Machining thin-walled structures with a high aspect ratio using Wire EDM can lead to geometrical errors, primarily of two types; overcut error due to kerf formation and thermal deformation of the entire wall section. To understand the driving mechanisms behind these errors three distinct numerical models were developed. Initially, a model based on a moving heat source was created, employing the apparent heat capacity approach to predict kerf width and the associated overcut error. These insights were then utilized to formulate a transient temperature distribution model with a redesigned geometry, considering time-dependent evolution of the kerf and corresponding changes in the material properties of the sub-domains. Finally, a thermo-mechanical coupled model was developed to predict geometrical errors caused by the deflection of the wall, considering the varying stiffness of the part. A series of experiments were conducted to gain insight into the effect of the designed wall thickness on wall deflection. For the selected design profile and machine parameters, the model predicts a 62.4% reduction in thickness and a corresponding over-cut error of 188μm. Similarly, the model predicts wall deformation in the range of 6μm to 312μm for various wall thickness levels and these findings were validated with experimental observations.