The Republic of Korea government has set yearly targets of hydrogen cars and buses and plans to install hydrogen refueling stations nationwide. This paper proposes a methodology for developing a strategic deployment plan with three mathematical models. For a given target, future refueling demand locations and amount from general road and expressway are systematically estimated. First, the required number of refueling stations to satisfy the target covering ratio of the total demand set by the government is determined by the Station number determination model. Next, the locations of the capacitated stations and the allocation of demand to the stations are determined by the second Max cover and the third p-median models. Since the max covering is more important than minimizing the travel time, the two models are used sequentially. The nationwide hydrogen station deployment plan for the years 2022–2040 obtained by the proposed methodology is reported.