Dense Layer Research Articles

Enhanced accident tolerance properties of AlCrCuFeMoNbx high entropy coating for nuclear fuel cladding

High entropy alloy AlCrCuFeMoNbx (x=0.5, 0.8, 1.4, 2.0) coatings were deposited on Zr-1Nb alloy substrates by magnetron co-sputtering to improve the accident tolerance capability of the nuclear fuel cladding. The structural and accidental tolerant properties of high-entropy alloy coatings have been investigated comprehensively. The results show that coatings with varying Nb contents exhibit amorphous structures. The hardness and elastic modulus of the coatings increase with the Nb content, reaching their maximum values at x = 2.0, which are 11.38GPa and 186.05GPa, respectively. In both the simulated normal operating and accident environment of the nuclear fuel cladding, the oxidation resistance of the coating has been investigated. The best oxidation resistance was achieved at x=0.8 in pure water at 360℃under 18.6MPa for 3 days. The dense Cr2O3 and CrNbO4 oxide films generated on the surface hinder the diffusion of oxygen ions, and account for the lower weight gain 5.10mg/dm2, decreased by 56.4% compared to that of the uncoated zirconium alloy. The coating with x=0.5 showed a drastic reduction in oxidized weight gain by 84.02% compared to the uncoated zirconium alloy in water steam at 1200℃, demonstrating excellent accident tolerance, which is due to the dense α-Al2O3 and CrNbO4 protective layer generated on the surface of the coating. These findings suggest that high entropy alloy coatings have promising accidental tolerance capabilities for nuclear fuel cladding.

A study on microstructure evolution of MCrAlY coatings after thermal aging in Te environment

The effects of thermal exposure on tellurium (Te) diffusion behavior in MCrAlY coatings were investigated at 800 °C in Te vapor. The results showed that the diffusion depth of Te in MCrAlY coatings gradually increased with the exposure time, and the dense Cr3Te4 layer formed on the coating surface in the initial stage was no longer continuous, especially under aging conditions with higher Te concentration. The high Cr content of the coating promoted the solid phase transition of the surface reaction product from Cr3Te4 to Cr7Te8, and resulting in the formation of large α-Cr phase either within or beneath the reaction layer during long aging processes. As a result of this phase transition, excess Te atoms were released from Cr3Te4 and continued to diffuse into the coating. Te did not exhibit obvious intergranular diffusion characteristics within the coating. When it encountered Y, it was captured by Y and formed a YTe phase. After aging for 3000 h, Te was distributed throughout the coating, and numerous voids were formed at the interface between the coating and the substrate. These two factors deteriorated the plasticity and adhesion of the coating. Results from molten salt corrosion tests indicated that the high content of Cr and Al in the coating, as well as high densities of grain boundaries providing diffusion pathways, reduced the corrosion resistance of the coating to molten salt.

Influence of ZrSiO4-SiC reinforcement on the decarburization and thermal shock behavior of MgO-C refractories

The slag corrosion resistance and thermal shock and of MgO-C refractories are crucial in the steelmaking industry. The current study presents a novel approach to enhance these properties by incorporating reinforcing particles such as zircon and silicon carbide. MgO-C refractories containing various amounts of ZrSiO4 and SiC were prepared and subjected to slag corrosion and thermal shock tests. X-ray diffraction analysis (XRD), scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDS) were used to characterize the microstructure and chemical composition of the samples. The findings demonstrated significant improvements in the overall performance of the refractories with the addition of zircon and silicon carbide. Thermal shock resistance increased from 11 cycles for MgO to 18 and 15 cycles due to the increased fracture toughness and altering crack propagation paths with the addition of ZrSiO4 and SiC particles. The formation of a CaZrO3 phase within pores significantly improved slag corrosion resistance. This led to a reduced slag penetration depth and a thinner decarburized layer compared to the unreinforced MgO-C refractory. SiC decomposition formed a protective silica layer, while zircon particles locked MgO grain boundaries, further enhancing corrosion resistance. The study proposes a corrosion mechanism based on the formation of microstructure containing dense and decarburized layers. These findings highlight the potential of reinforcing particles to improve the performance of MgO-C refractories in steelmaking applications.

Efficient Li+/Mg2+ separation by two-dimensional montmorillonite membrane with stable channel structure through ion exchange and metal–organic coordination strategy

Two-dimensional (2D) nanochannel membranes stacked by nanosheets are promising membrane separation materials. However, intrinsic swelling properties of 2D membrane have emerged as a significant challenge to establish stable nanochannels and achieve high separation performance. Inspired by the natural ion exchange property of montmorillonite (MMT), we constructed a two-dimensional MMT membrane with robust nanochannels by exchanging Fe3+ into interlayer of the membrane, and further achieved efficient separation of Li+/Mg2+ through coordination manipulation of tannic acid (TA) and Fe3+. Swelling was dramatically prevented by strong interlayer interaction between exchanged Fe3+ and nanosheets resulting in a 32-fold increase in anti-swelling properties. Furthermore, experiments and simulations revealed that TA could rapidly chelate with Fe3+ to form a dense hydrophilic functional layer on the membrane interface, which endowed MMT membranes with enhanced mechanical strength, cation transport and recognition, as well as anti-fouling properties. Consequently, the resulting MMT membranes showed the Li+/Mg2+ selectivity as high as 9.98 with a fast Li+ permeation rate (0.108 mol m-2h−1), which exceeded most of the previously reported membranes. This study proposed a novel strategy to diminish the trade-off effect among stability, ion flux, and selectivity of membranes, and inspired the development of next-generation ion selective separation membranes.

Nrf2 Activation in Keratinocytes: A Central Role in Diabetes-Associated Wound Healing.

Wound healing is a complex biological process crucial for tissue repair, wherein keratinocytes play a pivotal role in initiating, sustaining and completing the cascade. Various local and systemic factors, such as lifestyle, age metabolic disorders and vascular insufficiency, can influence this process, and in the context of diabetic wounds, disrupted biological mechanisms, including inflammation, tissue hypoxia, decrease in collagen production along with increased oxidative stress and keratinocyte dysfunction, contribute to delayed healing. During re-epithelialisation, keratinocytes undergo rapid multiplication and migration, forming a dense hyperproliferative epithelial layer that restores the epidermal barrier. Nuclear factor-erythroid 2-related factor (Nrf2), a vital transcription factor, emerges as a central regulator in managing antioxidant proteins and detoxifying enzymes, serving as a guardian against elevated reactive oxygen species (ROS) levels during stress. Nrf2 also orchestrates angiogenesis and anti-inflammatory responses crucial for wound repair. Studies demonstrate that under high-glucose conditions, Nrf2 activation promotes wound healing by enhancing cell proliferation and migration while reducing apoptosis. Nrf2 activators stimulate endogenous antioxidant production, thereby mitigating oxidative stress. Furthermore, Nrf2 upregulation is associated with decreased expression of cytokines such as TNF-α and IL- 6. Recent research underscores the potential of bioactive molecules, including dietary polyphenols, traditional medicinal compounds and pharmacological agents, in activating Nrf2 and preventing diseases such as diabetes due to their robust antioxidative properties. This review aims to investigate the activation of Nrf2 by these bioactive molecules in cultured keratinocytes and animal models, elucidating the key molecular regulatory mechanisms involved in alleviating oxidative stress and facilitating the diabetic wound healing process. Understanding these complex pathways may offer insights into novel therapeutic strategies for enhanced wound healing in diabetes-associated complications.

Microstructure evolution and degradation process of AlCrTiSiN coatings with different Si contents at high temperatures

The microstructure evolution of AlCrTiN and AlCrTiSiN coatings containing 4, 6.8, and 10.6 at.% Si was studied at temperatures ranging from 800 to 1100 °C. The AlCrTiN coating exhibits a single-phase fcc-(Al,Cr,Ti)N structure, while the AlCrTiSiN coatings transition from a nanocomposite structure, composed of fcc-(Al,Cr,Ti)N and amorphous a-SixNy, to a fully amorphous structure as the Si content increases. The hardness and adhesion strength of coatings initially rise, peaking at 24 GPa and 44 N respectively, due to the formation of the nanocomposite structure. However, these properties decline as the coatings become fully amorphous. At elevated temperatures, severe oxidation leads to the gradual formation of layered oxides. Concurrently, phase transformation, spinodal decomposition, and crystallization occur within the nitride layer. The addition of Si enhances oxidation resistance by promoting the rapid formation of a dense and protective oxide layer, and by reducing nitrogen release and TiO2 formation. However, at 1000 and 1100 °C, the coating with 10 at.% Si exhibits slightly faster oxidation compared to the 6.8 at.% Si coating, as the increased Si content reduces the Al content, limiting the coating's ability to regenerate the protective oxide layer.

Calcium titanate corrosion inhibitor enabling carbon as inert anode for oxygen evolution in molten chlorides

The corrosion inhibition efficacy of titanate (CaTiO3) for carbon anodes in molten salts was investigated through various analytical techniques, including linear sweep voltammetry, X-ray diffraction, scanning electron microscopy, and energy dispersion spectroscopy. The results demonstrate that the addition of CaTiO3 corrosion inhibitor efficiently passivates the carbon anode and leads to the formation of a dense CaTiO3 layer during the electrolysis process in molten CaCl2−CaO. Subsequently, the passivated carbon anode effectively undergoes the oxygen evolution reaction, with an optimal current density for passivation identified at 400 mA/cm2. Comprehensive investigations, including CaTiO3 solubility tests in molten CaCl2−CaO and numerical modeling of the stability of complex ionic structures, provide compelling evidence supporting “complexation−precipitation” passivation mechanism. This mechanism involves the initial formation of a complex containing TiO2·nCaO by CaTiO3 and CaO, which subsequently decomposes to yield CaTiO3, firmly coating the surface of the carbon anode. In practical applications, the integration of CaTiO3 corrosion inhibitor with the carbon anode leads to the successful preparation of the FeCoNiCrMn high-entropy alloy without carbon contamination in the molten CaCl2−CaO.

Synergistic effect of Co-MOF/epoxy modified tannic acid/ammonium polyphosphate on flame retardancy, anti-melt dripping and mechanical properties of polylactic acid

Achieving flame retardancy and anti-dripping properties in polylactic acid (PLA) while preserving its mechanical integrity remains a significant challenge. In this study, a novel organic ligand rich in phosphorus (P) and nitrogen (N) was synthesized and coordinated with Co2+ions to form a cobalt-based metal–organic framework (Co-MOF) with a multilayer mesoporous structure, acting as an effective carbonization agent. This Co-MOF was then compounded with epoxy-modified tannic acid (eTA) and ammonium polyphosphate (APP) to create a synergistic flame-retardant system for PLA (PLA/MAT). The Co-MOF provides numerous active sites for catalytic oxidation, promoting the formation of a uniform, hill-like expanded carbon layer. During pyrolysis, the Co-MOF and APP yield cobalt oxides and polyphosphates, which catalyze the dehydration of PLA and eTA, facilitating carbonization and forming a continuous, dense protective layer. Consequently, the PLA/MAT system exhibits both robust mechanical properties and excellent flame retardancy, as demonstrated by a limiting oxygen index (LOI) of 27.0 % and a UL-94 V-0 rating, with no melt dripping observed during combustion tests. This work offers a novel approach for enhancing the flame retardancy and anti-dripping performance of PLA, with potential applications in engineering, electronics, and the automotive industry.

Super-large diameter slurry shield tunnel encountering boulder formation: Detection, treatment and data analysis

Boulders pose substantial challenges in coastal urban tunnel engineering. This study, for the first time, utilizes extensive closely spaced borehole data from 3486 drilling points obtained during actual tunnelling through boulder strata to evaluate the effectiveness of microtremor detection, analyze variations in operational parameters, and assess the efficiency of blasting treatment. Additionally, leveraging borehole data, a 3D reconstruction of the soil-boulder-bedrock stratum was developed, and the stratum content ratio at the excavation face was derived. A multivariate linear regression model was established to explore the relationship between boulder geology and construction parameters. The results demonstrated that microtremor surveys effectively identified boulder distributions by analyzing horizontal-to-vertical spectral ratio curves and differences in surface wave phase velocity. Field drilling confirmed the high accuracy of microtremor predictions, particularly in areas with dense or thick boulder layers. Post-blasting secondary drilling revealed boulder fragments smaller than 30 cm, meeting the operational requirements for shield cutter and crusher systems. The presence of boulders was found to increase thrust, torque, and overturning moments, as well as cause abnormal cutter wear. Blasting significantly reduced the standard deviation of operational data, demonstrating its effectiveness in stabilizing tunnelling performance. Regression analysis showed a strong correlation between geological conditions and tunnelling parameters, with results indicating that blasting operations effectively mitigate the adverse impacts of boulders on shield tunnelling performance. This study aims to provide valuable insights and references for future engineering projects encountering similar complex geological conditions.

Anti-biofouling membrane coated with polyvinyl alcohol/sodium carboxymethylcellulose/tannic acid hydrogel for efficient dye/salt separation

Biofouling is the most severe challenge for separation membranes. In this study, a metal-organic framework (MOF)-based mixed-matrix membranes (MMMs) with polyvinyl alcohol (PVA)/sodium carboxymethylcellulose (CMC)/tannic acid (TA) hydrogel coating exhibited a comprehensive anti-biofouling property and high efficient for dye/salt separation. For the hydrogel layer, ethanol inhibited the cross-linking of the hydrogen bond between the PVA, CMC and TA, forming a uniform “hydrogel paint” applied to the membrane surface using the coating method. Subsequently, the hydrogen bond was re-established by evaporating the ethanol. The hydrogel coating could form a dense hydrated layer, endowing the membrane with excellent anti-fouling properties, including oil, proteins, and bacteria. For the MOF-based MMMs layer, the skeleton structure of polyvinylidene fluoride anchored the bimetallic MOF crystals to mitigate the phenomenon of “trade-off”. The hydrogel-coated MOF-based MMMs showed excellent properties, such as the water permeability was ~200 Lm−2 h−1, the rejection for Reactive Blue 19 was 100 %, the rejection for NaCl was 10.9 %, and it showed excellent stability for long-term service. Furthermore, the hydrogel-coated MOF-based MMMs presented a significant inhibitory effect on surface bacteria growth. In brief, this paper provided a new insight into preparing hydrogel-coated MOF-based MMMs, which had potential applications in separating dye/salt.

HNTs Improve Flame Retardant and Thermal Insulation of the PVA/CA Composite Aerogel.

Porous materials are widely used in construction, batteries, electrical appliances, and other fields. In order to meet the demand for flame-retardant and thermal insulation properties of organic porous materials, in this work, poly(vinyl alcohol)/calcium alginate/halloysite nanotube (PVA/CA/HNTs) aerogels with a hierarchical pore structure at micrometer-nanometer scales were prepared through freeze-drying using PVA as the substrate. The cross-linking reactions of PVA with H3BO3 and sodium alginate (SA) with CaCl2 constructed a double cross-linking network structure within the aerogel. And the HNTs were incorporated as reinforcing agents. The experimental results showed that the PVA/CA/HNTs aerogels had excellent flame-retardant and thermal insulation properties, and the heat release rate (HRR) and total heat release (THR) were effectively reduced compared to the PVA/CA aerogel. In addition, PVA/CA/HNTs aerogels had a high limiting oxygen index (LOI 60%) and low thermal conductivity (0.040 W/m·K). While their surface was subjected to a flame (800-1000 °C) for 25 min, the temperatures of the back surface were still lower than 80 °C. The low thermal conductivity of HNTs with hollow nanotube-like structures and the excellent flame-retardant properties of CA contributed to this phenomenon. The presence of HNTs and CA facilitated the formation of a dense carbon layer during combustion, enhancing the flame retardancy for PVA. In addition, the interpenetrating cross-linking network and the unique nanopores of HNTs collectively established a hierarchical pore structure within the gel, effectively impeding substance and heat exchange between the substrate and external environment. As the flame-retardant and thermal insulating material, PVA/CA/HNTs aerogels have a promising development prospect and potential in the fields of construction, transportation, electronics, and electrical appliances.

Anion-cation coupled electrolyte additive enhancing the performance of lithium-oxygen batteries

The rational design of electrolyte via introducing additive is an efficient strategy to improve the electrochemical performance of lithium-oxygen batteries (LOBs). In this work, coupling LiCl and Sn(TFSI)2 as the anion-cation electrolyte additive achieved the high-performance of LOBs by promoting the oxygen electrode reactions, regulating the Li+ solvation structure, and inducing the growth of the SEI protective layer. Specifically, Cl− with strong coordination affinity to Li+ could weaken the binding between Li+ and TEGDME solvent molecules, leading to the formation of an anion-dominant Li+ solvation structure, which facilitates the diffusion of Li+ in the electrolyte bulk and electrolyte/electrode interface. On the other hand, Sn2+ can serve as a redox mediator to catalyze ORR on the cathode and participate in the growth of smooth and dense SEI protective layer on Li metal anode surface, thus effectively promoting the oxygen electrode reaction kinetics and suppressing the corrosion of Li anode. As a consequence, the LOBs with coupled LiCl and Sn(TFSI)2 additive exhibited a ultra-high discharge capacity of 21517.1 mA h g−1 and an excellent cycling life of 334 cycles. This work provides a deep understanding for designing efficient electrolyte with additive for LOBs.

Study on A New Type of High Temperature Resistant Adsorption Type Retarded Acid System

Abstract Deep carbonate reservoirs present significant hurdles for reservoir stimulation due to extreme temperatures and rapid acid-rock reactions. The dense adsorption layer has the ability to postpone the interaction between rock and hydrogen ions, which is crucial for lowering the acid rock reaction rate. Based on the surfactant and film-forming agent’s synergistic impact, the retarding agent SH-1—which has the ability to generate a dense adsorption film on the surface of rock samples—was chosen for this study. After adding synergist and corrosion inhibitor, a new type of high temperature resistant adsorption type retarding acid system ’ 0.9% SH-1 + 20% HCl + 0.1% synergist + 1.5% corrosion inhibitor ’ was developed. The retarding performance of the retarding acid system at high temperature and various parameters of acid rock reaction kinetics were studied. The results show that the new adsorption-type retarded acid system can achieve good retarding effect at high temperature and ultra-high temperature, and the retarding rate is 90 % at 180 °C. In comparison to traditional hydrochloric acid, the new adsorption-type retarded acid exhibits a lower hydrogen ion mass transfer rate and a higher acid-rock reaction activation energy. These differences can effectively lower the acid-rock reaction rate. Additionally, an examination of the etching morphology reveals that the retarded acid is more easily etched along the cracks leading to the deep core. The novel adsorption-delayed acid offers excellent retarding power, high temperature resistance, and minimal damage. Consequently, it has certain reference value for the study of acidification transformation of ultra-high temperature deep carbonate reservoirs.

Exploring the comprehensive performance of lotus-leaf-inspired biomimetic NdYbZr2O7 thermal barrier coatings

Two micro-nano structural NdYbZr2O7 thermal barrier coatings (TBCs) inspired by lotus leaf were fabricated by ultrafast laser direct writing technology, which are defined as coating A and B respectively. The biomimetic coatings exhibit an outstanding volcanic ash repellence within a short-term period (1200 °C/10 min), while this performance dramatically deteriorates with time due to destruction of micro-conoids caused by the chemical reaction rather than the high-temperature sintering of nanoparticles. Additionally, this chemical reaction is responsible for the formation of dense reaction layer composed of c-ZrO2 and apatite grains in the sides of conoids, which effectively protects the underneath coating substrate from the infiltration and corrosion of molten volcanic ash. Thermal conductivity of these two laser-ablated coatings increases approximately 30 % than that of as-sprayed counterpart because of both the increase in dispersity of interface discontinuity and the decrease in coating thickness. During the wear process, the conoids are susceptible to abrupt fracture in the presence of load stress, as well as the initial deposited nanoparticles, resulting in the reduce of wear resistance against hard debris.

Evaluation of macular and optic nerve head changes by optical coherence tomography angiography in glaucomatous eyes

Background Optical coherence tomography angiography (OCTA) is introduced as a safe, noninvasive, and dye-free technology that provides an assessment of both large vessels and microvasculature of the retina and some parts of the choriocapillaris. Measuring vessel densities using OCTA at both the macula and optic nerve head (ONH) in glaucomatous eyes and comparing them with those of normal eyes will give us an idea about the effect of glaucoma on vessel densities and the role of OCTA in controlling and monitoring glaucoma progression, which remains despite the various medical and surgical treatment options, the second most common reason of blindness worldwide. Aims The current study aimed to assess vessel densities in glaucomatous patients at both the macula and ONH and compare them with vessel densities of normal participants and to assess if OCTA can be useful in the diagnosis and monitoring of the disease. Settings and design Case–control study. Patients and methods The study enrolled 60 patients who were divided into two groups. Group 1 included 30 patients with any type of glaucoma and group 2 included 30 normal participants. OCTA was performed on all of them to assess the macular and ONH vessel densities. Results Glaucomatous patients showed decreased vessel density at the macula and the ONH. The vessel densities at the foveal and all quadrants of parafoveal regions of the macula were decreased when compared with vessel densities of normal participants. Vessel densities at all quadrants of the peripapillary region also decreased when compared with those of normal participants with a strong positive correlation between average peripapillary vessel density and average peripapillary retinal nerve fiber layer thickness. Conclusions Both macular vessel density and ONH vessel density are affected in glaucoma and that may play a role in the diagnosis and follow-up of the disease.

Impact of precursor content on microstructure and properties of in-situ synthesized Ni60A-xTiC ceramic composite coating

To improve the surface properties of copper components, Ni60A-xTiC composite coatings with different precursor (TiFe and Cr3C2) contents were fabricated on copper surface by plasma cladding in this paper. The surface of all composite coatings forms a ceramic film composed of a dense layer (TiO2 and Ti2O3) and a loose layer (Fe2O3 and FeO). As the precursor content increases, the number and size of TiC particles in the composite coating have a tendency to increase, resulting in a gradual increase in microhardness. The wear resistance of the composite coating increases first and then decreases. Too high precursor content (20 wt. %) can lead to poor interface connection and wear resistance deterioration of the coating. Furthermore, the melting loss resistance of the composite coating is significantly better than that of the Ni60A coating due to the barrier effect of the ceramic film, and it becomes better with the increase of precursor content. To sum up, the composite coating with 15 wt. % precursor content is more suitable because of its smooth appearance, good interface connection and excellent comprehensive performance.

Laser-optical technologies for space debris removal

Technologies for the removal of space debris fragments of artificial (man-made) origin from near-Earth space is being proposed in order to provide the security of space flights. The fundamental principle of the proposed method is based on the utilization of intense solar radiation to direct and concentrate at space debris fragments with the aim of creating a plasma braking and transferring the fragment from a circular to an elliptical orbit following its subsequent burn up in the dense layers of the atmosphere. At the same time, the generation of substantial solar radiation is facilitated by a synthesized multi-aperture optical system situated in a heliosynchronous space orbit and permanently oriented towards the Sun.

High-accuracy gearbox fault detection using deep learning on vibrational data

Abstract In the face of escalating demands for reliability in industrial machinery, this study introduces an advanced deep-learning model aimed at the early detection of faults in rotating gear systems. Addressing the need for timely fault diagnosis to prevent operational disruptions and financial setbacks, our work utilizes a novel neural network approach applied to vibrational data from Kaggle’s Gearbox Fault Diagnosis Dataset. The methodology involves data preprocessing steps, including normalization and one-hot encoding, followed by training a sequential neural network with multiple dense layers and dropout for regularization. The model, trained using the Adam optimizer and evaluated over 50 epochs, significantly outperforms traditional machine learning techniques, achieving a remarkable 98.63% accuracy in distinguishing between healthy and compromised gear conditions. This research marks a significant stride in predictive maintenance, providing a robust foundation for future development toward prognostic health management systems that anticipate maintenance needs and ensure uninterrupted industrial productivity.

Wettability regulation of the electric double-layer structural evolution of complex fluids: Insights into thermodynamic and electrical properties

Understanding the structural evolution at the electrode is essential for accurate prediction of complex fluid applications, where the carbon nanotube is chosen as the carrier of CO2-ionic liquids (ILs) in electroreduction. Then, the electrical double layer with tunable wettability is investigated by molecular dynamics simulations. The competition and cooperation between van der Waals and Coulomb interactions are evaluated by examining the structural and electric characteristics. When an external potential (φ) is initiated, the co-ions are repelled from the electrode and the counter-ions compete with CO2 in the electric double layer (EDL), with different thermodynamics produced by varying the proportion of CO2/ionic liquid. As the solid–liquid interaction parameter (β) increases, more counter-ions aggregate, producing double density peaks for Tf2N− and sharply increasing the density of CO2. With increases in β and φ, the local charge density and local field potential increase, and the EDL thickness decreases. However, the location of the CO2 density layer shifts ahead to the counter-ions, weakening their shielding effect and capacitance. Using a combination of structural analysis, the first and second peaks of Tf2N− of EDL are composed of sulfonyl and trifluoromethyl, respectively. As a response, the steric hindrance of CO2 decreases, and more molecules migrate to the surface in a parallel orientation. The structural evolution is quantitatively evaluated in terms of the entropy, results show that the orientation transition is prominent in structural evolution. The coupling relation between thermodynamic and electrical properties plays a pivotal role in determining the structural evolution of complex mixtures, and these findings could benefit the advancement of ILs-based CO2 electroreduction and other complex fluid applications.

Effect of The Density and Height of F2 layer on Ground-Based Observation of Jupiter's Radio Signal

The density and height of the ionospheric F2 layer affect the observation of Jupiter's radio signals. The study aims to determine an approximate observation threshold from the values of the F2 peak density and the height of the F2 peak. The Florida and Lamy stations in the USA were selected. Utilizing actual observation data of Jupiter's radio signals from the Radio JOVE Data Archive for the years 2014-2015. The Radio Jove Pro software was employed to predict radio emissions from Jupiter. Ionospheric data were sourced from the International Reference Ionosphere (IRI) website. The primary focus of this study is to examine the role of the ionosphere in blocking the radio signals emanating from Jupiter. It was found that 49% and 31% (for the Florida and Lamy stations, respectively) of the predicted radio emission events from Jupiter were not observed. The likelihood of observation is higher after sunset and depends on Jupiter's elevation above the horizon relative to the observer. The F2 peak density during nighttime and throughout the year ranged from approximately 1011 to 1012 m-3 at altitudes of about 260-360 km. 89% and 98% (for the Florida and Lamy stations, respectively) of the observations occurred when the F2 peak density was less than around 6×1011 m-3. In contrast, 80% and 56% (for the Florida and Lamy stations, respectively) of the cases of non-observation occurred when the F2 peak density was greater than approximately 6×1011 m-3. As for The height of the F2 peak (hmF2), 85% and 93% of the observations occurred when the hmF2 was greater than about 300 km for the Florida and Lamy stations, respectively. The probability of observation is significantly influenced by the relationship between the electron density and its corresponding altitude.