Ignition Delay Time Research Articles

Thermal shock triggers microexplosion combustion in graded fuel and oxidizer encapsulation microspheres with improved combustion efficiency

The combustion agglomeration of aluminum (Al) and the long heat and mass transfer distance between Al and oxidizer cause serious two-phase flow loss and slag accumulation in the engine of solid propellants. Here, we present an effective strategy by in-situ encapsulating graded nano-aluminum (nAl) and micron-aluminum (μAl) in ammonium perchlorate (AP) simultaneously by using hydroxymethyl cellulose (HMC) as adhesive and constructing a compact coupling fuel oxidizer complex high-energy microsphere (μAl/nAl@AP/HMC) to enhance the energy release efficiency and combustion efficiency. Compared with physical mixture (PM), the ignition delay time and combustion time of μAl/nAl@AP/HMC microspheres are reduced by 69.58 % and 69.87 %, owing to the decomposition process control of AP through the adsorption and spatial constraint effect on the interface between metal fuels and oxidizer. Furthermore, the nAl embedded in the AP surface forms a hot spot around the μAl to promote the combustion reaction, thereby shortening the cavitation threshold and tensile limit time of μAl and accelerating the occurrence of microexplosion. Microexplosion effect in μAl/nAl@AP/HMC microsphere significantly weakens combustion agglomeration and improves combustion efficiency and energy release efficiency by sharp shrinkage of combustion condensation products, which addresses the challenges on energy output and combustion efficiency in high-density solid propellants.

Effects of in-cylinder water injection on knocking and combustion stability generated by expanding the lean burn limit

The integration of direct water injection (DWI) with the lean burn (LB) process can significantly enhance engine performance. This study reveals that an increase in the water-fuel (W/F) ratio suppressed knocking by extending the ignition delay time. Specifically, the knocking of stoichiometric combustion was suppressed, while that of deeper LB (excess air ratio (λ)˃1.5) was sensitive to a larger W/F ratio. The intensity of knocks during stoichiometric combustion decreased significantly (more than twofold) when the W/F ratio increased from 0.1 to 0.2. Under identical W/F conditions, a shorter ignition delay (CA0–10) and combustion duration (CA10–90) of the main combustion flame were identified as important factors for knocking when λ increased from 1 to 1.5. However, for λ values exceeding 1.5, CA10–90 emerged as the primary knocking determinant. Faster flame propagation and higher oxygen concentration caused by LB and an early spark promoted autoignition of the end-gas and increased the autoignition heat release rate, thus strengthening knock intensity (KI). Furthermore, a minimal amount of water (W/F ≤ 0.3) exerted negligible influence on the stoichiometric combustion stability. As the LB approached its limit, the average KI remained relatively consistent, with combustion stability emerging as the key factor in elevating the LB performance. A 0.3 W/F ratio and precise spark timing ensured that a balance exists between combustion stability and knocking, while simultaneously elevating λ to 2.0.

Combustion and mechanical properties of pellets from biomass and industrial waste

Experimental research findings are reported on the impact of industrial waste additives on the mechanical properties of pellets, their ignition and combustion. The compositions under study consisted of wood sawdust with coal slime/peat/a mixture of straw and rice husk. Composite pellets exhibited high moisture resistance and durability when subjected to vibration. The respective coefficients were 6–32 % higher than for sawdust without additives. The ignition characteristics of wood pellets tended to worsen when additional components were used in their composition. The ignition delay times increased by a factor of 3–4. In most cases, the use of additives increased the combustion duration of pellet fuels. The greatest environmental benefits in terms of carbon oxides were gained from mixtures of straw with rice husk and coal slime. СО2 and СО emissions decreased by 10–20 % and 10–54 %, respectively. A high nitrogen content in peat, coal slime and straw led to 5–94 % higher emissions of NOx for composite pellets. Using plant biomass and peat reduced the concentrations of sulfur oxides almost 3-fold. The results of multi-criteria analysis covering 13 energy, operational, economic and environmental components suggest that the difference in the relative efficiency indicator of wood pellets and compositions with industrial waste additives is 4.4–6.5 %.

A Reduced Kinetics Model for the Oxidation of Transcritical/Supercritical Gasoline Surrogate/Ethanol Mixtures Using Real Gas State Equations

ABSTRACT Efforts to combat the harmful effects of vehicle emissions on our environment and health include exhaust emissions and fuel efficiency regulations. One promising solution is direct fuel injection in supercritical conditions, where the fuel mixture is above critical temperature and pressure. This study presents a reduced kinetics mechanism (129 species and 1015 reactions) utilizing real gas equations to simulate the combustion of supercritical/transcritical gasoline surrogate/ethanol blends. It was developed by combining two reduced models – a Toluene reference fuel (TRF) with a Diisobutylene (DIB) and an ethanol model – and validated through simulations of ignition delay time (IDT). The Arrhenius parameters of key reactions for each fuel component were modified to improve accuracy. An adjusted Redlich-Kwong cubic state equation was employed to segregate each surrogate mixture tested as supercritical, transcritical, or subcritical. The new mechanism was then validated against experimental results using high-pressure conditions and the cubic Peng-Robinson and Redlich-Kwong equation of state parameters. Critical properties of each species were obtained through Joback’s Group Method and the Ambrose-Walton vapor pressure equation. The TRF/DIB/E mechanism results were consistent with shock tube experimental data at high pressure, indicating a potential for modeling combustion in ultra-high pressure direct injection engines.

N-Alkyl-1,2,4-triazole–Borane Complexes as High-Density Hypergolic Materials

AbstractHydrazine and its derivatives have served as a conventional bipropellant fuel for several decades. However, their extremely acute toxicity and carcinogenicity, high volatility, and environmental impact have attracted significant attention. In order to synthesize green bipropellant fuels with high density, high specific impulse, and good thermal stability, three novel N-alkyl-1,2,4-triazole–borane complexes were successfully synthesized by reacting alkylated 1,2,4-triazole coordinated with sodium borohydride in the presence of ammonium sulfate. During the droplet test with white fuming nitric acid, there was a relatively short ignition delay time of 98 ms. Additionally, these hypergolic fuels possessed a high density exceeding 1.10 g cm–3, and the specific impulse is ranging from 187 to 199 s, and the highest decomposition temperature reaches 153.4 °C. These results demonstrate their great potential as hypergolic fuels or hypergolic ionic liquid additives in the field of hypergolic materials.

Shock tube and comprehensive kinetic modeling study of ammonia/diethyl ether (DEE) mixtures

Ammonia (NH3) is a promising alternative clean fuel due to its carbon-free and high hydrogen content, along with the well-established infrastructure for storage and distribution. To overcome the issue of the low reactivity of NH3, a feasible strategy is co-burning ammonia with highly reactive fuels. Diethyl ether (DEE) is considered a promising alternative and biomass-oxygenated clean diesel substitute. Therefore, the NH3/DEE blend is also a promising carbon neutral alternative fuel. In this work, we measured the ignition delay times (IDTs) of NH3/DEE mixtures with DEE fractions (XDEE) of 0.05, 0.10, 0.30, and 1.00 at equivalence ratios of 0.5, 1.0, and 2.0, pressures of 1.75 and 10 bar, and temperature ranges from 1102 K to 1673 K in a shock tube. The DEE-NH3 model was proposed in this work, which included the DEE sub-model, NH3 sub-model, and some new cross-reactions between N-containing species and C-containing species. The DEE sub-model from Shrestha et al. (Fuel Communications, 2022) was modified in this work, NH3 sub-model was from our previous work (Reaction Chemistry & Engineering, 2023). The DEE-NH3 model was extensively validated by the IDTs, laminar flame speeds (LFSs), and species profiles (SPs) of NH3/DEE mixtures as well as pure DEE and NH3. The comparison of the prediction performance between the DEE-NH3 model and the Shrestha model was conducted for the ignition, flame propagation, and NH3 consumption. The effects of the cross-reactions on the NH3/DEE ignition and combustion were studied in detail.

Experimental and kinetic modeling study on auto-ignition of ammonia/n-heptane mixtures at intermediate temperatures

Ignition delay times (IDTs) were measured in a shock tube facility for NH3/n-heptane mixtures with NH3 concentrations in the blending fuel ranging from 0.3 to 0.95 by molar fraction. The measurements were conducted under low pressure of 2 atm and intermediate temperatures of 1350–1500 K at equivalence ratios of 0.5, 1, and 2. With the increase of n-heptane content or equivalence ratio, there is a decrease in the IDTs of NH3/n-heptane mixtures at intermediate temperatures. A detailed mechanism was updated in this study based on the mechanism of Dong et al. Subsequently, the proposed mechanism was compared to existing blending mechanisms of ammonia and n-heptane in terms of laminar burning velocities (LBVs), IDTs, and species profiles reported in literature. The present model improved the predictions in reproducing the performed experimental measurements compared to previous mechanisms. Finally, rate of production (ROP), sensitivity analysis, and instantaneous and cumulative reaction path analysis were performed to interpret the experiment observations and deepen the understanding of auto-ignition kinetics of ammonia and n-heptane. The results indicate that intermediate species, such as C2H4 and C3H6, characterized by long lifespans and high concentrations during n-heptane decomposition, play a crucial role at elevated temperatures, while the significance of n-heptane dehydrogenation by NH2 diminishes with increasing temperature.

Study on laser ignition and combustion characteristics of micron-sized aluminum and Al-Mg alloys particles

In response to the problems of easy sintering and long ignition delay time of micron aluminum in the combustion of aluminum-containing propellants, choose the way to add magnesium to metal aluminum to construct an alloy system, through boiling, micro-explosions are generated during the ignition and combustion process to weaken the sintering behavior and shorten the ignition delay time of aluminum. Selecting aluminum and Al-Mg alloy powder fuel with a particle diameter of about 10 μm as the research object, a set of individual-particle fuel laser ignition and microscopic high-speed imaging experimental devices was built that can observe the whole process of ignition and combustion of micron-sized fuel. Thermal analysis was used to detect and characterize the thermal decomposition process of micron-sized aluminum and Al-Mg alloy powders; combined with the results of scanning electron microscopy, the difference in ignition performance of micron-sized individual particle aluminum and Al-Mg alloys was studied. Experiments have found that, compared with aluminum, the initial oxidation temperature of Al-Mg alloys is lower and the combustion is more complete. However, the effect of adding magnesium to aluminum is only reflected before 900 °C. The ignition and combustion images and flame propagation laws of micron-sized single-particle aluminum and Al-Mg alloys were obtained. It was found that adding magnesium shortened the ignition delay time, and the combustion produced less residual.

Revisit the benzene oxidation at elevated pressure

The benzene (A1) oxidation was examined in a jet-stirred reactor (JSR) within the temperature range of 880–1010 K at 12.0 atm under both fuel lean (Φ = 0.5) and rich (Φ = 3.0) conditions. Eighteen intermediates and products were identified and quantified by gas chromatography (GC) and gas chromatograph-mass spectrometer (GC–MS). A kinetic model comprising 280 species and 1734 reactions was developed and validated against the experimental data to investigate the benzene reactions occurring at high pressure and low temperature. According to the sensitivity analysis, A1 + OH = A1- + H2O is the most promoting reaction for fuel consumption, while A1OH + O2 = A1O + HO2 and A1OH + OH = A1O + H2O exhibited the most inhibiting effects. HO2 radicals play an important role in the initial reaction temperature of A1 high-pressure oxidation, where the reaction rate of A1OH + O2 = A1O + HO2 is particularly critical. In comparison to previous works on A1 oxidation, oxygenated polycyclic aromatic hydrocarbons (OPAHs) benzofuran (C8H6O) and dibenzofuran (C12H8O) were newly measured and analyzed in this work. As one of the most important OPAHs species, the consumption pathway of C8H6O was updated to better describe the high-pressure oxidation. The C8H6O would potentially compete with A1 for molecular oxygen via the pathway A1 → A1O → C8H6O → decomposition products, and the process of decomposition enhances the oxygen depletion. Compared with previous oxidation studies at atmospheric pressure, the A1 initial reaction temperature shifted from 1000 to 950 K, and the temperature window of fuel conversion sharply reduced from 300 K to 70 K. Additionally, the model was effectively applied to predict the oxidation of A1 in a Jet-Stirred Reactor (JSR) over a wide range of pressures, from 0.46 to 12.0 atm. Furthermore, the developed model was compared with the laminar flame velocities (LBVs, ranging from 1.0 - 10.0 atm) and the ignition delay times (IDTs, ranging from 2.4 – 9.0 atm) data in the literature, and satisfactory agreement was obtained across a broad pressure range. The newly reported data and kinetic model provide helpful in further understanding the combustion mechanisms of aromatic hydrocarbon fuels.

Exploring the combustion mechanism of single micron-sized aluminum particles with a numerical model

In this work, we explore the combustion mechanism of single micron-sized aluminum particles using a numerical model. The Burcat database and Catoire mechanism is considered as the thermodynamic data and the kinetic mechanism for our numerical model of aluminum combustion. Two independent experiments, including particle temperature profiles, ignition delay and burning time, are selected to evaluate the performance of the numerical model. The model shows great agreement for all considered properties. A parametric study is further conducted to identify the effect of involved physical parameters on the combustion process. The diffusion coefficient (D) of oxidizers and the activation energy of surface kinetics (Esurf) and evaporation coefficient (α) of aluminum impact the particle temperature the most. Burning time is most sensitive to the activation energy of surface kinetics (Esurf). The optical measurement in a solid propellant combustion indicates that the contact angle of the oxide cap on Al particle is between 10° and 20°. It is found that the selection of contact angle of the oxide cap significantly impacts the prediction of combustion time and residual of active aluminum. The current work highlights the importance of physical properties on the prediction of Al combustion, suggesting that more detailed evaluation from experiments and theory is encouraged.

An experimental and chemical kinetic modeling study of octane isomer oxidation. Part 1: 2,3,4-trimethyl pentane

2,3,4-trimethyl pentane (234-TMP) is an isomer of octane with the same number of methyl branching groups as 2,2,4-trimethyl pentane (iso-octane). However, there are very few studies of this fuel available in the literature. In this work, a detailed chemical kinetic model is developed to describe the oxidation of 234-TMP using NUIGMech1.3 as the core mechanism. The rate constants for some important reaction classes are updated following a review of literature rate constants. Additionally, the impact of each rate constant on simulated ignition delay times for 234-TMP compared to 2,2,3-trimethyl pentane and 2,2,4-trimethyl pentane (iso-octane) is discussed. The thermodynamic data of the alkanes (RH), alkyl (Ṙ), alkyl peroxy (RȮ2), hydroperoxy-alkyl Q˙OOH, and peroxy hydroperoxyalkyl (Ȯ2QOOH) radicals are newly estimated based on recently updated group values in the literature. Moreover, this study presents the first set of data available for the oxidation of 234-TMP at higher pressures (15 and 30 atm), in the temperature range 600–1600 K, and at fuel/‘air’ equivalence ratios (φ) of 0.5, 1.0 and 2.0. The chemical kinetic model shows general good agreement with the experimental measurements. In addition, flux and sensitivity analyses are conducted to identify the important pathways and reactions controlling fuel oxidation at different temperatures. Furthermore, the reactivity of 234-TMP is compared to that of iso-octane, indicating that 234-TMP is slower to react as it has more tertiary carbon sites compared to iso--octane.

Preparation and Reactivity of Core-Shell Al@CL-20 Composites Embedded with Graphene-Based Complexes as Catalysts.

Incomplete combustion of Al in solid propellants can be effectively resolved by coating of an oxidizer at the microscale. In this paper, Al@CL-20 composites with polydopamine as the interfacial layer were prepared using this strategy. The structure, heat of reaction, thermal decomposition properties, and combustion performances of these composites under the effects of graphene oxide (GO) and graphene-based carbohydrazide complexes (GO-CHZ-M, M = Co2+, Ni2+) have been comprehensively investigated. The experimental results show that the heat of reaction of Al@CL-20 is 6482 J g-1, which is 561 J g-1 higher than that of the corresponding mechanical mixture. The presence of GO-CHZ-Co can further increase the heat of reaction of Al@CL-20 to 6729 J g-1 with a decreased activation energy by about 54.8%. Under the synergistic effect of interfacial control and GO-CHZ-M, the ignition delay time of Al@CL-20-Co decreases from 5.1 to 4.2 ms. Besides, the D50 of the combustion condensed products (CCPs) decreased from 5.62 to 4.33 μm, indicating the combustion efficiency of Al is greatly improved.

Synchronized Initiation of Two Cylindrical Rotating Detonation Engines

A coupled cylindrical rotating detonation engine (RDE) with two cylindrical RDEs (both combustors had a combustor inner diameter of 23 mm and an axial length of 30 mm) placed next to each other was tested for rocket clustering application. The objective of the experiment was to achieve two-engine synchronized initiation with a single igniter. Experiments were conducted on the inner wall of the combustors with different connecting-hole diameters and wall heights to evaluate the ignition delay time, combustion mode, and propulsion performance. The propellants were gaseous ethylene and oxygen, and experiments were conducted under constant conditions of mass flow rate (40±2 g/s), equivalence ratio (1.0±0.1), and backpressure (approximately 10 kPa). When the two combustion chambers were completely separated by a wall, ignition occurred with a time delay of 260 ms in the chamber without an igniter. However, when a large hole (10-mm diameter) was placed in the wall separating the two combustion chambers, synchronous initiation was successful. Synchronous initiation was also successful when the wall height was lowered (7-mm height). Under both conditions, the same level of specific impulse was achieved as for RDEs operating at the same mass flux.

Functional energetic materials: Simple preparation of fluorinated materials to improve safety, preservation and energy release performance of energetic materials

Paraffin wax (PW) coatings are widely used in the military as the most effective way to reduce the sensitivity of energetic materials, but their inert nature is not conducive to energy release. In this work, paraffin-like fluorine-containing molecules (FPW) which are highly anticipated on a large scale were synthesized by combining crystalline units with fluorine units via a simple method. Core-shell Al@FPW was prepared for further characterization. FPW exhibits better lubrication and greater density (1.14 g/cm3 vs. 0.81 g/cm3) than PW, which can provide favorable guarantees for reduced friction sensitivity and increased energy density. The similar melting temperatures and crystallization enthalpies (168 J/g vs. 201 J/g) of FPW and PW are advantageous for mitigating the temperature sensitivity of nano-Al. Furthermore, the improved hydrophobicity of Al@FPW prevents further oxidation of the active metal, thereby enhancing the preservation of nano-Al. Moreover, the reaction process of Al@FPW was characterized by DSC-Tg. Notably, the combustion pressure, pressurization rate and calorific value of Al@FPW are significantly increased compared to Al@PW. Meanwhile, the ignition delay time is reduced by 83 % and the combustion rate is increased by 330 %, which is attributed to the action of fluorine during the reaction. The exceptional performance of FPW holds great potential for replacing PW in various applications.

Investigation of aluminum particle ignition dynamics in various propellant environments

The ignition delay of aluminum particles can be profoundly influenced by the agglomeration and combustion characteristics of solid propellants. In this experimental study, the ignition of individual aluminum particles in nitrate ester plasticized polyether (NEPE) and hydroxyl‑terminated polybutadiene (HTPB) propellant atmospheres was examined using laser ignition tests and high-speed photography. Focus was directed at the effects of the atmospheric composition, pressure, and aluminum particle size (500, 800 and 1000 µm). It was observed that the non-homogeneous reaction heat generation and convective heat exchange rates during particle ignition could be increased by increasing the CO2 content or ambient temperature, resulting in a shorter ignition delay time. This explains why aluminum particles tended to burn more efficiently in nitrate ester plasticized polyether than in hydroxyl‑terminated polybutadiene. In addition, it was found that the ignition delay time decreased with increasing pressure and was inversely proportional to the particle size squared. An ignition model for aluminum particle ignition in a multi-component atmosphere was developed and validated to describe the temperature change and energy transfer during ignition. The calculated ignition delay times were found to be within 5% of the experimental values. The model also showed that increasing the ambient temperature was more effective than increasing the CO2 content at enhancing ignition, and that CO2 was more effective than O2, which was itself more effective than H2O. Overall, this study provides useful insight into the ignition characteristics of aluminum particles in different propellant environments. The results could be used to develop more effective propellant formulations, optimize combustion processes, and improve safety in the handling and use of aluminum-based propellants.

Combustion characteristics of water-oil emulsion droplets with special additives

Relevance. Fuel oil application in power plants is characterized by increased values of underburning and anthropogenic emissions. One way to reduce anthropogenic emissions is the use of oil-water emulsions. Also, additional specialized additives are used to reduce anthropogenic emissions and improve fuel combustion characteristics. Aim. To determine the optimal fuel oil additive to reduce anthropogenic emissions and ignition delay times. Methods. The following additives: ION-M, Rosneft R503V3, Rosneft R502V1 (relative mass concentration 0.5%) were added to the water-oil fuel. The physicochemical properties of fuel oil M-100, as well as the elemental composition of CHNSO, were determined. The rheological characteristics of water-oil fuel compositions were established. Using high-speed photography, the droplet ignition delay times were determined. Using the gas analyzer, it was possible to prevent anthropogenic emissions. Results and conclusions. The results of the study showed that the additive based on a special combination of positively and negatively charged ions (ION M) reduces ignition delay times by 20–60%, when the gas temperature varies in the range from 700 to 900 °C. The addition of the additive based on fatty vegetable acids (P502B3) reduced the ignition delay times by 7–10%, when the temperature changed in the range from 700 to 900 °C relative to water-oil fuel. It was found that when using the P502B1 additive in water-oil fuel, it was possible to reduce the ignition delay times by 15–50%. It was determined that in the presence of combustion catalysts, water binds with heavy hydrocarbons and thus the release of volatile substances occurs faster, i. e. the supplied heat is not wasted on heating water into droplets, but evenly affects the entire volume of fuel. The results of the study of anthropogenic emissions showed that the use of additives when burning water-oil fuel reduces the concentrations of CO, CO2, NO, SO2 by 8, 6, 10 and 13%, respectively, compared to fuel oil.

Features of ignition and combustion of low-grade coal mixed with pyrolysis liquid

THE RELEVANCE of the study lies in the need to use pyrolysis liquid from wood processing for combustion in boilers of medium and low power as part of mixtures with coal. The unpredictability of the ignition and combustion properties of such mixtures, as well as the lack of calculation methods, predetermined a predominantly experimental approach to the study of these processes. At the same time, for the widespread implementation of such technological solutions in practice, it is necessary to have relatively simple methods for assessing the ignition and combustion characteristics of these components. THE PURPOSE. Synthesize samples of pyrolysis liquid from two different sorts of wood and perform their characterization. Develop an experimental method for studying ignition and combustion characteristics of pyrolysis liquid mixed with low-reactivity coal. Perform research on ignition delay times and the composition of released gas-phase products. Determine the main mechanisms of action of the components in the mixture of low-grade coal with pyrolysis liquid they’re during ignition and combustion. METHODS. The study was carried out using an experimental technique based on a high-temperature muffle furnace equipped with a high-speed video camera and a once-through gas analyzer. RESULTS. The article presents the dependences of the ignition delay times and the concentration curves of gas-phase products released during combustion of mixtures of low-grade coal and two types of pyrolysis liquid in the temperature range of the heating medium 600-800 °C and additive concentrations from 0 to 20 wt.%. Linear approximation dependences of ignition delay times on additive concentrations were obtained, and the mechanism of action of the additive during combustion was formulated. CONCLUSION. It was found that an increase in the concentration of the additive in the mixture leads to a stable decrease in the ignition delay times, while the amount of gas-phase products formed varied additively with respect to the composition of the mixture. The shape of the concentration curves for the release of CO and NOx indicates the independent action of the components of the mixture. The mechanism of action of additives was proposed. It was based on significant contribution of their evaporation process followed by combustion in the gas phase, which, in turn, initiats the ignition of coal.

Autoignition enhancement of methane by admixture of low fraction of acetaldehyde: Simulations and RCM experiments in stoichiometric and rich mixtures

AbstractThe effect of small fractions of acetaldehyde (CH3CHO) on the ignition delay time of methane (CH4) was examined at high pressure. Measurements are reported for the ignition delay time obtained in a rapid compression machine (RCM) at a compression pressure (Pc) of ∼60 bar and temperatures after compression (Tc) in the range 750–900 K for fuel‐air equivalence ratios ϕ in the range 1–4. The results show that mixtures of 2%–5% CH3CHO in CH4 ignite under conditions at which pure methane does not ignite experimentally. The efficiency of acetaldehyde as a promoter seems to be comparable to that of other oxygenated fuels like alcohols and ethers. For comparison with the experimental results, ignition delay times are computed using an updated reaction mechanism and two mechanisms from the literature for CH3CHO oxidation. For most conditions, the simulations using the current mechanism agree with the measurements to within a factor of two. The ignition profile shows a pre‐ignition temperature rise and two‐stage ignition similar to that previously observed in low fractions of dimethyl ether in ammonia; both phenomena are captured by the simulations. Analysis of simulations at constant volume indicates that CH3CHO is oxidized much more rapidly than CH4, producing reactive species that initiate the oxidation of CH4 and generates heat that accelerates oxidation toward ignition. The low‐temperature chain‐branching reactions of CH3CHO are important in the early oxidation of the fuel mixture. Additional simulations were performed for equivalence ratios of ϕ = 1 and 4, at a compression pressure (Pc) of 100 bar and Tc = 750–1000 K. The simulations indicate that CH3CHO has a strong ignition‐enhancing effect on CH4, with small fractions reducing the ignition delay time by up to a factor of 100, depending on the temperature, as compared to pure CH4.

Evaluation of the use of ammonia/hydrogen blends in turbocharged gas engines

The potential for ammonia/hydrogen (NH3/H2) blends as fuel in modern, turbocharged, gas engines is evaluated by comparing the combustion properties of these blends with those of methane. To ensure proper combustion phasing in existing spark-ignited (SI) engines, the laminar burning velocity (LBV) is used, while the ignition delay times (IDT) of the mixtures are compared to assess the risk of engine knock. The chemical mechanisms used for the computation of IDT and/or LBV of NH3/H2 mixtures are selected from 8 chemical mechanisms based on their ability to predict experimental data. The application of a turbocharger is shown to “boost” the temperature in the cylinder after compression to values that admit the use of NH3/H2 mixtures in natural-gas SI engines without increasing the compression ratio (CR). The analysis also identifies regions of temperature and H2 fraction that increase the risk of knock. Using the conditions in a practical turbocharged SI engine as an example, 40–50% H2 in NH3 yields combustion phasing equivalent to that obtained with methane, while avoiding the risk of knock. Analysis of the IDT for the conditions in a high-pressure direct-injection natural-gas engine also shows that the use of a turbocharger in compression-ignition (diesel-type) engines strongly reduces the demands on CR for achieving the conditions necessary for reliable ignition of NH3/H2 mixtures. Increasing the temperature by only a few tens of degrees above the conditions studied will yield an IDT for ∼20% H2 in NH3 that satisfies the ignitibility requirements for use in a turbocharged diesel engine.

Ignition and combustion of Al–Mg–Li alloy particles at elevated pressures

Al–Mg–Li ternary alloy particles can be a promising metal additive to replace aluminum in solid propellants to improve combustion efficiency by reducing agglomeration during combustion. In this paper, Al–Mg–Li ternary alloy was prepared and its basic physical and chemical characterization parameters were obtained by SEM-EDS, ICP-AES, and XRD analysis. The ignition and combustion characteristics of single Al–Mg–Li particles under different pressures were investigated by using a self-developed experimental setup. The ignition process and combustion flame structure of Al–Mg–Li particles were significantly affected by the increasing pressure, and the ignition delay and combustion time decreased. The ignition mode was clearly identified: surface ignition (0.1–0.2 MPa) and gas phase ignition (0.4–1.2 MPa). Al–Mg–Li particles showed white-pink flame during combustion, and the characteristic peaks of AlO, MgO, and Li were identified, confirming that the particles performed a gas-phase combustion at pressures above 0.4 MPa. The combustion temperature of Al–Mg–Li particles could exceed 3000 °C when the pressure surpassed 0.6 MPa. The composition of different regions in the condensed combustion products were analyzed. Reaction mechanism was proposed to reveal the addition of elemental Mg and Li could improve the ignition and combustion characteristics of Al, especially at higher ambient pressures.