Dental Zirconia Research Articles

Effect of various storage media on the physicochemical properties of plasma-treated dental zirconia

This study investigated the effect of various storage media on the physicochemical properties of plasma-treated 3-mol% yttria-stabilized tetragonal zirconia: air, vacuum, deionized water (DIW), and plasma-activated water (PAW). Each group was divided into five subgroups based on storage periods: immediately after NTP irradiation (T0), and after 1 week (T1), 2 weeks (T2), 3 weeks (T3), and 4 weeks (T4). The control group (C) received no treatment. The storage groups were monitored weekly using various analytical techniques, including contact angle measurements, scanning electron microscopy (SEM), focused ion beam (FIB)-SEM, confocal laser scanning microscopy (CLSM), x-ray photoelectron spectroscopy (XPS), and x-ray diffraction (XRD). Our results demonstrate that plasma-treated zirconia surfaces stored in DIW retained or even increased their hydrophilicity due to the formation of hydrogen bonds and preservation of nitrogen functionalities. In contrast, surfaces stored in air exhibited significant hydrophobic recovery. FIB-SEM analysis showed no adverse internal structural changes regardless of storage medium. The roughness of the zirconia surface slightly increased after plasma treatment and was generally retained across all storage groups for 4 weeks, except for the air storage group. This study concludes that storage in DIW effectively preserves the enhanced surface properties of plasma-activated zirconia for up to 4 weeks.

Impact of Speed Sintering on Translucency, Opalescence and Microstructure of Dental Zirconia with a Combination of 5 mol% and 3 mol% Yttria-Stabilized Zirconia

Optical characteristics and microstructure of multilayered zirconia with different yttria contents in each layer can be influenced differently with a layer after speed sintering. The layer-wise translucency and opalescence of dental zirconia (E.max, E.max ZirCAD prime; Cercon, Cercon ht ML) after conventional (control) and speed sintering were analyzed using a spectrophotometer (n = 5). Specimens were subjected to microstructural analyses (n = 2) using field-emission scanning electron microscopy (FE-SEM) and phase analyses (n = 1) using high-resolution X-ray diffraction (HRXRD) and Rietveld refinement. The translucency parameter (TP) and opalescence parameter (OP) were analyzed using a 3-way ANOVA, followed by Scheffé’s post hoc test (α = 0.05). The average grain size was analyzed using the Welch’s t-test and Kruskal–Wallis test, followed by the Bonferroni–Dunn post hoc test (α = 0.05). Changes to the TP and OP after speed sintering were only observed in the dentin layers. Although the TP of E.max increased (p < 0.05), the difference was below the 50:50% perceptibility threshold (ΔE00 = 0.8). The OP of E.max decreased slightly, whereas that of Cercon increased slightly (p < 0.05). The microstructure and phase fraction of both zirconia barely changed. Therefore, speed sintering is considered to have a negligible clinical impact on the optical characteristics and microstructure.

Coloring Multilayer Zirconia May Affect Its Optical and Mechanical Properties

The coloring process of monolithic dental zirconia caused considerable debate on the possible effects of different coloring methods. The main objective of this study was to investigate the influence of pigments in 3 multilayer 5-mol% yttria partially stabilized zirconia (5Y-PSZ) disks (Lava Esthetic A2 [Zr-AGG_A2] and Bleach [Zr-AGG_BL], both 3M Oral Care, and Katana STML A2 [Zr-NoAGG], Kuraray Noritake). The influence of pigment addition on the translucency parameter (TP00), fracture toughness, Vickers hardness, biaxial strength, and hydrothermal stability was assessed and correlated with the microstructure and phase composition. The pigment composition and distribution were evaluated by light and fluorescence microscopy, electron probe microanalysis, and nano–scanning electron microscopy. The chemical and phase composition and aging behavior were assessed using X-ray fluorescence and X-ray diffraction, respectively, while the aging sensitivity of the pigments was evaluated using micro-Raman spectroscopy. In contrast to Zr-NoAGG, possessing a typical 5Y-PSZ microstructure, the pigment additions in both Zr-AGG_A2/BL zirconia resulted in large yellow and blue fluorescent Er-, Hf-, and Al-containing agglomerates composed of small grains (0.57 µm and 0.38 µm, respectively, vs. 0.92 µm for the surrounding grains) with lower Y2O3 content. Zr-AGG_A2 had the lowest aging resistance, with transformation degradation occurring exclusively within the pigment agglomerates. All zirconia grades had a high Y2O3 content (4.2%–5.7 mol%) tetragonal ZrO2 phase and a high (42%–55 wt%) cubic ZrO2 phase content. Although no statistical differences were measured for hardness and toughness, Zr-NoAGG had a significantly higher TP00, higher flexural strength, and lower mechanical reliability compared to both Zr-AGG_A2/BL zirconia. The rare-earth oxide-containing zirconia agglomerates that were added as pigments to the multilayered monolithic Zr-AGG_A2/BL zirconia are the cause for their lower optical and mechanical properties and reduced aging resistance.

Optimizing the microstructure, mechanical, and optical properties of recycled zirconia for dental applications

Efficient recycling of dental zirconia residues from computer-aided design/manufacturing processes is crucial for sustainable development in dentistry. This study employed ball milling to modify recycled zirconia powder (RZP). Initial RZP and ball-milled RZP (RZP-BM) were pre-sintered at 1000–1150 °C and then final sintered at 1500 °C. Initial RZP had irregular shapes, while RZP-BM showed finer and more uniform morphology, higher packing density, and improved de-agglomeration after 6 h of ball milling. For pre-sintered zirconia, RZP-BM samples achieved properties comparable with commercial zirconia at 1100 °C, whereas initial RZP required 1150 °C. For final sintered zirconia, initial RZP samples exhibited lower Vickers microhardness, density, strength, and transmittance, with numerous defects in its microstructure. RZP-BM samples showed significant improvement in mechanical and optical properties, comparable with commercial zirconia. This study establishes a viable approach for recycling dental zirconia residues, enhancing its properties for potential reuse as dental materials.

Enhancing Fracture Toughness of Dental Zirconia through Incorporation of Nb into the Surface.

Our previous study found that the addition of pentavalent cations like niobium (Nb) to yttria-stabilized zirconia increased fracture toughness but also raised the coefficient of thermal expansion (CTE), and opacity also increased undesirably. A new surface treatment is required to boost fracture toughness without altering CTE or translucency. The surfaces of pre-sintered 3 mol% yttria-stabilized tetragonal zirconia polycrystal (3Y-TZP) and 4.2 mol% yttria-stabilized partially stabilized zirconia (4.2Y-PSZ) were treated with a Nb sol solution containing Nb2O5 nanoparticles. After drying and sintering, a high-Nb-content surface layer formed with a depth of approximately 1 mm. The Nb content in this surface layer matched that of a bulk material with 1 mol% Nb2O5. The tetragonality of the surface zirconia increased, enhancing the surface fracture toughness without changing the CTE or translucency. Adding Nb near the surface improved the fracture toughness without affecting the CTE or translucency. This method could strengthen zirconia prostheses, allowing more reliable dental restorations.

Exploring physical and mechanical properties of hydrothermally processed recycled non-sintered dental zirconia wastes

Background and aimThe present investigation explored the potential for recycling residual blocks obtained from the machining processes under hydrothermal conditions. Furthermore, the study examined the recycled samples’ various physical and mechanical properties to assess their viability for further use. Materials and methodsIn this in vitro study, Aman Girbach blocks were collected, half of which underwent a hydrothermal process, while the other half did not. The blocks were then subjected to ball milling. Uniaxial and isostatic pressed blocks were prepared, and 10 samples were obtained from each type of recycled block. These samples were compared to a commercial material, and four groups were formed based on the powder type and pressing method used. The quality control analysis of the recycled samples included assessing particle size distribution, identifying crystalline phases, analyzing color differences, examining microstructure, and evaluating mechanical properties. Statistical tests such as normal distribution calculations (k-s test), one-way ANOVA, Brown-Forsythe, Tukey HSD, and Games-Howell tests were used to compare the four groups and perform pairwise comparisons. ResultsThe flexural strength and density of the control commercial group were significantly higher than the other experimental groups (P = 0.000). Linear shrinkage of recycled isostatic pressed experimental bodies was significantly lower than that of others (P = 0.000). Qualitative evaluation of microstructure and crystalline phase by FESEM and XRD showed no significant difference in grain size and crystalline phase between different groups. ConclusionThe hydrothermal process is a promising way to recycle zirconia ceramic with lower energy consumption. Recycled waste demonstrates potential as a cost-effective and viable option for ceramic prostheses in situations with low to medium stress levels.

Zirconia Dental Implant Designs and Surface Modifications: A Narrative Review.

Titanium currently has a well-established position as the gold standard for manufacturing dental implants; however, it is not free of flaws. Mentions of possible soft-tissue discoloration, corrosion, and possible allergic reactions have led to the development of zirconia dental implants. Various techniques for the surface modification of titanium have been applied to increase titanium implants' ability to osseointegrate. Similarly, to achieve the best possible results, zirconia dental implants have also had their surface modified to promote proper healing and satisfactory long-term results. Despite zirconium oxide being a ceramic material, not simply a metal, there have been mentions of it being susceptible to corrosion too. In this article, we aim to review the literature available on zirconia implants, the available techniques for the surface modification of zirconia, and the effects of these techniques on zirconia's biological properties. Zirconia's biocompatibility and ability to osseointegrate appears unquestionably good. Despite some of its mechanical properties being, factually, inferior to those of titanium, the benefits seem to outweigh the drawbacks. Zirconia implants show very good success rates in clinical research. This is partially due to available methods of surface treatment, including nanotopography alterations, which allow for improved wettability, bone-to-implant contact, and osteointegration in general.

The Composition of Graded Dental Zirconias

Zirconia dental ceramics have evolved from uniform blocks of 3 mol.% yttria (3Y) to strength- and color-graded blocks containing 3 mol.% and 5 mol.% components. Relatively little is known about the graded materials’ compositions and microstructures. Concerns have been raised about aging and degradation. This study investigated the microstructure, elemental composition, and phase content of different zones of strength- and color-graded zirconia blocks using scanning electron microscopy, x-ray fluorescence, and x-ray diffraction. Specimens were made from green-state blocks using CAD/CAM machining and sintering. Two strength- and color-graded zirconia materials had different grain sizes, elemental compositions, and phase contents between their top and bottom zones, these data being internally consistent as well as being broadly consistent with prior compositional physical property data. A color-graded zirconia material did not exhibit substantial differences between its top and bottom zones, consistent with expectations and previously published data. Modeling phase content for complex yttria-doped zirconia crystal systems with multiple heterogeneous crystal lattices from XRD data was inherently difficult, which may account for the ranges among previously published data; authors should describe detailed methodologies. Detailed compositional data at the scale of the microstructure is needed to relate composition to phase content, physical behavior, including crack evolution.

High Performance Dental Zirconia Ceramics Fabricated by Vat Photopolymerization Based on Aqueous Suspension

Currently, a significant challenge in the fabrication of ceramic dental prostheses via vat photopolymerization lies in the utilization of slurries composed of organic monomers, which compromises environmental sustainability and impedes commercial viability. In this research, we successfully develop a low-viscosity aqueous zirconia ceramic suspension with a solid loading of 40 vol% and 20 vol% deionized waters, incorporating 3 wt% dispersant and 0.5 wt% photoinitiator for printing dental crowns using vat photopolymerization. The resulting green bodies require only water washing to remove unreacted material. The printed ceramics demonstrate an average flexural strength of 708 MPa, a relative density of 98.3 %, and a Vickers hardness of 14.7 GPa. A dental crown is ultimately fabricated with an accuracy of 92.8 %. This study demonstrates that zirconia ceramics fabricated by vat photopolymerization with aqueous suspension exhibit excellent mechanical properties and accuracy, highlighting their potential for broad applications in dental restorations through an environmentally sustainable approach.

Development of multicomponent glasses for application as a glazing layer on dental zirconia

Development of multicomponent glasses for application as a glazing layer on dental zirconia

Does dental material type influence bacterial adhesion under the same polishing conditions? Direct observation using a fluorescent staining technique: An in vitro study.

Highly polished 3, 4, and 5 mol% yttria-stabilized zirconia and CAD/CAM composite resin samples were prepared, and the influence of surface roughness (Ra and Sa, 21 areas/group), wettability (contact angle and surface energy, 3 samples/group), and surface chemical composition (2 samples/group) on single-strain bacterial adhesion models (Porphyromonas gingivalis, Streptococcus oralis, Streptococcus sanguinis, Streptococcus gordonii, and Streptococcus mutans) were compared via fluorescent staining with graphical analysis (21 areas/group). Statistical analysis was performed using the Shapiro-Wilk test followed by one-way analysis of variance with Tukey's test or the Kruskal-Wallis test with Dunn's test (α=0.05) and linear regression. For dental zirconia with the same surface roughness, the yttria content did not significantly influence the initial bacterial adhesion. However, higher bacterial adhesion was detected for the composite resin owing to its high C, O, and Si contents. There was no correlation between surface energy and bacterial adhesion for any bacterial strain (p<0.005).

Surface modification of dental zirconia implants with a low infiltration temperature glass.

The glass infiltration technique was employed for surface modification of zirconia implants in this study. The prepared glass-infiltrated zirconia with low infiltrating temperature showed excellent mechanical properties and enough infiltrating layer. The zirconia substrate was pre-sintered at 1,200°C and the glass infiltration depth reached 400 μm after infiltrating at 1,200°C for 10 h. The infiltrating glass has good wetting ability, thermal expansion match and good chemical compatibility with the zirconia substrate. Indentation fracture toughness and flexural strength of the dense sintered glass-infiltrated zirconia composite are respectively 5.37±0.45 MPa•m1/2 and 841.03±89.31 MPa. Its elasticity modulus is 163.99±7.6 GPa and has about 500 μm infiltrating layer. The glass-infiltrated zirconia can be acid etched to a medium roughness (1.29±0.09 μm) with a flexural strength of 823.65±87.46 MPa, which promotes cell proliferation and has potential for dental implants.

Comparison of the Shear Bond Strength Using Primers with Different Application Numbers on Dental Zirconia.

This study examined the effect of the number of phosphate-containing primer applications on the shear bond strength (SBS) of zirconia to resin cement. 315 square specimens (10 × 10 × 4 mm3) were manufactured from Cercon ht presintered zirconia blocks. Alumina particles were used to sandblast zirconia specimens. These specimens were randomly divided into six primer-based groups: No primer application (NP), CLEARFIL CERAMIC PRIMER (C), PANAVIA V5 Tooth Primer (T), M&C PRIMER (MC), Monobond N (MN), and Z-PRIME plus (Z), and then separated into application number (1-4) groups (excluding NP). Each specimen was bonded with resin cement. The SBS was measured using a universal testing machine. The debonded surface was examined with a stereomicroscope. The SBSs were analyzed using two-way analysis of variance. Applying the primer twice exhibited the highest SBSs in each group, with significant differences in the T, MN, and Z groups. However, the SBS in the MC group was significantly lower on the second application. One-hundred percent adhesive failure was observed in all groups. Within the limitations of this study, prior to cementation, the sandblasted zirconia surface should be applied twice with a phosphate-containing primer other than MC to maximize the SBS at the zirconia-resin cement interface.

Impact of CAD/CAM burs lifetime on surface properties of dental zirconia: Implications for biocompatibility of custom abutments.

To evaluate the effect of the deterioration of computer aided design/computer aided manufacturing (CAD/CAM) burs during zirconia milling, on surface roughness, contact angle, and fibroblast viability. Ceramic blocks were milled and 75 ceramic disks (8 × 1.5 mm) made and allocated into three groups (n = 25): G1-brand new 2L and 1L burs, G2-2L bur at the end of lifetime and brand new 1L bur and G3-both burs at the end of their lifetimes. Roughness (Ra, Rq, and Rz) was evaluated using a 3D optical profilometer, the contact angle by the sessile drop method and the cell viability of the mouse NIH/3T3 fibroblast, using the Alamar Blue assay at intervals of 24, 48, and 72 h (ISO 10993-5). Data were analyzed by one-way ANOVA and Kruskal-Wallis tests (p ≤ 0.05). Roughness increased as the burs deteriorated and G3 (0.27 ± 0.04) presented a higher value for Ra (p < 0.001). The highest contact angle was observed in G3 (86.2 ± 2.66) when compared with G1 (63.7 ± 12.49) and G2 (75.3 ± 6.36) (p < 0.001). Alamar Blue indicated an increase in cell proliferation, with no significant differences among the groups at 24 and 72 h (p > 0.05). The deterioration of the burs increased the surface roughness and decreased the wettability, but did not interfere in cell viability and proliferation. The use of custom zirconia abutments represents an effective strategy for single crowns restorations. Our findings suggest that these abutments can be efficiently milled using CAD/CAM burs within their recommended lifetime.

Effect of rapid cooling on residual stress and surface fracture toughness of dental zirconia

Short-time sintering of dental zirconia not only improves manufacturing efficiency of zirconia prosthetics, but also enables an attractive situation in which prosthetic treatment can be completed within a single visit. Although many studies have clarified the effects of heating rate and dwell time on the properties of dental zirconia during short-time sintering, there are only a few studies on rapid cooling. In this study, we investigated the effect of cooling rate on dental zirconia. It was found that the cooling rate had no effect on the three-point flexural strength, but a fast cooling rate improved fracture toughness at the material surface. Raman piezo-spectroscopy showed that a compressive stress layer formed in the neighborhood of the zirconia surface and that its thickness increased with increasing cooling rate. From the above results, it was concluded that the compressive stress layer formed on the surface by rapid cooling improved the apparent fracture toughness at the material surface.

Critical evaluations on the crystallographic properties of translucent dental zirconia ceramics stabilized with 3-6 mol% yttria

ObjectivesThis study aimed to determine the crystalline phase composition of 3–6 mol% yttria-stabilized zirconia (3–6YSZ), specifically investigating the presence of tetragonal (t), cubic (c), and/or additional yttria-rich tetragonal (t’) phase. MethodsLaboratory-fabricated specimens comprising 3–5YSZ, resembling translucent dental zirconia ceramics (TZ specimens), and a blend of 3YSZ and 8YSZ, representing a c-phase reference, were prepared. Additionally, 25 dental zirconia products stabilized with 3–6 mol% yttria were analyzed. Whole X-ray diffraction (XRD) patterns were obtained for Rietveld analysis, complemented by fine scanning in the 2θ region from 72º to 76º for qualitative phase analysis. Moreover, yttria concentrations in each specimen were determined using X-ray fluorescence (XRF) spectroscopy. ResultsIn the 2θ region from 72º to 76º, TZ and dental zirconia product specimens displayed four peaks attributed to t- and t’-phases, but the c-phase peak was absent. Rietveld analysis of the whole XRD patterns, utilizing a t-t’ model, demonstrated the t-phase fraction ranging from 86 mass% in 3YSZ to 11 mass% in 6YSZ. Rietveld analysis appeared reliable, as the yttria contents calculated based on lattice parameters aligned well with those measured by XRF. This study established that dental 3–6YSZ consisted of yttria-lean t- and yttria-rich t’-phases. SignificanceThe present study enhances understanding of the crystalline structure of dental zirconia ceramics. Future crystallographic analyses of these ceramics should consider the presence of t- and t’-phases.

Critical cutting thickness model considering subsurface damage of zirconia grinding and friction–wear performance evaluation applied in simulated oral environment

Ductile mode removal is always a popular topic in zirconia ceramic cutting and grinding. The completely undamaged ductile mode grinding is extremely inefficient and difficult to control, which limits the clinical application of dental zirconia ceramics. Hence, considering the effect of subsurface damage, this paper redefines the ductile mode grinding removal of ceramic materials and establishes a critical cutting thickness model for zirconia ceramic grinding. Results show that the better the lubrication condition, the smaller the subsurface damage degree and the larger the removal range of ductile zone. To verify the model, grinding experiments of zirconia ceramic under different lubrication conditions are conducted. The results show that grinding under nanofluid minimum quantity lubrication obtains the lowest friction coefficient, which is reduced by 58.54 % and 18 % compared with dry grinding and minimum quantity lubrication (MQL), respectively. Under nanofluid minimum quantity lubrication (NMQL) condition, the critical cutting thickness is 2.27 µm, which is 160.92 % larger than that under dry grinding. The error between the theoretical model and the experimental results is 10.67 %, which verifies the correctness of the theoretical model. Furthermore, using the workpiece material obtained from grinding experiments, friction–wear experiments are conducted on dental zirconia ceramics under different loads in a simulated oral environment. The results show that zirconia ceramics obtained by NMQL grinding achieve better anti-friction and anti-wear performance than that of MQL. When the maximum cutting thickness of zirconia ceramics processed by NMQL grinding is 2.27 µm, the wear rate of the workpiece is 3.06 × 10−5 mm3/N·m, and at 2.6418 µm, the wear rate of the workpiece is 2.01 × 10−3 mm3/N·m. This paper aims to provide theoretical guidance and technical support for the ductile mode removal of hard, brittle materials.

Utilization of Slip Casting Process for Recycling CAD/CAM Dental Zirconia Wastes

This study aimed to find the ideal parameters for shaping waste zirconia powders from dental laboratories using the slip-casting process. Additionally, the qualities of ceramic products created in this manner were evaluated using microstructural characterization and physical-mechanical tests. Various dental laboratories provided the waste CAD/CAM zirconia powder used in the investigation. Wastes in powder form were first calcined. Afterward, an attritor mill was used to grind the grain size until it was usable, following the completion of the grain size distribution analysis. Waste and commercial zirconia powders were combined using various dispersants to create slip-casting slurries. The rheological characteristics of these slurries were then ascertained. By evaluating the rheological properties of slip-casting slurries prepared in this way, the most suitable casting parameters were determined, and ceramic products were formed by slip-casting technique from the slurries to be prepared in accordance with these parameters. The shaped samples were dried and sintered at two different temperatures, 1400-1450°C, and samples were designed for physical, mechanical, and microstructural characterization. The pore percentages, bulk densities, and water absorption of the sintered samples, according to Archimedes’ principle, as well as their strengths, were determined by the three-point bending strength test. Phase analysis was performed with XRD (X-ray diffractometer) microstructure studies with SEM (Scanning Electron Microscopy). It has been concluded that waste zirconia can be used in dental applications.

Assessing the Impact of Various Decontamination Instruments on Titanium and Zirconia Dental Implants: An In Vitro Study.

This study investigates the impact of various instrumentation techniques on material removal and surface changes in titanium (Ti)- and zirconia (Zr) implant discs. Ti- and Zr discs were subjected to standardized experiments using various instruments including airflow, ultrasound, carbide, and diamond burs. Instrumentation was performed for 60 s with continuous automatic motion. Abrasion and changes in surface roughness were assessed using profilometry, while scanning electron microscopy was used to examine morphological changes and particle size. Carbide burs predominantly caused abrasion on Ti discs, while diamond burs caused more abrasion on Zr discs. The Ti discs were more susceptible to surface changes. However, among the materials tested, machined Zr discs treated with diamond burs produced the largest particle. In certain cases, a statistical significance (p < 0.05) was observed between the groups, while in others, there was no considerable difference among the means (p > 0.05). These results highlighted the statistical significance of our findings. These results found diverse alterations in surface characteristics of Ti- and Zr discs due to different instruments, with carbide and diamond burs causing notable effects. The findings highlight the need for a careful balance between promoting healing and minimizing harm during implantoplasty.

Development and characterization of Al2O3/SrAl12O19 reinforced zirconia with high fracture toughness and low-temperature degradation-resistant for dental applications

The low fracture toughness and sensitivity to low-temperature degradation (LTD) are the primary reasons for the suboptimal long-term performance of dental zirconia. Composite ceramics of zirconia have gained popularity due to their ability to combine the benefits of various reinforcements. In this study, Al2O3–SrAl12O19–3Y/4Y/5Y–ZrO2 composite ceramics were fabricated using the Pechini method, and the optimal sintering temperature and time were investigated. The relative density, microstructure, grain size, mechanical properties, and LTD resistance of the samples were characterized. The results indicated that the composite achieved optimal performance when sintered at 1500 °C for 3 h. Al2O3 and SrAl12O19 primarily influence the properties of the zirconia composite ceramics by modulating their density and grain size. With an increase in the content of Al2O3 and SrAl12O19, the relative density first increases and then decreases, while the grain size exhibits an inverse trend, resulting in an initial increase followed by a decrease in fracture toughness. Additionally, the rate of increase in the m-phase fraction of the zirconia composite slowed down, but it reached a similar level after 64 h of LTD. The incorporation of 8 vol% Al2O3 and 8 vol% SrAl12O19 into 3Y–ZrO2 resulted in a ceramic composite with the highest fracture toughness values and acceptable LTD sensitivity, measured at 5.23 ± 0.25 MPa m1/2 and 48.35 ± 5.70% m-phase (LTD 64 h), respectively. This composite also exhibited high bending strength (990.09 MPa) and hardness (16.52 GPa), making it a promising alternative to conventional 3Y-TZP ceramics commonly used in dentistry.