velocity (vcr), normal coefficient of restitution (COR), and angle deflection of incident particles. Results indicate that self-assembled particle layers remain stable within an impact velocity range and experimental data within this stable range exhibit good repeatability. These layers significantly enhance kinetic energy dissipation. A semi-logarithmic plot revealed a negative linear relationship between vcr and particle size ratio. The effect of particle layer on COR depends on particle layer diameter and impact velocity. Specifically, the dissipation of particle layer diminishes and approaches zero for smaller layer particles (0.5 μm), but increases and stabilizes for larger particles (2 μm). Moreover, statistical results indicate that angle deflection decreases as particle size ratio increases, aligning with a power-law relationship predicted by Monte Carlo simulations. Overall, this study presents a novel method for understanding micro and nano particle layers' influence on incident particle dynamics.

Advances in optical coating uniformity of interference filters

We propose a method to obtain uniform multilayer coatings using vacuum assemblies with a linear ion source to manufacture narrow-band interference filters essential in astrophysical research for space object imaging in important spectral lines, and to provide multi-channel fiber-optic transmission of information. Interference filters and other optical systems, for example, high-reflective mirrors, steep-front beam splitters contain up to hundreds of film layers deposited onto a substrate. During the coating deposition, film thickness on the substrate must be strictly withstood and be uniform throughout the entire surface. This can be achieved by placing the linear source and target on the same platform and by conducting a test target sputtering on a fixed substrate. There is an inflection line on the coating thickness distribution on the substrate. By moving the platform, the inflection line midpoint is aligned with the center of the rotating working substrate, and in this position, the substrate is coated to a specified thickness, which is monitored during the deposition process.

A comprehensive transformation-thermomechanical model on deformation history in directed energy deposition of high-speed steel

ABSTRACT Phase transformation is a crucial factor that determines the quality and deformation of components in laser-directed energy deposition (L-DED). Owing to the limitations of in situ observation methods, there is a lack of effective means to study the complete phase transformation and their impacts on deformation during the deposition process. In this study, multilayer heterogeneous deposition was investigated with the high-carbon high-speed steel by modelling the coupled phase transformation-thermomechanical physics. The methodology was proposed to identify the specific phase transformations by iteratively comparing the whole deformation history between digital image correlation (DIC) measurements and simulations. Besides the thermo-mechanical coupling effect and basic volumetric phase transformation, carbon partitioning between precipitated carbides and matrix was manifested, which also resulted in a rise of the Ms point by 208.4 °C and a reduction of the transformation rate by 73.2%. Additionally, an increase of 13.8% in energy absorption could be attributed to the surface oxidation of the deposited layer. The model predictions exhibited good consistency with the DIC in-situ measurement data, indicating that the deformation history contained sufficient information on the phase transformations. Based on the proposed transformation-thermomechanical coupling model, it helps to understand the complete phase transformation during deposition.

Physical Vapor Deposition of Indium-Doped GeTe: Analyzing the Evaporation Process and Kinetics

Chalcogenide glasses have broad applications in the mid-infrared optoelectronics field and as phase-change materials (PCMs) due to their unique properties. Chalcogenide glasses can have crystalline and amorphous phases, making them suitable as PCMs for reversible optical or electrical recording. This study provides an in-depth analysis of the evaporation kinetics of indium-doped chalcogenides, GeTe4 and GeTe5, using the physical vapor deposition technique on glass substrates. Our approach involved a detailed examination of the evaporation process under controlled temperature conditions, allowing precise measurement of rate changes and energy dynamics. This study revealed a significant and exponential increase in the evaporation rate of GeTe4 and GeTe5 with the introduction of indium, which was particularly noticeable at higher temperatures. This increase in evaporation rate with indium doping suggests a more complex interplay of materials at the molecular level than previously understood. Furthermore, our findings indicate that the addition of indium affects the evaporation rate and elevates the energy requirements for the evaporation process, providing new insights into the thermal dynamics of these materials. This study’s outcomes contribute significantly to understanding deposition processes, paving the way for optimized manufacturing techniques that could lead to more efficient and higher-performing optoelectronic devices and memory storage solutions.

Fabricating Large-Area Thin Films of 2D Conductive Metal-Organic Frameworks.

ConspectusRecent years have witnessed significant interest in two-dimensional metal-organic frameworks (MOFs) due to their unique properties and promising applications across various fields. These materials offer distinct advantages, including high porosity and excellent charge transport properties. Their tunability allows precise control over various factors, including the electronic structure adjustments and local reactivity modulation, facilitating a wide range of properties and applications, such as material sensing and spin dynamics control. Moreover, the precise crystal structure of 2D MOFs supports rational design and mechanism studies, providing insights into their potential applications and enhancing their utility in various scientific and technological endeavors.To fully unveil the latent capabilities of 2D MOFs and advance their applications across diverse fields, thin film synthesis is crucial. Thin films provide a platform for investigating the intrinsic electrical properties of 2D MOFs with anisotropic structures, enabling the exploration of their unique characteristics comprehensively. Additionally, thin films offer the advantage of minimizing interference at contacts and junctions, thereby enhancing the performance of 2D MOFs for various applications. Furthermore, the properties of thin films can vary with thickness, presenting an opportunity to tailor their characteristics based on specific requirements.In this Account, we present an overview of our research focusing on the synthesis of 2D conductive MOF thin films encompassing two primary methods: chemical vapor deposition and solution processing. The chemical vapor deposition method allows for one-step, all-vapor-phase processes resulting in MOFs with edge-on orientation, controllable film thicknesses ranging from 55 to 662.7 nm, and smooth, homogeneous surfaces. On the other hand, solution-processing introduces a novel MOF, Cu3(HHTATP)2, by reducing interlayer interactions through the addition of pendent Brønsted bases on a ligand, enabling spin coating for thin film synthesis. This method yields a concentrated 2D MOF solution, enabling spin coating for thin film synthesis, where reversible electrical conductivity changes occur through doping with an acid and dedoping with a base. Additionally, we discuss various other synthesis methods, such as interfacial synthesis, layer-by-layer assembly, and microfluidic-assisted synthesis, offering versatile approaches for fabricating large-area thin films with tailored properties. Finally, we address ongoing challenges and potential strategies for further advancement in 2D conductive MOF thin film synthesis. We hope that this Account provides insights for selecting synthesis methods tailored to specific purposes, contributes to the development of varied synthesis techniques, and facilitates the exploration of diverse applications, unlocking the full potential of 2D conductive MOFs for next-generation technologies.

Numerical simulation of dust deposition characteristics of photovoltaic arrays taking into account the effect of the row spacing of photovoltaic modules

Dust deposition on the surfaces of Photovoltaic (PV) arrays during their operation markedly affects their power generation efficiency. Previous research has overlooked the impact of the row spacing of PV modules on the actual dust deposition on PV arrays. This study investigates the dust deposition process and its behavior on PV arrays considering variations in row spacings, inlet wind speeds, dust particle sizes, and dust particle counts. By employing commercial Computational Fluid Dynamics (CFD) software, incorporating the SST k-ω turbulence model and discrete particle model, numerical simulations were performed to analyze the airflow field, dust particle trajectories, dust deposition patterns, and deposition rates on the PV array through grid-independent verification and numerical validation. At the same time, we performed a comparative analysis of the deposition rate considering the rebound of dust particles on the PV module surface versus the case where rebound is not considered. Results revealed that the maximum dust deposition rates at different inlet wind speeds were 6.84 %, 8.84 %, 11.0 %, and 14.6 %, corresponding to dust sizes of 50 μm, 100 μm, 120 μm, and 300 μm, respectively. Smaller dust particles exhibited lower deposition rates, while larger particles were influenced more by mass inertia and gravity, leading to predominant deposition on the front row of PV modules. Larger dust particles are more likely to deposit primarily on the front row of PV modules in a PV array. The tilt angles of 30°, 45°, and 60° were chosen to study the effects of different tilt angles on the dust deposition of PV arrays, and the results show that the dust deposition rate decreases as the tilt angle increases, and it is worth noting that the larger the tilt angle, the larger the dust deposition rate is when the dust particles are especially small as 5 μm. When wind speeds are low and dust particles are small, the dust deposition rate gradually rises as the row spacing increases. However, at higher wind speeds with small dust particles, the row spacing has minimal impact on the dust deposition rate. Conversely, with larger dust particles, increasing the row spacing results in a lower dust deposition rate. These findings underscore the significance of optimizing PV array design for enhanced power generation efficiency.